• Title/Summary/Keyword: chloride corrosion

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Characteristic of Chloride ion Diffusion in Mortar According to the Substitution Ratios of the Additive (혼합재 치환율에 따른 모르타르의 염소이온 확산 특성)

  • 양승규;정연식;이웅종;유재상;이종열
    • Proceedings of the Korea Concrete Institute Conference
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    • 2002.10a
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    • pp.17-22
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    • 2002
  • Chloride ions have a tendency to penetrate into concrete and proceed the corrosion by depassivating rebar surface. Thus the deteriorated concrete is subject to experience severe degrading of durability under marine environment. Physical properties of mortar, such as, compressive strength and penetration depth of chloride ion were investigated. And to investigate the effect of containing SG, FA in mortar, the diffusion coefficient of chloride was measured through an electro - migration test. The diffusion coefficient of chloride was decreased with the increase of replacement ratio of SG compared with plain specimen.

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Air-borne Chloride Content of Highway Bridges Exposed to Marine Environment (해양환경에 위치한 국내 고속도로 교량의 비래염분량 측정 결과)

  • 정해문;유환구;류종현;안태송;김수만;오병환
    • Proceedings of the Korea Concrete Institute Conference
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    • 2002.05a
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    • pp.743-748
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    • 2002
  • Chloride ingress into concrete followed by reinforcement corrosion and deterioration of concrete structures is a major problem for many structures under chloride attacks. Large-scale concrete structures directly exposed to seawater such as SeoHae Grand Bridge are increasingly constructed along the coast in Korea. It is necessary to investigate the environmental conditions of concrete structures exposed to chloride attacks. In this study, the air-borne chloride contents of highway bridges exposed to marine environment in Korea were measured.

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Chloride penetration in the marine concrete pier considering diffusion and convection (확산과 이송을 고려한 해양 콘크리트 교각의 염소이온 침투해석)

  • Kim, Ki-Hyun;Cha, Soo-Won;Jang, Sung-Yup
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.413-416
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    • 2008
  • Reinforcement corrosion is generally prohibited under normal condition by the alkalinity of the pore water in the concrete. However, concrete structures in marine environment are subjected to chloride attack due to the high salinity of the sea water. Thus the probability of steel corrosion becomes higher when the chloride ions are introduced into the concrete. Steel corrosion is a decisive factor for the determination of service life of the marine concrete structure because chloride ions are abundant in the sea, and piers are the typical construction elements in concrete structures in marine environment. Hence, it is of great importance to evaluate the service life of the piers. In this paper, chloride penetration analysis for the rectangular pier in the marine environment is performed considering the diffusion and convection movement of chlorides. Result reveals that the service life of the reinforcement with drying-wetting cycles is much shorter than that of the reinforcement with saturated condition. This may be due to the fact that moisture movement is much faster that chloride diffusion.

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A Study on Prediction Model of Chloride ion Permeation of Cement Mortar by Steel Powder (염해환경에서의 염화물이온 침투 예측에 관한 연구)

  • Kim, Jeong-Jin;Park, Soon-Jeon;Ko, Joo-Hwan;Han, Cheon-Goo
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.513-516
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    • 2008
  • In this study the prediction model of Chloride Ion progress rate of concrete using steel powder as an addition is developed, in which the reduction of not only the diffusion rate of $Cl^-$ but also the corrosion rate by replenishment of pore by corrosion products. The model is based on the diffusions of $Cl^-$ and its reaction with $Fe^{2+}$, in chloride attack progression region. The model can also explain the characteristics of chloride ion permeation resistance of concrete that the matrix is densified due to corrosion products. The prediction by the model agreed well the experimental data in which the concrete using steel powder, and it showed the lower rate in long-term age to Chloride Ion progress rate than the concrete without steel powder. Consequently the model can predict Chloride Ion progress rate of concrete exposed in the atmosphere regardless of the water-to-cement raito, the amount of the content of steel powder, etc.

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Studies on the Concrete Reinforcement Corrosion by Electrochemical Impedance Spectroscopy (전기화학적 임피던스법에 의한 철근콘크리트의 부식연구)

  • Kang, Tae-Hyuk;Cho, Won-Il;Cho, Byung-Won;Ju, Jeh-Beck;Yun, Kyung-Suk
    • Applied Chemistry for Engineering
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    • v.9 no.6
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    • pp.907-913
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    • 1998
  • Corrosion behavior of steel reinforcements embedded in concrete containing various chloride ion concentrations was investigated by an electrochemical impedance spectroscopy(EIS). Chloride ions were introduced into the concrete by dissolving the NaCl and $CaCl_2$ in the water with a given weight of cement. Based on the impedance parameters measured by EIS, more complete equivalent circuit, a schematic physical model, and the mechanism of concrete reinforcement corrosion were suggested. By the implement of experimental impedance parameters obtained from the model with corresponding CNLS-fitting data, the corrosion rate of steel reinforcement with chloride ions could be predicted.

