• Title/Summary/Keyword: chemical resistance test

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Mechanical Characteristic Evaluation of Proper Material for Ultra-fine Dies (초소형 금형소재의 기계적 특성평가)

  • KANG Jae-hoon;LEE Hyun-yong;LEE Nak-kyu
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 2005.05a
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    • pp.473-476
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    • 2005
  • Today's manufacturing industry is facing challenges from advanced difficult-to-machine materials (WC-Co alloys, ceramics, and composites), stringent design requirements (high precision, complex shapes, and high surface quality), and machining costs. Advanced materials play an increasingly important role in modem manufacturing industries, especially, in aircraft, automobile, tool, die and mold making industries. The greatly-improved thermal, chemical, and mechanical properties of the material (such as improved strength, heat resistance, wear resistance, and corrosion resistance), while having yielded enormous economic benefits to manufacturing industries through improved product performance and product design, are making traditional machining processes unable to machine them or unable to machine them economically. In this paper, mechanical characteristic evaluation test of fine powder type WC-Co alloy was accomplished to obtain clear data for miniaturized special die parts machining with high reliability and high quality.

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A Study on the Antibacteria Effect and the Properties Change by Treatment of Chrome-Tanned Garment Leathers. -On the Changes by Dry Cleaning- (의류용 크롬유혁의 가공처리에 따른 항미생물효과 및 특성변화에 관한 연구 -드라이클리닝에 의한 변화를 중심으로-)

  • Cho, Seung-Shick;Sim, Mi-Sook;Kim, Un-Bae
    • Textile Coloration and Finishing
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    • v.3 no.2
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    • pp.10-15
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    • 1991
  • This study was to examine the anti-bacteria effect and the changes of chemical properties of chrome-tanned garment leathers on the preservative treatment. Various test methods, such as investigation of preservative treatment process, resistance test and chemical analysis by cleaning, antbbacterial test by shake flask method are carried out in this study. The results can be obtained as follows: 1. Bacterial reduction percentage of chrome-tanned garment leathers on the preservative treatment was 28.6%. 2. In the antbbacterial effect by dry cleaning, preservative treated leathers has no resistance. 3. Fats content has been removed by dry cleaning using perchloroethylene, so garment leathers properties were altered. 4. PH value was changed by dry cleaning. But once after fats removing, it was changed the little by dry cleaning numbers.

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Development of chemical conversion coating technology by environment friendly method for Zn electroplated steel (아연 전기 도금 강의 환경친화적인 화성처리 기술 개발)

  • Kim, Seong-Jong;Kim, Jeong-Il;Jang, Seok-Ki
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2006.06a
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    • pp.271-272
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    • 2006
  • Zinc confers high corrosion resistance by acting as a sacrificial anode, and a zinc coating improves the appearance of steel. Chromate conversion coating (CCC) films are still one of the most efficient surface treatments for steel. Although such films can self-repair via the dissolution of Cr(VI), dissolved Cr(VI) have adverse effects on humans, and the environment. Therefore, we examined the corrosion protection property and morphology of colloidal silica conversion films as an alternative to CCC films. The corrosion behavior was investigated in 3% NaCl solution using electrochemical techniques, including electrochemical impedance spectroscopy, open circuit potential, and the salt spray test(SST). Corrosion was implied by the appearance of red rust on the specimen surface. In corrosion resistance at 3% NaCl solution, red rust appeared at 15-20, 55-70, and 83-98 days on Zn-electroplated steel, colloidal silica conversion-coated specimens, and CCC-coated specimens, respectively. In the salt spray test, the colloidal silica film provided better corrosion protection than CCC films, i.e., red rust appeared at 96 hours on the Zn-electroplated steel sheet, at 432 hours with the CCC films, and at 888 hours with silica conversion coating.

