• Title/Summary/Keyword: chloride permeability

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Fundamental Study of Alkali-Activated Concrete Properties based on Modified Slag (개질 슬래그 기반 알칼리 활성 콘크리트의 기본 물성 연구)

  • An, Ji-Hwan;Jeon, Sung-Il;Kwon, Soo-Ahn
    • International Journal of Highway Engineering
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    • v.17 no.2
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    • pp.1-11
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    • 2015
  • PURPOSES : This study set out to investigate the fundamental properties of alkali-activated concrete (AAC) using modified slag as the pavement maintenance material. METHODS: The material properties of modified slag based alkali-activated concrete (MSAAC) were analyzed and evaluated against those of alkali-activated slag concrete (AASC). Several mix formulations were considered, including one MSACC and four AASCs. The main variables considered in the study were slump, air content, compressive strength, rapid chloride permeability test, scaling resistance, freeze-thaw test, XRD, SEM, and EDS. RESULTS: MSAAC exhibits a compressive strength in excess of 21 MPa six hours after curing. Also, the charge passed of the MSACC was found to be less than 2000 coulombs after seven days and about 1000 coulombs after 28 days. The weight loss determined from a scaling test did not exceed $1kg/cm^2$ in the case of the MSACC, but that of the AASCs had already exceeded $1kg/cm^2$ at the 10th cycle. Based on the results of the freeze-thaw test, the relative dynamic modulus of every mix was found to be in excess of 90%. An energy dispersive spectroscopy(EDS) analysis found that the weight rate percentage of the calcium and aluminum in the MSAAC mix is twice that of the AASC mixes. CONCLUSIONS : It was found that the MSAAC mix exhibits significantly better performance than AASC mixes, based on various fundamental properties.

Durability Assessment for Crushed Sand Wet-mix Shotcrete Mixed with Mineral Admixtures (부순모래를 사용한 습식 숏크리트의 광물성 혼화재료 혼입에 따른 내구성 평가)

  • Lee, Kyeo-Re;Han, Seung-Yeon;Nam Gung, Kyeong;Yun, Kyong-Ku
    • Journal of the Korea Concrete Institute
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    • v.26 no.5
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    • pp.607-614
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    • 2014
  • The purpose of this dissertation was to investigate the effect of mineral admixtures, such as fly ash, blast furnace slag powder, meta kaolin and silica fume, on the basic properties and durability of crushed sand shotcrete, selecting a series of shotcrete mixtures with a variable admixture. Compressive strength increased as the content of mineral admixtures increased, specially it was the most effective when using meta kaolin both at sample specimen and core after shotcreting. Rapid chloride ion permeability test and sulfuric acid resistance test showed that both durability increased as the substitute rate of mineral admixture increased. In air void analysis with image analysis, the targeted the spacing factor and specific surface were not satisfied because air-entrained agent was not used.

The Effects of Sopungsan and Gamisopungsan on Immune Response and the Anti-Allergic Reaction to Rats and Mice (消風散과 加味消風散이 免疫反應 및 抗 알레르기에 미치는 影響)

  • Kim, Jung-Ho;Chae, Byeong-Yun
    • The Journal of Korean Medicine Ophthalmology and Otolaryngology and Dermatology
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    • v.4 no.1
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    • pp.1-22
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    • 1991
  • The object of this research is to find out the clinical effects of Sopungsan and Gamisopungsan on Immune response and the An1i-allergic reaction to rats and mice. The results obtained are as follows: 1. Both sopungsan and Gamisopungsan have a tendency to decrease on the delayed type hypersensitivity response in methotrexate treated mice, but are not recognized as having significance. 2. Both Sopungsan and Gamisopungsan reveal the increasing effects with significance on the hemagglution titer in mice. 3. Gamisopungsan reveals the increasing effect with significance on the hemolysin titer in mice. 4. Both Sopungsan and Gamisopungsan have a tendency to increase on the appearance of Rosette forming cells in mice, but are not recognized as having significance. 5. Both Sopungsan and Gamisopungsan reveal the increasing effects with significance on phagocytic index K and a in mice 6. Sopungsan reveals the decreasing effect, on the homologous passive cutaneous anaphylaxis in rats provoked by the IgE-like antibody aganist egg white albumin. 7. Gamisopungsan reveals the decreasing effect with significance on vascular permeabi1ity response to intradermal histamin in rats. 8. Sopungsan reveals the decreasing effect with significance, on vascular permeability response to intradermal serotonin in rats. 9. Both Sopungsan and Gamisopungsan reveal the decreasing effects with significance on the delayed type hypersensitivity response to picryl chloride in mice. 10. Both Sopungsan and Gamisopungsan reveal the decreasing effects with significance on the delayed type hypersensitivity response to sheep red blood cell in mice. According to the above results, Sopungsan and Gamisopungsan are concluded to have the increasing effect of immunity and anti-allergic reaction.

