• Title/Summary/Keyword: chemical resistance test

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The Change of Physical and Chemical Properties of Processed Leaf Tobacco During Long-term Storage (장기저장시 가공 원료잎담배의 이화학성 변화)

  • 김상범;안동명;이종철;이경구;조수헌
    • Journal of the Korean Society of Tobacco Science
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    • v.23 no.1
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    • pp.31-39
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    • 2001
  • This study was carried out to investigate the changes of physical and chemical properties and the usability of long-term stored leaf tobacco. The physical chemical properties of the flue-cured and burley leaves produced in 1993, processed in 1994 were analysed from Nov. 1996 to Nov. 1999. The pH and moisture content in leaf decreased slowly until 4 years’storage after processing, while those of leaf changed little thereafter. However, total sugar content continuously decreased until 5 years after processing. The filling capacity increased and shatter resistance index decreased in long-term stored leaf. The sensory test, cilia stasis and the chemical components of cigarette smoke had no significant differences between short and long-term stored leaves. When the processed leaves were stored till 5 years after processing, there were no deteriorative effects on quality and usability of leaf tobacco. Therefore, it is considered that the processed leaf may be stored for 5 years or more under the inevitable situation.

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Durability of MEA Using sPEEK Membrane Reinforced with Poly Imide in PEMFC (고분자전해질연료전지에서 폴리이미드 강화 sPEEK막 MEA의 내구성)

  • Lee, Hye-Ri;Na, Il-Chai;Oh, Sung-Jun;Park, Kwon-Pil
    • Korean Chemical Engineering Research
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    • v.55 no.3
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    • pp.296-301
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    • 2017
  • Recently, there are many efforts focused on development of more economical non-fluorinated membranes for PEMFCs (Proton Exchange Membrane Fuel Cells). In this study, sulfonated poly (ether ether ketone) (sPEEK) membrane reinforced with poly imide was made to enhance of membrane durability. In order to test durability of single (un-reinforced) membrane and reinforced membrane MEA (Membrane and Electrode Assembly), degradation accelerated stress test was used. Before and after degradation, I-V polarization curve, hydrogen crossover current, electrochemical surface area, membrane resistance and charge transfer resistance were measured. As a result of experiments, hydrogen crossover current of reinforced MEA was lower than that of single MEA, therefor durability of reinforced MEA was higher than that of single MEA. There was not especially short phenomena in reinforced MEA after degradation accelerated stress test.

Changes of physico-chemical properties of the activated sludges with anaerobic storage time (혐기화 시간에 따른 활성슬러지의 물리ㆍ화학적 특성변화)

  • 이창한;나영수;김도한;이송우;송승구
    • Journal of Environmental Science International
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    • v.11 no.4
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    • pp.339-346
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    • 2002
  • Physico-chemical properties of the activated sludges(Suyoung and Changlim treatment plant), such as SVI(sludge volume index), absorbance, specific surface area, and specific resistance using Buchener funnel test were investigated with changing anaerobic storage time. This experimental condition was found that it was possible to estimate a linear relationship between their parameters such as specific surface area specific resistance, and sludge volume index(SVI). The specific surface area and the specific resistance to filtration of the activated sludges of Suyoung and Changlim treatment plant were found as 123.6~136.6$m^2$/gDS and 41.5~44.9$m^2$/gDS(dry solid), and 1.09$\times$10$^{14}$ ~5.48$\times$10$_{14}$ m/kg and 1.05$\times$10$^{14}$ ~2.48$\times$10$^{14}$ m/kg, respectively. The results gave a good linear relationship between the specific surface area and the specific resistance, r=2.25$\times$10$^{12}$ s-8.10$\times$10$^{13}$ ($R^2$=0.8885) at Suyoung treatment plant and r=1.26$\times$10$^{13}$ s-4.75$\times$10$^{14}$ ($R^2$=0.8756) at Changlim treatment plant.

