• 한국환경농학회지
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• 제42권2호
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• pp.93-103
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• 2023

Persistence and degradation patterns of acequinocyl and its metabolite, hydroxyl-acequinocyl (acequinocyl-OH) and fenpyroximate in butterburs (Petasites japonicus Max.) were investigated after pesticide application. Butterburs, one of the minor crops in South Korea, was planted in two plots (plot A for double and plot B for single application) in a greenhouse. Butterburs samples were also planted in a separate plot without pesticide treatment, as the control. A commercial pesticide containing acequinocyl and fenpyroximate was applied to the foliage of butterburs at hourly intervals after dilution. Recoveries of acequinocyl and acequinocyl-OH were 78.6-84.7% and 83.7-95.5%, respectively; the relative standard deviation of the two compounds were less than 5%. The method limit of quantification was 0.01 mg/kg. The total (Ʃ) acequinocyl residues in butterburs reduced by 96.0% at 14 days and 75.9% at 7 days, in plot A and B, respectively, after final pesticide applications. The biological half-life (DT₅₀) of Ʃ acequinocyl and fenpyroximate, calculated using the dissipation rate, was 3.0 days and 4.0 days, respectively. These data were used to set up maximum residue and safe standard levels when the pesticides are applied to control pests during butterbur cultivation. Risk assessment results showed that the maximum % acceptable daily intake was 7.74% for Ʃ acequinocyl and 0.16% for Ʃ fenpyroximate. The theoretical maximum daily intake of Ʃ acequinocyl and fenpyroximate was 26.3% and 35.8%, respectively. In conclusion, the concentrations of Ʃ acequinocyl and fenpyroximate in butterburs pose no significant health risks to Koreans.

• 공업화학
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• 제9권7호
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• pp.985-989
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• 1998

본 연구는 가스크로마토그래피를 이용하여 사과와 고추에 대해 물, 주방용합성세제, 살균소독제 등의 다양한 세척제에 의한 농약의 세척 제거효율을 조사하였다. 농약의 회수율을 높이기 위해 대상 농약별로 상이한 전처리 조건으로 실험하였고 최적의 전처리 조건을 조사하였다. 분리관은 supelco STB-608을 사용했고 검출기로 전자포획검출기(ECD)를 사용했다. 농약제거효율은 알콜소독제>주방용합성세제>물 순서로 높았다.

• 한국환경농학회지
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• 제16권3호
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• pp.274-284
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• 1997

농경지로부터 농약의 유출은 수생태계 뿐만 아니라 사람에게도 영향을 미치는 중요한 요인으로, 유출될 수 있는 농약의 양에 대한 연구와 수생태계에 유입되어 환경생물에 영향을 미칠 가능성을 평가하는 환경독성학적 연구, 인체위해성에 대한 연구가 절실한 상황이다. 그러나 유출에 관여하는 요인이 너무 다양하여 단편적인 자료만으로 농약의 유출을 예측하기 어렵기 때문에 명확한 연구지침이 확립되어 있지 않으며, 국내에서도 연구가 적극적으로 시도되지 않고 있다. 따라서 농약의 유출에 대한 전반적인 연구사례 및 방법등에 대해 자연포장에서의 유출연구, 인공강우 모의포장을 이용한 유출연구, 그리고 computer 모델을 사용한 유출연구등 다양한 측면에서 고찰하여 보았다.

• Bulletin of the Korean Chemical Society
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• 제32권12호
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• pp.4265-4269
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• 2011

A method based on ethyl acetate extraction and gas chromatography with tandem mass spectrometry was developed for determining tetraconazole residues in fruits and vegetables. A 10 g homogenized sample was mixed with 10 mL ethyl acetate, shaken vigorously for 3 min, stored at $-20^{\circ}C$ for 15 min, and then vortexed vigorously for 1 min; 1 g NaCl and 4 g anhydrous $MgSO_4$ were added. The clean-up was carried out by applying dispersive solid-phase with 150 mg $MgSO_4$and 50 mg primary secondary amine. Three precursor product ion transitions for tetraconazole were measured and evaluated to provide the maximum degree of confidence. Average recoveries in fruits and vegetables at three levels (0.005, 0.05 and 0.5 mg/kg) ranged from 85.53% to 110.66% with relative standard deviations ($RSD_r$) from 1.3% to 17.5%. The LODs ranged from 0.002 to 0.004 ${\mu}g$/kg, and LOQs ranged from 0.006 to 0.012 ${\mu}g$/kg. This method was also applied to determine tetraconazole residue in cucumber dissipation experiment under field conditions. The half-lives of tetraconazole in cucumber were in the range of 2.1-3.1 days.

