• Title/Summary/Keyword: chemical water quality

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Use of Multivariate Statistical Approaches for Decoding Chemical Evolution of Groundwater near Underground Storage Caverns (다변량통계기법을 이용한 지하저장시설 주변의 지하수질 변동에 관한 연구)

  • Lee, Jeonghoon
    • Journal of the Korean earth science society
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    • v.35 no.4
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    • pp.225-236
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    • 2014
  • Multivariate statistical analyses have been extensively applied to hydrochemical measurements to analyze and interpret the data. This study examines anthropogenic factors obtained from applications of correspondence analysis (CA) and principal component analysis (PCA) to a hydrogeochemical data set. The goal was to synthesize the hydrogeochemical information using these multivariate statistical techniques by incorporating hydrogeochemical speciation results calculated by the program, commonly used, WATEQ4F included in the NETPATH. The selected case study was LPG underground storage caverns, which is located in the southeastern Korea. The highly alkaline groundwaters at this study area are an analogue for the repository system. High pH, speciation of Al and possible precipitation of calcite characterize these groundwaters. Available groundwater quality monitoring data were used to confirm these statistical models. The present study focused on understanding the hydrogeochemical attributes and establishing the changes of phase when two anthropogenic effects (i.e., disinfection activity and cement pore water) in the study area have been introduced. Comparisons made between two statistical results presented and the findings of previous investigations highlight the descriptive capabilities of PCA using calculated saturation index and CA as exploratory tools in hydrogeochemical research.

Characteristic of Cementitious Mortar Using High Volume of Recycled Fine Aggregate (순환잔골재의 다량 사용에 따른 모르타르의 특성)

  • Kim, Sang-Chel;Park, Do-Kuk;Yoog, Keun-Chang
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.3
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    • pp.235-242
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    • 2016
  • As for a possibility of using high volume of recycled aggregate in concrete mixture, recycled fine one which is known to be worse in quality and hard to control was selected and investigated in terms of performance of mortar as the replacement ratio to natural fine aggregate was changed. As a result of test, it is found that grade of recycled fine aggregate was beyond standard one and fineness modulus of that itself was increased in compare to natural one. In case of making mortar with recycled fine aggregate, disadvantageous results such as less fluidity and air content including the increase of dry shrinkage were shown but strengths of mortar were comparable to the one making with natural aggregate, which means that planned strength of common concrete structure can be achieved by controlling W/C and the amount of chemical admixture, and also that large amount of recycled fine aggregate is applicable to the precast concrete products generally free to the amount of water.

A Study on the Shelf-life of Sausages in Refrigerated Storage (냉동 온도에서 소시지의 저장 수명에 관한 연구)

  • 이용욱;김종규
    • Journal of Food Hygiene and Safety
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    • v.10 no.2
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    • pp.111-131
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    • 1995
  • Quality changes of sausages in refrierated storage for 60 days were investigated. Nine types of sausages produced in Korea were stored at 4$^{\circ}C$(3~5$^{\circ}C$), and then chemical, microbiological, and sensory characteristics were evaluated on every 10 days. The proximate analysis showed considerable variation in fat (23.97%, 17.10~30.20%) with less variation in moisture (51.96%, 48.10~56.30%) and protein (12.96%, 11.40~13.95%), pH value decreased over time averaging from 6.31 to 6.22 with no significant difference. Water activity was consistent over refrigerated storage averaging 0.95. Volatile basic nitrogen (VBN) values were still within 20 mg% though VBN for all types significantly increased over time (p<0.05). Thiobarbituric acid (TBA) values were well below 1.0 though TBA showed significant differences among storage periods (p<0.05). Standard plate counts (SPCs) significantly increased during storage (p<0.05) while coliform group was not counted in all cases. SPCs reached 104 CFU/g in two types after 50 days' storage and were below 105 CFU/g in all types after 60 days' storage. Instrumental texture analysis showed that springiness, adhesiveness, and hardness signficantly decreased over time (p<0.05) while no change was observed in external color. significantly decreased over time the 60-day storage period (p<0.05) while cohesiveness, chewiness and gumminess did not change. Lightness, redness and yellowness of the internal Hunter color significantly decreased over time (p<0.05) while no change was observed in external color. Sensory profile showed that flavor, taste, texture and overall acceptable after 60 days' storage at 4$^{\circ}C$. However, the shelf-life of the samples should be decided in the consideration of the growth rate other spoilage flora coupled with the bacterial growth after 50 days' storage.

