• Journal of Korean Society of Water and Wastewater
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• v.25 no.3
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• pp.367-373
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• 2011

Mechanism of rapid mixing effect on chemical phosphorus removal is evaluated in this study. Assuming that chemical phosphorus removal is unaffected by mixing time, only rapid mixing intensity is evaluated. In order to find out the mechanism, it is hypothesized that rapid mixing affects the Al hydrolysis speciation, and that formation of more monomeric species ($Al^a$) results in better removal of phosphorus. According to a ferron assay, more $Al^a$ formed at higher mixing intensity than at lower intensity. Subsequent experiments revealed that better phosphorus removal was obtained at higher intensity than at lower intensity, in terms of the molar ratio of $Al_{added}/P_{removed}$. The proposed hypothesis was proved in this study. Chemical phosphorus removal is affected by rapid mixing intensity due to its effect on the Al hydrolysis speciation.

• Computers and Concrete
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• v.26 no.5
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• pp.411-420
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• 2020

Deep Convolution neural network (DCNN) has been widely used in the healthy maintenance of civil infrastructure. Using DCNN to improve crack detection performance has attracted many researchers' attention. In this paper, a light-weight spatial attention network module is proposed to strengthen the representation capability of ResNet and improve the crack detection performance. It utilizes attention mechanism to strengthen the interested objects in global receptive field of ResNet convolution layers. Global average spatial information over all channels are used to construct an attention scalar. The scalar is combined with adaptive weighted sigmoid function to activate the output of each channel's feature maps. Salient objects in feature maps are refined by the attention scalar. The proposed spatial attention module is stacked in ResNet50 to detect crack. Experiments results show that the proposed module can got significant performance improvement in crack detection.

• Journal of the Korean Chemical Society
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• v.22 no.3
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• pp.173-183
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• 1978

Bulk polymerization of propylene sulfide with o-sulfobenzoic anhydride as initiator was carried out and the polymerization proceeded by a zwitterionic mechanism. Chemical and spectroscopic investigation of the purified polymer revealed that the polymer contained two end groups-thiolester of benzoic acid o-sulfonate anions and acyclic tert-sulfonium ions which were formed by termination of episulfonium ions with sulfide groups in the polymer chains. The concentration of sulfonate anions was nearly the same as the concentration of acyclic tert-sulfonium ions, as expected for macrozwitterions. The cocatalysis mechanism by a trace of water was excluded and the other possible mechanisms were discussed on the basis of end group analysis.

• Journal of the Korean Vacuum Society
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• v.5 no.4
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• pp.354-358
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• 1996

High indium incorporation was observed in InGaAs growth by precursor alternating metalorganic chemical vapor deposition (PAMOCVD). A possible mechanism of high indium incorporation into the crystal in PAMOCVD was proposed by considering the decomposition products of gallium and indium precursors, and thus the different adsorption behavior of the decomposed precursor molecules.

• 한국생물공학회:학술대회논문집
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• 2003.10a
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• pp.604-605
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• 2003

• Bulletin of the Korean Chemical Society
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• v.35 no.6
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• pp.1832-1836
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• 2014

A deep understanding of the metallic silver catalysts formation process on oxide support and the formation mechanism is of great scientific and practical meaning for exploring better catalyst preparing procedures. Herein the thermal decomposition process of supported silver catalyst with silver oxalate as the silver precursor in the presence of ethylenediamine and ethanolamine is carefully investigated by employing a variety of characterization techniques including thermal analysis, in situ diffuse reflectance infrared Fourier transform spectroscopy, scanning electron microscopy, and X-ray diffraction. The formation mechanism of supported silver particles was revealed. Results showed that formation of metallic silver begins at about $100^{\circ}C$ and activation process is essentially complete below $145^{\circ}C$. Formation of silver was accompanied by decomposition of oxalate group and removal of organic amines. Catalytic performance tests using the epoxidation of ethylene as a probe reaction showed that rapid activation (for 5 minutes) at a relatively low temperature ($170^{\circ}C$) afforded materials with optimum catalytic performance, since higher activation temperatures and/or longer activation times resulted in sintering of the silver particles.

• Bulletin of the Korean Chemical Society
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• v.23 no.10
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• pp.1445-1450
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• 2002

Solvolytic rate constants at 25 $^{\circ}C$ are reported for solvolysis of chlorodithioformate (1) in binary mixtures of water with acetone, ethanol, methanol, methanol-d, 50%methanol-d/50%D2O, and 2,2,2-trifluroethanol (TFE), and also in TFE-ethanol mixtures. The Grunwald-Winstein plot shows that the three aqueous mixtures exhibit dispersions into separate line. The correlation is improved only slightly by additional parameters NT for solvent nucleophilicity and/or I for aromatic ring parameter. Rate ratios in solvents of the same $Y_cl$ value, having different nucleophilicity provide measures of the minimum extent of nucleophilic solvent assistance, and the value of 3.35 for $[$k_{40EW}$/$k_97TFE$]_Y$ (EW = ethanol-water), is consistent with an essentially SN1 reaction mechanism. This study has shown that the magnitude of l, m and h values associated with a change of solvent composition is able to predict the SN1 reaction mechanism. log(k/$k_o$) = mY + lN + hI

• 한국생물공학회:학술대회논문집
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• 2003.10a
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• pp.313-313
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• 2003

• 한국생물공학회:학술대회논문집
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• 2003.04a
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• pp.102-102
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• 2003

• Bulletin of the Korean Chemical Society
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• v.28 no.7
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• pp.1087-1088
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• 2007