• Title/Summary/Keyword: chemical testing

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Application Effect of Organic Fertilizer and Chemical Fertilizer on the Watermelon Growth and Soil Chemical Properties in Greenhouse (유기질비료와 화학비료의 시용수준에 따른 시설수박 생육과 토양화학성의 변화)

  • Uhm, Mi-Jeong;Noh, Jae-Jong;Chon, Hyong-Gwon;Kwon, Sung-Whan;Song, Young-Ju
    • Korean Journal of Environmental Agriculture
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    • v.31 no.1
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    • pp.1-8
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    • 2012
  • BACKGROUND: Organic fertilizers in watermelon cultivation are widely used to supply nutrient and organic matter. This study was conducted to investigate the effects of application rate of organic fertilizer on the watermelon growth and soil chemical properties in greenhouse METHODS AND RESULTS: The organic fertilizers used in this experiment were mixed expeller cake (MEC) and mixed organic fertilizer (MOF). The treatments were conducted with 4 levels (1.0 N, 0.7 N, 0.5 N and 0.3 N) on the basis of soil testing nitrogen fertilization (STNF) using MEC or MOF as the basal dressing, and using chemical fertilizers (CF) as the additional dressing on the rest of STNF. These fertilizations were compared to CF 1.0 N (0.3 N as the basal and 0.7 N as the additional dressing) and non fertilization (NF). The leaf area of watermelon in treatment 0.5 N and 0.3 N using MEC or MOF was similar to CF treatment. The absorbed nutrient amounts by leaf, weight and sugar contents of fruit in the 0.5 N and 0.3 N treatments were higher than other treatments. In 0.5 N and 0.3 N treatments using MEC or MOF on the basis of STNF, soil chemical properties such as electrical conductivity (EC), available $P_2O_5$ and exchangeable K concentrations after experiment showed tendency to decreasing or similar level before experiment. CONCLUSION(s): These results suggest that the MEC or MOF application as the basal dressing at the 30~50% level of STNF and CF application as the additional dressing on the rest of STNF be best to maintain adequate nutrient of soil and to increase marketable yield for watermelon.

The Thermal Properties Analysis of the Mixtures Composed with Epoxy Resin and Amine Curing Agent (에폭시 수지/방향족 아민 경화물의 배합비 변화에 따른 열적 특성 분석)

  • Kim, Daeyeon;Kim, Soonchoen;Park, Young-Il;Kim, Young Chul;Lim, Choong-Sun
    • Journal of Adhesion and Interface
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    • v.15 no.3
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    • pp.100-108
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    • 2014
  • In this work, a series of molar ratios composed with YD-128 and DDM were chosen based on the viscosity analysis. The mixtures of YD-128 and DDM with the different molar ratios were cured at $170^{\circ}C$ for 15 min followed by post cure at $190^{\circ}C$ for two hours. The thermal properties of the cured samples were investigated with DSC, TGA, DMA, and TMA. The conversion ratio of the mixtures of YD-128 and DDM (1 : 1.1) was calculated by dividing ${\Delta}H$ obtained from DSC experiments for each cured sample by ${\Delta}H$. The TGA data of the cured samples showed that the thermal stability and thermal degradation activation energy were proportional to the amount of DDM in the mixtures. However, the highest tan ${\delta}$, and the lowest thermal expansion data with DMA and TMA respectively were obtained from the stoichiometric mixture of YD-128 and DDM. Furthermore, the different ratio of mixtures were applied to test specimens to be cured at $170^{\circ}C$ to measure single lap shear strength with universal testing machine.

Thermal and Mechanical Properties of Epoxy Composites Using Silica Powder (실리카 파우더를 이용한 에폭시 복합소재의 열적/기계적 특성)

  • Lee, Hye Ryeon;Song, JeeHye;Kim, Daeyeon;Lim, Choong-Sun;Seo, BongKuk
    • Journal of Adhesion and Interface
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    • v.17 no.1
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    • pp.7-14
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    • 2016
  • Epoxy composites with concentrations of 5-70 wt% of silica particles were prepared in order to improve mechanical property and poor thermal stability. The mechanical and thermal properties were investigated and compared to the corresponding properties of neat epoxy composite. Furthermore, the effects of silane compound treatment on silica particles were observed by the experimental results of the tensile strength, glass transition temperature, and thermal stability of epoxy composite. Tensile strength of epoxy composites was measured by universal testing machine (UTM) and after that, the structure and morphology analysis of epoxy nanocomposites were analyzed by field emission scanning electron microscope (FE-SEM) and energy dispersive spectroscopy (EDS). The increased solid content of CA0030 particle improved the tensile strength of epoxy/ modified composites to give 30-50 MPa. The thermal expansion coefficients (CTE) of neat epoxy resin and epoxy/silica composites measured with a thermomechanical analyzer (TMA) showed that the incorporation of silica particles was helpful to reduce the CTE of neat epoxy resin.