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Characterization of Nitrate Contamination and Hydrogeochemistry of Groundwater in an Agricultural Area of Northeastern Hongseong (홍성 북동부 농촌 지역 지하수의 질산성 질소 오염과 수리지구화학적 특성)

  • Ki, Min-Gyu;Koh, Dong-Chan;Yoon, Heesung;Kim, Hyun-Su
    • Journal of Soil and Groundwater Environment
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    • v.18 no.3
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    • pp.33-51
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    • 2013
  • Spatial and temporal characteristics of nitrate contamination and hydrogeochemical parameters were investigated for springs and surficial and bedrock groundwaters in northeastern part of Hongseong. Two field investigations were conducted at dry and wet seasons in 2011 for 120 sites including measurement of field parameters with chemical analyses of major dissolved constituents. Nitrate concentrations were at background levels in springs while 45% of bedrock groundwater and 49% of surficial groundwater exceeded the drinking water standard of nitrate (10 mg/L as $NO_3$-N). The difference in nitrate concentrations between surficial and bedrock groundwater was statistically insignificant. Cumulative frequency distribution of nitrate concentrations revealed two inflection points of 2 and 16 mg/L as $NO_3$-N. Correlation analysis of hydrogeochemical parameters showed that nitrate had higher correlations with Sr, Mg, Cl, Na, and Ca, in surficial groundwater in both dry and wet season. In contrast, nitrate had much weaker correlations with other hydrogeochemical parameters in bedrock groundwater compared to surficial groundwater and had significant correlations only in wet season. Temporally, nitrate and chloride concentrations decreased and dissolved oxygen (DO) increased from dry season to wet season, which indicates that increased recharge during the wet season affected groundwater quality. Aerobic conditions were predominant for both surficial and bedrock groundwater indicating low natural attenuation potential of nitrate in the aquifers of the study area.

Nitrogen Compounds of Korea ginseng and Their Physiological Significance (고려인삼의 함질소 화합물과 생리학적 중요성)

  • Park, Hoon;Cho, Byung-Goo;Lee, Mee-Kyoung
    • Journal of Ginseng Research
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    • v.14 no.2
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    • pp.317-331
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    • 1990
  • Nitrogen compounds of Panax ginseng and their biological activities in plant and animal were reviewed. Major nitrogen combounds found in P. ginseng are free amino acids, Water soluble teins, insoluble proteins and peptides. Minor nitrogen compounds are dencichine. glycol)roteins. amines, alkaloides, methoxy or alkyl pyrazine derivatives. free nucleosides and nllrleir arid bases. 4-me- thymi-5-thiazoleethanol and pyroglutamic acid. The contents of total nitrogen and protein in root increased until 13 years old rvhich was the highest age tinder investigation. Soluble protein content increased With the root weight and was higher in xylem pith than cortex-epidermis indicating the rlosc relation with root growth. Arginine which covered 58% of total free amino aroids may serve as a storage nitrogen. Arginine seems to be changed into proline in rhizome, threonine in stem and again threoning and arginine in leaf. The greater the root weight the higher the polyaminc content. Polyamine stimulated the growth of root callus. Physiological roles of other minor nitrogen compounds are unknown although dencichine content is relatively high (0.5% d.w.). biochemical and pharmatological activities of some nitrogen compounds for animal were more investigated than physiological roll iota plant itself. Radiation and U.V. protective function (heat stable protein), insulin-like activity in lipogenesis and lipolysis (adenosine and pyroglutamic acid), depression of blood sugar content (glycopeptide). hemostatir and nellrotoxic activity (denrichine) and. sedative and hypnotic activity (4-methyl-5-thiazoleethilnol) are reported. Heat stable protein increased with root age. The traditional quality critsria appear to be well in accordance with biological activities of nitrogen compounds. Chemical stlldies of nitrogen compounds seem relatively rare, probably dole to difficulty of isolation, subsequently the investigations of biological activities are little.

