• Title/Summary/Keyword: chemical surface treatment

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Manufacture of Water-Resistant Corrugated Board Boxes for Agricultural Products in the Cold Chain System(III) - Effects of types of base paper and surface treatments on physical properties of the base paper for water resistant corrugated board - (농산물 저온유통용 내수 골판지 상자의 제조(제3보) -원지의 종류와 표면처리 방법에 따른 내수 골판지 원지의 물성-)

  • Jo Jung-Yeon;Min Choon-Ki;Shin Jun-Seop
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.37 no.2 s.110
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    • pp.70-77
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    • 2005
  • For the purpose of developing liner board for water resistant corrugated board in the cold chain system, several types of base paper for corrugated board were purchased from the market and 6 different boards were produced in the mill by applying the chemicals, chosen in the previous studies, on the base paper. Then water-moisture resistance and physical properties of the boards were compared each other. The liner board which is dried at high temperature with pressure by Condebelt (CK paper) showed a superior performance in strength over common liner boards. Strength of the board increased by surface chemical treatment up to $60\%$ of compressive strength and $30\%$ of burst strength. Starch insolubilization with Ammonium Zirconium Carbonate and surface coating with a surface sizing agent and a moisture resistant chemical on CK paper showed the best result. Therefore this method was recommended to produce the outer liner board for water resistant corrugated board.

A experimental study about plasma ion treatment to improve hardness of electro-polished surface (전해연마면의 표면경도 향상을 위한 플라즈마 이온질화 처리법에 관한 실험적 연구)

  • Kim, Jin-Beom;Hong, Pil-Gi;Seo, Tae-Il;Son, Chang-Woo
    • Design & Manufacturing
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    • v.13 no.1
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    • pp.13-18
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    • 2019
  • The size and prospects of the domestic semiconductor equipment market are increasing every year. In the case of various parts used inside semiconductor equipments, high durability such as high strength and abrasion resistance is demanded. Particularly, the gases used in semiconductor production processes are toxic. In order to prevent such toxic gas leakage, a precision processing technique and a surface treatment technique for preventing corrosion are required. Electro-polishing is an electro-chemical method of polishing a metal surface to make it smooth and polished. Electro-polishing is mainly used in the finishing process of metal surface. Unlike mechanical polishing, electro-polishing is used in many fields, such as fine chemical etching equipment, since no damaged layer or burr, fine polishing groove and particles are generated. However, in order to withstand the gas used in the semiconductor equipment, the parts must have high corrosion resistance. However, the surface hardness generally become lowered through electro-polishing. Therefore, in this study, surface hardness were experimentally observed before and after electro-polishing. Then, a method of improving hardness by preparing a nitrided layer by plasma ion nitriding treatment.

Carrier Gas Assisted Solvent Vapor Treatment for Surface Nanostructuring of Molecular Thin Films

  • Gong, Hye-Jin;Kim, Jin-Hyun;Yim, Sang-Gyu
    • Bulletin of the Korean Chemical Society
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    • v.33 no.3
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    • pp.825-827
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    • 2012
  • In this study, the variation in surface morphology of copper phthalocyanine (CuPc) thin films treated with a flow of acetone vapor assisted by nitrogen carrier gas was investigated. The CuPc nanorods with similar dimensions were well dispersed throughout the whole film surfaces after ~20 min. of treatment. However, the electronic absorption spectra only changed slightly, which indicates that molecular stacking was not altered during treatment. This treating method is simple and more advantageous compared to other solvent treating technologies such as mixed solvent spray treatment using organic solvents and water since it requires relatively mild treating conditions and does not need the presence of water.

