• Journal of the Korean Applied Science and Technology
• /
• v.23 no.4
• /
• pp.290-299
• /
• 2006

This article investigated to polymer-clay nanocomposite, especially in interfacial respect clay structure, its dispersion into polymer matrix, and clay modification is studied. The cationic exchange of surfactants with clay gallery results in preparing organo-clay capable of compatiblizing to monomer or polymer and increasing interlayer adhesion energy due to expansion of interlayer spacing. The orientation of surfactant in clay gallery is affected by chemical structure and charge density of clay, and interlayer spacing and volume is increased with alkyl chain length of surfactant, or charge density of clay. Also, the interaction between clay and polymer in preparing polymer-clay nanocomposite is explained thermodynamically. In the future, the study and development of polymer-clay nanocomposite is paid attention to the interfacial adhesion, clay dispersion within polymer, mechanism of clay intercalation or exfoliation.

• Proceedings of the Korean Geotechical Society Conference
• /
• 2010.03a
• /
• pp.338-350
• /
• 2010

As existing materials for ground reinforcement, chemical grout material using cementitous materials and waterglass was used. But many problems in terms of ground reinforcement effects were implicated. In this study, for development and applicability verification of new materials, viscosity, fluidity, permeability, Self-Leveling, keeping of drilled hole, antiwashout underwater, resistance of water (groundwater dilution and minimize material eluting) and the early strength and long-term strength characteristics of developed materials was confirmed, and material standards, and establishing construction standards for the various model tests were conducted. As a result, high viscosity, flowability, permeability and keeping of drilled hole characteristics are excellent, in addition to the early strength properties, dilution does nat occur to groundwater, including groundwater is available for dealing with environmental issues. Application of basic and reinforcement method by Filler function in addition to structure can also or development of a new concept can be expected. In addition, middle and large-diameter drilled shaft, micropile, ground anchors, soil-nailing, steel pipes multi-grouting reinforcement for cement injection process could be used enough to even be considered.

• Bulletin of the Korean Chemical Society
• /
• v.31 no.8
• /
• pp.2261-2264
• /
• 2010

In this work, mechanical and electrical properties of graphenes (GP)/carbon nanotubes (CNTs) co-reinforced high density polyethylene (HDPE) matrix composites were studied. The microstructure, morphologies, and electric properties of the composites were evaluated by XRD, TEM, and 4-probe methods, respectively. It was found that the electric resistivity of 0.5 wt %-GP/HDPE was immeasurable, and 2.0 wt %-CNTs/HDPE showed high resistivity ($6.02{\times}10^4{\Omega}{\cdot}cm$). Meanwhile, GP (0.5 wt %)/CNTs (2.0 wt %)/HDPE showed excellent low resistivity ($3.1{\times}10^2{\Omega}{\cdot}cm$). This result indicates that the co-reinforcement systems can dramatically decrease electric resistivity of the carbon/polymer nanocomposites.

• Proceedings of the Korean Geotechical Society Conference
• /
• 2004.03b
• /
• pp.189-196
• /
• 2004

In this study, the colloidal silica grouts (PSG) with novel chemical compositions for permanent reinforcement and water cut-off of the ground were prepared and their engineering charateristics were investigated. The optimum mixing recipes for both homogeneous solution grouts and heterogeneous suspension grouts were investigated and established through many repeated lab tests. The various physical properties(such as compressive strength, durability and syneresis) of the grout gels derived from the colloidal silica were investigated and compared with those of the well-known existing watergalss grouts. The all experimental results showed that the novel colloidal silica grouts(PSG) had greatly excellent performances as permanent grouts, especially in comparison with the existing watergalss grouts.

• International Journal of Control, Automation, and Systems
• /
• v.2 no.3
• /
• pp.263-278
• /
• 2004

This paper reviews dynamic programming (DP), surveys approximate solution methods for it, and considers their applicability to process control problems. Reinforcement Learning (RL) and Neuro-Dynamic Programming (NDP), which can be viewed as approximate DP techniques, are already established techniques for solving difficult multi-stage decision problems in the fields of operations research, computer science, and robotics. Owing to the significant disparity of problem formulations and objective, however, the algorithms and techniques available from these fields are not directly applicable to process control problems, and reformulations based on accurate understanding of these techniques are needed. We categorize the currently available approximate solution techniques fur dynamic programming and identify those most suitable for process control problems. Several open issues are also identified and discussed.

