• Title/Summary/Keyword: chemical regime

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Differentiation among stability regimes of alumina-water nanofluids using smart classifiers

  • Daryayehsalameh, Bahador;Ayari, Mohamed Arselene;Tounsi, Abdelouahed;Khandakar, Amith;Vaferi, Behzad
    • Advances in nano research
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    • v.12 no.5
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    • pp.489-499
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    • 2022
  • Nanofluids have recently triggered a substantial scientific interest as cooling media. However, their stability is challenging for successful engagement in industrial applications. Different factors, including temperature, nanoparticles and base fluids characteristics, pH, ultrasonic power and frequency, agitation time, and surfactant type and concentration, determine the nanofluid stability regime. Indeed, it is often too complicated and even impossible to accurately find the conditions resulting in a stabilized nanofluid. Furthermore, there are no empirical, semi-empirical, and even intelligent scenarios for anticipating the stability of nanofluids. Therefore, this study introduces a straightforward and reliable intelligent classifier for discriminating among the stability regimes of alumina-water nanofluids based on the Zeta potential margins. In this regard, various intelligent classifiers (i.e., deep learning and multilayer perceptron neural network, decision tree, GoogleNet, and multi-output least squares support vector regression) have been designed, and their classification accuracy was compared. This comparison approved that the multilayer perceptron neural network (MLPNN) with the SoftMax activation function trained by the Bayesian regularization algorithm is the best classifier for the considered task. This intelligent classifier accurately detects the stability regimes of more than 90% of 345 different nanofluid samples. The overall classification accuracy and misclassification percent of 90.1% and 9.9% have been achieved by this model. This research is the first try toward anticipting the stability of water-alumin nanofluids from some easily measured independent variables.

Dynamics and Instability of a Polymeric Paint in Roll Coating Process for Automotive Pre-coating Application (자동차 선도장을 위한 롤코팅 공정에서 고분자 도료의 동적 거동 및 불안정성)

  • Kim, Jin-Ho;Lee, In-Jun;Noh, Seung-Man;Kang, Choong-Yeol;Nam, Joon-Hyun;Jung, Hyun-Wook;Park, Jong-Myung
    • Polymer(Korea)
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    • v.35 no.6
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    • pp.574-579
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    • 2011
  • 3-Roll coating process as a key application technology for manufacturing automotive pre-painted metal-sheets has been studied. The 3-Roll coating system for this study consists of pick-up roll for picking up and distributing coating liquid from the reservoir, metering roll to properly meter coating liquid in metering gap regime, and applicator roll for directly transferring liquid into metal-sheet surface. Flow dynamics and operable coating windows of a polymeric paint (primer) with shear-thinning rheological property have been correlated with processing parameters such as speed ratio and metering gap between pick-up and metering rolls. In the uniform coating regime, dry coating thickness increased with increasing metering gap or decreasing speed ratio. Ribbing and cascade instabilities were observed in low speed and high speed ratio conditions, respectively. It is revealed that lower speed ratio makes severity and wavelength of the ribbing increase, aggravating flow instability in coating systems.

High Temperature Drying of North American Ginseng for Management Decision Making

  • Bailey, W.G.;Dalfsen, K.B.van;Guo, Y.P.
    • Journal of Ginseng Research
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    • v.27 no.3
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    • pp.141-145
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    • 2003
  • The multi-year production cycle for ginseng can be rapidly depreciated by inferior post-harvest activities. This research examines the character of high temperature drying regimes for North American ginseng root to assist management decision making. The objective is a very rapid drying regime, that will not result in physical or chemical damage to the root and that would not alter the actual dry root weight. Research is presented using drying temperatures of 55, 70 and 105 C. Temperatures above these rapidly cause substantive physical damage to the root samples and seriously compromise the dry root values determined. Temperatures below these behaved quite similar to actual dryer regimes (approximately 38 C). Laboratory results indicate that there are differences between the three temperature regimes tested. Careful usage of the 70 C regime, over a period of two to three days in a convection drying oven, has distinct merit.