Electrochemical Behaviors of Platinum Catalysts Deposited on the Plasma Treated Carbon Blacks Supports (플라즈마 처리된 카본블랙 담지체에 담지된 백금 촉매의 전기화학적 거동)

  • Kim, Seok;Cho, Mi-Hwa;Lee, Jae-Rock;Ryu, Ho-Jin;Park, Soo-Jin
    • Korean Chemical Engineering Research
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    • v.43 no.6
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    • pp.756-760
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    • 2005
  • In this study, the effect of $N_2$-plasma treatment on carbon blacks (CBs) was investigated by analyzing acid-base surface values and surface functional groups of CBs. The surface characteristics of the CBs were determined by fourier transformed-infrared (FT-IR) spectrometer, X-ray photoelectron spectroscopy (XPS), and Boehm's titration method. Electrochemical properties of the plasma-treated CBs-supported Pt (Pt/CBs) catalysts were analyzed by cyclic voltammetry (CV) experiments. From the results of FT-IR and acid-base values, $N_2$-plasma treatment at 300 W intensity on the CBs led to the formation of the free radical. The peak intensity was increased with increasing the treatment time due to the formation of new basic functional groups(such as C-N, C=N, $-NH_3{^+}$, -NH, and =NH) by the free radical. Accordingly, the basic values were increased by the basic functional groups. However, after a specific reaction time, $N_2$-plasma treatment could hardly influence change of surface functional groups of CBs, due to the disappearance of free radical. Consequently, it was found that optimal treatment time was 30 second for electro activity of Pt/CBs catalysts.

Technology Trends in Stainless Steel for Water Splitting Application (스테인레스 강의 수전해 전극 응용기술 동향)

  • Kim, Moonsu;Ha, Jaeyun;Kim, Yong-Tae;Choi, Jinsub
    • Journal of the Korean Electrochemical Society
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    • v.24 no.2
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    • pp.13-27
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    • 2021
  • Stainless steel, which includes Ni and Cr with Fe balance, is most often applied for a wide range of applications such as structure and equipment material. It is not only suitable for use in these applications due to its good corrosion resistance, but also can be applied to catalyst, supporting material, and current collector due to intrinsic properties of Ni and Fe contained in stainless steel. Therefore, in recent years, a lots of surface treatment methods have been studied to activate stainless steel, developing application of water splitting system. In this review paper, the research on the surface treatment technology of stainless steel for water splitting is summarized. It is expected to be able to propose the diverse surface treatment approaches of stainless steel for application to low-cost and highly efficient water splitting electrode.

Analyses on the Increment of Surface Hydrophobicity of Epoxy Composites by Thermal Treatment (열철리에 따른 Epoxy 복합재료의 표면 소수성증가에 관한 해석)

  • Lim, Kyung-Bum;Lee, Beak-Su;Chung, Mu-Yong;Lee, Duck-Chool
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.50 no.4
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    • pp.153-160
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    • 2001
  • In order to analyze the degradation process of epoxy/glass fiber for outdoor condition, FRP laminate was exposed to high temperature. Then, the degradation process was evaluated by comparing contact angle, surface potential, surface resistivity, and XPS. The experimental results showed that the amount of weight loss, contact angle, surface potential and surface resistivity increased up to 200 $^{\circ}C$ as a function of temperature. These phenomena show the existence of hydrophobic surface. With the change to the hydrophobic surface and the electrical potential and resistivity on FRP surface increased. In XPS to analyze surface chemical structures, the increased hydrophobicity in thermal increase of unsaturated double bond in carbon chains. Aslo, thermal treatment caused the discoloration on the point of treated surface. These phenomena were attributed to the generations of ether group.

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A study on the chemical treatment of biodeterioration about stone pagoda of Iksan Mireuksaji-Focusing on bio-treatment using K201 (익산 미륵사지석탑의 생물침해 방지를 위한 보존처리제 적용실험-K201 생물처리제를 중심으로)

  • Yang, Hee-Jae;Chung, Yong-Jae;Kim, Sa-Dug;Kim, Gwaoung-Hun
    • 보존과학연구
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    • s.24
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    • pp.81-98
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    • 2003
  • The biodeterioration on Iksan Mireuksaji pagoda has been studied with fucus on application of K201 as a chemical treatment. Total of 39species, including 10 algae, 16 lichens, 6 mosses and 7 unidentified bacteria and fungi, were collected and identified on the surface of the pagoda. Most of them caused serious discoloration on the surface. The effectiveness and stability of K201 was examined by applying it on some part of the pagoda. A mild spraying of solution diluted to half of original reagent was good enough to eliminate all the deteriorating species on the surface. Most of discoloration disappeared after the treatment except the red color caused by iron substance. The effectiveness of the regent was compared with water wash. The stone was first washed with water and the dirt on the surface was scrubbed off from the surface. The initial surface of the stone was clearer in water wash. However, many of the deteriorating species reappear in 4 weeks after water wash. Although spraying of the reagent K201 could noteliminate all the remnant of dead organisms as good as scrubbing the surface, no deteriorating algae or lichen was observed until two month after treatment. Therefore, spraying method with chemicals seems more stable and reliable way to remove the biodeterioration than physical scrubbing of the surface.

