• Journal of Applied Reliability
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• v.17 no.2
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• pp.122-128
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• 2017

Purpose: To investigate the corrosion inhibition effect of the natural spearmint oil extracted from Mentha Spicata plants on 304 stainless steel in different concentrations of hydrochloric acid. Method: The anti-corrosive effect has been investigated in 0.5m, 1m and 2m HCl using weight loss test and electrochemical polarization method as a function of inhibitor concentration and immersion time in strong chloride environment. The surface morphology was analysed by scanning electron microscopy (SEM). Results: The corrosion rate of steel decreased and inhibition efficiency increased with the increase in inhibitor concentration. Microscopic evaluation revealed significant corrosion in the specimens immersed in uninhibited conditions. Potentiodynamic polarization test results showed an increase in corrosion potential (Ecorr) and decrease in corrosion current (icorr) value with increasing concentration of inhibitor. Conclusions: Immersion of steel in higher concentration of inhibitor resulted in greater surface coverage value and hence lesser number of surface corrosion sites/pores were formed; thus lowering the corrosion rate.

• Computers and Concrete
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• v.6 no.4
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• pp.281-303
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• 2009

The lack of safety of bridge deck structures causes frequent repair and strengthening of such structures. The repair induces great loss of economy, not only due to direct cost by repair, but also due to stopping the public use of such structures during repair. The major reason for this frequent repair is mainly due to the lack of realistic and accurate assessment system for the bridge decks. The purpose of the present research was to develop a realistic expert system, called Bridge Slab-Expert which can evaluate reasonably the condition as well as the service life of concrete bridge decks, based on the deterioration models that are derived from both the structural and environmental effects. The diagnosis assessment of deck slabs due to structural and environmental effects are developed based on the cracking in concrete, surface distress and structural distress. Fuzzy logic is utilized to handle uncertainties and imprecision involved. Finally, Bridge Slab-Expert is developed for prediction of safety and remaining service life based on the chloride ions penetration and fick's second law. Proposed expert system is based on user-friendly GUI environment. The developed expert system will allow the correct diagnosis of concrete decks, realistic prediction of service life, the determination of confidence level, the description of condition and the proposed action for repair.

• Korean Journal of Materials Research
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• v.16 no.11
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• pp.663-667
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• 2006

CTAB(cetyltrimethylammonium bromide)-capped CdSe nanoparticles were prepared by using a 4 : 1(v/v) distilled water-isopropyl alcohol mixture. The cadmium chloride and sodium selenosulfate were used as the cadmium and selenium source. By the analysis of XRD and XPS, the resultant particle was confirmed to be cubic CdSe phase. TEM image showed CdSe nanoparticles with empty core. The CTAB-capped sample showed an maximum absorption at 418nm, blue-shifting compared with bulk CdSe, which indicated stronger quantum confinement effect compared with uncapped sample. From FT-IR analysis, it was found that the presence of the new peaks in the $850{\sim}1250cm^{-1}$ range indicated the existence of chemical bonding between CTAB and surface of CdSe nanoparticles. Also TG analysis indicated that there were two weight-loss steps for the CTAB-capped CdSe nanoparticles. It was suggested that CTAB played a significant role in protecting CdSe nanoparticles.

• Journal of the Korean institute of surface engineering
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• v.49 no.4
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• pp.344-348
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• 2016

Stainless steel is widely applied in many industrial fields due to its excellent anti-corrosion and durability characteristics. However, stainless steel is very vulnerable to cavitation attack caused by high speed flow of fluid in the chloride environments such as marine environment. These conditions promote intergranular corrosion and cavitation-erosion, leading to degradation of the structural integrity and service life. In order to prevent these problems, the stabilized stainless steel is applied to the offshore and shipbuilding industries. In this study, Ti was added to 19%Cr-9%Ni as the stabilizer element with different concentrations (0.26%, 0.71%), and their durabilities were evaluated with cavitation-erosion experiment by a modified ASTM G32 method. The microstructural change was observed with the stabilizer element contents. The result of the observation indicated that the amount of carbide precipitation was decreased and its size became finer with increasing Ti content. In the cavitation-erosion experiment, both weight loss and surface damage depth represented an inverse proportional relationship with the amount of Ti element. Consequently, the stainless steel containing 0.71% of Ti had excellent durability characteristics.