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Effects of Paddy-Upland Rotation on Soil Characteristics and Crop Productivity in Rice Fields on Reclaimed Tidal land (신간척지 벼 재배 농지의 답전윤환에 따른 토양 특성 및 작물 생산성 변화)

  • Oh, Yang-Yeol;Kim, Young-Joo;Lee, Su-Hwan;Ryu, Jin-Hee;Kim, Sun;Lee, Jung-Tae;Jun, Jae-Beum;Kim, Kil-Young
    • Journal of Environmental Science International
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    • v.27 no.8
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    • pp.641-650
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    • 2018
  • Paddy-upland rotation system is one of the important cropping system for improving soil quality and crop productivity. we conducted to investigate the effect of paddy-upland rotation system on soil properties and crop productivity in reclaimed tidal land. The paddy-upland rotation could be effective to conserve soil water contents and prevent from salt damage when cultivating upland crops. The first two years of maize cultivation after rice cultivation could be effective to secure stable production. However, in case of soybean crop, the rotation effect might be lower than that of maize. In the first year, the yield of soybean was 214 kg/10a. In the second and third year, the yields of soybean decreased consecutively to 152, 123 kg/10a respectively. In this paper, it would be suggested that maize be cultivated for up to two years and soybean be cultivated for one year after rice crop grown in reclaimed tidal land. This study could be provide basic data of the physico-chemical properties applicable to paddy-upland rotation system at reclaimed tidal lands.

Preparation and Coating of Red Colored Artificial Pearl by CVD Method (CVD법을 이용한 적색 인조진주 코팅 및 제조)

  • Shin, Cheol-Woo;Choi, Kyoung-Rim;Lee, Dong-Kyu
    • Journal of the Korean Applied Science and Technology
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    • v.35 no.3
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    • pp.857-864
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    • 2018
  • Demand for developing artificial green pearl that meets the needs of modern people has been increasing. In this paper, eco-friendly inorganic pearlescent pigment was used instead of organic pigment and urethane resin was substituted for nitrocellulose which has been used as main materials in previous preparation method, increasing gloss from 73.4% to 86.7%. Urethane was coated on substrate before finishing with CVD, resulting high gloss of 96%. Colorimeteric analysis shows that a* and b* of CIE value was changed from +37.7 and +24.5 to +31.9 and +14.2 respectively because of CVD finishing, obtaining colorful, high gloss and durable artificial pearl. Quality and toxicity of samples was established by chemical resistance, glossiness, colorimeter, surface roughness, wear resistance, content of heavy-metal, and salt water test.

New Approach to Air Quality Management (대기오염관리의 새로운 접근방법)

  • 윤명조
    • Journal of environmental and Sanitary engineering
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    • v.8 no.2
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    • pp.25-48
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    • 1993
  • International concern over the environmental pollution is ever increasing, and diversified countermeasures must be devised in Korea also. Global trend, damages, problems and countermeasures with respect to issues mentioned in the Rio Declaration, such as prevention of ozone layer destruction, reduction of migratory atmospheric pollution between neighboring countries, and prevention of global greenhouse effect, were discussed in this report. Conclusion of the report is summarized as follows : A. Measurement, Planning and Monitoring (1) Development and implementation of a global network for measurement and monitoring from the global aspects such factors as related to acid rain(Pioneer substances, pH, sulfate, nitrate), effect of global temperature(Air temperature, $CO_2$, $CH_4$, CFC, $N_2O$) and destruction of ozone layer($CFC_S$). (2) Establishment of network system via satellite monitoring movement of regional air mass, damage on the ozone layer and ground temperature distribution. B. Elucidation of Present State (1) Improvement and development of devices for carbon circulation capable of accurately forecasting input and output of carbon. (2) Developmental research on chemical reactions of greenhouse gas in the air. (3) Improvement and development of global circulation model(GCM) C. Impact Assessment Impact assessment on ecosystem, human body, agriculture, floodgate, land use, coastal ecology, industries, etc. D. Preventive Measures and Technology Development (1) Development and consumption of new energy (2) Development of new technology for removal of pioneer substances (3) Development of substitute matter for $CFC_S$ (4) Improvement of agriculture and forestry means to prevent the destruction of ozone layer and the greenhouse effect of the globe (5) Improvement of housing to prevent the destruction of ozone layer and the greenhouse effect of the globe (6) Development of new technology for probing underground water (7) Preservation of forest (8) Biomass 5. Policy Development (1) Development of strategy model (2) Development of long term forecast model (3) Development of penalty charge effect and expense evaluation methods (4) Feasibility study on regulations By establishing the above mentioned measures for environmentally sound and sustainable development to establish the right to live for humankind and to preserve the one and only earth.

