• Title/Summary/Keyword: chemical variation

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NOx Emission Characteristics in Parametrically Varied Methane-Air Coflow Flames (메탄 분류 화염에서의 연소 조건에 따른 NOx 배출 특성)

  • Lee, Sang-Han;Oh, Chang-Bo;Lee, Chang-Eon
    • 한국연소학회:학술대회논문집
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    • 2000.05a
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    • pp.35-44
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    • 2000
  • It was numerically studied that NOx emission characteristics of confined $CH_{4}$ jet flames with the variation of the diameter of inner fuel nozzle, the flow rate of $CH_{4}$ and equivalence ratio. Parabolic type equations were adopted in the calculation and GRI-2.1I mechanism was used for the chemical reaction. NOx emission index (EINOx) was introduced to evaluate NOx emission quantitatively in parametrically varied flames and the contribution of Thermal and Prompt NO mechanism was discussed. The results showed that Total EINOx varied sensitively with the variation of the flow rate of$CH_{4}$ but it was not sensitive to the variation of the diameter of inner fuel nozzle. Thermal EINOx showed the similar tendency to total EINOx and Prompt EINOx showed insensitivity to the variation of the diameter of inner fuel nozzle and the flow rate of $CH_{4}$.

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Variation of Chemical Composition and Relative Movement of Major Elements on the Weathering of Hwang-Dung Granite (황등화강암(黃登花崗岩)의 풍화(風化)에 따른 화학조성(化學組成)의 변화(變化)와 주요원소(主要元素)의 상대적(相對的) 이동(移動))

  • Nam, Ki Sang
    • Economic and Environmental Geology
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    • v.6 no.2
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    • pp.115-122
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    • 1973
  • The writer intended to observe the relative mobility of elements in weathering process of granite, on the outskirts of IRI city at Jeollabukdo KOREA. He analysed fresh granites and weathered ones of Hwang-Dung granite mass and had following conclusions by the triangular diagrams and the oxidized variation diagrams of the analysis. 1) The increasing phenomena of $H_2O$ observed clearly in early and late stage of weathering processes. 2) Granites was weathered by physical weathering in early stage, and it was weathered by chemical weathering in late stage. 3) The ratio of $FeO/Fe_2O_3$, FeO/MgO, and $SiO_2/Al_2O_3$ decreased uniformly from early to late stage of weathering processes. 4) It was proved that weathering potential of granite was larger than that of basaltic rock. 5) The order of mobility in major elements was Ca, Na, K>Si>Mg>Fe, Al.

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Comparison of the effects of physico-chemical factors on the zonation and vertical distribution of benthic microalgal communities in the tidal flats of south-west Korea (한국 남서부 갯벌의 저서성 미세조류의 대상분포와 수직분포에 미치는 이화학적 요인의 효과에 관한 비교)

  • 이학영
    • Journal of Environmental Science International
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    • v.11 no.6
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    • pp.529-535
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    • 2002
  • Efffcts of physico-chemical factors on the zonation and vertical distribution of benthic microalgal communities in the tidal flats of Youngkwang and Canaiin, Korea, were studied. Concentrations of nutrients were low throughout the study period. A 38 species of benthic microaigae was identified. Most of the algae were pennate diatoms with small size. Cell numbers at silty sediments were higher than sandy sediments, and showed high patchy distribution. Zonal distributions of benthic microalgae showed higher variation from silty sediment than sandy sediments. Benthic microalgae showed vertical migration within the upper few mm of sediment with periodicity closely related to tidal cycles. Maximum cells were observed from 0 mm depth both sandy and silty sediments. Cells of benthic microalgae in the 1 - 2 mm depth decreased after desiccation of sediments. The variation of cells was higher at sandy sediments than silty sediments. Cell numbers of benthic microalgae showed no positive relationships with pH and nutrinets except NH$_4$-N.

Calculation of the Polarizability for Simple Molecules by the Variation Method (변분법에 의한 간단한 분자의 편극율의 계산)

  • Sangwoon Ahn
    • Journal of the Korean Chemical Society
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    • v.22 no.2
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    • pp.62-66
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    • 1978
  • The polarizability tensor components for $NH_3,\;BH_3,\;HCN,\;C_2H_4,\;PO,\;PO^-$ and CO molecules are calculated by the variation method. The parallel components of the polarizability are closer to the experimental values than those of CNDO/2, MINDO/1 and MINDO/2, but the perpendicuar components of the polarizability are not closer to the experimental values than those of the other methods.

