• Title/Summary/Keyword: chemical weathering

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Material Characteristics and Deterioration Assessment for Multi-storied Round shape Stone Pagoda of Unjusa Temple, Hwasun, Korea (화순 운주사 원형다층석탑의 재질특성과 훼손도 평가)

  • Park, Sung Mi;Lee, Myeong Seong;Kim, Jae Hwan;Lee, Chan Hee
    • Korean Journal of Heritage: History & Science
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    • v.45 no.1
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    • pp.86-101
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    • 2012
  • The constituting rocks of Multi-storied Round shape stone Pagoda of Unjusa Temple are lithic tuff and rhyolite tuff breaccia which show green or grey and also rock fragment with poor roundness are present in the structure. lithic tuff is composed of feldspar and quartz which are glassy texture and cryptocrystalline and also micro crystalline are scattered. phenocryst quartz and feldspar in the substrate composed of feldspar and opaque minerals are found in rhyolite tuff breaccia. dust, exfoliation, cavity, fracture and crack are observed in all the stone of the pagoda and the result of Infrared Thermography shows partial inter cavities have developed severely which may cause further exfoliation. In addition, a great deal of various grey, green, and yellow brown lichen as well as bryophyte are present at the upper part of eastern and western roof stone located above the third floor. Discolors remarkably shown at stereobate and roof stone are identified as inorganic pollutants such as manganese oxide, iron oxide and iron hydroxide. The stone of the pagoda of the Chemical Index of Alteration (CIA) and the Weathering Potential Index (WPI) are 55.69 and 1.12 respectively and this corresponds to a highly weathered stage. The measured values, average ultrasonic velocity 2,892m/s, coefficient of weathering 0.4k and compressive strength $1,096kg/cm^3$, suggest that the rock strength and durability are weakened.

Reconsideration and Conservational Scientific Diagnosis of Silla Stone Monument in Bongpyeong-ri, Uljin (울진 봉평리 신라비의 재판독과 보존과학적 진단)

  • Jo, Young-hoon;Lee, Chan-hee;Shim, Hyun-yong
    • Korean Journal of Heritage: History & Science
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    • v.46 no.3
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    • pp.48-67
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    • 2013
  • This study was focused on the recognition of historical values and the establishment of conservation schemes for a Silla stone monument in Bongpyeong-ri, Uljin by combining the humanistic investigation of inscription reinterpretation and the scientific conservational diagnosis of deterioration. According to the investigation of inscription, a total of 13 letters were reconsidered compared to the preceding researches. Thus, the meaning and interpretation of previous inscription was partially changed. This monument is composed of gneissose leucogranite and the most suitable site as provenance of the stone would be the Jukbyeon seashore (2.1km). The site shows similar color, size and composition of minerals, gneissose structure and magnetic susceptibility as the Bongpyeong stone monument. This monument developed a structural crack (crack index 0.4) and a microcrack (crack index 2.0) along the gneissose structure. The horizontal strength is weaker than the vertical strength. Therefore, the cracks should be reinforced and treated. However, consolidating is not urgently needed because the total weathering grade by ultrasonic velocity shows the stage of moderate weathering(3,403m/s, 0.32). Also, the major problems of chemical deterioration are blackening (85.2%) with soil, iron oxide,rubbing mark, and salt crystals (17.3%) from the sea. Therefore, the contaminants and the salt crystals should be removed using pressure spray and pulp paper, while the application of poultice should be examined through clinical tests.

