• Title/Summary/Keyword: chemistry-fiber

Search Result 587, Processing Time 0.022 seconds

Processing and Mechanical Properties of Mullite Fiber / Fe Composite

  • Niibo, Yoshihide;Yuchi, Kazuhiro;Sameshima, Soichiro;Hirata, Yoshihiro
    • Proceedings of the Korea Association of Crystal Growth Conference
    • /
    • 2000.06a
    • /
    • pp.195-214
    • /
    • 2000
  • The high-speed steel (shorten as HSS) consists of Fe and several kinds of transition metal carbides. The cutting tools or wear-resistant materials made from HSS experience relatively high thermal shock because a coolant such as water or oil is flowed over the surface of heated HSS. The purpose of this research is to increase the hardness, strength, fracture toughness and thermal shock resistance of HSS. A possible strategy is to incorporate a hard ceramic material with high strength in HSS matrix. This paper describes the processing, microstructure and mechanical properties of the oriented unidirectional mullite fiber/HSS composite. The unidirectional mullite fibers of 10${\mu}{\textrm}{m}$ diameter were dispersed by the ultrasonic irradiation of 38 kHz in an ethylenglycol suspension containing HSS powder of 11${\mu}{\textrm}{m}$ median size. The dried green composites with 4-68 vol% fibers were hot-pressed for 2h at 100$0^{\circ}C$ in Ar atmosphere under a pressure of 39 MPa. The higher density was achieved in the composite with a lower content of fibers. The oriented unidirectional fibers were well dispersed in the HSS matrix. The average distance between the center of fibers in the cross section was close to the value calculated from the fiber fraction. No reaction occurred at the interfaces between HSS and mullite fibers in the composites. The composite with 13.6 vol% fibers showed 100 MPa of four point flexural strength at room temperature. The thermal expansion of composite with heating was influenced by the orientation of mullite fibers.

  • PDF

Melt Rheology and Property of Short Aramid Fiber Reinforced Polyethylene Composites (아라미드단섬유강화 폴리에틸렌복합재료의 용융특성 및 물성)

  • Choi, Chi Hoon;Ok, Young Sook;Kim, Byung Kyu;Ha, Chang Sik;Cho, Wong Jei;Shin, Young Jo
    • Applied Chemistry for Engineering
    • /
    • v.3 no.1
    • /
    • pp.81-87
    • /
    • 1992
  • Polyethylenes were reinforced with short aramid fibers on an open roll. Fiber orientation and the anisotropy of physical property were studied using scanning electron microscopy and tensile tester, together with the melt properties from an RDS rheometer. It was found that fiber orientation was obtained in roll operation, and the anisotropy of property became greater with the increase of fiber loading. Melt viscosity measurements indicated that the viscosity increases with fiber loading, with the effect much more pronounced at low loading and low frequency.

  • PDF

DGEBA-MDA-SN-Hydroxyl Group System and Composites : 2. Fracture Energy of Fiber Reinforced Composites (DGEBA-MDA-SN-Hydroxyl Group System의 합성 및 복합재료 제조 : 2. 섬유강화 복합재료의 파괴에너지)

  • Lee, Jae-Young;Shim, Mi-Ja;Kim, Sang-Wook
    • Applied Chemistry for Engineering
    • /
    • v.5 no.4
    • /
    • pp.737-742
    • /
    • 1994
  • The fracture energy of glass fiber/carbon fiber/epoxy resin hybrid composite system was investigated in the aspect of fracture mechanism. Epoxy resin matrix was DGEBA-MDA-SN-HQ system. On the interface of glass fiber and matrix, post debone friction energy provided a major contribution to the fracture energy, and debonding energy and pull-out energy were of the similar value. In the case of fracture on the interface of carbon fiber and matrix, pull-out energy was the major contributor.

