• Title/Summary/Keyword: chemical recycle

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Study on the Comparison of New and Used Reliquefaction System of Boil-Off-Gas by LNG Cold Energy (냉열을 이용한 LNG 증발기체 BOG 재액화 신공정과 기존공정에 관한 비교연구)

  • Lee, Dong-Hyuck;Jang, Chang-Bong;Jung, Sang-Yong;Kim, Jung-Hwan;Lee, Heon-Seok;Kim, Bum-Su;Ko, Jae-Wook
    • Journal of the Korean Institute of Gas
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    • v.14 no.1
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    • pp.42-46
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    • 2010
  • BOG(Boil Off Gas) is formed about 0.05 vol%/day from LNG(Liquefied Natural Gas) tanks of LNG receiving terminal. To recycle the BOG using direct contacting, Previously the quantities of LNG and BOG is mixed at the ratio of 11:1 by mass. However simple this process uses, there is the difficulty of processing operation resulted from decrease of using LNG in summer. To complement these shortcomings, Advantages of the process are investigated by comparison of cost and analysis of the indirect contact method using LNG cold energy. It was studied that principles and types of development using LNG cold energy which is abandoned in the carburettor and found how to contact each to find the appropriate cold energy development process. Therefore, in this research, the indirect contact method will be investigated the feasibility of a comparative analysis by using HYSYS.

Phyto-restoration Potential of Soil Properties using Secale cereale for Recycle of Soils with Residual TPHs (Total Petroleum Hydrocarbons) after Off-site Treatment (잔류유분 함유 반출처리토 재활용을 위한 호밀 식재 식물상 토성회복 가능성)

  • Park, Jieun;Bae, Bumhan;Joo, Wanho;Bae, Seidal;Bae, Enjoo
    • Journal of Soil and Groundwater Environment
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    • v.19 no.3
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    • pp.25-32
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    • 2014
  • The amount of TPH contaminated soil treated at off-site remediation facilities is ever increasing. For the recycle of the treated-soil on farmlands, it is necessary to restore biological and physico-chemical soil characteristics and to remove residual TPH in the soil by an economic polishing treatment method such as phytoremediation. In this study, a series of experiments was performed to select suitable plant species and to devise a proper planting method for the phyto-restoration of TPH-treated soil. Rye (Secale cereale) was selected as test species through a germination test, among 5 other plants. Five 7-day-old rye seedlings were planted in a plastic pot, 20 cm in height and 15 cm in diameter. The pot was filled with TPH-treated soil (residual TPH of 1,118 mg/kg) up to 15 cm, and upper 5 cm was filled with horticulture soil to prevent TPH toxic effects and to act as root growth zone. The planted pot was cultivated in a greenhouse for 38 days along with the control that rye planted in a normal soil and the blank with no plants. After 38 days, the above-ground biomass of rye in the TPH-treated soil was 30.6% less than that in the control, however, the photosynthetic activity of the leaf remained equal on both treatments. Soil DHA (dehydrogenase activity) increased 186 times in the rye treatment compared to 10.8 times in the blank. The gross TPH removal (%) in the planted soil and the blank soil was 34.5% and 18.4%, respectively, resulting in 16.1% increase of net TPH removal. Promotion of microbial activity by root exudate, increase in soil permeability and air ventilation as well as direct uptake and degradation by planted rye may have contributed to the higher TPH removal rate. Therefore, planting rye on the TPH-treated soil with the root growth zone method showed both the potential of restoring biological soil properties and the possibility of residual TPH removal that may allow the recycle of the treated soil to farmlands.