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A Comparative Quantitative Analysis of IDEAL (Iterative Decomposition of Water and Fat with Echo Asymmetry and Least Squares Estimation) and CHESS (Chemical Shift Selection Suppression) Technique in 3.0T Musculoskeletal MRI

  • Kim, Myoung-Hoon;Cho, Jae-Hwan;Shin, Seong-Gyu;Dong, Kyung-Rae;Chung, Woon-Kwan;Park, Tae-Hyun;Ahn, Jae-Ouk;Park, Cheol-Soo;Jang, Hyon-Chol;Kim, Yoon-Shin
    • Journal of Magnetics
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    • v.17 no.2
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    • pp.145-152
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    • 2012
  • Patients who underwent hip arthroplasty using the conventional fat suppression technique (CHESS) and a new technique (IDEAL) were compared quantitatively to assess the effectiveness and usefulness of the IDEAL technique. In 20 patients who underwent hip arthroplasty from March 2009 to December 2010, fat suppression T2 and T1 weighted images were obtained on a 3.0T MR scanner using the CHESS and IDEAL techniques. The level of distortion in the area of interest, the level of the development of susceptibility artifacts, and homogeneous fat suppression were analyzed from the acquired images. Quantitative analysis revealed the IDEAL technique to produce a lower level of image distortion caused by the development of susceptibility artifacts due to metal on the acquired images compared to the CHESS technique. Qualitative analysis of the anterior area revealed the IDEAL technique to generate fewer susceptibility artifacts than the CHESS technique but with homogeneous fat suppression. In the middle area, the IDEAL technique generated fewer susceptibility artifacts than the CHESS technique but with homogeneous fat suppression. In the posterior area, the IDEAL technique generated fewer susceptibility artifacts than the CHESS technique. Fat suppression was not statistically different, and the two techniques achieved homogeneous fat suppression. In conclusion, the IDEAL technique generated fewer susceptibility artifacts caused by metals and less image distortion than the CHESS technique. In addition, homogeneous fat suppression was feasible. In conclusion, the IDEAL technique generates high quality images, and can provide good information for diagnosis.

A Study on the Disinfection of Coliform Group in the Effluent of Sewage Plant by High Voltage Electric Field Treatment (고전압 전기장을 이용한 하수처리장 방류수 중의 대장균군 소독에 관한 연구)

  • Lee, Min-Gyu;Chung, Geun-Sik;Kam, Sang-Kyu
    • Journal of Environmental Science International
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    • v.17 no.7
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    • pp.817-826
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    • 2008
  • Using high voltage electric fields induced by high voltage AC (10-12 kV/cm, 20 kHz) and pulsed (20-30 kV/cm, 40 Hz) electric field generator as a semipermanent and environment-friendly disinfecting apparatus, the disinfection effect of coliform group in the effluent of sewage plant was investigated. The effects of electric field strength, treatment time, discharge area of a discharge tube, water quality factors (electric conductivity, pH and SS) on its death rate were examined. The death rate of coliform group was increased with increasing electric field strength and treatment time. For AC and pulsed electric field generator, the critical electric field strength was 6 kV/cm and 2 kV/cm, respectively, and the critical treatment time was 5 min and 2 min, respectively, regardless of electric field strength. Comparing the death rate of coliform group by AC and pulsed electric fields used in this study, its death rate was higher for the latter than the former, but did not increase linearly with increasing electric field strength. The results obtained for the effects of discharge area, electric conductivity, pH and SS on the death rate of coliform group using AC electric field (12 kV/cm, 20 kHz) were as follows: its death rate showed the trend to increase linearly with increasing discharge area; for the effect of electric conductivity, its death rate was increased with increasing electric conductivity, regardless of ionic species, increased with increasing cationic valency, but was similar between the same cationic valency; the pH $5{\sim}9$ used in this study did not affect its death rate; its death rate was decreased with increasing SS concentration.