A Report on Patterned Ground in the Baekdusan (백두산 일대에 나타나는 구조토 보고)

  • CHOI, In-Sook;SEONG, Yeong Bae;KIM, Jong Wook;PARK, Seung-Phil;LI, Chun Jing
    • Journal of The Geomorphological Association of Korea
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    • v.17 no.1
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    • pp.59-72
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    • 2010
  • This study is based on the observation on the patterned ground found in the northern part of the Baekdusan during two fieldtrips of 2008 summer. The patterned grounds are found in two areas-Dalmun and Socheonji. The patterned ground found around Dalmun are well-sorted, having fine materials in the center and coarse (boulder size) materials in the rim, and stretching in the form of stairs. Meanwhile, the types of patterned ground found around Socheonji are various, including polygon, stripe, and circular patterns. The particle size analysis and morphological analysis of comprising materials are carried out only for the patterned ground of Socheonji. The mean short and long axis of the patterned grounds are 91cm and 163cm, respectively. The distribution pattern of material size from the most samples increase toward the rim, indicating the patterned grounds are well-sorted. The comprising materials are dominated by silt, which is very susceptible for freeze-thaw cycle. The lower ratio of clay (low less than 10%), suggests that physical weathering is more dominant rather than chemical weathering. The involution structure found in the vertical section of the patterned grounds is likely to have formed by active cryoturbation which is one of the dominant geomorphic processes in the periglacial environments like the study area.

Deterioration Characteristic Analysis for Stone Properties in the Taereung Royal Tomb of the Joseon Dynasty using Nondestructive Analysis (비파괴 분석을 활용한 조선왕릉 태릉 석조물의 손상특성 분석)

  • Lee, Myeonseong;Choie, Myoungju;Lee, Taejong;Chun, Yungun
    • Korean Journal of Heritage: History & Science
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    • v.53 no.2
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    • pp.222-241
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    • 2020
  • The Taereung Royal Tomb from the Joseon Dynasty is the tomb of Empress Munjeong, the second queen of King Jungjong, and it contains various types of stone artifacts. All of these stone artifacts were constructed using coarse- to medium-grained biotite granite. The major types of deterioration of the stone artifacts are identified as surface weathering and biological contaminants. Exfoliation (145 sculptures), granular decomposition (138 sculptures), and repair materials (156 sculptures), along with biological contaminant algae (154 sculptures), lichen (165 sculptures) and moss (97 sculptures), have a high occurrence frequency. In particular, it is deemed that immediate conservation treatment is required, as biological deterioration (algae) represents the most serious condition (grade 3 or higher in 94% of all stones), and it is thought that exfoliation and granulation decomposition are required for long-term conservation management. As a result of equo -tip hardness and ultrasonic measurement, more than 70% of stones were found to have very weak physical properties. Through hyperspectral analysis, organisms were shown to inhabit more than 80% of the surface of burial mound stone artifacts, and P (phosphorus), S (sulfur), Cl (chlorine), and Ca (calcium) were detected in this area. This is because Taereung Royal Tomb has been exposed to the outdoors for hundreds of years and has been weathered by physical, chemical, and biological factors. Therefore, among the stone artifacts in the Taereung Royal Tomb, those with high physical weathering grades are considered to require consolidation to reinforce them physically. Since organisms are highly likely to cause stone damage, they must be removed via dry and wet cleaning. In addition, in order to delay the reoccurrence of organisms following conservation treatment, it is necessary to regularly clean up the soil that has flowed into the burial mound, and to monitor conservation conditions over the long term.

Mineralogical and Physico-chemical Properties of Fine fractions Remained after Crushed Sand Manufacture (국내 화강암류를 이용한 일부 인공쇄석사 제조과정에서 생기는 스러지의 광물.물리화학적 특성)