Effects of Aluminum Addition and Recycle of NaOH Waste Solution on the Quality of Zeolite Synthesized from Fly Ash (알루미늄 첨가 및 NaOH 폐용액의 재활용이 Fly Ash로부터 합성한 Zeolite의 품질에 미치는 영향)

  • Choi, Choong-Lyeal;Lee, Dong-Hoon;Park, Man;Song, Kyung-Sik;Rhee, In-Koo;Choi, Jyung;Kim, Jang-Eok
    • Korean Journal of Soil Science and Fertilizer
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    • v.38 no.2
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    • pp.72-77
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    • 2005
  • This study was performed to examine the effects of aluminum addition and recycle of NaOH waste solution on CEC and crystallinity of zeolite synthesized from fly ash. The added aluminum was used as the source of zeolite framework in zeolitization of fly ash. CEC and crystallinity of Na-P1 zeolite synthesized with aluminum addition were increased from 285 to $365cmol_c\;kg^{-1}$ and from 44.3 to 57.1% compared to that of simple hydrothermal treatment, respectively. The recycled NaOH solution did not affect the CEC of reaction products, though the crystallinity was decreased a little. Therefore, the additional supply of aluminum could improve the quality of zeolite synthesized from fly ash and the recycle of NaOH during zeolite synthesis can save the chemical without any adverse effects in the quality of synthesized seolite.

Recycling Technology of Cementitious Powder for Completely Recycling of Concrete Waste (폐콘크리트의 순환이용을 위한 폐미분말의 재활용 기술)

  • Park, Cha-Won;Kang, Byeung-Hee
    • Journal of the Korea Institute of Building Construction
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    • v.5 no.3 s.17
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    • pp.109-116
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    • 2005
  • Recently, there have been many studies seeking towards the utilization of cementitious powder from concrete waste as recycled cement. However, most of the studies actually have been researches about the reuse of mortar or paste, not concrete waste. In fact, either mortar or paste is quite different from a real concrete waste in terms of age and mixture. Thus the purpose of this study is to examine basic physical properties of recycled cement, manufactured with cementitious powder from concrete waste, and analyze differences in chemical and hydraulic properties of the cement and its tested model. As a result of the chemical analysis, recycle cement is composed mainly of CaO and $SiO_2$, and that it is even lower in the content of CaO than Portland cement, which is also supported by previous studies. But, Differently from previous studies, calcining temperature of 650 was found an optimal condition under which cementitious powder from concrete waste could restore its hydraulic properties.

Resource recovery and harmless treatment of waste oil-in-water drilling fluid

  • Tang, Chao;Xie, Shui Xiang
    • Environmental Engineering Research
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    • v.22 no.3
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    • pp.277-280
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    • 2017
  • Destablization and demulsification is a difficult task for the treatment of waste oil-in-water drilling fluid because of its "three-high" characteristics: emulsification, stabilization and oiliness. At present, China is short for effective treating technology, which restricts cleaner production in oilfield. This paper focused on technical difficulties of waste oil-in-water drilling fluid treatment in JiDong oilfield of China, adopting physical-chemical collaboration demulsification technology to deal with waste oil-in-water drilling fluid. After oil-water-solid three-phase separation, the oil recovery rate is up to 90% and the recycled oil can be reused for preparation of new drilling fluid. Meanwhile, harmless treatment of wastewater and sludge from waste oil-in-water drilling fluid after oil recycling was studied. The results showed that wastewater after treated was clean, contents of chemical oxygen demand and oil decreased from 993 mg/L and 21,800 mg/L to 89 mg/L and 3.6 mg/L respectively, which can meet the requirements of grade one of "The National Integrated Wastewater Discharge Standard" (GB8978); The pollutants in the sludge after harmless treatment are decreased below the national standard, which achieved the goal of resource recovery and harmless treatment on waste oil-in-water drilling fluid.

A Study on Inorganic Chemical Treatment Method of Animal Wastes Using by Electroflotation for Recycle (전해부상 장치를 이용한 축산폐수의 유기질비료와 용수 재활용에 관한 연구)

  • Sung Ki-chun;Kim Yong-Ryul;Kim Ki-Jun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.5 no.6
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    • pp.588-591
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    • 2004
  • There is an increasing interest in the use of electrochemical methods for the animal waste treatment The technologies using the electrochemical method provide ideal tools for approaching industrial and animal wastes problems. Unlike other chemical treatments, the electrochemical systems do not make the volume of the secondary waste increase. The electrochemical methods can be operated with electrochemical apparatus and inorganic agent allow selective separation and recovery and even quieter than others. This study concerns design factors, electrode construction and wastewater treatment process of the electrochemical apparatus. The experiment of color, COD and BOD removal is much effective in using electrochemical method with ultrasonication and ozonation.