The Development of Water-Soluble Black Coloring Agent and Its Application (수용성 흑색 착색제의 개발과 이의 응용)

  • Kim, M.G.;Jung, B.H.;Moon, M.J.;Kim, S.S.
    • Journal of the Korean Society for Heat Treatment
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    • v.15 no.5
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    • pp.213-218
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    • 2002
  • In order to develop the economic and environmental water-soluble black coloring agent, some adequate chemical mixtures were mixed and this solution was applied to coat quenched and tempered 51B20 steel bolt. Some basic properties of the solution and characteristics of the coated film in addition to the corrosion resistance were investigated. The developed 100 kg of water-soluble black coloring agent solution was a chemical mixture consisted of 10 kg of aqueous coloring agent, 40 kg of surface active agent, 0.3 kg of anti-foam agent and $50{\ell}$ of water. The coated film of the bolt was composed of hard layer of about $2{\mu}m$ and the disbondable soft layer of about $4{\mu}m$ above the hard layer. Many surface active agents peaks and a few hydrophilic peaks were observed in the coated film. Surface roughness value of the coated bolt was lower than that of the non-coated bolt. Corrosion resistance of the coated bolt considerably improved and also relatively showed a good polarization resistance at test condition of $40^{\circ}C$ colorizing temperature and 5% the solution concentration in 3% NaCl anodic polarization test. Initial appearance time of the surface rust was greatly retarded owing to the coated film in salt spray test.

Interfacial Evaluation and Damage Sensing of Carbon Fiber/Epoxy-AT-PEI Composite using Electro-Micromechanical Techniques (Electro-micromechanical 시험법을 이용한 탄소섬유 강화 Epoxy-AT PEI 복합재료의 손상 감지능 및 계면물성 평가)

  • Kim, Dae-Sik;Kong, Jin-Woo;Park, Joung-Man;Kim, Minyoung;Kim, Wonho;Ahn, Byung-Hyun;Park, Jin-Ho
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2002.10a
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    • pp.212-215
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    • 2002
  • Interfacial evaluation and damage sensing of the carbon fiber/epoxy-amine terminated (AT)-polyetherimide (PEI) composites were performed using micromechanical test and electrical resistance measurement. As AT-PEI content increased, the fracture toughness of epoxy-AT-PEI matrix increased, and thus their interfacial shear strength (IFSS) was improved due to the improved toughness. After curing process, the changes in electrical resistance (ΔR) with increasing AT-PEI contents increased gradually because of the changes in thermal expansion coefficient (TEC) and thermal shrinkage of matrix. Matrix fracture toughness was correlated to the IFSS, residual stress and electrical resistance. The results obtained from the electrical resistance measurement during curing process, reversible stress/strain, and durability test were consistent with modified matrix toughness properties.

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A study on Zn corrosion resistance of WC spray coating sealed with carbon nanotube suspensions (탄소 나노튜브 혼합액으로 봉공처리된 텅스텐 카바이드 용사층의 아연 내부식성에 대한 연구)

  • Kim, Bong-Hun;Lee, Bo-Young
    • Journal of Welding and Joining
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    • v.33 no.1
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    • pp.49-53
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    • 2015
  • An experimental study was conducted to investigate the effect of carbon nanotubes on the zinc corrosion resistance of sealing layer formed on the Tungsten Carbide spray coating. Using the nanotubes, a sealing agent in the form of solid-liquid suspensions was made and applied to the surface of spray coating. A series of experiments, consisted of three stages such as preparation of test piece, molten-pot immersion test, and evaluation of micro structure, were undertaken to demonstrate complicated interaction existing between zinc ions and sealing layer containing the nanotubes. Experimental results showed newly developed sealing layer were less susceptible to corrosion and thus coated layer was well protected even in the case of 10 days exposure. Comparison of the micro structure after molten pot test also indicated that carbon nanotubes still remained in the matrix and organized more reliable frame work constituted with boron nitride and chromium compound. It was revealed that carbon nanotubes in the sealing layer played positive role to enhance zinc corrosion resistance in the perspective of both fibrous structure and inherent chemical stability.

