• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2004년도 추계 학술발표회 제16권2호
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• pp.325-328
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• 2004

According to demand the increase of the rate of strength development for rapid constructions and repairs, many efforts have progressed to improve on performance of concrete. The use of regulated set cement helps make it possible to increase the rate of strength development. However it has some problems as like increasing its permeability and accelerate its long-term deterioration caused by internal and external factors. The purpose of this study is to improve the performance of regulated set cement, which mixed with the mineral admixtures. In this paper, setting time, compressive/flexural strength and chloride permeability of mortar according to the substitute ratio of SF, FA and BS in the range of $5\~20\%$ were conducted. Based on the test results, 5% substitute of silica fume for binder was showed good performance.

• 한국막학회:학술대회논문집
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• 한국막학회 2004년도 Proceedings of the second conference of aseanian membrane society
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• pp.207-210
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• 2004

The pore-filled anion-exchange membranes were prepared in this study with an asymmetric poly(vinylidene fluoride)(PVDF) membrane as a nascent membrane and poly(vinylbenzyl chloride)(PVBCl) as a polyelectrolyte. The solution of PVBCI having the chloromethylate aryl ring of 80 percents and 1,4-diaminobicyclo [2,2,2]octane(DABCO) was made with the solvent of tetrahydrofuran(THF) and N,N-Dimethylformamide(DMF), which is in the rotio of 8:2. A new preparation method in this study, i.e. in-situ crosslinking, enabled us to produce the pore-filled membranes without change of size, and to control the properties of final membrane with various degree of cross-linking. From the result of surface morphologies of SEM and AFM the polyelectrolyte exists in the pores of nascent membrane as a certain configuration. From the investigation of the solvent affecting much to the permeability and rejection, it was found. that the membranes using DMF and THF showed better performances than the membranes produced by THF only. The water permeability of the final membrane at low pressure(100㎪) showed a typical ultrafiltation membrane's permeability (8-10kg/㎡hr) and good values of rejection(55∼60 percent).

• 한국지반환경공학회 논문집
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• 제2권1호
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• pp.81-89
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• 2001

본 연구에서는 차수벽 재료로 자주 사용되는 흙-벤토나이트 혼합물의 투수계수가 해수로 인하여 어떻게 영향을 받는지 고찰하였으며 혼합물로 축조된 가상의 제방에 해수가 침입할 때 어떻게 영향을 받는지를 고찰하였다. 유한요소법을 이용한 RFP 방법을 사용하였으며 투수계수변화를 이 해석에 도입하였다. 해석을 위하여 정상흐름상태와 비정상 흐름 상태에서 경계면을 구한 결과 투수계수변화를 고려하지 않았던 과거의 방법과 비교할 때 해수쪽으로는 낮게 담수영역에서는 경계면이 높게 나타났다.

• 한국건설순환자원학회논문집
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• 제8권1호
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• pp.134-142
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• 2020

본 연구에서는 시멘트 복합체의 자기치유 성능평가를 위해 정수위투수시험, 염소이온 확산시험, 반복휨시험을 활용한 시험방법 및 분석방법을 제시하였고, 균열 유발방법과 균열폭 제어방법을 제안하였다. 정수위 투수시험은 시험체의 균열부를 통과하는 단위유출수량의 감소율을 이용하여 치유성능을 평가하는 시험방법으로 등가 균열폭을 활용하여 치유재령에 따른 치유효과를 직관적으로 규명할 수 있다. 염소이온 확산계수시험은 ASTM C 1202의 시험장치를 활용하여 구한 염소이온 확산계수의 감소율로 치유율을 평가하는 방법이다. 또한, 반복 휨 시험을 통하여 얻은 하중과 CMOD의 관계 그래프로부터 강도회복지수(ISR)과 손상복구지수(IDR)을 산정하여 역학적 치유성능을 평가할 수 있다. 마지막으로, 자기치유 소재의 혼입 유무에 따른 균열 시험체의 실험을 통해 본 연구에서 제시한 자기치유 평가방법의 적용성을 검토하였다.

• 대한토목학회논문집
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• 제29권2A호
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• pp.171-179
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• 2009

콘크리트의 공극률은 유해인자의 주된 이동통로가 될 뿐 아니라, 수분을 보유할 수 있는 역할을 하게 되므로, 열화물질 이동 저항성을 평가할 수 있는 주된 지표가 되고 있다. 내구성에 대한 연구가 중요해짐에 따라, 공극구조를 기본으로 하는 열화모델이 최근 들어 개발되고 있으며, 공극구조와 내구특성간의 관계는 매우 중요하게 평가되고 있다. 본 연구는 5가지의 다른 물-시멘트비(40%, 45%, 50%, 55%, 60%)를 가진 시멘트 모르타르를 제조하여, 공극률을 포함한 다양한 내구성 실험을 수행하였다. 내구특성 실험은 기본적인 압축강도 실험을 포함하여, 투기성 실험, 염화물 확산계수 실험, 흡수율 및 수분 확산계수 실험 등이 수행되었다. 평가된 내구성 실험결과는 물-시멘트비와 공극률에 따라 분석되었다. 공극률이 1.45 배 높아질수록, 강도는 0.6배 수준으로 감소하였으며, 투기성, 염화물 확산계수, 흡수율, 수분확산계수는 각각 2.3배, 2.1배, 5.5배, 그리고 3.7배 수준으로 증가하였다. 이러한 내구특성 변화율은 높은 상관성을 보이며, 공극률에 따라 선형적으로 변화함을 알 수 있었다. 한편, 실험결과와 문헌분석을 통하여, 목표내구성능을 설정하였으며, 이에 따라서 고내구성 콘크리트를 위한 공극를을 제안하였다.