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Estimation on the Durability of High-Performance Concrete Using Metakaolin (Metakaolin 혼합 고강도 콘크리트의 내구특성 평가)

  • Moon Han Young;Yum Jun Hwan;Moon Su Dong;Lee Sang Ho
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.05a
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    • pp.196-199
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    • 2004
  • Metakaolin is a cementitious material for producing high-strength concrete. This material is now used as substitute for silica-fume. In this paper, we tested the compressive strength of concrete according to the substitute ratio of metakaolin, silica-fume. And we did the durability test such as chloride ion diffusion and chemical attack. In the compressive strength test, the result shows that $10\%$ substitute of metakaolin & silica-fume for binder is optimum. In the chloride ion diffusion test, according to the increase of substitute of metakaolin & silica-fume for binder, the diffusion coefficient is more reduced. And in the chemical attack test, according to the increase of substitute, the resistance is more excellent. In the durability test, we recognized that metakaolin is able to used as a substitute for silica-fume.

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Reactivity and Attrition Resistance of Three Oxygen Carrier Particles for Chemical-Looping Combustor (매체순환식 가스연소기 적용을 위한 세 가지 산소공여입자들의 반응성 및 내마모성)

  • Ryu, Ho-Jung;Jin, Gyoung-Tae
    • Transactions of the Korean hydrogen and new energy society
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    • v.15 no.3
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    • pp.208-219
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    • 2004
  • To find a suitable oxygen carrier particle for a 50kW chemical-looping combustor, which was designed and installed to demonstrate continuous oxidation and reduction, three oxygen carrier particles(NiO/bentonite, $NiO/NiAl_2O_4$, $CoO_x/CoAl_2O_4$) were prepared. The reactivity and the attrition resistance of particles were measured and investigated by a thermo-gravimetrical analyzer and an attrition test apparatus respectively. From the viewpoints of oxygen transfer capacity, optimum reaction temperature(operating temperature range), reaction rate, carbon deposition rate, and attrition resistance, NiO/bentonite particle showed better performance than the other particles, therefore we selected NiO/bentonite particle as an optimum oxygen carrier particle.

An Electro-chemical Combined-stress Degradation Test of Rubber for Automotive Radiator Hoses (자동차 냉각기 호스용 고무의 전기화학적 복합노화시험)

  • Kwak, Seung-Bum;Seo, Boo-Seok;Choi, Nak-Sam
    • Transactions of the Korean Society of Automotive Engineers
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    • v.19 no.4
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    • pp.107-113
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    • 2011
  • Coolant rubber hoses for automotive radiators under thermal and mechanical loadings can be degraded and thus failed due to the influences of the locally formed electricity. In this study, an advanced test method was developed to simulate the failure problem of the rubber hose. For carbon black filled EPDM (ethylene-propylene dine monomer) rubber used as a radiator hose material the ageing behaviors by the electro-chemical stresses combined with a tensile strain were analyzed. As the tensile strain increased, the current of the rubber specimen reduced indicating an increase of the internal defects and electrical resistance of the rubber specimen. Elongation at break and IRHD hardness rapidly decreased with increasing the ageing time. Both electro-chemical stress and mechanical tensile stress clearly accelerated the degradation of EPDM rubber.

Stiffness Degradation and Unconfined Strength of the Chemically Grouted Sand Subjected to Cyclic Shear (반복전단을 받는 고화 처리토의 강성저하와 일축압축강도)

  • Kwon, Youngcheul;Lee, Bongjik;Bae, Wooseok
    • Journal of the Korean GEO-environmental Society
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    • v.8 no.5
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    • pp.23-29
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    • 2007
  • The performance of the improved soil against liquefaction depends upon the chemical density, and it has been decided on the basis of the unconfined compressive strength of the improved soil up to date. On the other hand, several authors have proposed that the stiffness degradation could be treated as the clue for the judgment of the possibility of liquefaction. In this study, therefore, the stiffness degradation of the improved soil was estimated as the resistance against liquefaction by using the strain controlled cyclic triaxial test equipment. Based on the test results, it is concluded that the chemically treated sand can resist against the liquefaction in aspect of the reduction in effective stress and in the stiffness. Furthermore, even in the case of low chemical density, such as 2% in this study, has enough liquefaction resistance when compared with the 5~6% which often used in practical design. Considering this fact, the design of chemical density based on the unconfined strength can lead the overestimation in chemical density, and chemical density can be reduced when considering the stiffness reduction shown in this study.

