• Title/Summary/Keyword: chitosan solution

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Foliar Fertilization Effect of Environmentally-Friendly Organic Agricultural Materials for Grape Cultivation (포도재배를 위한 친환경 유기농자재의 엽면시비 효과)

  • Moon, Young-Hun;Ahn, Byung-Koo;Cheong, Seong-Soo;Lee, Jin-Ho
    • Korean Journal of Soil Science and Fertilizer
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    • v.45 no.5
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    • pp.760-763
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    • 2012
  • This study was conducted to investigate foliar treatment effects of organic agricultural materials for the environmentally-friendly cultivation of grape. The organic materials applied were chitosan, wood vinegar (pyroligneous acid), amino acid solution, and ginkgo leaf extract. All the organic materials were relatively strong acidic ranging lower than pH 4.6. when comparing with other organic materials, amino acid solution contained relatively high contents of selected plant nutrients, such as N, P, K, Ca, Mg, Cu, Fe, Mn, and Zn. As comparison of selected soil properties in the grape cultivating field, soil pH values were lower at the harvest stage than at the first stage of grape growing (before treating the organic materials), and electrical conductivity (EC) and soil organic matter content were higher at the harvest stage in the all plots. The concentrations of available phosphorus increased in most of the plot soils except in control plot (conventional treatment). The concentrations of exchangeable K decreased in the plot treated with ginkgo leaf extract and the control plot. The exchangeable Mg concentrations decreased in soils of all the plots. On the other hand, the concentrations of N and K in the grape leaves were higher with the treatments of chitosan and amino acid solution, P concentrations were higher with the applications of chitosan, wood vinegar and amino acid solution, and Ca and Mg concentrations were higher with chitosan and amino acid solution treatments, respectively, than with others. The yields of grape were higher, $1,581{\sim}1,583kg\;10a^{-1}$, in the control and wood vinegar treatment plots than others. Sugar contents of grape were not different among all the plots.

The Permeability of Capsule Type Fertilizer and Herbicide with Chitoasn and Alginic Acid (Chitosan과 Alginic Acid를 이용한 캡슐형 비료 및 제초제의 투과특성)

  • LEE Keun-Tai;KIM Sang-Moo;PARK Seong-Min;SON Byung-Yil;KIM Hyoung Seub;LEE Sang-Ho
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.30 no.2
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    • pp.313-318
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    • 1997
  • Effects of the concentration of NaCl, the concentration and the molecular weight of chitosan on the permeability of capsule type fertilizer and herbicide were investigated. The encapsulating process was based on the electrostatic interaction between chitosan (a polycationic polymer) and sodium alginate (an anionic polysaccharide). Sodium alginate solution $(1\%)$ was dropped into chitosan solution $(1\%)$ in which various amounts of NaCl was added. The capsule strength was increased with the addition of NaCl and the maximum value of capsule strength was observed at 0.3M NaCl. Capsule type fertilizer and herbicide were immersed in deionized water to determine its permeability, and it was affected by the concentration of NaCl and chitosan, and the molecular weight of chitosan. As the concentration of NaCl in chitosan solution increased, permeability of the capsule increased and marked the maximum value of $ 88\%$(fertilizer), $87\%$ (herbicide) at 0.75M NaCl. As concentration of chitosan solution increased, permeability tended to decreased; it showed the maximum value of $90\%$ (fertilizer) and $90.3\%$ (herbicide) at $0.25\%$ chitosan and the minimum value of $83\%$ (fertilizer) and $82\%$ (herbicide) at $1\%$ chitosan. Permeability of fertilizer and herbicide also decreased, as the molecular weight of chitosan (material of capsule) was decreased; it was showed $86\%$ (fertilizer) and $83\%$ (herbicide) at M.W 330,000 (sonication time 0min) and $52\%$ (fertilizer) and $51\%$ (herbicide) at M.W 119,000 (sonication time 180 min). The chitosan-alginic acid capsule was manufactured (defined as prepared capsule), dried for 6 hrs and immersed in deionized water (defined as restored capsule) to examine restoration of capsule. Restoration of capsule was good, and capsule strength was slightly decreased form $20g/cm^2$ (prepared capsule) to $17g/cm^2$ (restored capsule)