Combustion of Diesel Particulate Matters under Mixed Catalyst System of Fuel-Borne Catalyst and Perovskite: Influence of Composition of Perovskite (La1-x A'xBO3: A' = K, Sr; 0 ≤ x ≤ 1; B = Fe, Cr, Mn) on Combustion Activity (Fuel-Borne Catalyst와 Perovskite로 구성된 복합촉매 시스템에 의한 디젤 탄소입자상 물질의 연소반응: 반응성능과 Perovskite 촉매조성 (La1-x A'xBO3: A' = K, Sr; 0 ≤ x ≤ 1; B = Fe, Cr, Mn)의 상관관계)

  • Lee, Dae-Won;Sung, Ju Young;Lee, Kwan-Young
    • Korean Chemical Engineering Research
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    • v.56 no.2
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    • pp.281-290
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    • 2018
  • As the internal combustion engine vehicles of high fuel efficiency and low emission are demanded, it becomes important to procure technologies for improving low-temperature performance of automotive catalyst systems. In this study, we showed that the combustion rate of diesel particulate matter is greatly enhanced at low temperature by applying fuel-borne catalyst and perovskite catalyst concurrently. It was tried to examine the correlation between elemental composition of perovskite catalyst and combustion activity of mixed catalyst system. To achieve this goal, we applied temperature-programmed oxidation technique in testing the combustion behavior of perovskite-mixed particulate matter bed which contained the element of fuel-borne catalyst or not. We tried to explain the synergetic action of two catalyst components by comparing the trends of concentrations of carbon dioxide and nitrogen oxide in temperature-programmed oxidation results.

Development of an Efficient Bioassay Method for Testing Resistance to Bacterial Soft Rot of Radish (효과적인 무 무름병 저항성 검정법 개발)

  • Lee, Soo Min;Choi, Yong Ho;Jang, Kyoung Soo;Kim, Hun;Lee, Seon-Woo;Choi, Gyung Ja
    • Research in Plant Disease
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    • v.24 no.3
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    • pp.193-201
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    • 2018
  • Pectobacterium carotovorum subsp. carotovorum (Pcc) causes bacterial soft rot on a wide range of crops worldwide, especially in countries with warm and humid climates. This study was conducted to establish an efficient screening method for resistant cultivars of radish (Raphanus sativus) to bacterial soft rot. Resistance degrees of 60 commercial radish cultivars to the Pcc KACC 10421 isolate were investigated. For further study, six radish cultivars (Awooriwoldong, YR Championyeolmu, Jeonmuhumu, Bitgoeunyeolmu, Sunbongaltari, Housecheongok) showing different level of resistance to the bacterium were selected. The development of bacterial soft rot on the cultivars was tested according to several conditions such as incubation temperature, seedling stage of radish, inoculum concentration to develop the disease. On the basis of the results, we suggest that an efficient screening method for resistant radish to Pcc is to inoculate twenty-day-old seedlings with a bacterial suspension of Pcc at a concentration of $8{\times}10^5cfu/ml$ and then to cultivate the plants in a growth room at $25^{\circ}C$ and 80% RH with 12-hour light per day.

Preparation and characterization of high density polyethylene/silane treated pulverized-phenol resin composites (고밀도 폴리에틸렌과 실란 처리된 분쇄페놀수지 복합재의 제조 및 특성)

  • Park, Jun-Seo;Han, Chang-Gue;Nam, Byeong-Uk
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.9
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    • pp.27-33
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    • 2016
  • Phenolic resin has excellent heat resistance and good mechanical properties as a thermosetting resin. However, its thermosetting characteristics cause it to produce a non-recyclable waste in the form of sprue and runner which is discarded and represents up to 15~20% of the overall products. Forty thousand tons of phenolic resin sprue and runner are disposed of (annually). The (annual) cost of such domestic waste disposal is calculated to be 20 billion won. In this study, discarded phenol resin scraps were pulverized and treated by silanes to improve their interfacial adhesion with HDPE. The sizes of the pulverized pulverulent bodies and fine particles were (100um~1000um) and (1~100um), respectively. The pulverized phenol resin was treated with 3-(methacryloyloxy) propyltrimethoxysilane and vinyltrimethoxy silane and the changes in its characteristics were evaluated. The thermal properties were evaluated by DSC and HDT. The mechanical properties were assessed by a notched Izod impact strength tester. When the silane treated phenol resin was added, the heat distortion temperature of HDPE increased from $77^{\circ}C$ to $96^{\circ}C$ and its crystallinity and crystallization temperature also increased. Finally, its impact strength and tensile strength increased by 20% and 50%, respectively, in comparison with the non-treated phenol resin.

