• 제어로봇시스템학회논문지
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• 제20권3호
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• pp.277-288
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• 2014

This article reviews various state estimation methods for nonlinear systems, particularly with a perspective of a process control engineer. Nonlinear state estimation methods can be classified into the following two categories: stochastic approaches and deterministic approaches. The current review compares the Bayesian approach, which is mainly a stochastic approach, and the MHE (Moving Horizon Estimation) approach, which is mainly a deterministic approach. Though both methods are reviewed, emphasis is given to the latter as it is particularly well-suited to highly nonlinear systems with slow sampling rates, which are common in chemical process applications. Recent developments in underlying theories and supporting numerical algorithms for MHE are reviewed. Thanks to these developments, applications to large-scale and complex chemical processes are beginning to show up but they are still limited at this point owing to the high numerical complexity of the method.

• 한국축산식품학회지
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• 제28권4호
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• pp.463-469
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• 2008

The objective of the present study was to compare the chemical, rheological and sensory properties of regular process cheese (control) and cholesterol-reduced block-type process cheese. The cholesterol-reduced process cheese was made by accelerated ripened cholesterol-reduced Cheddar cheese and cholesterol-reduced butter treated by crosslinked $\beta$-cyclodextrin ($\beta$-CD). The composition of the block-type process cheese was similar to the control cheese. Approximately 91.0% of cholesterol removal was observed when treated by crosslinked $\beta$-CD. The production of total free amino acids was significantly higher in cholesterol-reduced process cheese in all storage periods compared with those in the control. In sensory analysis, a significantly higher score of acidic, salty and bitterness. and lower score of elasticity were found. However, no difference was found in free fatty acids, rheological properties, and TBA test between the control and cholesterol-reduced process cheese. Therefore, the present study indicated that even though some of the significant difference was observed in sensory properties in the cholesterol-reduced block-type process cheese, most of chemical and rheological properties were comparable to the control process cheese.

• Korean Chemical Engineering Research
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• 제44권5호
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• pp.425-434
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• 2006

석유화학공업으로 대표되는 공정산업의 연속공정들은 지난 20여 년간 모델예측제어를 중심으로 고급제어(APC)기법들이 도입되며 운전성 및 생산성 향상에 많은 진보를 이루었다. 이에 반하여 중합반응기를 비롯한 각종 회분공정에는 APC 기법의 도입이 아직 활발히 이루어지지 않고 있다. 이것은 회분공정의 독특한 문제점을 극복하며 원하는 성능을 보장할 수 있는 방법론이 제시되지 못한 데에 가장 큰 이유가 있다고 할 수 있다. 그러나 최근 이러한 문제점들을 극복할 수 있는 APC 기법들이 반복학습제어(ILC)에 근거하여 개발되며 회분공정 APC 환경에 큰 변화가 일어나고 있다. 본 논문에서는 이들 기법들이 다양한 실제 공정에 활발하게 적용되어 운전을 개선할 수 있기를 기대하며, ILC를 기반으로 한 최근의 회분공정 APC 연구동향을 이론과 실례를 통해 소개한다.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2006년도 제37회 하계학술대회 논문집 C
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• pp.1384-1385
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• 2006

Platinum is a candidate of top and bottom electrode in ferroelectric random access memory and dynamic random access memory. High dielectric materials and ferroelectric materials were generally patterned by plasma etching, however, the low etch rate and low etching profile were repoted. We proposed the damascene process of high dielectric materials and ferroelectric materials for patterning process through the chemical mechanical polishing process. At this time, platinum as a top electrode was used for the stopper for the end-point detection as Igarashi model. Therefore, the control of removal rate in platinum chemical mechanical polishing process was required. In this study, an addition of $H_{2}O_{2}$ oxidizer to alumina slurry could control the removal rate of platinum. The removal rate of platinum rapidly increased with an addition of 10wt% $H_{2}O_{2}$ oxidizer from 24.81nm/min to 113.59nm/min. Within-wafer non-uniformity of platinum after chemical mechanical polishing process was 9.93% with an addition of 5wt% $H_{2}O_{2}$ oxidizer.

• 한국펄프종이공학회:학술대회논문집
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• 한국펄프종이공학회 2008년도 제33회 펄프종이기술 국제세미나
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• pp.87-122
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• 2008

In order to manage the papermaking procedure in an effective way, it is inevitably required to measure and estimate the various changing parameters of wet-end process control. This content is devoted to the explanation of lab scale new investigating method regarding wet-end process of paper machine by using RDA.

