• Title/Summary/Keyword: chemical surface treatment

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Effect of the Clay Mineral Illite on the Growth of Cherry Tomato in the Bed Soil (상토에서 점토광물 일라이트 (illite) 처리에 따른 방울토마토 생육 효과)

  • Kim, Hee-Jung;Kim, Hong-Ki;Kwon, Sang-Moon;Lee, Seok-Eon;Woo, Sun-Hee;Park, Man;Chung, Keun-Yook
    • Korean Journal of Soil Science and Fertilizer
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    • v.43 no.3
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    • pp.322-328
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    • 2010
  • This study was initiated to investigate the physical and chemical properties of the clay mineral illite and its effect on the growth of cherry tomato (Hongjak) as affected by the forms and concentrations of illite using the bed soil in the glass house. The composition of illite was analyzed by SEM(scanning electron microscope). The cherry tomato was cultivated in the bed soil in the glass house at Chungbuk National University for 10 weeks of total duration. The application rates of illite used as particulate and powder forms were standard 1:20 (w/w), two times 1:10 (w/w), four times 1:5 (w/w) of standard application, respectively. The surface of illite used in the study appeared to be hexagonal sheet and it included K and the variety of other elements. The growth lengths of cherry tomato were 11-23% greater in the pots treated than in the untreated pots. Based on the analyses of the major cations, K, Ca, and Mg from the cherry tomato the amounts of K taken in the leaf and stem of the cherry tomato were 8-45% and 3-30% greater than untreated pots, respectively. The amount of Ca in the leaf and stem taken up by the cherry tomato were 6-39% and 11-40% greater than untreated pots, respectively. The amounts of Mg in the leaf and stem taken up by the cherry tomato were 17-62% and 19-54% greater than untreated pots, respectively. Based on the analysis for the amount of cations, such as K, Ca, and Mg taken up by cherry tomato in treated and untreated bed soil, it appears that the illite treatment enhanced the early growth of cherry tomato.

CHANCE IN CONCENTRATION OF SALIVARY STREPTOCOCCUS MUTANS FOLLOWING THE APPLICATION OF VARNISH CONTAINING CHLORHEXIDINE IN ORTHODONTIC PATIENTS (교정 치료 환자에 있어 항균 varnish 처치 전후의 타액 내 Streptococcus mutans 균주의 변화에 관한 연구)

  • Chang, Young-Il;Kim, Tae-Woo;Chung, Chong-Pyoung;Nahm, Dong-Seok;Yang, Won-Sik;Suhr, Cheong-Hoon
    • The korean journal of orthodontics
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    • v.24 no.3 s.46
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    • pp.659-672
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    • 1994
  • Dental caries is one of the most prevalent dental diseases in Korea and its prevention is very important in orthodontic therapy. For the cleansing action of saliva itself and/or tooth-brushing is lowered in patient with fixed orthodontic appliance, oral hygiene of the patient becomes worse, which provides more favorable environment for micro-organisms. Chlorhexidine, one of the series of bisguanide, has been reported to be strong antimicrobial agent and very effective on Streptococcus mutans. The purpose of this study is to evaluate the possibility of chlorhexidine as a anticariogenic agent in fixed orthodontic therapy. We used the varnish containing chlorhexidine as a main ingredient for the chemical control of salivary S.mutans in patients with fixed appliance therapy We applied the varnish containing chlorhexidine on the labial and interproximal surface of the teeth before bonding and banding teeth of our patients(N=20) and compared to control group patients(N=20). Before the application of chlorhexidine varnish and four times periodically after the completion of fixed appliance set-up, we sampled saliva of both group patients and incuvate S.mutans for 24 hours. In the culture study of sampled saliva, counting the number of S.mutans colonies, we founded as follows : 1. In patients with fixed appliance therapy, the risk of dental caries increase when it compared to that of preorthodontic treatment ; The number of salivary S.mutans increase in Patient's oral cavity. 2. The experimental agent that contain chlorhexidine is effective to reduce the number of salivary S.mutans. 3. For the effect of this agent is not ever-lasting, periodical application is needed, and additional study for economical interval and number of application is needed.

