• Title/Summary/Keyword: chemical water quality

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A Survey on Fish Habitat Conditions of Domestic Rivers and Construction of Its Database (국내 어류 서식환경 조사 및 데이터베이스 구축)

  • Jung, Jin-Hong;Park, Ji-Young;Yoon, Young-Han;Lim, Hyun-Man;Kim, Weon-Jae
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.3
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    • pp.221-230
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    • 2014
  • In order to restore an ecologically damaged river, freshwater fish which inhabit at the target aquatic ecosystem have a great applicability as one of the essential indicators. Although the informations about the habitat conditions of freshwater fish are key elements reflecting biological, physical, and chemical properties of the aquatic environment, because of the lack of preceding related research and insufficient database with scattered data, they have not been applied effectively for the ecological river restoration projects in Korea. To cope with these problems, based on the nation-wide detailed investigation for domestic freshwater fish habitat conditions, we have selected 70 species considering the possibility for the candidates of flagship species, constructed a database for their population, physical, and chemical habitat properties, and suggested its application methodology for the river restoration projects. In particular, the utilization of the database has been enhanced by the additional statistical analysis to present their resistance and optimum ranges for physical, and chemical habitat properties respectively. It is expected that the database constructed in this study can be utilized for the calculation and evaluation of the appropriate ecological flow rate and target water quality for the selected flagship species (fish), and the basic data for the restoration of river environment.

Chemical Properties and Nitrite Scavenging and Acetylcholinesterase Inhibitory Activities from Salicornia herbaciea Seed (함초 씨앗의 화학적 특성과 아질산염 소거능 및 아세틸콜린에스터레이스 저해 효과)

  • Lim, Geum-Sook;Kim, Ran;Jeon, Kyung-Mi;Choi, Hyun-Suk;Cho, Hoon;Koh, Ha-Young;Choi, Chang-Nam
    • KSBB Journal
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    • v.28 no.6
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    • pp.372-379
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    • 2013
  • This study was to investigate the chemical properties and nitrite scavenging and acetylcholinesterase inhibitory activities from Salicornia herbaciea seed. The lactic acid content of seed was about 2.0 fold higher than that of stem. Among various free sugars, the maximum fructose of seed, glucose of stem, and mannose contents of root were obtained, 176.3, 125.6, and 112.8 mg/100g, respectively. The maximum leucine content of seed among the essential amino acid was obtained, 853.7 mg/100g, which was about 3.0 or 6.0 folds higher than that of root or stem. In the case of glutamic acid of seed, it was 2,388.7 mg/100g, which was 5.6 or 9.8 folds higher han that of root or stem. The ratio of essential amino acid and total amino acid of seed was 30.14%. The ${\gamma}$-aminobutyric acid contents of seed, stem, and root were 43.87, 23.88, and 27.8 mg/100g, respectively. The catechin content of seed was an order of epigallocatechin (723.2 mg/100g) > epigallocatechingallate (654.3 mg/100g) > epicatechin (443.5 mg/100g) > gallocatechin (314.1 mg/100g). Especially, the non-gallated catechins content was about 2.0 folds higher than that of gallated catechins content. The nitrite scavenging activity of seed increased from 38.7 to 65.9% when the hot-water extract content of seed at pH 1.2 increased from 1.0 to 5.0 mg/mL. However, it was decreased to 25.7% at pH 6. The acetylcholinesterase inhibitory activity of seed was increased from 13.2 to 44.6% when the extract content increased from 20 to 100 mg/mL. These results show that S. herbaciea seed has a good potential to be used as a source of material or additive in cosmetics, food, and drug compositions.

Recovery of Paraffin Components from Pyrolysis Oil Fraction of Waste Plastic by Batch Cocurrent 4 Stages Equilibrium Extraction (회분 병류 4단 평형추출에 의한 폐플라스틱 열분해유 유분 중의 파라핀 성분의 회수)

  • Kang, Ho-Cheol;Shin, Sung Soon;Kim, Doo Han;Kim, Su Jin
    • Applied Chemistry for Engineering
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    • v.29 no.5
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    • pp.630-634
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    • 2018
  • The recovery of paraffin components contained in the fraction as a part of improving the quality for the fraction of waste plastics pyrolysis oil (WPPO) was investigated by batch cocurrent 4 stages equilibrium extraction. The fraction at a distilling temperature of $120-350^{\circ}C$ recovered from WPPO by the simple distillation and a little water-added dimethylformamide (DMF) solution were used as a raw material and solvent, respectively. As the number of equilibrium extraction (n) and the carbon number of paraffin component increased, the concentration of paraffin component contained in the raffinate increased. The concentrations of $C_{12}$, $C_{14}$, $C16$ and $C_{18}$ paraffin components present in the raffinate recovered at n = 4 were about 1.2, 1.5, 1.6 and 1.8 times higher than those of using the raw materials, respectively. Recovery rates (residue rates present in raffinate) of paraffin components rapidly decreased with increasing n, and increased sharply with increasing the carbon number. Furthermore, it was possible to predict the recovery rates at n = 1 - 4 for all paraffin components ($C_7-C_{24}$) contained in the raw material. The raffinate recovered through this study is expected to be used as a renewable energy.