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Recycling Technology of Crosslinked-Polymers Using Supercritical Fluid (초임계 유체를 이용한 가교고분자 재활용기술)

  • Koo, Chong-Min;Yu, Si-Won;Baek, Bum-Ki;Cho, Hang-Kyu;Lee, Youn-Woo;Hong, Soon-Man
    • Elastomers and Composites
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    • v.47 no.2
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    • pp.111-120
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    • 2012
  • Industrial wastes of crosslinked polymers have been burned or disposed of in landfills because there is no recycling technology due to their insoluble and infusible network chain structure. However, recycling of cross-linked polymers has been taken a growing attention because of issues of environmental pollution and of resources conservation. In this paper, uprising recycling technologies of crosslinked polymers using supercritical fluid are reviewed.

Thermo-reversible Crosslinking Elastomer through Supramolecular Networks (초분자 네트워크를 이용한 열가역성 가교 탄성체)

  • Bae, Jong-Woo;Oh, Sang-Taek;Kim, Gu-Ni;Baik, Hyen-Jong;Kim, Won-Ho;Choi, Sung-Seen
    • Elastomers and Composites
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    • v.45 no.3
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    • pp.165-169
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    • 2010
  • Recently supramolecular network thermo-reversible crosslinking elastomer having flexibility, various functionality, and advantages of thermoplastic elastomer (TPE) such as recycle and easy processbility is introduced. Although thermo-reversible bonds such as hydrogen bond and ionic cluster is recognized as a common technology since 1990, control technology of bonding and dissociation of crosslink in supramolecular network is a recent technology. In this review, characteristics of thermo-reversible crosslinking elastomer having rheological properties of TPE and reinforcing behaviors of thermoset elastomer are summarized.

Polymer-supported Zinc Tetrahalide Catalysts for the Coupling Reactions of CO2 and Epoxides

  • Lee, Bo-Ra;Ko, Nan-Hee;Ahn, Byoung-Sung;Cheong, Min-Serk;Kim, Hoon-Sik;Lee, Je-Seung
    • Bulletin of the Korean Chemical Society
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    • v.28 no.11
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    • pp.2025-2028
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    • 2007
  • Homogeneous zinc tetrahalide complexes, highly active catalysts for the coupling reactions of alkylene oxide and CO2 produce alkylene carbonates, were heterogenized due to their tendency to decompose produced alkylene carbonates during the distillation process. Heterogenization of homogeneous zinc tetrahalide complexes was achieved by polymerizing 1-alkyl-3-vinylimidazolium zinc tetrahalides. These polymerized zinc tetrahalide catalysts displayed similar activities to their corresponding monomeric analogues for the coupling reactions of carbon dioxide with ethylene oxide (EO) or propylene oxide (PO) to produce ethylene carbonate (EC) or propylene carbonate (PC). TGA studies showed that the polymer-supported zinc tetrahalide catalysts are thermally stable up to 320 oC. The catalyst recycle test showed that the supported catalysts could be reused over six times. After removal of the polymer-supported catalyst through a simple filtration, EC was able to be isolated without decomposition.

Use of Selective Ethanol Adsorption for Ethanol Concentration (선택적 에탄올 흡착을 활용한 에탄올 농축공정개발)

  • Jin, Li-Hua;Lee, Jung-Heon
    • KSBB Journal
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    • v.25 no.5
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    • pp.466-470
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    • 2010
  • In this study, we developed simple process for ethanol concentration. We developed magnetically separable polyanilline nanofiber (PAMP) for selective ethanol adsorption. PAMP can adsorbed 80% of ethanol in the solution. After adsorption, the ethanol was recovered with simple magnetic separation and centrifugation process. After 10 times recycle of PAMP, the ethanol adsorption maintained 92% of its initial adsorption capacity. Using ethanol concentration process, the ethanol concentration increased up to 197.6 g/L from 46 g/L which was 4.3 folds increase.