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Strength Property Improvement of OCC-based Paper by Various Mechanical and Chemical Treatments of its Fiber (골판지 고지의 물리화학적 처리에 의한 강도향상)

  • Seo, Yung B.;Lee, Jong Hoon
    • Korean Journal of Agricultural Science
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    • v.26 no.1
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    • pp.21-30
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    • 1999
  • To increase the strength properties of recycled fiber, especially OCC (Old Corrugated Container) in this study, we used the mechanical pretreatment on the fibers before refining. The mechanical action in the Hobart mixer induced high shear and compression on the fibers, which resulted in the breakdowns of fiber internal structure, and microcompressions on the surface of the fibers. We evaluated the degree of mechanical treatment by fiber curl index. Four different refining techniques were applied to the pretreated fibers (Valley beater, Kady mill, PFI mill, and Impact refining) to find the best combination of the pretreatment and the refining methods. Conclusions were summarized as followed. 1. In keeping the fiber length from shortening, Kady mill and PFI mill refining were effective. Kady mill and Valley beater application tended to straighten out the fiber shapes. 2. Valley beating increased the breaking length of the handsheets better than other methods, while lowering the tear strength most. The mechanical pretreatment increased breaking length about 10% in average irrespective of four different refining methods. 3. Tear strength was increased by the mechanical pretreatment and by the PFI mill refining. 4. Burst strength was increased by the mechanical pretreatment and by valley beating method. 5. In increasing the breaking length and burst strength while keeping tear strength, combination of mechanical pretreatment and Valley beating were most effective.

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Review of root canal irrigant delivery techniques and devices (최신 근관 세척 방법과 기구에 대한 고찰)

  • Yoo, Yeon-Jee;Shin, Su-Jeong;Baek, Seung-Ho
    • Restorative Dentistry and Endodontics
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    • v.36 no.3
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    • pp.180-187
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    • 2011
  • Introduction: Eliminating the residual debris and bacteria in the root canal system is one of the main purposes of the endodontic treatment. However, the complexity on the anatomy of the root canal system makes it difficult to eliminate the bacterial biofilm existing along the root canal surface and necrotic pulp tissue by mechanical instrumentation and chemical irrigation. Recently, more effective irrigant delivery systems for root canal irrigation have been developed. The purpose of this review was to present an overview of root canal irrigant delivery techniques and devices available in endodontics. Review: The contents of this paper include as follows; - syringe-needle irrigation, manual dynamic irrigation, brushes - sonic and ultrasonic irrigation, passive ultrasonic irrigation, rotary brush, RinsEndo, EndoVac, Laser Conclusion: Though technological advances during the last decade have brought to fruition new agitation devices that rely on various mechanisms, there are few evidence based study to correlate the clinical efficacy of these devices with improved outcomes except syringe irrigation with needle and ultrasonic irrigation. The clinicians should try their best efforts to deliver antimicrobial and tissue solvent solutions in predictable volumes safely to working length.

Changes of Soil Physical Properties by Glomalin Concentration and Rice Yield using Different Green Manure Crops in Paddy (녹비작물 환원 시 Glomalin 함량에 따른 토양물리성 및 벼 수량 변화)

  • Jeon, Weon-Tai;Seong, Ki-Yeong;Kim, Min-Tae;Oh, Gye-Jeong;Oh, In-Seok;Kang, Ui-Gum
    • Korean Journal of Soil Science and Fertilizer
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    • v.43 no.2
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    • pp.119-123
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    • 2010
  • This experiment was conducted at Sinheung series (fine loamy, mixed, nonacid, mesic family of Fluvaquentic Endoaquepts) in 2007 to 2008 at the National Institute of Crop Science (NICS), RDA, Suwon, Gyeonggi province, Korea. Three kinds of green manure crops (hairy vetch, barley, rye) incorporated in soil for rice cultivation. 6.3 kg N $10a^{-1}$, and3.2 kg $P_2O_5$ $10a^{-1}$ were applied to rye and barley plot before rice transplanting. Chemical fertilizers had not been applied to hairy vetch plot. Glomalin concentration, soil bulk density, and porosity were measured in soil from different green manure crops incorporation after rice harvesting in paddy. Soil bulk density and porosity after rice harvesting improved at surface soil of hairy vetch incorporation plot. Degree of water stable aggregates increased all green manure incorporation plots. Glomalin concentrations significantly increased at hairy vetch incorporation treatment. In barley plot, the concentration of glomalin increased at 10-20 soil depth. There were no differences relationship between soil carbon, and glomalin concentration, but relationship between soil aggregate stability, and glomalin concentration significantly positive under green manure crop-rice cropping system. Rice yield decreased at hairy vetch incorporation plot because of field lodging. We suggested that hairy vetch incorporation should be considered about application amount, and water management using rice cultivation because of soil properties changes.