Advanced Metallic Coating for the Improvement of Corrosion and Erosion Resistance of Iron Base Materials Used in Buildings and Special Works

  • Jayaraj, J.;Seok, H.K.;Byun, K.H.;Fleury, E.;Hong, K.T.
    • Corrosion Science and Technology
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    • v.4 no.2
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    • pp.64-68
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    • 2005
  • Various metallic materials are coated on Fe base materials via thermal spraying or welding process to improve both corrosion resistance as well as erosion resistance of the Fe base materials used in buildings and special works. The mechanical properties and corrosion resistance of the coat are estimated by means of hardness measurement and anodic polarization test. In additions, the effect of alloying elements and microstructure of the coatings on the mechanical and chemical properties of the coat is investigated using X- ray diffraction, Optical microscope, Transmission electron microscopy and Auger analysis. The coating deposited by tungsten inert gas (TIG) welding exhibit a good combination of hardness and corrosion properties.

Effect of Environmental Factors on the Properties of Polymeric Material : Oil and Ozone Reaction Time (고분자재료의 물성에 미치는 환경인자의 영향: 오일 및 오존반응시간)

  • 박찬영
    • Journal of Environmental Science International
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    • v.9 no.6
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    • pp.511-515
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    • 2000
  • The purpose of this experiment is to prepare ethylene propylene diene terpolymer(EPDM)/ acrylonitrile butadiene rubber(NBR) blend which represents good environmental resistant properties including favorable oil and ozone resistance. With incorporation of EPDM, NBR and other ingredients, the rubber and chemical additives were mixed by mechanical method such as Banbury mixer and open 2-roll mill. Then rubber vulcanizates were manufactured by hot press and mechanical properties, oil and ozone resistance of the test specimens were measured. The oil resistance and ozone resistance of EPDM and NBR, respectively, is remarkably improved by blending EPDM with NBR. The optimum results of oil and zone resistant characteristics were obtained at EPDM/NBR(=25/75 wt%) composition ratio.

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A Study on the Improvement of Antimicrobial Activity and Crease Resistance of Korean Traditional Hansan Ramie Fabrics (한국 전통한산모시의 항균성 및 방추도 향상에 관한 연구)

  • Kim, Ho Jung;Choi, Jae Hyeok;Kim, Han Do;Park, Cha Cheol
    • Textile Coloration and Finishing
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    • v.6 no.4
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    • pp.1-8
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    • 1994
  • To improve the antimicrobial activity and crease resistance of Korean traditional Hansan ramie fabrics, partially saponified polyethylene(PPS) was used as a softening water repellent agent and 3-(trimethoxysilyl)propyl dimethyl octadecyl ammonium chloride(QAC) as a antimicrobial agent. The antimicrobial activity was effective by treatments of PPS, QAC and PPS/QAC for shake flask test. For the halo test, PPS/QAC showed good antimicrobial activity. It was found that the desirable composition of H$_{2}$O/PPS/QAC is 98/1/1 for improving the antimicrobial activity and crease resistance of the fabrics.

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Effect of Fluoride Conversion Coating on the Corrosion Resistance and Adhesion of E-painted AZ31 Magnesium Alloy

  • Fazal, Basit Raza;Moon, Sungmo
    • Journal of the Korean institute of surface engineering
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    • v.49 no.5
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    • pp.395-400
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    • 2016
  • This article reports improved corrosion resistance and adhesion of electro-paint (E-paint) with fluoride conversion coating (FCC) on AZ31 Mg alloy for the first time. These improvements were observed in comparison to chemically polished samples with no chemical conversion coating and samples with cerium conversion coatings (CeCC). FCCs were prepared in a hydrofluoric acid (HF) solution for four different times; 10, 30, 60, and 120 s. The colour of the samples changed from light gold to brown with increasing immersion time, indicating the formation of thicker FCC coatings with increasing immersion time. The adhesion of the E-paint on FCC-coated AZ31 Mg alloy was tested after 500 h of immersion in deionized (DI) water. Salt spray test (SST) results revealed delamination of E-paint on the chemically polished sample, severe blistering on the samples with CeCC, but no delamination and no blistering on the samples with FCC.