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An Experimental Studies on the Anti-allergic Reaction, the Antipyretic Action, the Anti-inflammatory and the Analgesic Action of Yenhwagamchotang and Gamiyenhwagamchotang (銀花甘草湯과 加味方이 抗 알레르기, 解熱, 消炎, 鎭痛效果에 미치는 影響)

  • Choe, Gyu-Dong;Kim, Jung-Ho;Chae, Byeong-Yun
    • The Journal of Korean Medicine Ophthalmology and Otolaryngology and Dermatology
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    • v.6 no.1
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    • pp.15-29
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    • 1993
  • Yenhwagamchotang has been widely used in treatment of inflammatory disease which is based on Oriental Medical literatures. These studies were attempted experimental effects of Yenhwagamchotang(sample A), Yenhwagamchotang plus Forsythia koreana NAKAI.(sample B), and Yenhwa-gamchotang plus Taraxacum mongolicum HAND- MAZZ(sample C),on the Anti-allergic reaction, the antipyretic action,the anti-inflammatory and the analgesic action,in rats. THe results of the studies were as follow: 1. Vascular permeability responses to intradermal serotonin in rats were showed significant effect at all sample groups. 2. The homologous passive cutaneous anaphylaxis in rats provoked by the IgE-like antibody aganist egg white albumin showed the decreasing effect. 3. The delayed type hypersensitivity responses to picryl chloride in mice were showed significant effect at all sample groups. 4. The delayed type hypersensitivity response to sheep red blood cell in mice were showed significant effect at all sample groups. 5. In anti-pyretic effect by yeast method were showed significant effect at all sample groups. 6. The anti-inflammatory effect by carrageenin method were showed significant effect at all sample groups. 7. The analgesic action by acetic acid method in mice were showed significant effect at all sample groups. According to the above result, Yenhwagamchotang(sample A), Yenhwagamchotang plus Forsythia koreana NAKAI(sample B), AND yenhwagamchotang plus Taraxacum mongolicum HNAN- MAZZ.(sample C ) were concluded to have the anti-allergic reaction, the antipyretic action, the anti-inflammatory, the analgesic action.

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Adsorptive removal of Ni(II) ions from aqueous solution by PVDF/Gemini-ATP hybrid membrane

  • Zhang, Guifang;Qin, Yingxi;Lv, Chao;Liu, Xingtian;Zhao, Yiping;Chen, Li
    • Membrane and Water Treatment
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    • v.7 no.3
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    • pp.209-221
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    • 2016
  • As a highly hydrophilic fibrillar mineral in nature, attapulgite (ATP) is a promising new additive for preparation of ultrafiltration (UF) hybrid membrane. In this work, ATP particles, which were grafted with a new Gemini surfactant of Ethyl Stearate-di(octadecyl dimethyl ammonium chloride) to detach the crystal bundles to single crystal and enhance the uniform dispersion in an organic polymer matrix, were incorporated into poly(vinylidene fluoride) (PVDF) matrix, and PVDF/Gemini-ATP hybrid membranes for adsorptive removal of Ni(II) ions from aqueous solution were prepared via a phase inversion method. Chemical composition, crystalization and morphology of the modified ATP were characterized by Fourier transform infrared spectroscopy (FTIR), Transmission electron microscope (TEM) and X-ray diffraction (XRD), respectively. The morphology of the hybrid membrane was characterized by Scanning electron microscopy (SEM), the performance of permeability, hydrophilicity and adsorption of Ni(II) ions were studied, and the adsorption kinetics of the PVDF/ATP hybrid membranes were particular concerned. The results showed that the hybrid membrane displayed a good thermal stability and hydrophilicity. Comparing with PVDF membrane, the hybrid membrane possessed good adsorption capacity for Ni(II) ions, and the adsorption kinetics fit well with Lagergren second-order equation.