  • Yoo, Jang-Han;Ahn, Gi-Oh;Jang, Jun-Young
    • Journal of the Mineralogical Society of Korea
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    • v.19 no.4 s.50
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    • pp.355-361
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    • 2006
  • Artificially crushed sands occupy approximately 30 percent of the total consumption in South Korea. The demand for the crushed sands is expected to rise in the future. Most manufacturers use granitic rocks to produce the crushed sands. During the manufacturing process, fine fractions (i.e., sludges or particles smaller than 63 microns) are removed through the process of flocculation. The fine fraction occupies about 15% of the total weight. The sludges are comprised of quartz, feldspars, calcite, and various kinds of clay minerals. Non-clay minerals occupy more than 75 percent of the sluges weight, according to the XRD semi-quantification measurement. Micas, kaolinites, chlorite, vermiculite, and smectites occur as minor constituents. The sludges from Jurassic granites contain more kaolinites and $14{\AA}$-types than those from the Cretaceous ones. The chemical analysis clearly shows the difference between the parent rocks and the sludges in chemical compositions. Much of colored components in the sludges was accumulated as the weathering products. Particle size analysis results show that the sludges can be categorized as silt loam in a sand-silt-clay triangular diagram. This result was for her confirmed by the hydraulic conductivity data. In South Korea, the sludges remained after crushed sand production are classified as an industrial waste because of their impermeability, and which is caused by their high silt and clay fractions.

Factors affecting particle breakage of calcareous soil retrieved from South China Sea

  • Wang, Xinzhi;Shan, Huagang;Wu, Yang;Meng, Qingshan;Zhu, Changqi
    • Geomechanics and Engineering
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    • v.22 no.2
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    • pp.173-185
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    • 2020
  • Calcareous soil is originated from marine biogenic sediments and weathering of carbonate rocks. The formation history for calcareous sediment includes complex physical, biological and chemical processes. It is preferably selected as the major fill materials for hydraulic reclamation and artificial island construction. Calcareous sands possess inter pores and complex shape are liable to be damaged at normal working stress level due to its fragile nature. Thus, the engineering properties of calcareous soil are greatly affected by its high compressibility and crushability. A series of triaxial shear tests were performed on calcareous sands derived from South China Sea under different test conditions. The effects of confining pressure, particle size, grading, compactness, drainage condition, and water content on the total amount of particle breakage for calcareous soil were symmetrically investigated. The test results showed that the crushing extent of calcareous sand with full gradation was smaller than that a single particle group under the same test condition. Large grains are cushioned by surrounding small particles and such micro-structure reduces the probability of breakage for well-graded sands. The increasing tendency of particle crushing for calcareous sand with a rise in confining pressure and compactness is confirmed. It is also evident that a rise in water content enhances the amount of particle breakage for calcareous sand. However, varying tendency of particle breakage with grain size is still controversial and requires further examination.

Deterioration Mechanism Interpretation and Surface Contaminant Analysis of the Five-Storied Stone Pagoda in Tapriri, Uiseong (의성 탑리리 오층석탑의 표면오염물 분석 및 손상메커니즘 해석)

  • Lee, Mi Hye;Chun, Yu Gun;Lee, Myeong Seong
    • Economic and Environmental Geology
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    • v.46 no.5
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    • pp.445-453
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    • 2013
  • The Uiseong Tapriri Five-Storied Stone Pagoda (National Treasure No. 77) is typical stone cultural heritage in Unified Silla Dynasty, Korea. The pagoda has been occurred black, brown discoloration and microcrack, exfoliation, granularity decomposition with white discoloration because of continuous weathering. As the results of analysis for the contaminants, chemical weatherings are generated that black contaminant by manganese oxide, brown contaminant by iron oxide, white contaminants by gypsum and taranakite. And physical weatherings, such as microcrack, exfoliation, are occurred by salt(gypsum) crystallization. Therefore, these need to remove the contaminants according to the conservation treatment manual, and regular monitoring using P-XRF to preserve long-term the Five-Storied Stone Pagoda at Tapri-ri, Uiseong.