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Effects of Heat Treatment on Surface Properties of Aluminum 6061 Alloy After Anodization (알루미늄 6061 합금 양극산화 후 열처리에 따른 표면 특성 관찰)

  • Seungmin, Lee;Chanyoung, Jeong
    • Corrosion Science and Technology
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    • v.21 no.6
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    • pp.495-502
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    • 2022
  • Anodization is a representative electrochemical surface treatment method that can improve both heat resistance and corrosion resistance by forming an anodization film on the surface of the aluminum. However, these properties can be changed after an additional heat treatment process. In this study, Al 6061 was subjected to an anodization process at 60 V for 1 hour, 5 hours, or 9 hours. An additional heat treatment process was performed at 500 ℃ for 30 minutes. Field emission scanning electron microscopy (FE-SEM) analysis revealed that the thickness of the anodized film was increased in proportion to the anodization time. Both pore size and pore diameter of the anodized film was also increased after anodization. After an additional heat treatment process, there were no significant changes in the thickness, pore size, or pore diameter of the anodized film. Heat resistance was confirmed through thermal analysis and chemical resistance was evaluated with a potentiodynamic polarization test.

Improved Corrosion and Abrasion Resistance of Organic-Inorganic Composite Coated Electro-galvanized Steels for Digital TV Panels

  • Jo, Du-Hwan;Noh, Sang-Geol;Park, Jong-Tae;Kang, Choon-Ho
    • Corrosion Science and Technology
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    • v.14 no.5
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    • pp.213-217
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    • 2015
  • Recently, household electronic industries require environmentally-friendly and highly functional steels in order to enhance the quality of human life. Customers especially require both excellent corrosion and abrasion resistant anti-fingerprint steels for digital TV panels. Thus POSCO has developed new functional electro-galvanized steels, which have double coated layers with organic-inorganic composites on the zinc surface of the steel for usage as the bottom chassis panel of TVs. The inorganic solution for the bottom layer consists of inorganic phosphate, magnesium, and zirconium compounds with a small amount of epoxy binder, and affords both improved adhesion properties by chemical conversion reactions and corrosion resistance due to a self-healing effect. The composite solution for the top layer was prepared by fine dispersion of organic-inorganic ingredients that consist of a urethane modified polyacrylate polymer, hardener, silica sol and a titanium complex inhibitor in aqueous media. Both composite solutions were coated on the steel surface by using a roll coater and then cured through an induction furnace in the electro-galvanizing line. New anti-fingerprint steel was evaluated for quality performance through such procedures as the salt spray test for corrosion resistance, tribological test for abrasion resistance, and conductivity test for surface electric conductance regarding to both types of polymer resin and coating weight of composite solution. New composite coated anti-fingerprint steels afford both better corrosion resistance and abrasion properties compared to conventional anti-fingerprint steel that mainly consists of acrylate polymers. Detailed discussions of both composite solutions and experimental results suggest that urethane modifications of acrylate polymers of composite solutions play a key role in enhanced quality performances.

Estimation on the Durability of High-Strength Concrete using Metakaolin (Metakaolin 혼합 고강도콘크리트의 내구특성 평가)

  • Moon Han Young;Yum Jun Hwan;Moon Su Dong;Lee Sang Ho
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.11a
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    • pp.217-220
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    • 2004
  • Metakaolin is a cementitious material for producing high-strength concrete. This material is now used as substitute for silica-fume. In this paper, we did the durability test such as chloride ion diffusion, chemical attack. repeated freezing and thawing, carbonation. In the chloride ion diffusion test, according to the increase of substitute of metakaolin & silica-fume for binder, the diffusion coefficient is more reduced. And in the chemical attack test, according to the increase of substitute, the resistance is more excellent. In the other durability test, the concrete using metakaolin is also compared with those of the portland cement concrete and silica fume concrete. According to these tests, we recognized that metakaolin is able to be used as a substitute for silica-fume.

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