• 제목/요약/키워드: chemical properties.

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전력케이블에서 탄소나노튜브 함량에 따른 반도전층 재료의 특성 연구 (A Study on the Properties of Semiconducting Materials with contents of Carbon Nanotube in Power Cable)

  • 양종석;신동훈;이경용;박대희
    • 전기학회논문지
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    • 제56권3호
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    • pp.571-576
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    • 2007
  • In this paper, we have investigated chemical, mechanical and structural properties by changing the content of carbon nanotube, Which is a component part of semiconductive shield in underground power transmission cable. The multi luminescence spectrometer MLA-GOLDS was used to investigate chemical properties of specimens. Also, the density meter EW-200SG was used to investigate the mechanical properties of specimens, and the FE-SEM S-4300 in Hitachi was used for dispersion of CNT(Carbon nanotube). As a result, the cl intensity, which show the effect of oxidation, was decreased by CNT of 1 [wt%], and the density of semiconductive shield materials with CNT and EEA(Ethylene Ethyl Acrylate) is lower than that for commercial semiconductive shield materials. Also, the properties of dispersion showed an increase according to an increase in the ratio of CNT, and the properties were the best at 5 wt%. Therefore, excellent chemical, mechanical and structural properties can be improved with the small amount of CNT.

미생물 종별 특성과 토양에 장기간 노출된 화합물들의 Bioavailability와의 상관 관계 (Microbial Properties Influencing The Bioavailability of Aged Chemical in Soil.)

  • 박성희;조재경;이남영
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 1998년도 공동 심포지엄 및 추계학술발표회
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    • pp.137-141
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    • 1998
  • A chemical has been aging in soil environment is more less bioavailable than freshly added chemical. The amount of bioavailability of the aged chemical is different by bacterial strains. The difference could be depend on physiochemical properties of each strain. Phenanthrene was employed as an aged chemical. Seven bacteria were isolated from activated sludge and petroleum disposed soil. These strains were able to degrade phenanthrene and to grow using phenanthrene as a sole carbon source. According to the result of materialization and chemical extraction experiment, the bioavailable amount of aged phenanthrene which has been aged in Lima loam is different by each bacteria. Several physiochemical properties of each strain were tested to certify correlation with their different amount of bioavailability.

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POSS/Polyurethane Hybrids and Nanocomposites: A Review on Preparation, Structure and Performance

  • Diao, Shuo;Mao, Lixin;Zhang, Liqun;Wang, Yiqing
    • Elastomers and Composites
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    • 제50권1호
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    • pp.35-48
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    • 2015
  • Polyhedral oligomeric silsesquioxane (POSS) is an important inorganic-organic hybrid material with a three-dimensional structure. Polyurethane (PU) is a widely applied polymer that has versatile properties with the change of two phase structure. When POSS is incorporated into PU by physical or chemical methods, many properties can be greatly improved, such as mechanical properties, thermal stability, biodegradation resistance, and water resistance. This paper reviews the recent progress in preparation, structure, and performance of POSS-modified polyurethane from the viewpoint of physical blending and chemical modification.

Relationship between Soil Management Methods and Soil Chemical Properties in Protected Cultivation

  • Kang, Yun-Im;Lee, In-Bog;Par), Jin-Myeon;Kang, Yong-Gu;Kim, Seung-Heui;Ko, Hyeon-Seok;Kwon, Joon-Kook
    • 한국환경농학회지
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    • 제28권4호
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    • pp.333-339
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    • 2009
  • Various cultural practices have been promoted as management options for enhancing soil quality and health. The use of soil management methods can cause changes in fertility by affecting soil chemical properties. This study aimed to evaluate interactions between soil chemical properties and soil management methods in protected cultivation, and to classify soil management methods that similarly affect soil chemical properties. Water-logging and irrigation reduced soil pH and available $P_2O_5$ content. Application of animal manures has a positive effect on levels of organic matter, Av.$P_2O_5$, K, Zn, and Cu. The electrical conductivites tened to be low in the application of organic amendments, including rice and wood residues. Deeper plowing caused a reduction in Ca content. Practicing soil nutrient-considering fertilization and fertigation did not exert an influence on nutrient element contents. In a cluster analysis of the soil management methods according to major nutrients, low similarities were found with deeper plowing and crop rotation with rice in comparison with other practices. In a cluster analysis by minor nutrient characteristics, crop rotation and application of animal manures and rice residues were linked at a high Ward's distance, while other practices were found to be relatively low distinct. Each soil management method has a similar or different effect on soil chemical properties. These results suggest the necessity of establishing limits and standards according to the effects of soil management methods on soil chemical properties for economic soil practices.