Mineralogical and Geochemical Characteristics of PFA (Pulverised Fuel Ash) from Yongwol Power Plant (영월 화력발전소에서 배출된 석탄회의 광물학적, 지화학적 특성)

  • Lee, Gyoo Ho;Choi, Sun Kyung;Moon, Hi-Soo;Lee, Sang Hoon
    • Economic and Environmental Geology
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    • v.30 no.5
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    • pp.443-450
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    • 1997
  • The main purpose of this study is to investigate mineralogical and chemical changes during natural weathering, and assess the mobility of major and trace elements. Yongwol power plant utilize anthracite coal which is mainly composed of illite, kaolinite, pyrophyllite and quartz in mineralogy. Coal and coal-derived fly ash samples were sampled by the electrostatic precipitator in Yongwol coal-fired power plant in Korea. Short term weathered fly ash were also collected in ash disposal mound, and two profile soil samples were taken from an ash near the power plant. Amorphous materials are the main component of the fly ash, and mullite, quartz, magnetite and heamatite are present in all coal-derived fly ash. In chemistry, Si and Al are the most abundant elements of the total content. The ash samples were fractionated into upper $90{\mu}m$ and under $45{\mu}m$ size. Finer particles show higher concentrations in metal contents including Co, Cr, Cu, Ni, V, Zn and Pb. Concentration of Zn and Pb are nearly 4 times higher concentration in the finer particles. For the profile samples, the concentrations of $SiO_2$, $Na_2O$, MgO and $K_2O$ generally show increasing trends with depth, whereas those of $Fe_2O_3$ and $TiO_2$ appear to decrease with depth. Content of MnO does not show any specific depth trend. For the trace elements, Co, Cu, Ni and V show increasing concentrations with depth.

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Forming Process of Surface Contaminants on Ten-story Stone Pagoda of Wongaksa Temple, Seoul (서울 원각사지 십층석탑의 표면오염물 형성과정)

  • Chun, Yu Gun;Lee, Myeong Seong;Kim, Yuri;Lee, Sun Myung;Lim, Bo A
    • Journal of Conservation Science
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    • v.32 no.3
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    • pp.365-375
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    • 2016
  • This study was interpreted the forming process of surface contaminants on ten-story stone pagoda of Wongaksa temple, Seoul. Results of research, we estimated that black contaminants were formed by graphite stuck carbon in air pollution substance after that gypsum was generated by chemical weathering on stone pagoda. White contaminants were built by recrystallization of calcite that were made by decomposition of finishing materials and structure on the stone surface. To preserve a long-term of stone pagoda in Wongaksa temple, there were required that continuous monitoring, anticorrosion treatment and contaminants cleaning of protective facilities.

Spatial Pedological Mapping Using a Portable X-Ray Fluorescence Spectrometer at the Tallavera Grove Vineyard, Hunter Valley

  • Jang, Ho-Jun;Minasny, Budiman;Stockmann, Uta;Malone, Brendan
    • Korean Journal of Soil Science and Fertilizer
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    • v.49 no.6
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    • pp.635-643
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    • 2016
  • Wine consumers desire to drink a high quality wine. For producing high quality wine, high quality soil is required. Conventionally, soil quality is assessed qualitatively. Using traditional laboratory methods, quantitative data can be obtained for management purpose, but it is time consuming and expensive. Therefore, new technology aims to address these limitations, namely portable X-Ray fluorescence spectrometers (pXRF). This instrument can be used directly in the field, requires no soil sample preparations, and can simultaneously measure a wide range of elements qualitatively that are useful for pedological studies. The chemical composition (Ca, Fe, Ti and Zr) of soils at Tallavera Grove vineyard in New South Wales, Australia, was studied using a pXRF. The analysis of the soil's elemental concentration (i.e. Ca and Fe) using pXRF supports management decisions. Measuring the soil's Ca concentration can be used to identify Ca-rich parent materials (limestone). The limestone indicates good soil conditions for vine production. Fe content was used to identify areas of texture-contrast soils or soil with accumulation of clays in the B horizon. In addition, a soil weathering index was calculated using elemental concentrations (i.e. Ti and Zr) to explore the history of soil formation for making decision of management. This index showed that the soil in the vineyard was affected by two processes: the deposition of materials from elsewhere (Aeolian transport or soil erosion) and mixing of materials from upslope.