Performance Evaluation of Vortex Screen for Treatment of Fine Particles in Storm Runoff (Vortex Screen장치를 이용한 강우유출수내 미세입자 처리특성 분석)

  • Lee, Jun-Ho;Jung, Yun-Hee;Bang, Ki-Woong
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.4
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    • pp.256-262
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    • 2009
  • The use of hydrodynamic separator is becoming increasingly popular for suspended solids reduction in urban storm runoff. This study is a laboratory investigation of the use of Vortex Screen to reduce the solids concentration of synthesized storm runoff. The synthesized storm runoff was made with water and addition of particles; manhole sediment, road sediment, fly ash, and ployvinyl chloride powder. Vortex Screen was made of acryl resin with 250 mm of diameter and height of 700 mm. To determine the removal efficiency for various influent concentrations of suspended solids (SS) and chemical oxygen demand (COD), tests were performed with different operational conditions. The samples were taken simultaneously at the influent storage tank and effluent tank, and measured SS and COD concentrations. The ranges of surface loading rate were 110 to 1,550 $m^3/m^2$/day, and influent SS concentrations were varied from 141 to 1,986 mg/L. This paper was intended to evaluate the effect of inlet baffle and the ratio of underflow to overflow ($Q_U/Q_O$) on particle separation efficiency for various particle size using Vortex Screen. It was found that when increase of $Q_U/Q_O$ from 10% to 20%, SS removal efficiency was increased about 6%. The range of SS and COD removal efficiencies of road sediment particle size 125<$d_p$<300 ${\mu}m$ were 68.0~81.0%, 53.1~71.9%, respectively. Results showed that SS removal efficiency with inlet baffle improved by about 10~20% compared without inlet baffle.

Influence of Membrane Material and Structure on Fouling of a Submerged Membrane Bioreactor (침지형 막 분리 활성슬러지법에서 막의 재질 및 구조가 파울링에 미치는 영향)

  • Choi, Jae-Hoon;Kim, Hyung-Soo
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.1
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    • pp.31-36
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    • 2008
  • This work was performed to evaluate the effect of membrane material and structure on fouling in a submerged membrane bioreactor(MBR). Three types of microfiltration membranes with the same pore size of 0.1 $\mu$m but different materials, polytetrafluoroethylene (PTFE), polycarbonate(PCTE) and polyester(PETE), were used. While PETE membrane exhibited the most rapid flux decline throughout the operation, PCTE and PTFE had a similar tendency with regard to permeability. Difference in permeability between PETE and the other membranes gradually decreased with time, which was probably due to chemical cleaning. The higher TOC rejection of PETE membrane could be attributable to its faster fouling, resulting from a larger amount of foulants to get attached to the membrane in a shorter time. DOC fractionation using a DAX-8 resin showed that the composition of each fraction between the supernatant and permeates did not change significantly with operation time, indicating that membrane hydrophilicity/hydrophobicity was not a dominant factor affecting to MBR fouling in this study. Compared to other membranes, the fouling of PETE membrane was more influenced by pore clogging (irreversible fouling), which would probably contribute to a higher organic rejection of the PETE membrane.

LABORATORY STUDIES ON MIC OF AISI TYPE 304 STAINLESS STEEL USING BACTERIA ISOLATED FROM A W ASTEWATER TREATMENT SYSTEM

  • Sreekumari, Kurissery R.;Kyozo, Hirotani;Katsuya, Akamatsu;Takashi, Imamichi;Yasushi, Kikuchi
    • Proceedings of the KWS Conference
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    • 2002.10a
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    • pp.260-265
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    • 2002
  • Microbiologically influenced Corrosion (MIC) is one of the most deleterious effects of metal microbe interactions. When a fresh metal surface comes in contact with a non-sterile fluid, biofilm formation is ensued. This might result in the initiation of corrosion. The sites and materials where MIC is implicated are versatile. Industries such as shipping, power generation, chemical etc are reported to be affected. The rapid and unexpected failure of AISI type 304 stainless steel was investigated in the laboratory by simulation studies for a period of 4 months. Slime and water samples from the failure site were screened for corrosion causing bacteria. Both aerobic and anaerobic nora were enumerated and identified using PCR techniques. Pseudomonas sp. and Bacillus sp. were the most common aerobic bacteria isolated from the water and slime samples, whilst sulfate reducing bacteria (SRB) were the major anaerobic bacteria. The aerobic bacteria were used for the corrosion experiments in the laboratory. Coupon exposure studies were conducted using a very dilute (0.1%V/V) nutrient broth medium. The coupons after retrieval were observed under a Scanning Electron Microscope (SEM) for the presence of MIC pits. Compared to sterile controls, metal coupons exposed to Pseudomonas sp and Bacillus sp. showed the initiation of severe pitting corrosion. However, amongst these two strains, Psudomonas sp. caused pits in a very short span of 14 days. Towards the end of the experiment, severe pitting was observed in both the cases. The detailed observation of pits showed they vary both in number and shapes. Whilst the coupons exposed to Bacillus sp. showed widely spread scales like pits, those exposed to Pseudomonas sp. showed smaller and circular pits, which had grown in number and size by the end of the experiment. From these results it is inferred that the rapid and unexpected failure of 304 SS might be due to MIC. Pseudonwnas sp. could be considered as the major responsible bacteria that could initiate pits in the metallic structures. As the appearance of pits was different in both the tested strains, it was thought that the mechanisms of pit formation are different. Experiments on these lines are being continued.