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Effect of Chitosan and Mordant Treatments on the Color Change of Cotton and Nylon Fabrics Dyed using Japanese Pagoda Tree (면(棉)과 나일론 직물(織物)의 괴화 염색(槐花 染色)에서 Chitosan 처리(處理)와 매염(媒染)이 색상(色相)에 미치는 영향(影響))

  • Hwang, Hui-Youn;Choi, Jeong-Im;Jeon, Dong-Won
    • Journal of Fashion Business
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    • v.10 no.2
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    • pp.18-26
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    • 2006
  • In this study, the effects of chitosan pre-treatment on the mordanting effect and dyeability were investigated in the dyeing using Japanese pagoda tree. The chitosan treatment effects were evaluated mainly focused on the colors after dyeing of cotton and nylon fabrics which were treated with acidic aqueous solution of chitosan. In the case of chitosan untreated fabrics, the mordanting effects on the cotton and nylon were insignificant and the dyeability was very low. Regardless of the mordant types(Al, Sn, and Fe), the dyed fabrics exhibited almost identical yellowish colors. In the case of chitosan treated fabrics, dark colors were obtained compared to the case of chitosan untreated and ${\Delta}E$ values were increased significantly. In cotton fabrics, the most excellent result was obtained under the condition of unmordanted and chitosan treated fabrics. This verifies the fact that routin coloring matters establish direct linkages with the chitosan components, which exhibit cationic nature, easily. In nylon fabrics, the effects of mordanting treatment and chitosan treatment are so insignificant that the routin coloring matters are presumed to establish direct dyeing with the nylon molecular chains.

Effect of Chitosan Pretreatment on the Dyeing of Cotton and Silk Fabrics using Caesalpinia sappan - Effect of the Change in Chitosan Molecular Weight - (키토산 사전 처리가 면과 견직물의 소목 염색에 미치는 영향 - 키토산의 분자량 변화에 따른 효과 -)

  • Choi In-Ryu;Kim Jong-Jun;Jeon Dong-Won
    • The Research Journal of the Costume Culture
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    • v.13 no.4 s.57
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    • pp.576-588
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    • 2005
  • The effect of chitosan pretreatment on the dyeing of cotton fiber and silk fiber was investigated. However, it has been difficult to evaluate the effect of the chitosan precisely, since the characterization of the molecular weight and effect of the degree of deacetylation were not elucidated for the application. The treatment effect may change diversely since the chitosan solution viscosity differs a lot based on the chitosan molecular weight. In this study, three chitosan specimens, varying in molecular weight, were applied for the fabric pretreatment in order to investigate the effect of chitosan molecular weight. Also, in order to maximize the efficacy of the chitosan, highly deacetylated chitosan specimens, meeting the deacetylation degree of $100\%$, were selected far the application. The air-permeability change according to the chitosan molecular weight change, influence on the mordanting, color change, and wash fastness change were investigated.

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A Study on the Handle of Cotton Fabric treated with Chitosan Polyurethane Mixed Solution by KES (II) (키토산-폴리우레탄 혼합용액(混合溶液)으로 처리(處理)된 면직물(綿織物)의 KES에 의한 태분석(態分析) (II))

  • Yoon, Se-Hee;Jeon, Dong-Won;Kim, Jong-Jun
    • Journal of Fashion Business
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    • v.8 no.1
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    • pp.156-163
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    • 2004
  • The purpose of this study is to investigate the change of handle when cotton fabric is treated with chitosan-polyurethane mixed solution and crosslinked with epichlorohydrin in order to form three-dimensional crosslinks in the molecules, which in turn would improve the wash-fastness of the chitosan-treated fabrics. The application of epichlorohydrin decreased the EM(Tensile extensibility) and WT(Tensile energy) values, indicating the stiffness increased in the treated fabrics due to the 3-dimensional crosslinking. The crosslinking of the cotton fabric samples resulted in the increase in T.H.V. effectively for the use of summer dress shirt fabric.