Status and Change in Chemical Properties of Polytunnel Soil in Korea from 2000 to 2012

  • Kang, Seong Soo;Roh, Ahn Sung;Choi, Seung Chul;Kim, Young Sang;Kim, Hyun Ju;Choi, Moon Tae;Ahn, Byoung Gu;Kim, Hee Kwon;Park, Sang Jo;Lee, Young Han;Yang, Sang Ho;Ryu, Jong Soo;Sohn, Yeon Gyu;Kim, Myeong Sook;Kong, Myung Suk;Lee, Chang Hoon;Lee, Deog Bae;Kim, Yoo Hak
    • Korean Journal of Soil Science and Fertilizer
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    • v.46 no.6
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    • pp.641-646
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    • 2013
  • Chemical properties of agricultural soils in Korea have been investigated at four-year interval in order of paddy, polytunnel, upland, and orchard soils since 1999; polytunnel soils were investigated over the whole country in 2000, 2004, 2008, and 2012. Polytunnel soils were taken from the surface (0-15 cm) and subsurface (15-30 cm) at 2,651, 1,274, 1,374 and 1,374 sites in all provinces of South Korea. One hundred sampling sites located in more than 400 m altitude were additionally investigated in 2008 and 2012. Average of soil chemical properties in 2012 except Jeju province were 6.6 for pH, 3.2 dS $m^{-1}$ for EC, 37 g $kg^{-1}$ for organic matter (OM), 1,049 mg $kg^{-1}$ for available (Avail.) phosphate, 1.58 $cmol_c\;kg^{-1}$ for exchangeable (Exch.) K, 10.6 $cmol_c\;kg^{-1}$ for Exch. Ca, and 3.3 $cmol_c\;kg^{-1}$ for Exch. Mg. Except pH, averages of all chemical properties exceeded the upper limit of optimal range. The median values except pH showed a lower value than the averages. The pH, OM and Exch. Ca had slightly increased from 6.3 to 6.6, from 34 to 37 g $kg^{-1}$, and from 7.7 in 2000 to 10.6 $cmol_c\;kg^{-1}$ in 2012, respectively. The order of sample ratios exceeding the optimal range were Avail. $P_2O_5$ (83%) > Exch. Ca (80%) > Exch. K (70%) > Exch. Mg (65%) > EC (55%) > OM (48%) > pH (29%) in 2012. The order of sample ratios below the optimal range was OM (25%) > Exch. K (25%) > pH (20%), Exch. Mg and Avail. $P_2O_5$ (9%) > Exch. Ca (6%) in 2012. The excessive proportion of pH, Exch. Ca, Exch. Mg and OM slightly increased, while the insufficient proportion of those decreased. Approximately 55% of polytunnel soils exceeding EC 2 dS $m^{-1}$ was evaluated with salt accumulated soils having the risk of growth disorder of crops. Nutrient contents in polytunnel soils in Korea showed high level especially Avail. $P_2O_5$ and Exch. cations. Therefore, recommended fertilization based on soil testing or plant testing is needed for soil nutrient management.

A Study on Salt Removal in Controlled Cultivation Soil Using Electrokinetic Technology (전기동력학 기술을 이용한 시설재배지 토양의 염류제거 효과연구)

  • Kim, Lee Yul;Choi, Jeong Hee;Lee, You Jin;Hong, Soon Dal;Bae, Jeong Hyo;Baek, Ki Tae
    • Korean Journal of Soil Science and Fertilizer
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    • v.45 no.6
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    • pp.1230-1236
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    • 2012
  • To verify that the electrokinetic remediation is effective for decreasing salinity of fields of the plastic-film house, field tests for physical property, chemical property, and crop productivity of soils have been conducted. The abridged result of those tests is as follows. In the EK treatment, the electrokinetic remediation has been treated at the constant voltage (about 0.8 V $cm^{-1}$) for fields of the farm household. At this time, an alternating current (AC) 220 V of the farm household was transformed a direct current. The HSCI (High Silicon Cast Iron) that the length of the stick for a cation is 20cm, and the Fe Plate for an anion have been spread out on the ground. As the PVC pipe that is 10 cm in diameter was laid in the bottom of soils, cations descend on the cathode were discharged together. For soil physical properties according to the EK treatment, the destruction effect of soil aggregate was large, and the infiltration rate of water was increased. However, variations of bulk density and porosity were not considerable. Meanwhile, in chemical properties of soils, principal ions of such as EC, $NO_3{^-}$-N, $K^+$, and $Na^+$ were better rapidly reduced in the EK treated control plot than in the untreated control plot. And properties such as pH, $P_2O_5$ and $Ca^{2+}$ had a small impact on the EK. For cropping season of crop cultivation according to the EK treatment, decreasing rates of chemical properties of soils were as follows; $NO_3{^-}$-N 78.3% > $K^+$ 72.3% > EC 71.6% $$\geq_-$$ $Na^+$ 71.5% > $Mg^{2+}$ 36.8%. As results of comparing the experimental plot that EK was treated before crop cultivation with it that EK was treated during crop cultivation, the decreasing effect of chemical properties was higher in the case that EK was treated during crop cultivation. After the EK treatment, treatment effects were distinct for $NO_3{^-}$-N and EC that a decrease of nutrients is clear. However, because the lasting effect of decreasing salinity were not distinct for the single EK treatment, fertilization for soil testing was desirable carrying on testing for chemical properties of soils after EK treatments more than two times. In the growth of cabbages according to the EK treatment, the rate of yield increase was 225.5% for the primary treatment, 181.0% for the secondary treatment, and 124.2% for third treatment compared with the untreated control plot. The yield was increased by a factor of 130.0% for the hot pepper at the primary treatment (Apr. 2011), 248.1% for the lettuce at the secondary treatment (Nov.2011), and 125.4% for the young radish at the third treatment (Jul. 2012). In conclusion, the effect of yield increase was accepted officially for all announced crops.