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Characteristics of Isotherm, Kinetic and Thermodynamic Parameters for the Adsorption of Acid Red 66 by Activated Carbon (활성탄에 의한 Acid Red 66의 흡착에 대한 등온선, 동력학 및 열역학적 특성)

  • Lee, Jong-Jib
    • Clean Technology
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    • v.26 no.1
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    • pp.30-38
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    • 2020
  • The kinetic and thermodynamic parameters of Acid Red 66, adsorbed by granular activated carbon, were investigated on areas of initial concentration, contact time, and temperature. The adsorption equilibrium data were applied to Langmuir, Freundlich, Temkin, Redlich-Peterson, and Temkin isotherms. The agreement was found to be the highest in the Freundlich model. From the determined Freundlich separation factor (1/n = 0.125 ~ 0.232), the adsorption of Acid Red 66 by granular activated carbon could be employed as an effective treatment method. Temkin's constant related to adsorption heat (BT = 2.147 ~ 2.562 J mol-1) showed that this process was physical adsorption. From kinetic experiments, the adsorption process followed the pseudo-second order model with good agreement. The results of the intraparticle diffusion equation showed that the inclination of the second straight line representing the intraparticle diffusion was smaller than that of the first straight line representing the boundary layer diffusion. Therefore, it was confirmed that intraparticle diffusion was the rate-controlling step. From thermodynamic experiments, the activation energy was determined as 35.23 kJ mol-1, indicating that the adsorption of Acid Red 66 was physical adsorption. The negative Gibbs free energy change (ΔG = -0.548 ~ -7.802 kJ mol-1) and the positive enthalpy change (ΔH = +109.112 kJ mol-1) indicated the spontaneous and endothermic nature of the adsorption process, respectively. The isosteric heat of adsorption increased with the increase of surface loading, indicating lateral interactions between the adsorbed dye molecules.

Study on Fiber Laser Annealing of p-a-Si:H Deposition Layer for the Fabrication of Interdigitated Back Contact Solar Cells (IBC형 태양전지 제작을 위한 p-a-Si:H 증착층의 파이버 레이저 가공에 관한 연구)

  • Kim, Sung-Chul;Lee, Young-Seok;Han, Kyu-Min;Moon, In-Yong;Kwon, Tae-Young;Kyung, Do-Hyun;Kim, Young-Kuk;Heo, Jong-Kyu;Yoon, Ki-Chan;Yi, Jun-Sin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.430-430
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    • 2008
  • Using multi plasma enhanced chemical vapor deposition system (Multi-PECVD), p-a-Si:H deposition layer as a $p^+$ region which was annealed by laser (Q-switched fiber laser, $\lambda$ = 1064 nm) on an n-type single crystalline Si (100) plane circle wafer was prepared as new doping method for single crystalline interdigitated back contact (IBC) solar cells. As lots of earlier studies implemented, most cases dealt with the excimer (excited dimer) laserannealing or crystallization of boron with the ultraviolet wavelength range and $10^{-9}$ sec pulse duration. In this study, the Q-switched fiber laser which has higher power, longer wavelength of infrared range ($\lambda$ = 1064 nm) and longer pulse duration of $10^{-8}$ sec than excimer laser was introduced for uniformly deposited p-a-Si:H layer to be annealed and to make sheet resistance expectable as an important process for IBC solar cell $p^+$ layer on a polished n-type Si circle wafer. A $525{\mu}m$ thick n-type Si semiconductor circle wafer of (100) plane which was dipped in a buffered hydrofluoric acid solution for 30 seconds was mounted on the Multi-PECVD system for p-a-Si:H deposition layer with the ratio of $SiH_4:H_2:B_2H_6$ = 30:120:30, at $200^{\circ}C$, 50 W power, 0.2 Torr pressure for 20 minutes. 15 mm $\times$ 15 mm size laser cut samples were annealed by fiber laser with different sets of power levels and frequencies. By comparing the results of lifetime measurement and sheet resistance relation, the laser condition set of 50 mm/s of mark speed, 160 kHz of period, 21 % of power level with continuous wave mode of scanner lens showed the features of small difference of lifetime and lowering sheet resistance than before the fiber laser treatment with not much surface damages. Diode level device was made to confirm these experimental results by measuring C-V, I-V characteristics. Uniform and expectable boron doped layer can play an important role to predict the efficiency during the fabricating process of IBC solar cells.

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