• Title/Summary/Keyword: chemical testing

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High-temperature Structural Analysis of Small-scale Prototype of Process Heat Exchanger (III) (공정열교환기 소형 시제품에 대한 고온구조해석(III))

  • Song, Kee-Nam;Lee, Heong-Yeon;Kim, Chan-Soo;Hong, Seong-Duk;Park, Hong-Yoon
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.35 no.2
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    • pp.191-200
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    • 2011
  • A PHE (Process Heat Exchanger) is a key component of nuclear hydrogen system for massive production of hydrogen; the PHE transfers the very high temperature heat ($950^{\circ}C$) generated from the VHTR (Very High Temperature Reactor) to a chemical reaction. The Korea Atomic Energy Research Institute developed a small-scale gas loop for testing the performance of VHTR components and manufactured a modified PHE prototype for carrying out the testing in the gas loop. In this study, as a part of the evaluation of the high-temperature structural integrity of the modified PHE prototype which is scheduled to test in the gas loop, we carried out high-temperature structural analysis modeling, macroscopic thermal and structural analysis of the PHE prototype under the gas loop test conditions as a precedent study before carrying out the performance test in the gas loop. The results obtained in this study will be used to design the performance test setup for the modified PHE prototype.

EFFECTS OF SURFACE TREATMENT AND BONDING AGENTS ON SHEAR BOND STRENGTH OF THE COMPOSITE RESION TO IPS-EMPRESS CERAMIC (IPS-Empress 도재에 대한 콤포짓트 레진의 전단결합강도)

  • Yoon, Byeung-Sik;Im, Mi-Kyung;Lee, Yong-Keun
    • Restorative Dentistry and Endodontics
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    • v.23 no.1
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    • pp.413-423
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    • 1998
  • Dental ceramics exhibit excellent esthetic property, compressive strength, chemical durability, biocompatibility and translucency. This study evaluated the shear bond strength of composite resin to the new heat-pressed ceramic material (IPS-Empress System) depending on the surface treatments and bonding agents. The surface treatments were etching with 4.0% hydrofluoric acid, application of silane, and the combination of the two methods. Composite resin was bonded to ceramic with four kinds of dentin bonding agents(All-Bond 2, Heliobond, Scotch bond Multi-purpose and Tenure bonding agents). The ceramic specimen bonded with composite resin was mounted in the testing jig, and the universal testing machine(Zwick 020, Germany) was used to measure the shear bond strength with the cross head speed of 0.5 mm/min. The results obtained were as follows 1. The mean shear bond strength of the specimens of which the ceramic surface was treated with the combination of hydrofluoric acid and silane before bonding composite resin was significantly higher than those of the other surface treatment groups(p<0.05). 2. In the case of All-Bond 2 and Scotchbond Multi-purpose bonding agent group, the surface treatment methods did not influenced significantly on the shear bond(p>0.05). 3. Of the four bonding agents tested, the shear bond strength of Heliobond was significantly lower than those of other bonding agents regardless of the surface treatment methods(p<0.05). 4. The highest shear bond strength($12.55{\pm}1.92$ MPa) was obtained with Scotchbond Multipurpose preceded by the ceramic surface treatment with the combination of 4% hydrofluoric acid and silane.

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Characterization of Partial Interfacial Fracture on Resistance Spot-Welded TRIP Steels for Automotive Applications (자동차 차체용 TRIP강판의 저항 점용접부 Partial Interfacial Fracture 특성에 관한 연구)

  • Choi, Chul Young;Kim, In-Bae;Kim, Yangdo;Park, Yeong-Do
    • Korean Journal of Metals and Materials
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    • v.50 no.2
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    • pp.136-145
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    • 2012
  • Resistance spot welding of TRIP780 steels was investigated to enhance understanding of weld fracture mode after tensile shear testing (TST) and L-shape tensile testing (LTT). The main failure mode for spot welds of TRIP780 steels was partial interfacial fracture (PIF). Although PIF does not satisfy the minimum button diameter (4${\surd}$t) for acceptable welds, it shows enough load carrying capacity of resistance spot welds for advanced high strength steels. In the analysis of displacement controlled L-shape tensile test results, cracks initiated at the notch of the faying surface and propagated through the interface of weldments, and finally, cracks change path into the sheet thickness direction. Use of the ductility ratio and CE analysis suggested that the occurrence of PIF is closely related to high hardness and brittle welds, which are caused by fast cooling rates and high chemical compositions of TRIP steels. Analysis of the hold time and weld time in a welding schedule demonstrated that careful control of the cooling rate and the size of a weld nugget and the HAZ zone can reduce the occurrence of PIF, which leads to sound welds with button fractures (BFs).