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Physical Characteristics of PECVD SiON Films with Composition Variation (조성변화에 따른 PECVD SiON 박막의 물성특성)

  • Cho Yu Jung;Han Kil Jin;Kim Yeong Cheol;Seo Hwa Il
    • Journal of the Semiconductor & Display Technology
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    • v.4 no.3 s.12
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    • pp.1-4
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    • 2005
  • Silicon oxynitride films were deposited using ammonia as a nitrogen source via PECVD (plasma enhanced chemical vapor deposition) to study the physical properties of the films. Silane and nitrous oxide were used as silicon and oxygen sources, respectively. The composition of the silicon oxynitride films was well controlled by changing the ratios of the sources and confirmed by XPS. The silicon oxynitride films with high oxygen content showed bigger compressive stress and less refractive index, while the values of surface roughness were around 1 nm, irrespective of the variation of the source ratios.

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Treatment Characteristics of Wastewater with Flow Rate Variation in Anaerobic-Aerobic Activated Sludge Process

  • Lee Min-Gyu;Suh Kuen-Hack;Hano Tadashi
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.1 no.1
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    • pp.11-17
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    • 1997
  • The treatment performances of anaerobic-aerobic activated sludge process were investigated under various operation conditions. The treatment system proposed in this study gave a relatively stable performance against hourly change of the flow rate and showed a satisfactory removal efficiency of nitrogen and phosphorus compounds under experimental conditions. The average removal efficiency of total nitrogen gradually decreased as the influent total nitrogen concentration was increased. High C/N ratio of the wastewater was required for the complete removal of nitrogen. Glucose as a carbon source was more efficient than starch and the removal ability for all components become higher with the increase of the fraction of glucose.

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Adsorption of Ammonia on Municipal Solid Waste Incinerator Bottom Ash Under the Landfill Circumstance

  • Yao, Jun;Kong, Qingna;Zhu, Huayue;Zhang, Zhen;Long, Yuyang;Shen, Dongsheng
    • Korean Chemical Engineering Research
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    • v.53 no.4
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    • pp.503-508
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    • 2015
  • The adsorption characteristics of ammonia on MSWI bottom ash were investigated. The effect of the variation of the landfill environmental parameters including pH, anions and organic matter on the adsorption process was discussed. Results showed that the adsorption could be well described by pseudo-second-order kinetics and Langmuir model, with a maximum adsorption capacity of 156.2 mg/g. The optimum adsorption of ammonia was observed when the pH was 6.0. High level of ion and organic matter could restrict the adsorption to a low level. The above results suggested that MSWI bottom ash could affect the migration of ammonia in the landfill, which is related to the variation of the landfill circumstance.

Development and Application of Crown Ether-based HPLC Chiral Stationary Phases

  • Hyun, Myung-Ho
    • Bulletin of the Korean Chemical Society
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    • v.26 no.8
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    • pp.1153-1163
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    • 2005
  • Crown ether-based HPLC chiral stationary phases (CSPs) have been successfully utilized in the resolution of various racemic compounds containing a primary amino group. Especially, CSPs based on chiral crown ethers incorporating chiral binaphthyl unit or tartaric acid unit and based on phenolic pseudo chiral crown ethers have shown high chiral recognition efficiency. In this account paper, a review on the development of crown etherbased HPLC CSPs, their structural characteristics and applications to the resolution of racemic compounds including chiral drugs containing a primary or secondary amino group with the variation of the type and the content of mobile phase components and with the variation of the column temperature is presented.

Extraction Rate and Temperature Dependency of Distribution Ratio of 4f and 5f Series Element in the Various Phosphorus Compounds (各種 燐化合物溶媒 抽出系에 있어서 4f 및 5f 系列 元素의 抽出速度 및 分配率의 溫度依存性)

  • Rhee, Chin-Taik
    • Journal of the Korean Chemical Society
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    • v.13 no.3
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    • pp.199-204
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    • 1969
  • The distribution rate of 4f and 5f series elements in chelate and ion association extraction system was studied. Clear difference between lighter and heavier part of 4f series are observed. Trivalent Am and Cm were appeared to be grouped into the lighter part of 4f series. And also the variation of distribution ratio according to the varied temperature was studied. The variation modes of distribution ratio are different according to the extraction system. Atomic number dependence in the chelate extraction system was observed.

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Treatment Characteristics of Wastewater with Flow Rate Variation in Anaerobic-Aerobic Activated Sludge Process

  • Min-Gyu Lee;Kue
    • Journal of Environmental Science International
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    • v.1 no.1
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    • pp.11-17
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    • 1992
  • The treatment performances of anaerobic-aerobic activated sludge Process were investigated under various operation conditions. The treatment system proposed in this study gave a relatively stable performance against hourly change of the flow rate and showed a satisfactory removal efficiency of nitrogen and phosphorus compounds under experimental conditions. The average removal efficiency of total nitrogen gradually decreased as the influent total nitrogen concentration was increased. High C/N ratio of the wastewater was required for the complete removal of nitrogen. Glucose as a carbon source was more efficient than starch and the removal ability for all components become hither with the increase of the fraction of glucose.

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