• 제어로봇시스템학회:학술대회논문집
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• 제어로봇시스템학회 2003년도 ICCAS
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• pp.1804-1809
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• 2003

In a large-scale chemical plant, there are scheduling problems in inventory and packing process although production process is stabilized. The profit of the plant is restricted by these problems. In order to improve these problems, integrated scheduling model, which is concerned with whole processes from production to shipment, has been developed in this paper. In this model, decision variables are production sequence, silo allocation, amounts of bulk shipment and packing amounts. In case of a real plant, it is hard to solve by deterministic methods because there are too many decision variables to solve. In this paper, genetic algorithm is presented to solve a PVC process scheduling model within an hour with PCs.

• KSBB Journal
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• 제6권2호
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• pp.189-194
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• 1991

The effect of wtlitc light on unaeraten growth of Baker's yeast and the accompanying ethanol production has been studied in a batch process at 27$^{\circ}C$. Over the 80-hour period of the Champagne yeast process without pH control, the cull growth was inhibited by the fluorescent light. Another observed difference between the runs is that the drop and subsequent rise in redox potential occurred much sooner in the fermentation with light than in the fermentation without light. This preliminary study indicated that ethanol production could be enhanced by light as the cell concentration is repressed. The possible pathway, shift of the sugar substrate toward ethanol and away from cells was manifested by another difference as well. As observed under the microscope, many of the yeast cells grown under light budded without dividing by the normal fission process as they did in the dark. Furthermore, the undivided and branched (light grown) cell did not agglutinate at the end of the fermentation process as did the distinct spherical (dark grown) cells.

• 제어로봇시스템학회:학술대회논문집
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• 제어로봇시스템학회 1996년도 한국자동제어학술회의논문집(국내학술편); 포항공과대학교, 포항; 24-26 Oct. 1996
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• pp.1120-1123
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• 1996

DMC(Dynamic Matrix Control) algorithm has been successfully used in industries for more than a decade. It can handle constraints and easily extended to MIMO case. The application of DMC, however, is limited to the open loop stable process because it uses the FIR(Finite Impulse Response) or FSR(Finite Step Response) model. Integrating process widely used in chemical process industry, is the representative open loop unstable process. The disturbance rejection of DMC is relatively poor due to the assumption that the current disturbance is equivalent to the future disturbance. We propose the IDMC(Improved Dynamic Matrix Control) for the integrating process, as well as non-integrating process. IDMC has shown better disturbance rejection using multi-step ahead predictor for the disturbance.

• 한국세라믹학회지
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• 제43권9호
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• pp.564-568
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• 2006

AlO(OH) nano gel is used in precursor of ceramic material, coating material and catalyst. For use of these, not only physiochemical control for particle morphology, pore characteristic and peptization but also studies of synthetic method for preparation of advanced application products were required. In this study, AlO(OH) nano gel was prepared through the aging and drying process of aluminum hydroxides gel precipitated by the hydrolysis reaction of dilute NaOH solution and aluminum sulfate solution. In this process, optimum synthetic condition of AlO(OH) nano gel having excellent pore volume as studying the effect of water and aluminum sulfate mole ratio on gel precipitates has been studied. Water and aluminum sulfate mole ratio brought about numerous changes on crystal morphology, surface area, pore volume and pore size. Physiochemical properties were investigated as using XRD, TEM, TG/DTA, FT-IR, and $N_2$ BET method.

• Bulletin of the Korean Chemical Society
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• 제30권10호
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• pp.2362-2364
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• 2009

We report Pt hexapod nanoparticles with $6.4\;{\sim}\;9.7$ nm in size by a polyol process in the presence of PVP as a stabilizer and additive as a kinetic controller. The structure and morphology of Pt nanostructures are confirmed by field-emission transmission electron microscopy. The morphological control over platinum nanoparticles is achieved by varying the amount of seeds in the polyol process, where platinum precursor is reduced by ethylene glycol to form Pt nanoparticle at $150\;{^{\circ}C}$. As volume ratio between precursor-solution and seed-solution is increased from 10 to 50, the shape of Pt nanostructures is evolved from small seeds to tripod and hexapod. In addition, the size-controlled platinum hexapod nanostructures are successfully obtained using seeding method.