• Corrosion Science and Technology
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• v.20 no.5
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• pp.281-288
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• 2021

Due to advancement of the industry, operation of a device in a harsh environment is increasing. Especially, the marine environment contains Cl^- ions which causes localized corrosion such as pitting and crevice corrosion of stainless steel and various metals. In this study, electrochemical corrosion behaviors of austenitic stainless steel (STS 316L) and nickel alloy (Inconel 600) with different seawater concentrations (fresh water, seawater, mixed water) were investigated. The STS 316L and Inconel 600 were etched in 10% oxalic acid and composed of an austenitic phase. Results of Tafel analysis in seawater showed that STS 316L and Inconel 600 presented the highest corrosion current densities of 7.75 × 10^-4 mA/cm² and 1.11 × 10^-4 mA/cm² and the most negative pitting potentials of 0.94 V and 1.06 V, respectively. The maximum damage depths and surface damage ratio by pitting corrosion increased with chloride concentration. The STS 316L had higher PREN than Inconel 600. However, the surface damage and weight loss of Inconel 600 were superior to STS 316L. It was difficult to compare the pitting resistance of STS 316L based on Fe and Inconel 600 based on Ni with PREN simply.

• Corrosion Science and Technology
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• v.20 no.2
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• pp.94-104
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• 2021

Atmospheric corrosion severity associated with aircraft parking environment was studied using metallic specimens, and temperature and humidity sensors installed at each aircraft operating base. Data were analyzed after a year of exposure. Silver was used to measure chloride deposition by integrating X-ray photoelectron spectroscopy depth profiles. Carbon steel was utilized to determine the corrosion rate by measuring the weight loss. The time of wetness was determined using temperature and humidity sensor data. Analysis of variance followed by Tukey's "honestly significant difference" test indicated that atmospheric environment inside the shelter varied significantly from that of unsheltered parking environment. The corrosion rate of unsheltered area also varies with the roof. Hierarchical clustering analysis of the measured data was used to classify air bases into groups with similar atmospheric corrosion. Bases where aircraft park at a shelter can be grouped together regardless of geographical location. Unsheltered bases located inland can also be grouped together with sheltered bases as long as the aircraft are parked under the roof. Environmental severity index was estimated using collected data and validated using the measured corrosion rate.

• Journal of Korean Society of Forest Science
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• v.105 no.3
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• pp.303-308
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• 2016

To investigate the effect of calcium chloride ($CaCl_2$) using for deicing salts in winter on gas exchange and stomatal responses of 3-year-old Prunus serrulata, we treated twice (1 L) $CaCl_2$ solution (0.5%, 1.0% and 3.0%) in the root zone before leaf unfolding. Stomatal conductance ($g_s$), photosynthetic rate ($P_n$), transpiration rate ($T_r$) and water use efficiency (WUE) in the leaves of P. serrulata were decreased with increasing of $CaCl_2$ concentration. Even though stomatal conductance and photosynthetic rate were reduced by $CaCl_2$, intercellular $CO_2$ concentration ($C_i$) in $CaCl_2$ treatments has similar or higher values compared with control. These results suggest that non-stomatal limitation as well as stomatal limitation induced the reduction of photosynthetic rate together. On the other hands, treatment of $CaCl_2$ before leaf unfolding also affected leaf morphology traits. We proposed that reductions of stomatal length and leaf size and high pore density with increasing salinity is adaptative mechanism to reduce the water loss in plant.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.10
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• pp.121-127
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• 2018