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Filler-Elastomer Interactions : 4. Effect of Plasma Treatment on Surface Properties of Carbon Blacks (충전제-탄성체 상호작용 4. 플라즈마 처리가 카본블랙 표면 특성에 미치는 영향)

  • Kim, Jeong-Soon;Choi, Kyung-Eun;Park, Soo-Jin
    • Elastomers and Composites
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    • v.36 no.2
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    • pp.94-101
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    • 2001
  • In this work, the effect of NE plasma treatment generated by radio-frequency was investigated in acid-base surface values, ion adsorption characteristics, and surface free energies of carbon blacks. As the results, it was clearly found that the obvious improvement of the treatment is in the London dispersive component (${\gamma}s^L$) of surface free energy of carbon blacks. Also both electron-acceptor ( ${\gamma}s^+$) and -donor (${\gamma}s^-$) parameters for the specific component (${\gamma}s^{sp}$) were also increased with increasing the treatment time, resulting in increasing the surface functional groups of the carbon blacks studied, together with a consequence of the increases of acidic and basic surface functional groups, ion exchange, zeta potential, and ion mobility.

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Thermal Stability of Silicon-containing Diamond-like Carbon Film (실리콘 함유 DLC 박막의 내열특성)

  • Kim, Sang-Gweon;Kim, Sung-Wan
    • Journal of the Korean Society for Heat Treatment
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    • v.23 no.2
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    • pp.83-89
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    • 2010
  • Diamond-like carbon (DLC) coating was studied to be a good tribological problem-solver due to its low friction characteristics and high hardness. However, generally hydrogenated DLC film has shown a weak thermal stability above $300^{\circ}C$. However, the silicon doping DLC process by DC pulse plasma enhanced chemical vapor deposition (PECVD) for the new DLC coating which has a good characterization with thermal stability at high temperature itself has been observed. And we were discussed a process for optimizing silicon content to promote a good thermal stability using various tetramethylsilane (TMS) and methane gas at high-temperature. The chemical compositions of silicon-containing DLC film was analyzed using X-ray photoelectron spectroscopy (XPS) before and after heat treatment. Raman spectrum analysis showed the changed structure on the surface after the high-temperature exposure testing. In particular, the hardness of silicon-containing DLC film showed different values before and after the annealing treatment.

Effects of Oxygen Functional Groups introduced onto Activated Carbon Fibers on Gas Sensing Property of Chemical Warfare Agent (활성탄소섬유에 도입된 산소작용기가 유독성 화학작용제 감응특성에 미치는 영향)

  • Kim, Su Hyun;Kim, Min-Ji;Song, Eun Ji;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.30 no.6
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    • pp.719-725
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    • 2019
  • In this study, activated carbon fibers were treated with oxygen plasma to investigate gas sensing properties of the dimethyl methylphosphonate (DMMP), which is a simulant gas of the chemical warfare agent, according to oxygen functional group contents. As the flow rate of oxygen plasma treatment increased, oxygen groups were introduced to the surface of activated carbon fibers from 6.90 up to 36.6%, increasing the -OH group which influences the DMMP gas sensing properties. However, as the flow rate of oxygen plasma increases, the specific surface area tends to decrease because etching on the surface of activated carbon fibers occurs due to active species generated during the oxygen plasma treatment. The resistance change rate of the DMMP gas sensor increased from 4.2 up to 25.1% as the oxygen plasma treatment flow rate increased. This is attributed to the hydrogen bonding between DMMP gas and introduced hydroxyl functional group on activated carbon fibers by the oxygen plasma treatment. Therefore, the oxygen plasma is considered to be one of the important surface treatment methods for detecting chemical warfare agents at room temperature.