Effect of Membrane Materials on Membrane Fouling and Membrane Washing (막의 재질에 따른 막오염 특성 및 물리·화학적 세척의 영향)

  • Shim, Hyun-Sool;Jung, Chul-Woo;Son, Hee-Jong;Sohn, In-Shik
    • Korean Chemical Engineering Research
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    • v.45 no.5
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    • pp.500-505
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    • 2007
  • The objectives of this research were to (1) identify the membrane fouling potential due to different fractions of NOM (2) correlate the physicochemical properties of NOM and membranes with the adsorption of humic substances on membrane (4) find out the effect of membrane physical and chemical washing according to membrane material. The static adsorption test and adsorption test showed that hydrophobic organics adsorbed much more quickly than hydrophilic organics. In case of the effect of membrane properties on the adsorption of organic fractions, the adsorption rate ratio(a) of hydrophobic membrane (0.016, 0.077) was greater than that of hydrophilic membrane (0.010, 0.033) regardless of the kind of organic fractions. This suggests that the UF membrane fouling were occurred mainly by internal pore size decreasing due to adsorption of organic into pore surface for hydrophobic membrane, and by sieving of organics and forming a gel layer on the membrane surface for hydrophilic membrane. In conclusion, the decrease in the pore volume, which was caused by the organic adsorption into the internal pore, was greater with the hydrophobic membrane than with the hydrophilic membrane. In case of the effect of membrane properties on permeate flux, the rate of flux decline for the hydrophobic membrane was significantly greater than that for the hydrophilic membrane.

Chemical composition and in vitro digestibility of corn stover during field exposure and the fermentation characteristics of silage prepared with microbial additives

  • Gao, Jun Lei;Wang, Peng;Zhou, Chang Hai;Li, Ping;Tang, Hong Yu;Zhang, Jia Bao;Cai, Yimin
    • Asian-Australasian Journal of Animal Sciences
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    • v.32 no.12
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    • pp.1854-1863
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    • 2019
  • Objective: To effectively use corn stover resources as animal feed, we explored the chemical composition and in vitro digestibility of corn stover during field exposure and the fermentation characteristics of silage prepared with lactic acid bacteria (LAB) and cellulase. Methods: Corn ears including the cobs and shucks were harvested at the ripe stage. The corn stover was exposed in the field under natural weather conditions. Silages were prepared after 0, 2, 4, 7, 15, 30, and 60 d of exposure. Corn stover was chopped into approximately 1 to 2 cm lengths and then packed into 5 liter plastic silos. The ensiling density was $550.1{\pm}20.0g/L$ of fresh matter, and the silos were kept at room temperature ($10^{\circ}C$ to $25^{\circ}C$). Silage treatments were designed as follows: without additives (control), with LAB, with cellulase, and with LAB+ cellulase. After 45 d of fermentation, the silos were opened for chemical composition, fermentation quality and in vitro digestion analyses. Results: After harvest, corn stover contained 78.19% moisture, 9.01% crude protein (CP) and 64.54% neutral detergent fiber (NDF) on a dry matter (DM) basis. During field exposure, the DM, NDF, and acid detergent fiber (ADF) contents of corn stover increased, whereas the CP and water-soluble carbohydrate contents and in vitro digestibility of the DM and CP decreased (p<0.05). Compared to the control silage, cellulase-treated silage had lower (p<0.05) NDF and ADF contents. The pH values were lower in silage treated with LAB, cellulase, or LAB+cellulase, and lactic acid contents were higher (p<0.05) than those of the control. Silage treated with cellulase or LAB+cellulase improved (p<0.05) the in vitro DM digestibility (IVDMD) compared to that of the control or LAB-treated silage. Conclusion: Corn stover silage should be prepared using fresh materials since stover nutrients are lost during field exposure, and LAB and cellulase can improve silage fermentation and IVDMD.