• 분석과학
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• 제9권3호
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• pp.320-324
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• 1996

The dynamic range of mass selected detector, which is very popular recently because of the simplicity and cheap price, was determined by using priority pollutants. The applied priority pollutants were four pesticides, 4,4'-DDE and 4,4'-DDD, which show the sharp peaks, and ${\alpha}$-endosulfan and ${\beta}$-endosulfan, which show the broad peaks in SIM Chromatogram. The dynamic range of the 4,4'-DDE and the 4,4'-DDD was $0.1{\sim}3000{\mu}g/ml$. The broad peaks of the ${\alpha}$-endosulfan and ${\beta}$-endosulfan resulted in $0.25{\sim}3000{\mu}g/ml$ of dynamic range.

• Membrane and Water Treatment
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• 제8권6호
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• pp.529-541
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• 2017

A multi-effect air gap membrane distillation (ME-AGMD) module for pesticide wastewater treatment is studied with internal heat recovery, sensible heat of brine recovery, number of stages and the use of fresh feed as cooling water in a single module is implemented in this study. A flat sheet polytetrafluroethylene (PTFE) membrane was used in the 4-stage ME-AGMD module. The maximum value of permeate flux could reach $38.62L/m^2h$ at feed -coolant water temperature difference about $52^{\circ}C$. The performance parameter of the module like, specific energy consumption and gain output ratio (GOR) was investigated for the module with and without heat recovery. Also, the module performance was characterized with respect to the separation efficiency of several important water quality parameters. The removal efficiency of the module was found to be >98.8% irrespective water quality parameters. During the experiment the membrane fouling was caused due to the deposition of the salt/crystal on the membrane surface. The membrane fouling was controlled by membrane module washing cycle 9 h and also by acidification of the feed water (pH=4) using 0.1M HCl solution.

• 한국유기농업학회지
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• 제19권spc호
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• pp.263-266
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• 2011

Crop protection strategies in organic horticulture aim to prevent insect pest and plant disease problems through utilization of non-chemical based control means. In order to develop a model for management of plant diseases and insects in organic cucumber cultivation, we compared efficacies between chemical pesticide spraying system and biological control means in semi-forcing and retarding cucumber cultivation during 2005 and 2006. Conventional chemical spray program using various chemical pesticides was applied 5 - 10 days intervals, while two different non-chemical pesticide application programs using two formulated biopesticides Topseed$^{TM}$ and Q-fect$^{TM}$, Suncho$^{TM}$, and Sangsungje$^{TM}$ (biocontrol agents 1) and using egg-yolk and cooking oil(EYCO), Bordeaux mixture, Suncho$^{TM}$, and Sangsungje$^{TM}$ (biocontrol agents 2) were applied 5 - 7 days intervals during entire cucumber cultivation period. Efficacy of both biocontrol agents programs was effective to comparable to conventional chemical pesitice spray program to control plant diseases such as powdery mildew and downy mildew as well as insect pests such as aphids and thrips which are known as major threats in cucumber organic cultivation. In this study, we established and evaluated an effective and economic crop protection strategy using various biological resources can be used to control plant diseases and pests simultaneously in organic cucumber cultivation field.

• 농약과학회지
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• 제6권1호
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• pp.45-48
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• 2002

Bicyclic ketal subgroup을 갖는 새로운 벤젠술포닐우레아 유도체들을 합성하여 제초활성을 온실에서 시험하였다. 그중에서 화합물 6b는 표준물질 thifensulfuron methyl과 비교 실험한 결과 처리약량 $6{\sim}100g/ha$의 밭조건 발아후 처리에서 밀에 대해서 보다 좋은 선택성을 나타내었으며 밭잡초들에 대한 제초활성은 비슷하거나 약간 떨어지는 결과를 나타내었다.

• 농약과학회지
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• 제6권4호
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• pp.320-323
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• 2002

N-methylureido기를 갖고 있는 새로운 benzenesulfonylurea계 유도체들을 합성하였고, 밭조건에서 발아 전 및 발아후 토양처리를 통하여 제초활성을 시험하였다. 이 화합물들은 발아후 처리에서만 활성을 나타내었고 광엽보다 화본과 잡초에서 좋은 제초 활성을 보여주었다.

• 대한화학회지
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• 제37권6호
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• pp.590-598
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• 1993

미국의 환경청이 지정한 129종의 priority pollutants 중 16종의 유기살충제를 대상물질로 선정하여 수질시료 중의 극미량 분석방법을 연구하였다. 분석방법으로는 기체크로마토그래프-전자포획 및 기체크로마토그래프/질량분석기-SIM(selected ion moitoring)법을 검출방법으로 정하고, 시료용액의 추출 및 농축방법으로는 용매추출법(liquid-liquid extraction)과 고체상 추출법(solid-phase extraction)을 비교 연구하였다. 각 화합물들의 회수율, 상대표준편차 및 검출한계 등을 측정하여 EPA 분석법을 대체할 수 있는지의 가능성을 조사하였다.