  • PDF

Preparation of dietary fiber sources using apple pomace and soymilk residue (두유박과 사과쥬스박을 이용한 식이섬유원의 제조)

  • Hong, Jai-Sik;Kim, Myung-Kon;Yoon, Sook;Ryu, Nam-Soo
    • Applied Biological Chemistry
    • /
    • v.36 no.2
    • /
    • pp.73-79
    • /
    • 1993
  • Apple pomace and soymilk residue which have 36.3% and 20.2% of neutral detergent fiber, respectively, were evaluated as potential dietary fiber supplement. Apple pomace showed strong functional properties as source of dietary fiber when Created with water, and n-hexane continually. The neutral detergent fiber content of treated apple pomace was 60.9% and holding capacities were 11.3g water/g and 2.01g fat/g. Canon exchange capacity was 65.0meq./100g. Soymilk residue showed good functional properties as source of dietary fiber when treated continually with water, n-hexane, acid and alkali. The neutral detergent fiber content of treated soymilk residue was 52.7% and holding capacities were 10.2g water/g and 1.52g fat/g. Canon exchange capacity was 63.7meq./100g. The color of treated dietary fiber sources were slightly shifted to darkness.

  • PDF

Morphological Characteristics of Weed Seed Fibers (잡초 종자섬유의 형태적 특징 비교)

  • Yoon, A Ra;Lee, Min Woo;Kim, Seul Ki;Kim, Jin-Seog
    • Weed & Turfgrass Science
    • /
    • v.3 no.3
    • /
    • pp.196-205
    • /
    • 2014
  • In this study, to obtain basic data for searching potential resources as new natural fibers, we investigated morphological and classificatory characteristics of 21 weed seed fibers. According to classification keys in this study, the collected weed seed fibers could be classified into total 13 types, showing their diversity. Seven species among them belonged to BOT3 type. Two species belonged to B2N0 and DOS3 type, respectively. Many of weed seed fibers had not branched. However, three species had various branched fibers at one main fibers on the seed. Three species had various branched fibers at several main fibers on the seed. Eight species had a smooth fiber surface but 13 species had a weakly or significantly developed-corniculum on the fiber surface. In the fiber cell shape, fiber cells of eight weed species were composed of one long cell without septum. But others had a fiber cell shape composed of a bunch of several long cells. Based on the easiness of harvesting, productivity of fibers, and morphological characteristics of seed fiber, it seemed that five seed fibers (TYPLA, METJA, HEMLY, IMPCK, and EREHI) should be additionally investigated if they are practically applicable as renewable resources for new natural fibers.

Pectin from Passion Fruit Fiber and Its Modification by Pectinmethylesterase

  • Contreras-Esquivel, Juan Carlos;Aguilar, Cristobal N.;Montanez, Julio C.;Brandelli, Adriano;Espinoza-Perez, Judith D.;Renard, Catherine M.G.C.
    • Preventive Nutrition and Food Science
    • /
    • v.15 no.1
    • /
    • pp.57-66
    • /
    • 2010
  • Passion fruit fiber pectin gels represent a new alternative pectin source with potential for food and non-food applications on a commercial scale. Pectic polysaccharides were extracted from passion fruit (Passiflora edulis) fiber using citric acid as a clean catalyst and autoclaved for 20 to 60 min at $121^{\circ}C$. The best condition of pectin yield with the highest molecular weight was obtained with 1.0% of citric acid (250 mg/g dry passion fruit fiber pectin) for 20 min of autoclaving. Spectroscopic analyses by Fourier transform infrared, enzymatic degradation reactions, and ion-exchange chromatography assays showed that passion fruit pectin extracted for 20 min was homogeneous high methoxylated pectin (70%). Gel permeation analysis confirmed that the pectin extract obtained by autoclaving by 20 min showed higher molecular weights than those autoclaved for 40 and 60 min. Passion fruit pectin extracted for 20 min was enzymatically modified with fungal pectinmethylesterase to create restructured gels. Short autoclave treatment (20 min) with citric acid as extractant resulted in a significant increase of gel strength, improving pectin extraction in terms of functionality. The treatment of solubilized material (pectic polysaccharides) in the presence of insoluble material (cellulose and hemicellulose) with pectinmethylesterase and calcium led to the creation of a stiffer passion fruit fiber pectin gel, while syneresis was not observed.