Changes in Rice Yield and Soil Properties under Continued Application of Chemical Fertilizer for 50 Years in Paddy Soil (화학비료 50년 연용에 따른 벼수량과 논토양 특성 변화)

  • Yeon, Byeong-Yeol;Kwak, Han-Kang;Song, Yo-Seong;Jun, Hee-Joong;Kim, Chong-Ho
    • Korean Journal of Soil Science and Fertilizer
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    • v.40 no.6
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    • pp.482-487
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    • 2007
  • This study was conducted to investigate the effect of long-term continuous application of fertilizers for rice cultivation. Changes of physical and chemical properties of paddy soil and the rice yield by continuous application of NPK fertilizers, ammonium sulphate, and urea over fifty years, from 1954 to 2003, were investigated. The rice yield index of each treatment were 100 of NPK plots, 84 of ammonium sulphate plots, 81 of urea plots, and 62 of no fertilizer plots. The variance of yield was large according to the quality of irrigation water. Nutrient uptakes by rice plants in ammonium sulphate and urea plots were significantly smaller than those in NPK plots; 86 and 75% in T-N, 79 and 82% in $P_2O_5$, 64 and 58% in $K_2O$, and 94 and 90% in $SiO_2$, respectively. Bulk density of soil in NPK plots significantly decreased compared to those in no fertilizer, ammonium sulphate, and urea plots, whereas CEC in NPK plots increased compared to other plots. Soil pHs of all plots were higher than that before experiment which was 5.2; 6.0 in no fertilizer, 5.9 in urea and NPK, and 5.4 in ammonium sulphate plots. The available phosphate in soil increased by $2.5mg\;kg^{-1}\;yr^{-1}$ when $70kg\;ha^{-1}$ of P fertilizer applied for rice cultivation, and decreased by $1.8mg\;kg^{-1}\;yr^{-1}$ when no P fertilizer applied.

A Study on the Possibility of Using Cement Raw Material through Chemical Composition Analysis of Pond Ash (화력 발전소 매립 석탄회의 화학성분 분석을 통한 시멘트 원료 활용 가능성 연구)

  • Lee, Jae-Seung;Noh, Sang-Kyun;Suh, Jung-Il;Shin, Hong-Chul
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.24 no.6
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    • pp.180-188
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    • 2020
  • To replace Japanese coal ash used in the domestic cement production and to recycle large quantities of domestic pond ash, it is essential to develop the technologies for quality control of cement by using the domestic pond ash. Thus, in this study, the feasibility of using the pond ash as a raw material for cement was investigated through chemical composition and microstructure analysis. As a result, most of the domestic pond ash contained slightly more Fe2O3, chloride, and unburned carbon contents than Japanese coal ash. In particular, the contents of chloride were considerably low in the pond ash that was transferred to fresh water or collected from surface of landfill area. However, since circulating fluidized bed boiler coal ash had relatively high SO3 contents causing durability problems of cement, it was not suitable for use as a raw material for cement. Thus, to replace Japanese coal ash with the domestic pond ash, it is necessary to introduce the adjustment of mixture proportion of cement raw materials and the process of removing chloride in the pond ash.

Effects of Microbial Additives and Silo Density on Chemical Compositions, Fermentation Indices, and Aerobic Stability of Whole Crop Rice Silage (미생물 첨가와 사일로 밀도가 총체벼 사일리지의 영양소 함량, 발효특성 및 호기적 안전성에 미치는 영향)

  • Joo, Young Ho;Jeong, Seung Min;Seo, Myeong Ji;Lee, Seong Shin;Choi, Ki Choon;Kim, Sam Churl
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.42 no.2
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    • pp.96-102
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    • 2022
  • The present study investigated effects of microbial additives and silo density on chemical compositions, fermentation indices, and aerobic stability of whole crop rice (WCR) silage. The WCR ("Youngwoo") was harvested at 49.7% dry matter (DM), and ensiled into 500 kg bale silo with two different compaction pressures at 430 kgf (kilogram-force)/cm2 (LOW) and 760 kgf/cm2 (HIGH) densities. All WCR forage were applied distilled water (CON) or mixed inoculants (Lactobacillus brevis 5M2 and Lactobacillus buchneri 6M1) with 1:1 ratio at 1x105 colony forming unit/g (INO). The concentrations of DM, crude protein, ether extract, crude ash, neutral detergent fiber, and acid detergent fiber of whole crop rice before ensiling were 49.7, 9.59, 2.85, 6.74, 39.7, and 21.9%, respectively. Microbial additives and silo density did not affect the chemical compositions of WCR silage (p>0.05). The INO silages had lower lactate (p<0.001), but higher propionate (p<0.001). The LOW silages had higher lactate (p=0.004). The INO silages had higher yeast count (p<0.001) and aerobic stability (p<0.001). However, microbial counts and aerobic stability were not affected by silo density. Therefore, this study concluded that fermentation quality of WCR silage improved by microbial additives, but no effects by silo density.