Numerical Study on Vortex Structures in a Two-dimensional Bluff-Body Burner in the Transitional Flow Regime

  • Kawahara, Hideo;Nishimura, Tatsuo
    • Journal of the Korean Society of Combustion
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    • v.7 no.1
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    • pp.31-36
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    • 2002
  • Vortical structures are investigated numerically for both cold and combusting flows from a two-dimensional bluff-body burner in the transitional flow regime from steady to unsteady state. The Reynolds number of the central fuel flow is varied from 10 to 230 at a fixed air Reynolds number of 400. The flame sheet model of infinite chemical reaction and unit Lewis number are assumed in the simulation. The temperature dependence of the viscosity and diffusivity of the gas mixture is also considered. The vortex shedding is observed depending on the fuel flow. For cold flow, four different types of vortical structure are identified. However, for combusting flow of methane-air system the vortical structures change significantly due to a large amount of heat release during the combustion process, in contract to cold flow.

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Holographic Grating by Means of Polymer Liquid Crystals

  • Ikeda, Tomiki;Yoneyama, Satoshi;Yamamoto, Takahiro;Hasegawa, Makoto
    • Journal of Information Display
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    • v.2 no.3
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    • pp.6-12
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    • 2001
  • Formation of intensity gratings was studied with two s-polarized (s+s) configuration in polymer liquid crystals (PLCs) containing a photochromic moiety (azobenzene) and a mesogenic unit (tolane, T-AB; cyanobiphenyl, CB-AB) by photoinduced alignment of PLCs. Remarkable differences were observed between the two PLCs. T-AB showed a faster response to the change in the diffraction intensity than CB-AB. In T-AB, alignment change took place faster than that of CB-AB. By introducing the tolane unit at the side chain, we obtained a diffraction efficiency of 30 % in the Raman-Nath regime

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Growth Characteristics of Micro Carbon Structures Fabricated by Laser-Assisted Chemical Vapor Deposition (레이저 국소증착법에 의한 탄소 미세 구조물의 제조시 성장특성에 관한 연구)

  • Kim, Jin-Beom;Lee, Seon-Gyu;Lee, Jong-Hyeon;Jeong, Seong-Ho
    • Journal of the Korean Society for Precision Engineering
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    • v.19 no.7
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    • pp.106-115
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    • 2002
  • Growth characteristics of micro carbon structures fabricated by laser-assisted chemical vapor deposition are studied. Argon ion laser and ethylene were used as the energy source and reaction gas, respectively, to grow micro carbon rod through pyrolytic decomposition of the reaction gas. Experiments were performed at various conditions to investigate the influence of process parameters on growth characteristics such as the diameter or growth rate of the micro carbon rod with respect to reaction gas pressure and incident laser power. Reaction gas pressure in experiments ranges from 200 to 600Torr and the incident laser power from 0.3 to 3.8W. For these conditions, the diameter of the rod increases linearly with respect to the laser power but is almost independent of the reaction gas pressure. Growth rate of the rod changes little with gas pressure when the laser power remains below IW. For a constant reaction gas pressure, the growth rate increase with Increasing laser power, but the rate of increase decreases gradually, implying that the chemical vapor deposition condition changes from a kinetically-limited regime to a mass-transport-limited regime. When the carbon rod was grown at near threshold laser power, a very smooth surface is obtained on the rod. By continuously moving the focusing lens in the direction of growth, a micro carbon rod with a diameter of 287${\mu}{\textrm}{m}$ and aspect ratio of 100 was fabricated..

Thermal Decomposition of Tetrakis(ethylmethylamido) Titanium for Chemical Vapor Deposition of Titanium Nitride

  • Kim, Seong-Jae;Kim, Bo-Hye;Woo, Hee-Gweon;Kim, Su-Kyung;Kim, Do-Heyoung
    • Bulletin of the Korean Chemical Society
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    • v.27 no.2
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    • pp.219-223
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    • 2006
  • The thermal decomposition of tetrakis(ethylmethylamido) titanium (TEMAT) has been investigated in Ar and $H_2$ gas atmospheres at gas temperatures of 100-400 ${^{\circ}C}$ by using Fourier Transform infrared spectroscopy (FTIR) as a fundamental study for the chemical vapor deposition (CVD) of titanium nitride (TiN) thin film. The activation energy for the decomposition of TEMAT was estimated to be 10.92 kcal/mol and the reaction order was determined to be the first order. The decomposition behavior of TEMAT was affected by ambient gases. TEMAT was decomposed into the intermediate forms of imine (C=N) compounds in Ar and $H_2$ atmosphere, but additional nitrile (RC$\equiv$N) compound was observed only in $H_2$ atmosphere. The decomposition rate of TEMAT under $H_2$ atmosphere was slower than that in Ar atmosphere, which resulted in the extension of the regime of the surface reaction control in the CVD TiN process.