Annealing Effect on Structure of Poly(trimethylene terephthalate) Undrawn Fibers

  • Murase, Shigemitsu;Ohtaki, Manabu
    • Proceedings of the Korean Fiber Society Conference
    • /
    • 2003.10a
    • /
    • pp.59-60
    • /
    • 2003
  • The undrawn monofilament of poly (trimethylene terephthalate) (PTT) was obtained by melt-spinning. After being annealed at 40 C it was analyzed by the measurements of DSC, DMA, WAXD and ATR FT-IR. Tg of PTT fiber after annealing for more than 96 hours was 20 C higher than that before annealing as determined by the DSC and DMA measurements. The WAXD analysis showed very weak diffraction peaks at 2$\theta$=17$^{\circ}$ and 2$\theta$=24$^{\circ}$ for the annealing time of more than 96 hours. The ATR FT-IR measurements made clear the conformational change of methylene chains of PTT glycol residue from random to gauche-gauche conformation.

  • PDF

Spinning of Petroleum based Isotropic Pitch by Melt-blown Method

  • Kim, Chan;Lee, Su-Hyun;Kim, Young-Min;Yang, Kap-Seung
    • Carbon letters
    • /
    • v.3 no.1
    • /
    • pp.33-38
    • /
    • 2002
  • Petroleum based isotropic pitch was spun into short fiber by melt-blown spinning technology. The processing parameters chosen were air velocity, die temperature, and throughput rate of the pitch within the ranges of experimental tolerances. The fiber diameter was reduced to $6{\mu}m$ by increases of hot air velocity, and spin die temperature. Also, the fiber diameter was strongly dependent on the throughput rate of the pitch and jet speed of hot air through the spinnerets. Even fibers with $10{\mu}m$ diameter were produced at throughput rate of $0.17g/min{\cdot}hole$ and at die temperature of $290^{\circ}C$.

  • PDF

The Effect of Etching on Low-stress Mechanical Properties of Polypropylene Fabrics under Helium/Oxygen Atmospheric Pressure Plasma

  • Hwang, Yoon J.;An, Jae Sang;McCord, Marian G.;Park, Shin Woong;Kang, Bok Choon
    • Fibers and Polymers
    • /
    • v.4 no.4
    • /
    • pp.145-150
    • /
    • 2003
  • Polypropylene nonwoven fabrics were exposed to He/$O_2$ atmospheric pressure glow discharge plasma. Surface chemical analysis and contact angle measurement revealed the surface oxidation by formation of new functional groups after plasma treatment. Weight loss (%) measurement and scanning electron microscopy analysis showed a significant plasma etching effect. It was investigated in low-stress mechanical properties of the fabrics using Kawabata Evaluation System (KES-FB). The surface morphology change by plasma treatment increased surface friction due to an enhancement of fiber-to-fiber friction, resulting in change of other low-stress mechanical properties of fabric.

Preparation of Electrospun PI-based ACF Web for Electrode of Electric Double Layer Capacitior(EDLC) (정전기 방사에 의한 EDLC 전극용 폴리이미드계 활성탄소섬유 웹의 제조)

  • Choi, Young-Ok;Kim, Chan;Yang, Gab-Seung
    • Proceedings of the Korean Fiber Society Conference
    • /
    • 2003.10b
    • /
    • pp.134-137
    • /
    • 2003
  • 탄소섬유나 활성탄소섬유(activated carbon fiber, ACF)는 일반적으로 출발물질에 따라 polyacrylonitrile(PAN)계, 아크릴(acryl)계, 피치(pitch)계, 페놀(phenol)계 등으로 분류할 수 있다. 보통 습식, 용융 혹은 용융분사(melt-blown) 방사 방법에 의해 섬유 형태로 형성한 다음 산화성 가스 분위기에서 불융화 과정을 거쳐 열에 대한 안정성을 부여하여 불활성 분위기에서 탄소화하여 탄소섬유를 제조하거나, 수증기나 이산화 탄소와 같은 산화성 분위기에서 활성화하여 활성탄소섬유를 제조한다. (중략)

  • PDF