A comparison of metabolomic changes in type-1 diabetic C57BL/6N mice originating from different sources

  • Lee, Seunghyun;Kwak, Jae-Hwan;Kim, Sou Hyun;Yun, Jieun;Cho, Joon-Yong;Kim, Kilsoo;Hwang, Daeyeon;Jung, Young-Suk
    • Laboraroty Animal Research
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    • v.34 no.4
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    • pp.232-238
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    • 2018
  • Animal models have been used to elucidate the pathophysiology of varying diseases and to provide insight into potential targets for therapeutic intervention. Although alternatives to animal testing have been proposed to help overcome potential drawbacks related to animal experiments and avoid ethical issues, their use remains vital for the testing of new drug candidates and to identify the most effective strategies for therapeutic intervention. Particularly, the study of metabolic diseases requires the use of animal models to monitor whole-body physiology. In line with this, the National Institute of Food and Drug Safety Evaluation (NIFDS) in Korea has established their own animal strains to help evaluate both efficacy and safety during new drug development. The objective of this study was to characterize the response of C57BL/6NKorl mice from the NIFDS compared with that of other mice originating from the USA and Japan in a chemical-induced diabetic condition. Multiple low-dose treatments with streptozotocin were used to generate a type-1 diabetic animal model which is closely linked to the known clinical pathology of this disease. There were no significantly different responses observed between the varying streptozotocin-induced type-1 diabetic models tested in this study. When comparing control and diabetic mice, increases in liver weight and disturbances in serum amino acids levels of diabetic mice were most remarkable. Although the relationship between type-1 diabetes and BCAA has not been elucidated in this study, the results, which reveal a characteristic increase in diabetic mice of all origins are considered worthy of further study.

Historical Trends of Micromechanical Testing Methods for Structural Fiber Reinforced Composites to Evaluate the Interfacial Adhesion (구조용 섬유강화복합재료의 계면접착 특성 평가를 위한 미세역학시험법의 연구동향 고찰)

  • Park, Joung-Man;Kim, Jong-Hyun;Kim, Dong-Uk;Kwon, Dong-Jun
    • Journal of Adhesion and Interface
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    • v.23 no.3
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    • pp.59-69
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    • 2022
  • In composite materials, the adhesion and interfacial properties were the most important factors to obtain high performance of mechanical properties. This review paper had been focused on the micromechanical evaluation methods for the interfacial property historically. The interfacial property of fiber-reinforced composites (FRC) could be evaluated using only a single fiber and matrix via various micromechanical testing methods. Self-sensing due to the fracture behavior of FRC could be determined and discussed more critically and clearly using electro-micromechanical evaluation. In this paper, the research trends for micro-mechanical evaluation of composites was summarized, and their practical applications would be suggested in the future.

Analysis of CTOD Tests on Steels for Liquefied Hydrogen Storage Systems Using Hydrogen Charging Apparatus (수소 장입 장치를 활용한 액체수소 저장시스템 강재의 CTOD 시험 분석)

  • Ki-Young Sung;Jeong-Hyeon Kim;Jung-Hee Lee;Jung-Won Lee
    • Journal of the Korean Society of Industry Convergence
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    • v.26 no.5
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    • pp.875-884
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    • 2023
  • Hydrogen infiltration into metals has been reported to induce alterations in their mechanical properties under load. In this study, we conducted CTOD (Crack Tip Opening Displacement) tests on steel specimens designed for use in liquid hydrogen storage systems. Electrochemical hydrogen charging was performed using both FCC series austenitic stainless steel and BCC series structural steel specimens, while CTOD testing was carried out using a 500kN-class material testing machine. Results indicate a notable divergence in behavior: SS400 test samples exhibited a higher susceptibility to failure compared to austenitic stainless steel counterparts, whereas SUS 316L test samples displayed minimal changes in displacement and maximum load due to hydrogen charging. However, SEM (Scanning Electron Microscopy) analysis results presented challenges in clearly explaining the mechanical degradation phenomenon in the tested materials. This study's resultant database holds significant promise for enhancing the safety design of liquid hydrogen storage systems, providing invaluable insights into the performance of various steel alloys under the influence of hydrogen embrittlement.

Physical and Mechanical Properties of Light Red Meranti Treated with Boron Preservatives

  • Man Djun LEE;Ridge Wei Cheong TANG;Zeno MICHAEL;Miqdad KHAIRULMAINI;Azmi ROSLAN;Ahmad Faidzal KHODORI;Hazim SHARUDIN;Pui San LEE
    • Journal of the Korean Wood Science and Technology
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    • v.52 no.2
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    • pp.157-174
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    • 2024
  • This study investigates the influence of varying concentrations of boric acid (BA) preservative on the physical and mechanical properties of light red meranti (LRM) found in Sarawak. LRM or Shorea leprosula samples were treated with various concentrations of BA via the dip diffusion method using American Society for Testing and Materials (ASTM) standards. The physical property, particularly the retention rate and mechanical properties, bending strength, modulus of elasticity (MOE), tensile and compression strength parallel to grain of impregnated and control samples were tested to determine the effects of BA preservative. The retention rate was found to increase with increasing BA concentration and higher surface area to volume ratio. The mechanical properties in terms of the MOE and tensile strength parallel to grain were found to be greater than those of the control samples, whereas the bending strength and tensile strength parallel to grain were lower. Amongst the results, only the retention rate and MOE showed significant interaction effects at 5% level of significance between all factors tested (samples size and BA concentration for retention rate and BA concentration for MOE).