Characteristics of Gas-liquid Mass Transfer and Interfacial Area in a Bubble Column

  • Lim, Dae Ho;Yoo, Dong Jun;Kang, Yong
    • Korean Chemical Engineering Research
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    • v.53 no.3
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    • pp.315-320
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    • 2015
  • Characteristics of gas-liquid mass transfer and interfacial area were investigated in a bubble column of diameter and height of 0.102 m and 2.5 m, respectively. Effects of gas and liquid velocities on the volumetric gas-liquid mass transfer coefficient ($k_La$), interfacial area (a) and liquid side true mass transfer coefficient ($k_L$) were examined. The interfacial area and volumetric gas-liquid mass transfer coefficient were determined directly by adopting the simultaneous physical desorption of $O_2$ and chemical absorption of $CO_2$ in the column. The values of $k_La$ and a increased with increasing gas velocity but decreased with increasing liquid velocity in the bubble column which was operated in the churn turbulent flow regime. The value of $k_L$ increased with increasing gas velocity but did not change considerably with increasing liquid velocity. The liquid side mass transfer was found to be related closely to the liquid circulation as well as the effective contacting frequency between the bubbles and liquid phases.

Thickness Dependence of Size and Arrangement in Anodic TiO2 Nanotubes

  • Kim, Sun-Mi;Lee, Byung-Gun;Choi, Jin-Sub
    • Bulletin of the Korean Chemical Society
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    • v.32 no.10
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    • pp.3730-3734
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    • 2011
  • The degree of self-assembly and the size variation of nanotubular structures in anodic titanium oxide prepared by the anodization of titanium in ethylene glycol containing 0.25 wt % $NH_4F$ at 40 V were investigated as a function of anodization time. We found that the degree of self-assembly and the size of the nanotubes were strongly dependent on thickness deviation and thus indirectly on anodization time, as the thickness deviation was caused by the dissolution of the topmost tubular structures at local areas during long anodization. A large deviation in thickness led to a large deviation in the size and number of nanotubes per unit area. The dissolution primarily occurred at the bottoms of the nanotubes ($D_{bottom}$) in the initial stage of anodization (up to 6 h), which led to the growth of nanotubes. Dissolution at the tops ($D_{top}$) was accompanied by $D_{bottom}$ after the formed structures contacted the electrolyte after 12 h, generating the thickness deviation. After extremely long anodization (here, 70 h), $D_{top}$ was the dominant mode due to increase in pH, meaning that there was insufficient driving force to overcome the size distribution of nanotubes at the bottom. Thus, the nanotube array became disorder in this regime.

A Study on Laminar Lifted Jet Flames for Diluted Methane in Co-flow Air

  • Sapkal, Narayan P.;Lee, Won June;Park, Jeong;Kwon, Oh Boong
    • Journal of the Korean Society of Combustion
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    • v.20 no.3
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    • pp.1-7
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    • 2015
  • The laminar lifted jet flames for methane diluted with helium and nitrogen in co-flow air have been investigated experimentally. Such jet flames could be lifted in both buoyancy-dominated and jet momentum dominated regimes (even at nozzle exit velocities much higher than stoichiometric laminar flame speed) despite the Schmidt number less than unity. Chemiluminescence intensities of $OH^*$ radical (good indicators of heat release rate) and the radius of curvature for tri-brachial flame were measured using an intensified charge coupled device (ICCD) camera and digital video camera at various conditions. It was shown that, an increase in $OH^*$ concentration causes increase of edge flame speed via enhanced chemical reaction in buoyancy dominated regime. In jet momentum dominated regime, an increase in radius of curvature in addition to the increased $OH^*$ concentration stabilizes such lifted flames. Stabilization of such lifted flames is discussed based on the stabilization mechanism.