A system for diagnosing surface defects of long and large pipe inner overlay welds, 1m in diameter and 6m in length, was developed using a Liquid Penetrant Test (PT). First, CATIA was used to model all major units and PT machines in 3-dimensions. They were used for structural strength analysis and strain analysis, and to check the motion interference phenomenon of each unit to produce two-dimensional production drawings. Structural strength analysis and deformation analysis using the ANSYS results in a maximum equivalent stress of 44.901 MPa, which is less than the yield tensile strength of SS400 (200 MPa), a material of the PT Machine. An examination of the performance of the developed equipment revealed a maximum travel speed of 7.2 m/min., maximum rotational speed of 9 rpm, repeatable position accuracy of 1.2 mm, and inspection speed of $1.65m^2/min$. The results of the automatic PT-inspection system developed to check for surface defects, such as cracks, porosity, and undercut, were in accordance with the method of ASME SEC. V&VIII. In addition, the results of corrosion testing of the overlay weld layer in accordance with the ferric chloride fitting test by the method of ASME G48-11 indicated that the weight loss was $0.3g/m^2$, and met the specifications. Furthermore, the chemical composition of the overlay welds was analyzed according to the method described in ASTM A375-14, and all components met the specifications.

• The Korean Journal of Pharmacology
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• v.26 no.1
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• pp.55-66
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• 1990

In both resting and opsonized zymosan activated neutrophils, ATP stimulated superoxide generation, whereas adenosine inhibited it slightly. The superoxide generation in activated neutrophils to ATP was greater than that of resting neutrophils. In $Ca^{++}$ free medium, inhibitory effect of adenosine on superoxide generation was detectable, whereas ATP did not have any effect. The stimulatory effect of ATP on superoxide generation was inhibited by adenosine in a dose dependent manner. Neither ATP nor adenosine had any effect on NADPH oxidase acitivity. Effects of ATP or adenosine on superoxide generation were more prominent than that by other triphosphate nucleotides or nucleosides. ATP and ADP further stimulated $Ca^{++}$ uptake and increased cytosolic free $Ca^{++}$ level in neutrophils activated by opsonized zymosan, but adenosine inhibited a $Ca^{++}$ mobilization. Verapamil effectively and tetrodotoxin slightly inhibited an increase of cytosolic free $Ca^{++}$ level induced by ATP. Inhibitory effect of either verapamil or tetrodotoxin on superoxide generation in the ATP plus opsonized zymosan-activated neutrophils was greater than in the cells activated by opsonized zymosan alone. Tetraethylammonium chloride had no apparent effect on superoxide generation. CCCP, 2,4-dinitrophenol, diphenylhydantoin and procaine all inhibited superoxide generation in neutrophils activated by opsonized zymosan. Among these, CCCP only inhibited a stimulatory effect of ATP. ATP further stimulated a loss of sulfhydryl groups in activated neutrophils, whereas adenosine had no effect on it. These results suggest that functional responses of neutrophils may be regulated at least partly by purines. ATP and adenosine may further after functional responses of activated neutrophils through their effect on $Ca^{++}$ uptake, membrane phosphorylation and oxidation of soluble sulfhydryl groups.

• Journal of the Society of Cosmetic Scientists of Korea
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• v.40 no.2
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• pp.187-193
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• 2014

Dental caries are one of the most common oral diseases and Streptococcus mutans (S. mutans) plays an important role in the initiation and progression of dental caries. Oral malodor is primarily the result of microbial metabolism such as Porphyromonas gingivalis (P. gingivalis) that produce volatile sulfur compounds (VSCs), causing oral malodor. Prevotella intermedia (P. intermedia) is known as typical periodontopathic bacteria, and periodontal disease is chronic inflammatory disease that leads to damage of gingival connective tissue and alveolar bone, eventually loss of teeth. In this study, we investigated antimicrobial effect of mouthwash containing cetylpyridinium chloride (CPC), sodium fluoride (NaF), green tea water extract and pine needles water extract against cariogenic and periodontopathic bacteria sucn as S. mutans, P. gingivalis and P. intermedia. As a result, the reduction ratios of S. mutans and P. gingivalis were 4.00 Log and 4.68 Log reduction for 30 s, and P. intermedia were 2.40 Log reduction for 30 s and 2.70 Log reduction for 60 s. Dentocult SM Strip mutans (SM Strip) provides easy detection of visual data showing a significant inhibition on S. mutans. In conclusion, we expected that mouthwash containing CPC, NaF, green tea water extract and pine needles water extract could help preventing the dental disease like dental caries and oral malodor.