Effect of Microbial Product on Microorganisms in Soil and Growth of Chinese Cabbage (미생물제제 처리가 토양 미생물상의 변화 및 배추의 생육에 미치는 영향)

  • Seok, Woon-Young;Oh, Ju-Sung;Kim, Doh-Hoon;Chung, Won-Bok;Jeong, Soon-Jae
    • Korean Journal of Organic Agriculture
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    • v.12 no.4
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    • pp.399-409
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    • 2004
  • This study was conducted to investigate the effect of different concentrations of microbial products on growth of chinese cabbage and microorganisms in soil. Two different levels of microbial products, such as 50 times and 100 times diluted solutions of chitosan, wood vinegar and EM activity liquid, were treated for foliar application. the results were summarized as follows : Among foliar applications of microbial products, 100 times diluted solution of chitosan was effective on growth of chinese cabbage comparing to other levels of dilutions and untreated control plot. The number of microorganism in the soil tended to increase under the treatment of microbial products compared to control plot. Especially, the numbers of the bacteria and actinomycetes were estimated $73.67{\times}10^3$ CFU/g and $34.00{\times}10^3$ CFU/g, respectively, under the treatment of 100 times diluted solution of chitosan.

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Preparation of Trifluoroacetyl Chitosan Derivatives with Antiviral Activity (항바이러스 활성을 갖는 Trifluoroacetyl Chitosan 유도체의 제조)

  • Kim, Chun-Ho;Shin, Cha-Gyun;Shin, Kye-Sook;Son, Tae-il
    • Applied Chemistry for Engineering
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    • v.10 no.4
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    • pp.599-602
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    • 1999
  • Chitosan was depolymerized by using nitrous acid. In order to synthesize new fluorinated chitosan oligomer(FCO) derivative, free amine groups of resulting low molucular weight chitosan oligomers were reacted with trifluoroacetic anhydride. The structure changes in the samples were conformed by using FT-IR, $^{1}H\;NMR$, $^{13}C\;NMR$ and $^{19}F\{^{1}H\}NMR$. Antiviral activity of FCO was studied by measuring DAN amounts of the replication viruses at 36 hr after the cells were infected with the viral solution containing FCO of various concentrations. The viral replications in the cells infected with the viral solution containing FCO were proportionally decreased with the FCO does, compared to those of the control groups, indicating that FCO efficiently inhibits viral infection. In particular, viral replication was decreased to 40% in the 1% FCO-treated cells.

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Control of Drug Release from Polymeric Matrices Coated with Poly(DL-lactide) I. Effect of Coasting Substance on the Drug Release in pH 1.2 Hydrochloride Solution (Poly(DL-lactide)로 피막된 고분자 매트릭스로부터 약물 방출 조절 I. pH 1.2 염산 용액에서 피막물질이 약물방출에 미치는 영향)

  • 나재운;박영훈
    • KSBB Journal
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    • v.14 no.3
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    • pp.297-302
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    • 1999
  • The polymeric matrices coated with poly(DL-lactide) were prepared using chitosan derivatives such as chitosan, chitosan hydrochloride, and sulfonated chitosan for application of drug delivery systems. The drug release study using prednisolone as a model drug was performed in the hydrochloride solution at pH 1.2. The release rate of drug was decreased according to the increased content of matrices. The release rate of prednisolone according to the kinds of polymeric matrices coated were decreased in the order to chitosan, sulfonated chitosan, and chitosan hydrochloride. Drug release rate of polymeric matrices coated with poly(DL-lactide) was not only two times slower than noncoated one, but also the burst effect of initial period of drug release was decreased in comparison with noncoated one. From these results, it was expected that these formulations based on the chitosan derivative matrices coasted with poly(DL-lactide) were acceptable drug delivery devices for a sustained-release dosage form of drug.

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Mechanical Properties of Cellulose/Chitosan and Sericin/Chitosan Blend Films

  • Kiyohisa Takahashi;Kenji Nagata;Yoon, Heung-Soo
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10a
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    • pp.9-10
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    • 2003
  • Cellulose/chitosan and sericin/chitosan blend films with various mixing ratios were prepared and tensile properties, solubilities to the aqueous solution of acetic acid and the degree of swelling by the distilled water were measured. The interaction between the components of blend film and the blending effect were investigated.

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Effect of Humidity on the Electrospinning of Chitosan Solution (키토산 용액의 전기방사에 있어 습도의 영향)

  • Lee, Jin-Ah;Joo, Chang-Whan
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10b
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    • pp.273-274
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    • 2003
  • Chitin and chitosan have a wide range of application on the environmental and biomedical engineering by their biocompatibility, biodegradability, non-toxicity and adsorption property, etc. The efforts of manufacturing chitosan fibers are continuously maintained until now$\^$l.2)/. Electrospinning is new method to produce the nano-sized fibers for medical uses. Recently, formation of chitosan fiber using electrospinning is studied by many textile researchers. (omitted)

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