The Physical and Thermal Properties Analysis of the VOC Free Composites Comprised of Epoxy Resin, and Dicyandiamide (VOC Free Epoxy Resin/Dicyandiamide 경화물의 배합비 변화에 따른 물리적 특성 및 열적특성 분석)

  • Kim, Daeyeon;Kim, Soonchoen;Park, Young IL;Kim, Young Chul;Lim, Choong-Sun
    • Clean Technology
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    • v.21 no.1
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    • pp.76-82
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    • 2015
  • Volatile organic compounds (VOC) free adhesives have been interested by many scientists and engineers due to environmental regulations and the safety of industrial workers. In this work, a series of composites composed with bisphenol A epoxy resin used as solvent, dicyandiamide, and promoter were prepared to investigate the most appropriate molar ratio for steel-steel adhesion. The cured test specimen of each composite were measured with universal testing machine (UTM) to figure out mechanical properties such as tensile strength, Young’s modulus, and elongation. Furthermore, the lap shear strength of the specimen was tested with UTM while impact resistance was measured with Izod impact tester. The composite whose molar ratio of epoxy resin to curing agent is 1 : 0.9 (sample 3), showed better tensile strength, coefficient of elastic modulus, elongation, and impact strength than other composites did. The highest tanδ from dynamic mechanical analysis (DMA) was observed from sample 2 (epoxy resin: dicy = 1 : 0.7) while sample 3 showed slightly lower tanδ than that of 2. The morphology of the fracture surface of the cured composites from SEM showed that the number of subtle lines on the surface caused by impact increase as the contents of amine curing agent accrete. Furthermore, the viscosity change of sample 5 (epoxy resin: dicy = 1 : 1.3) was observed to confirm its storage stability.

Determination of Nitrogen Fertilizer Recommendation Rates Estimated by Soil-Testing for Different Types of Paddy Soils (토양검정에 의한 논토양 유형별 질소시비량 결정)

  • Moon, Young-Hun;Kwon, Young-Rip;Ahn, Byung-Koo;Lee, Jin-Ho;Choi, Dong-Chil
    • Korean Journal of Environmental Agriculture
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    • v.29 no.1
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    • pp.33-38
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    • 2010
  • To improve the existing nitrogen recommendation method based on chemical properties of soils and to establish new recommendation rates of nitrogen fertilizer due to different types of soils, the application rates of nitrogen fertilizer were examined in different soils of 12 experimental rice paddy fields. The application rates of nitrogen fertilizer estimated by soil-testing were higher than the rates of nitrogen standard recommendation that has been used. The application rates for minimum rice productivity ranged from a low of 168 kg/10a in sandy soil to a high of 315 kg/10a in saline soil. Amounts of nitrogen absorption in rice were proportional to the application amounts of nitrogen fertilizer in soils. Nitrogen use efficiency was the highest, 36.7%, in immatured paddy field and it was inversely proportional to the application amounts of nitrogen. the rice tasty value was the highest in the soils without nitrogen application, and also it was the lowest in the saline soils with or without nitrogen application. As comparing with the nitrogen application rates obtained by the existing nitrogen recommendation method, optimal nitrogen application rates estimated by the standardization of nitrogen application efficiency rate, environmental index, and rice quality were 1.0 fold in the well adapted soil and sandy soil fields, 0.92 fold in the immatured soil field, and 0.83 fold in the saline soil field.