Strength and durability of concrete in hot spring environments

  • Chen, How-Ji;Yang, Tsung-Yueh;Tang, Chao-Wei
    • Computers and Concrete
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    • v.6 no.4
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    • pp.269-280
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    • 2009
  • In this paper an experimental study of the influence of hot springs curing upon concrete properties was carried out. The primary variables of the investigation include water-to-binder ratio (W/B), pozzolanic material content and curing condition. Three types of hot springs, in the range $40-90^{\circ}C$, derived from different regions in Taiwan were adopted for laboratory testing of concrete curing. In addition, to compare with the laboratory results, compressive strength and durability of practical concrete were conducted in a tunnel construction site. The experimental results indicate that when concrete comprising pozzolanic materials was cured by a hot spring with high temperature, its compressive strength increased rapidly in the early ages due to high temperature and chloride ions. In the later ages, the trend of strength development decreased obviously and the strength was even lower than that of the standard cured one. The results of durability test show that concrete containing 30-40% Portland cement replacement by pozzolanic materials and with W/B lower than 0.5 was cured in a hot spring environment, then it had sufficient durability to prevent steel corrosion. Similar to the laboratory results, the cast-inplace concrete in a hot spring had a compressive strength growing rapidly at the earlier age and slowly at the later age. The results of electric resistance and permeability tests also show that concrete in a hot spring had higher durability than those cured in air. In addition, there was no neutralization reaction being observed after the 360-day neutralization test. This study demonstrates that the concrete with enough compressive strength and durability is suitable for the cast-in-place structure being used in hot spring areas.

AN EXPERIMENTAL INVESTIGATION ON MINIMUM COMPRESSIVE STRENGTH OF EARLY AGE CONCRETE TO PREVENT FROST DAMAGE FOR NUCLEAR POWER PLANT STRUCTURES IN COLD CLIMATES

  • Koh, Kyung-Taek;Park, Chun-Jin;Ryu, Gum-Sung;Park, Jung-Jun;Kim, Do-Gyeum;Lee, Jang-Hwa
    • Nuclear Engineering and Technology
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    • v.45 no.3
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    • pp.393-400
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    • 2013
  • Concrete undergoing early frost damage in cold weather will experience significant loss of not only strength, but also of permeability and durability. Accordingly, concrete codes like ACI-306R prescribe a minimum compressive strength and duration of curing to prevent frost damage at an early age and secure the quality of concrete. Such minimum compressive strength and duration of curing are mostly defined based on the strength development of concrete. However, concrete subjected to frost damage at early age may not show a consistent relationship between its strength and durability. Especially, since durability of concrete is of utmost importance in nuclear power plant structures, this relationship should be imperatively clarified. Therefore, this study verifies the feasibility of the minimum compressive strength specified in the codes like ACI-306R by evaluating the strength development and the durability preventing the frost damage of early age concrete for nuclear power plant. The results indicate that the value of 5 MPa specified by the concrete standards like ACI-306R as the minimum compressive strength to prevent the early frost damage is reasonable in terms of the strength development, but seems to be inappropriate in the viewpoint of the resistance to chloride ion penetration and freeze-thaw. Consequently, it is recommended to propose a minimum compressive strength preventing early frost damage in terms of not only the strength development, but also in terms of the durability to secure the quality of concrete for nuclear power plants in cold climates.