The effect of continuous application of the food waste composts on the paddy field environment (음식물류폐기물 활용 퇴비의 장기시용이 논 농업환경에 미치는 영향)

  • Kwon, Soon-Ik;So, Kyu-Ho;Hong, Seung-Gil;Kim, Gun-Yeob;Lee, Jeong-Taek;Seong, Ki-Seog;Kim, Kwon-Rae;Lee, Deog-Bae;Jung, Kwang-Yong
    • Journal of the Korea Organic Resources Recycling Association
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    • v.17 no.3
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    • pp.55-70
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    • 2009
  • The long-term effects and the soil environmental changes were examined to ensure the safety of food waste compost in agricultural use. Based on conventional nitrogen application rate of chemical fertilizer, Pig manure compost with $24g\;N\;kg^{-1}$, $8g\;P_2O_5\;kg^{-1}$, and $10.4g\;K_2O\;kg^{-1}$ and food waste compost with $20g\;N\;kg^{-1}$, $20.1g\;P_2O_5\;kg^{-1}$, and $6.5g\;K_2O\;kg^{-1}$ were applied to the paddy soil in $2{\times}2{\times}2m$ lysimeter in which paddy rice (Oryza sativa L. var Chucheong) were grown. The rice grown where food waste compost applied showed better growth responses than control, whereas less yield rate than chemical fertilizer applied. The contents of organic matter, nitrogen, and phosphorus after experiment were increased with compost applied. In addition, it improved soil aeration by the application of food waste compost, while little difference was observed in the quality of surface, infiltrated, and ground water compared to chemical fertilizer applied or control.

Evaluation of Treatment Efficencies of Pollutants in Juksancheon Constructed Wetlands for Treating Non-point Source Pollution (비점오염원 저감을 위한 죽산천 인공습지의 오염물질 정화효율 평가)

  • Choi, Ik-Won;Seo, Dong-Cheol;Kang, Se-Won;Lee, Sang-Gyu;Seo, Young-Jin;Lim, Byung-Jin;Park, Jong-Hwan;Kim, Kap-Soon;Heo, Jong-Soo;Cho, Ju-Sik
    • Korean Journal of Soil Science and Fertilizer
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    • v.45 no.4
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    • pp.642-648
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    • 2012
  • To evaluate the water quality in Juksancheon constructed wetlands for treating non-point source pollution, the removal rates of nutrients in water and the total amounts of T-N and T-P uptakes by water plants were investigated. Chemical characteristics of T-N and T-P in sediment were investigated. The concentrations of BOD (Biochemical Oxygen Demand), COD (Chemical Oxygen Demand), SS (Suspended Solids), T-N and T-P in inflow were 0.07~1.47, 0.60~2.65, 0.50~4.60, 1.38~6.26 and $0.08{\sim}0.32mg\;L^{-1}$, respectively. The removal rates of BOD, COD, SS, T-N, and T-P were -10, 51, 66, -3 and 5%, respectively. The maximum amount of T-N uptake by water plants in August was $368.7mg\;plant^{-1}$ in the $2^{nd}$ treatment stage by Nymphoides peltata, $1314.6mg\;plant^{-1}$ in the $3^{rd}$ treatment stage by Iris pseudacorus, $1160.4mg\;plant^{-1}$ in the $4^{th}$ treatment stage by Nymphaea tetragona GEORGI, respectively. The maximum amount of T-P uptake by water plants in August was $121.7mg\;plant^{-1}$ by Nymphoides peltata in the $2^{nd}$ treatment stage, $268.7mg\;plant^{-1}$ by Iris pseudacorus in the $3^{rd}$ treatment stage and $212.0mg\;plant^{-1}$ by Nymphaea tetragona GEORGI in the $4^{th}$ treatment stage, respectively. Organic matter contents in sediments were not different. Contents of T-N and T-P in sediments were higher in spring. Microbial biomass C:N:P ratios in sediments in spring, summer, autumn and winter were 117~140:1~4:1, 86~126:5~6:1, 68~101:2~6:1 and 47~138:2~4:1, respectively. We could conclude that Juksancheon constructed wetlands show high removal efficiencies of COD and SS. However, improvements of management in winter season should be considered to improve the removal efficiencies of pollutants.