• International Journal of Concrete Structures and Materials
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• 제6권2호
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• pp.87-100
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• 2012

The process of selecting a repair material is a typical one of multi-criteria decision-making (MCDM) problems. In this study Analytical Hierarch Process was applied to solve this MCDM problem. Many factors affecting a process to select an optimal repair material can be classified into quantitative and qualitative requirements and this study handled only quantitative items. Quantitative requirements in the optimal selection model for repair material were divided into two parts, namely, the required chemical performance and the required physical performance. The former is composed of alkali-resistance, chloride permeability and electrical resistivity. The latter is composed of compressive strength, tensile strength, adhesive strength, drying shrinkage, elasticity and thermal expansion. The result of the study shows that this method is the useful and rational engineering approach in the problem concerning the selection of one out of many candidate repair materials even if this study was limited to repair material only for chloride-deteriorated concrete.

• Korean Journal of Mathematics
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• 제7권1호
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• pp.27-35
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• 1999

As seen from the ammonium chloride experiment (Chen & Chen [1], Roberts & Loper [11], the interface near chimneys has an up-rising shape and we observe thickening of mush next to chimney. We analyze the thermal boundary layer around chimney that forms as the mush is cooled locally by the fluid rising through the chimney. We obtain solutions of the temperature, the solid fraction, and the pressure in the chimney wall. Also, our expression of the pressure shows that the fluid flow can require a huge pressure in order to pass through the chimney wall if its permeability is very small. We present a simple analytic description of the up-rising shape near the exit of the chimney, due to the fact that the comparatively solute (i.e. $NH_4Cl$ in the case of the ammonium chloride experiment)-rich fluid near the chimney tends to crystallize as it is chilled by the rising jet of cold fluid in the chimney.

• Bulletin of the Korean Chemical Society
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• 제20권6호
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• pp.672-676
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• 1999

Gas-Permeable polymeric membranes containing carboxyl groups which are suitable for enzyme immobilization were investigated in order to use them as gas electrode membranes in biosensors. Carboxylated polyurethane (CPU) was synthesized via a reaciton between 2,2-bis(hydroxymethyl)propionic acid as a chain extender and prepolymers prepared from polycarprolactone(Mn=2,000) and 4,4'-diphenylmethane diisocynate. It was difficult to prepared membranes from the pure CPU because of its high elasticity and cohesion. However, transparent free-standing membranes were easily prepared from the blend solution of CPU and carboxylated poly(vinyl chloride)(CPVC) in tetrahydrofuran. Both elasticity and cohesion of the CPU/CPVC membranes were decreased with increasing the content of CPVC. DSC experiment suggests that CPU and CPVC may be well mixed. Permeability coefficients for O₂and CO₂(Po₂and Pco₂)in the membranes increased as the proportion of CPU increased. The addition of dioxtyl phthalate(DOP), a plasticizer, significantly enhanced the Po₂and Pco₂which were 4,4 and 30 barrer, respectively, in the CPU/CPVC(80/20 wt/wt) membranes containing 20% of DOP at 25℃ and 100psi. Thus this type of membranes may have a potential for the use as gas electrode membranes in biosensors.

• International Journal of Concrete Structures and Materials
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• 제8권2호
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• pp.157-164
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• 2014

Ground granulated blast-furnace slag (GGBS) is a green construction material used to produce durable concrete. The secondary pozzolanic reactions can result in reduced pore connectivity; therefore, replacing partial amount of Portland cement (PC) with GGBS can significantly reduce the risk of sulfate attack, alkali-silica reactions and chloride penetration. However, it may also reduce the concrete resistance against carbonation. Due to the time consuming process of concrete carbonation, many researchers have used accelerated carbonation test to shorten the experimental time. However, there are always some uncertainties in the accelerated carbonation test results. Most importantly, the moisture content and moisture profile of the concrete before the carbonation test can significantly affect the test results. In this work, more than 200 samples with various water-cementitious material ratios and various replacement percentages of GGBS were cast. The compressive strength, electrical resistivity, chloride permeability and carbonation tests were conducted. The moisture loss and microstructure of concrete were studied. The partial replacement of PC with GGBS produced considerable improvement on various properties of concrete.

• 한국건축시공학회지
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• 제5권2호
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• pp.89-95
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• 2005

Various tests are performed with the recycled concrete including compressive strength, flexural strength, splitting tensile strength, bonding strength and chloride ion penetration test. The basic data obtained from the presented test could be accumulated for the purpose of utilization in concrete structure. Most of the strength tests show that strength decrease a little extent with increasing substitution ratio of recycled coarse aggregate except splitting tensile test for the concrete with $100\%$ recycled fine aggregate. But in case of the $50\%$ substitution of recycled coarse aggregate, compressive strength, flexural strength and bonding strength are almost equal to the normal concrete. Chloride ion penetration test shows that the penetration amounts of chloride ion becomes more in proportion to the substitution ratio of recycled aggregate. But most of the results show that the permeability of recycled concrete is proper to use. The results of present study nay imply that the use of recycled aggregate for steam curing concrete is possible but the substitution ratio of recycled aggregate should be determined through further studies.