Regression and ANN models for durability and mechanical characteristics of waste ceramic powder high performance sustainable concrete

  • Behforouz, Babak;Memarzadeh, Parham;Eftekhar, Mohammadreza;Fathi, Farshid
    • Computers and Concrete
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    • v.25 no.2
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    • pp.119-132
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    • 2020
  • There is a growing interest in the use of by-product materials such as ceramics as alternative materials in construction. The aim of this study is to investigate the mechanical properties and durability of sustainable concrete containing waste ceramic powder (WCP), and to predict the results using artificial neural network (ANN). In this order, different water to binder (W/B) ratios of 0.3, 0.4, and 0.5 were considered, and in each W/B ratio, a percentage of cement (between 5-50%) was replaced with WCP. Compressive and tensile strengths, water absorption, electrical resistivity and rapid chloride permeability (RCP) of the concrete specimens having WCP were evaluated by related experimental tests. The results showed that by replacing 20% of the cement by WCP, the concrete achieves compressive and tensile strengths, more than 95% of those of the control concrete, in the long term. This percentage increases with decreasing W/B ratio. In general, by increasing the percentage of WCP replacement, all durability parameters are significantly improved. In order to validate and suggest a suitable tool for predicting the characteristics of the concrete, ANN model along with various multivariate regression methods were applied. The comparison of the proposed ANN with the regression methods indicates good accuracy of the developed ANN in predicting the mechanical properties and durability of this type of concrete. According to the results, the accuracy of ANN model for estimating the durability parameters did not significantly follow the number of hidden nodes.

Effects of bis(2-ethylhexyl) phthalate(DEHP) on plant soil-borne pathogenic bacterium Pectobacterium carotovorum in vitro (Bis(2-ethylhexyl) phthalate가 in vitro에서 식물 토양병원성 세균 Pectobacterium carotovorum에 미치는 영향)

  • Yu-Ri Kim;Sang Tae Kim;Mee Kyung Sang
    • Korean Journal of Environmental Biology
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    • v.40 no.4
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    • pp.398-404
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    • 2022
  • Bis(2-ethylhexyl) phthalate (DEHP) is one of the plasticizers used in the polyvinyl chloride(PVC) industry. It is known to be easily released into the environment. In this study, we investigated effects of DEHP on growth, metabolic pathway, and virulence gene expression in soil-borne bacterial plant pathogen, Pectobacterium carotovorum SCC1 using in vitro assays. As a result, DEHP at 20 ㎍ mL-1 did not affect the growth, cell membrane permeability, or ATPase activity of P. carotovorum SCC1. However, it decreased succinyl-CoA synthase (SCS) activity in the tricarboxylic acid (TCA) cycle. Relative expression levels of virulence genes encoding pectate lyase and pectin were differentially influenced by DEHP treatment. These results suggest that biological characteristics of P. carotovorum might be influenced by DEHP in soil.

Application Research on Mechanical Strength and Durability of Porous Basalt Concrete

  • Zhu, Yuelei;Li, Jingchun;Zhu, He;Jin, Long;Ren, Qifang;Ding, Yi;Li, Jinpeng;Sun, Qiqi;Wu, Zilong;Ma, Rui;Oh, Won-Chun
    • Korean Journal of Materials Research
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    • v.32 no.3
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    • pp.115-124
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    • 2022
  • Porous basalt aggregate is commonly used in roadbed engineering, but its application in concrete has rarely been studied. This paper studies the application of porous basalt in concrete. Porous basalt aggregate is assessed for its effects on mechanical strength and durability of prepared C50 concrete; because it has a hole structure, porous basalt aggregate is known for its porosity, and porous basalt aggregates can be made full of water through changing the content of saturated basalt; after full-water condition is achieved in porous basalt aggregate mixture of C50 concrete, we discuss its mechanical properties and durability. The effects of C50 concrete prepared with basalt aggregate on the compressive strength, water absorption, and electric flux of concrete specimens of different ages were studied through experiments, and the effects of different replacement rates of saturated porous basalt aggregate on the properties of concrete were also studied. The results show that porous basalt aggregate can be prepared as C50 concrete. For early saturated porous basalt aggregate concrete, its compressive strength decreases with the increase of the replacement rate of saturated aggregate; this occurs up to concrete curing at 28 d, when the replacement rate of saturated basalt aggregate is greater than or equal to 40 %. The compressive strength of concrete increases with the increase of the replacement rate of saturated aggregate. The 28 d electric flux decreases with the increase of the replacement rate of saturated aggregate, indicating that saturated porous basalt aggregate can improve the chloride ion permeability resistance of concrete in later stages.