Physical and electrical properties of PLA-carbon composites

  • Kang Z. Khor;Cheow K. Yeoh;Pei L. Teh;Thangarajan Mathanesh;Wee C. Wong
    • Advances in materials Research
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    • 제13권3호
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    • pp.211-220
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    • 2024
  • Polylactic acid or polylactide (PLA) is a biodegradable thermoplastic that can be produced from renewable material to create various components for industrial purposes. In 3D printing technology, PLA is used due to its good mechanical, electrical, printing properties, environmentally friendly and non-toxic properties. However, the physical properties and excellent electrical insulation properties of PLA have limited its application. In this study, with the carbon black (CB) as filler added into PLA, the lattice spacing and morphology were investigated by using X-ray diffraction (XRD) and scanning electron microscope (SEM), respectively. The physical properties of PLA-carbon composite were evaluated by using tensile test, shore D hardness test and density and voids measurement. Impedance test was conducted to investigate the electrical properties of PLA-Carbon composites. The results demonstrate that the inclusion of carbon black as filler enhances the physical properties of the PLA-carbon composites, including tensile properties, hardness, and density. The addition of carbon black also leads to improved electrical conductivity of the composites. Better enhancement toward the electrical properties of PLA-carbon composites is observed with 1wt% of carbon black in N774 grade. The N550 grade with 2wt% of carbon black shows better improvement in the physical properties of PLA-carbon composites, achieving 10.686 MPa in tensile testing, 43.330 in shore D hardness test, and a density of 1.200 g/cm3 in density measurement. The findings suggest that PLA-carbon composites have the potential for enhanced performance in various industrial applications, particularly in sectors requiring improved physical and electrical properties.

Study on Synthesis of PAEKs Containing Triazole Units through Click Reaction and Their Properties

  • Wang, Lian-Jun;Li, Jie;Wang, Le-Yong
    • Bulletin of the Korean Chemical Society
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    • 제32권9호
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    • pp.3306-3310
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    • 2011
  • A series of novel linear aromatic ether ketone polymers containing triazole units were synthesized by click chemistry and their structures and properties were characterized by FT-IR, $^1H$ NMR, GPC, TGA, DSC and WAXD. The results showed that these polymers exhibited relatively small molecular weights distributions, good thermal stability and solvent-repelling which could have potential applications as engineering thermoplastic.