• Applied Chemistry for Engineering
• /
• v.9 no.6
• /
• pp.907-913
• /
• 1998

Corrosion behavior of steel reinforcements embedded in concrete containing various chloride ion concentrations was investigated by an electrochemical impedance spectroscopy(EIS). Chloride ions were introduced into the concrete by dissolving the NaCl and $CaCl_2$ in the water with a given weight of cement. Based on the impedance parameters measured by EIS, more complete equivalent circuit, a schematic physical model, and the mechanism of concrete reinforcement corrosion were suggested. By the implement of experimental impedance parameters obtained from the model with corresponding CNLS-fitting data, the corrosion rate of steel reinforcement with chloride ions could be predicted.

• Journal of the Korean Geotechnical Society
• /
• v.40 no.5
• /
• pp.51-58
• /
• 2024

Chemical ground reinforcement involves enhancing the mechanical properties of soil through chemical reactions. Existing ground reinforcement materials pose challenges, including environmental pollution during production and use, pH fluctuations caused by leaching into groundwater, and ecological disturbances. This study investigates the engineering performance of soils treated with casein polymer, a milk-derived, eco-friendly reinforcement material. The performance assessment was carried out by measuring unconfined compressive strength and hydraulic conductivity across different soil types, including Jumunjin sand, granite weathered soil, and soft soils. The analysis examined the relationship between unconfined compressive strength, hydraulic conductivity, and soil type. The findings indicate significant correlations based on the concentration of casein polymer and soil type. The outcomes of this study provide foundational data for the application of casein polymer in soil reinforcement efforts.

• Journal of Ocean Engineering and Technology
• /
• v.12 no.3 s.29
• /
• pp.68-74
• /
• 1998

An increase of concrete construction in marine environments as well as an increasing use of marine aggregate at the mixing stage of concrete has provoked an important problem. A high concentration of chloride ion in the vicinity of steel bars in concrete is the principal cause of premature reinforcement corrosion in concrete structures. In this study, the behavior of chloride ions introduced into concrete from concrete surface by marine evironment was analysed. A mathematical model including the diffusion of chloride ion in aqueous phase of pores, the adsorption and desorption of chloride ions to and from the surface of solid phase of concrete and the chemical reactions of chloride ions with solid phase was presented. Finite element method was employed to carry out numerical analysis. The results of this study may be used to predict the onset of reinforcement corrosion and to identify the maximum limit of chloride ions contained in concrete admixtures.

• Proceedings of the KSR Conference
• /
• 2004.10a
• /
• pp.1156-1161
• /
• 2004

The factors affecting the long-term design strength of geogrid for railroad reinforcement can be classified into factors on creep deformation, installation damage, temperature, chemical degradation, biological degradation. Especially, creep deformation and installation damage are considered as main factors to determine the long-term design strength of geogrid. This paper describes the results of a series of experimental study, which are carried out to assess the combined effect of installation damage and creep deformation for the long-term design strength of geogrid reinforcement. In this study, a series of field tests are carried out to assess installation damage of a various geogrids according to different fill materials, and then creep tests are conducted to assess the creep properties of both undamaged and damaged geogrids.

• Elastomers and Composites
• /
• v.30 no.3
• /
• pp.207-217
• /
• 1995

The reinforcement of Inorganic filler silica treated with LBR-MDI In SBR vulcanizates were Investigated. The inorganic filler silica treated with MDI on unmodified surface and that of silica treated by MDI was retreated with LBR. The charateristics of vulcanization, physical properties, surface properites and dynamic properties were investigated after mixing those silica with SBR and unmodified silica with SBR. Rheometric studies of the vulcanization showed that S-series has fast scorch $time(t_{10})$ and an optimum cure $time(t_{90})$ in the SBR compounds. And it was turned out that SBR vulcanizates compounded with LBR treated silica was better than any other componnds in hardness, tensile strenght, 100 300% modula and elongation. We could confirm that urea bonding is formed from IR spectrum. We concluded that L-series shows the best reinforcement effect in SBR vulcanizates.