Toxicity prediction of chemicals using OECD test guideline data with graph-based deep learning models (OECD TG데이터를 이용한 그래프 기반 딥러닝 모델 분자 특성 예측)

  • Daehwan Hwang;Changwon Lim
    • The Korean Journal of Applied Statistics
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    • v.37 no.3
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    • pp.355-380
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    • 2024
  • In this paper, we compare the performance of graph-based deep learning models using OECD test guideline (TG) data. OECD TG are a unique tool for assessing the potential effects of chemicals on health and environment. but many guidelines include animal testing. Animal testing is time-consuming and expensive, and has ethical issues, so methods to find or minimize alternatives are being studied. Deep learning is used in various fields using chemicals including toxicity prediciton, and research on graph-based models is particularly active. Our goal is to compare the performance of graph-based deep learning models on OECD TG data to find the best performance model on there. We collected the results of OECD TG from the website eChemportal.org operated by the OECD, and chemicals that were impossible or inappropriate to learn were removed through pre-processing. The toxicity prediction performance of five graph-based models was compared using the collected OECD TG data and MoleculeNet data, a benchmark dataset for predicting chemical properties.

Retention Time Prediction form Molecular Structure of Sulfur Compounds by Gas Chromatography (기체크로마토그래피에서 황화합물의 구조를 통한 용리시간 예측)

  • Kim, Young Gu;Kim, Won Ho;Pak, Hyung Suk
    • Journal of the Korean Chemical Society
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    • v.42 no.6
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    • pp.646-651
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    • 1998
  • The molecular structure of sulfur compounds and the retention relationship are studied by gas chromatography. Analyzed sulfur compounds are, hydrogen sulfide, sulfur dioxide, carbon disulfide, ethyl mercaptan, dimethyl sulfide, iso-propyl mercaptan, normal propyl mercaptan, ethyl methyl sulfide, tert-butyl mercaptan, tetrahydrothiophene, thiophene, and 2-chlorothiophene. Multiple linear regression explains the retention relationship of molecular descriptors. In GC the temperature program is 30$^{\circ}C$ held for 10.5 min, and then increased to 150$^{\circ}C$ at a rate 15$^{\circ}C$/min. Predicted equation for relative retention time (RRT) using SAS program is as follows; $RRT=0.121bp+14.39dp-8.94dp^2+0.0741sqmw-35.78\; (N=8,\; R^2=0.989, \;Variance=0.175,\;F=66.21)$. RRTs are function of boiling point, the square root of molecular weight, molecular dipole moment, and boiling point effects mostly on RRT. The RRT is maximized at the molecular dipole moment of 0.805D, when using nonpolar columns. The planar and highly symmetric compounds are eluted slowly. The square, of correlation coefficient $(R^2)$ using SAS program, is 0.989, and the variance is 0.175 in training sets. For three sulfur compounds, the variance between observed RRTs and predicted RRTs is 0.432 in testing sets.

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Effect of surface treatment on shear bond strength between artificial resin teeth and 3D printing denture base resin (인공치의 표면처리가 3D 프린팅 의치상레진과의 전단결합강도에 미치는 영향)

  • Choi, Jeehye;Lee, Younghoo;Hong, Seoung-jin;Paek, Janghyun;Noh, Kwantae;Pae, Ahran;Kwon, Kung-Rock;Kim, Hyeong-Seob
    • The Journal of Korean Academy of Prosthodontics
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    • v.58 no.4
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    • pp.300-305
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    • 2020
  • Purpose: The purpose of this study is to compare the shear bond strength of 3D printing denture base resin according to surface treatment of artificial teeth. Materials and methods: 3D printing denture base resin was fabricated as specimens using 3D printer. The experimental group divided the surface treatment of artificial teeth into five groups according to the application of sandblasting and primer (n=10). Shear bond strengths between denture base and artificial teeth were measured by universal testing machine. All measurements were analyzed by one-way ANOVA and Turkey test (α=.05). Fracture mode of each specimen was analyzed. Microscopic evaluation was conducted by using a scanning electron microscope. Results: Unsurfaced treated group represented the lowest value. The primer groups had significantly higher result values (P<.05). Most specimens of the primer groups had cohesive failure. Conclusion: In 3D printing denture base resin group, mechanical and chemical surface treatment of artificial teeth has increased the shear bond strength. Therefore, if dentures are produced using 3D printing, proper mechanical and chemical treatment of artificial teeth is necessary for adhesion of dentures and artificial teeth.