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Application of Macrocell Sensor System for Monitoring of Steel Corrosion in Concrete Structure Exposed to Marine Environment (해양 콘크리트구조물의 철근부식 모니터링을 위한 매크로셀 센서 시스템의 적용)

  • Lee, Seung-Tae;Moon, Dae-Joong;Kim, Wan-Jong;Moon, Jae-Heum;Kim, Hak-Soo
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.22 no.4
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    • pp.241-247
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    • 2010
  • Corrosion of steel embedded in concrete is one of the foremost factors that affect the durability of concrete structures in marine environments. This paper presents an application technique of anode-ladder-system to evaluate corrosion behaviours of marine concrete structure. In order to investigate the behaviours quantitatively, the measurement of potential and current was performed on the concrete elements subjected to the penetration and diffusion of chloride ions. The main variable was the heights from seawater level; namely 3.7, 6.0 and 8.2 m. As a result of the monitoring, it was found that the corrosion characteristics differently behaved with the increasing height. Additionally, through migration test, the relationship between compressive strength of concrete and diffusivity of chloride ions was observed. It is suggested, ultimately, that in order to reduce or mitigate steel corrosion, both appropriate concrete cover depth and high-quality of concrete in early ages should be done.

A Study on Corrosion Potential of Cracked Concrete Beam According to Corrosion Resistance Assessment (부식 저항성 평가에 따른 균열 콘크리트 보의 부식전위 연구)

  • Song, Ha-Won;Lee, Chang-Hong;Lee, Kewn-Chu
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.13 no.1 s.53
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    • pp.97-105
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    • 2009
  • Development and use of blended cement concrete is gaining more importance in the construction industry with reference to durability mainly due to the pore refinement and reduction in permeability. Cracks play a major role on important parameters like permeability, rate of chloride ingress, compressive strength and thus affect the reinforcement corrosion protection. Furthermore, when a crack occurs in the cover concrete, the corrosion of the steel reinforcement may be accelerated because the deterioration causing factors can pass through the crack. In recent years the effect of cracking on the penetration of concrete has been the subject of numerous investigations. Therefore assessing the service life using blended concrete becomes obviously in considering the durability. In the present study, the corrosion assessment of composite concrete beams with and without crack with of 0.3mm using OPC, 30% PFA, 60% GGBS, 10% SF was performed using half cell potential measurement, galvanic potential measurement, mass loss of steel over a period of 60days under marine environmental conditions and the results were discussed in detail.

Corrosion Level of RC Concrete Specimen Intermittently Attacked by Sea Water (해수간헐침투되는 철근콘크리트의 부식도 평가)

  • 정철희;정영수;최응규;원종필
    • Proceedings of the Korea Concrete Institute Conference
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    • 1996.10a
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    • pp.207-212
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    • 1996
  • Recently, massive concrete structures exposed to salt from ocean marine environments, or from winter deicing. The corrosion caused by chloride-penetration may affect severey the durability and service life of such a concretestructures. Thus, it is necessary to develop durable concrete to enhance the corrosion resistance. In this study, we investigate the usage of adequate corrosion-protection materials in order to reduce permability-coefficient of concrete and method of enhancing the durability of concrete structures using by penetrating corrosion-protection materials.

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Changing HCP of Tendon in Wet Soil Considering Local Position and Chloride Concentrations (습윤모래 조건에서 염화물 농도에 따른 텐던의 위치별 HCP의 변화)

  • Ji-Woan Choi;Ja-Ho Bang;Seung-Jun Kwon
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.12 no.3
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    • pp.239-245
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    • 2024
  • PS(Prestressed) tendons are under high tensile stress and have a smaller concrete cover than RC(Reinforced Concrete) member, so that the more conservative specifications on corrosion have been proposed for PS member. In this study, three levels of chloride concentrations(0.0 mol/l, 0.125 mol/l, and 0.25 mol/l) were prepared for evaluating the corrosion behavior in different position of 7 strand wires. For accelerating corrosion and measuring the corrosion amount in tendon, the tendon was embedded in partially saturated soil, and HCP(Half Cell Potential) was measured from the soil surface. During the test period of 28 weeks, HCP was measured every two weeks and the corrosion weight in the tendon was measured at 16 and 28 weeks of test period. Through the test, HCP result in tendon increased as the wires were located toward bottom due to high saturation. HCP in the lowest wire position showed an increase by 5.92 % compared to that in top position in 0.25 mol/l condition. The lower the position of the wire contained more saturation, which yielded increasing corrosion amount and HCP in tendon. In addition, the relation between corrosion weight and chloride concentration was quantitatively obtained through regression analysis.

A Study On the Corrosion Tendency of Bottom Plates and Corrosion Prevention Measures in Hazmat Tanks (위험물저장탱코밑판의 부식 성향분석 및 부식예방 방안에 관한 연구)

  • Choi, Jeong Soo;Ro, Kyung Jin
    • Journal of the Society of Disaster Information
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    • v.4 no.1
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    • pp.138-152
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    • 2008
  • The most important factor in the maintenance of chemical industry facilities is related with deterioration and corrosion. Leakage of hazardous materials is likely to occur because the confirmation and maintenance of bottom plates are very difficult while the bottom corrosion of the massive hazmat-storage facilities is most dangerous especially. As a result of the analysis of the corrosion locations, areas, usage condition of 287 hazmat-storage tanks on this syudy, it is concluded that the main external corrosion factors are the inflow of moisture and the materials inducing corrosion in the air such as sodium chloride and the main internal corrosion factors are corrosion react caused by stay of seawater, sulfur and moisture in hazmat for a long time without appropriate discharges. It is anticipated that the corrosion of bottom plates can be restrained effectively by establishing the proper measures for the each corrosion cause.

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