Nondestructive determination of physico-chemical properties in compost by NIRS

  • Seo, Sang-Hyun;Lee, Chang-Hee;Park, Sung-Hun;Cho, Rae-Kwang;Park, Woo-Churl
    • 한국근적외분광분석학회:학술대회논문집
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    • 한국근적외분광분석학회 2001년도 NIR-2001
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    • pp.1622-1622
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    • 2001
  • The purpose of this research was to develop a the reflection technique with near infrared (NIR) radiation for estimating physico-chemical properties in compost. The composts (cattle, pig, chicken and waste composts) were air dried and then ground to pass through a 0.5 or 2mm sieve for the physico-chemical properties and spectroscopic determinations. The physico-chemical properties of compost were shown high values ; moisture(30-60%), T-N(0.8-2.9%), organic matter(29-89%), pH(5.89-9.60) K$_2$O(0.27-5.66%), P2O$\sub$5/(0.07-2.62%), CaO(0.03-4.80%), MgO(0.09-1.56%), NaCl(0.01-1.13%), EC(1.41-13.76dS/m). Generally, we should select a simple calibration and prediction method for determining physico-chemical properties in compost under similar accuracy and precision of prediction. It should be remembered that the NIRS approach will never replace the traditional methods. However, NIRS technique may be an effective method for rapid and nondestructive measurements of a large number of compost samples. Near infrared reflectance spectra of composts was obtained by Infra Alyzer 500 scanning spectrophotometer at 2-nm intervals from 1100 to 2500nm. Multiple linear regression(MLR) or partial least square regression (PLSR) was used to evaluate a NIRS method for the rapid and nondestructive determination of physico-chemical properties and humic acid contents in composts. The standard error of prediction(SEP) for finely sized sample(<0.5mm) and coarsely sized sample(<2mm) did not show much difference. The NIR instrument of filter type showed the same accuracy of the monochromator scanning type to estimate the compost properties. The results summarized that NIR spectroscopy can be used as a routine testing method to determine quantitatively the OM, moisture, T-N, color, pH, cation content in the compost samples nondestructively.

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불수 sludge 시용이 배추의 생육과 토양의 화학성 변화에 미치는 영향 (Effects of the application of Sewage Sludge on the Growth of Chinese Cabbage(Brassica campestris L.) and Changes in Soil Chemical Properties.)

  • 김수영;조경철;정순주
    • 한국유기농업학회지
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    • 제9권1호
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    • pp.61-73
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    • 2001
  • This study was conducted to investigate the effect of sewage sludge application on the growth of chinese cabbage and the changes of chemical properties of soil. The experiment were set up with two different place and cultivated from Feb. 10 to June. 20 of 2000. Treatments are 0, 1.25, 2.5, 5, 10 and 20kg/3.3$\m^2$ of sewage sludge applicated into the soil and recorded the growth characteristics. Chemical properties of soil were also analysed before and after treatment. The application of the sewage sludge resulted in increasing the content of EC, cations exchange capacity, available phosphate and organic matter. And increased the growth characteristics in terms of the number of leaves, leaf area, fresh and dry weight regardless of crops experiments. Optimum amount of the sewage sludge depended on chemical properties of soil used. This results demonstrated that application of sewage sludge in the soil attribute to have play an important both improving soil chemical properties and promoting the crop growth. As lowering the soil pH(pH 6) heavy metal content increased compared with higher pH(pH 7). Feasibility was recognized in the application of sewage sludge as a fertilizer for the growth of chinese cabbage. Detrimental effects such as heavy metal in the soil and crop followed by the application of sewage sludge was not observed.

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Predicting Soil Chemical Properties with Regression Rules from Visible-near Infrared Reflectance Spectroscopy

  • Hong, Suk Young;Lee, Kyungdo;Minasny, Budiman;Kim, Yihyun;Hyun, Byung Keun
    • 한국토양비료학회지
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    • 제47권5호
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    • pp.319-323
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    • 2014
  • This study investigates the prediction of soil chemical properties (organic matter (OM), pH, Ca, Mg, K, Na, total acidity, cation exchange capacity (CEC)) on 688 Korean soil samples using the visible-near infrared reflectance (VIS-NIR) spectroscopy. Reflectance from the visible to near-infrared spectrum (350 to 2500 nm) was acquired using the ASD Field Spec Pro. A total of 688 soil samples from 168 soil profiles were collected from 2009 to 2011. The spectra were resampled to 10 nm spacing and converted to the 1st derivative of absorbance (log (1/R)), which was used for predicting soil chemical properties. Principal components analysis (PCA), partial least squares regression (PLSR) and regression rules model (Cubist) were applied to predict soil chemical properties. The regression rules model (Cubist) showed the best results among these, with lower error on the calibration data. For quantitatively determining OM, total acidity, CEC, a VIS-NIR spectroscopy could be used as a routine method if the estimation quality is more improved.