• Korean Journal of Chemical Engineering
• /
• 제35권12호
• /
• pp.2336-2347
• /
• 2018

The azeotrope of methyl acetate methanol and water was isolated using extractive distillation with water as entrainer. The pressure-swing extractive distillation (PSED) process and vapor side-stream distillation column (VSDC) with the rectifier process were designed to separate the methyl acetate, methanol and water mixture. It was revealed that the VSDC with the rectifier process had a reduction in energy consumption than the PSED process. Four control schemes of the two process were investigated: Double temperature control scheme (CS1), $Q_R/F$ feedforward control of reboiler duty scheme for PESD (CS2), $Q_R/F$ feedback control scheme for VSDC (CS3), the feedback control scheme of sensitive plate temperature of side-drawing distillation column to dominate the compressor shaft speed (CS4). Feed flow and composition disturbance were used to evaluate the dynamic performance. As a result, CS4 is a preferable choice for separation of methyl acetate-methanol-water mixture. A control scheme combining the operating parameters of dynamic equipment with the control indicators of static equipment was proposed in this paper. It means using the sensitive plate temperature of side-drawing column to control the compressor shaft speed. This is a new control scheme for extractive distillation.

• International Journal of Advanced Culture Technology
• /
• 제8권2호
• /
• pp.260-269
• /
• 2020

The Steam Assisted Gravity Drainage (SAGD) process is an enhanced method to extract oil from bitumen which involves surface and central process facilities. This paper describes the Central Process Facilities (CPF) of SAGD and proposes several retrofit plans to the Heat Exchanger Network (HEN). In this approach, the process integration scheme is applied to estimate the energy saving in HENs, and various cases are modeled in favor of a commercial simulator. Throughout this work, a minimum approach temperature of 10℃ is assumed. The results reveal that, due to the HEN optimization using process integration, the heating and cooling duties can be reduced to 29.68MW and 1.886MW, respectively. Compared with the Husky case, all cases considered in this study indicate a potential reduction of at least 6% in total cost, including investment and operation costs.

• 한국광학회지
• /
• 제16권3호
• /
• pp.196-200
• /
• 2005

[ $0.75delta\%$ ]의 평판광회로(PLC;Planar Lightwave Circuit)소자의 설계 및 제작기술을 가지고 저손실과 높은 누화율을 가진 파장 다중화 및 역다중화 소자를 개발하였다. C-band AWG(Arrayed Waveguide Grating)에서의 삽입손실은 2.503이하, 누화율은 35dB이상, 균일도는 1dB이하이며 L-band에서는 Vernier 디자인을 적용하여 ITU-T의 파장 정확도가 0.04nm이하가 되도록 제작하였다.

• 대한화학회지
• /
• 제57권2호
• /
• pp.172-175
• /
• 2013

We compare the relative usefulness of common basis functions and numerical integration methods in representing complex resonance state encountered in the molecular scattering problem of aluminum dimer electronic predissociation. Specifically, the basis set size and computing CPU times are monitored in order to find the minimum requirement for ensuring the modest accuracy of calculated resonance energies (0.1 $cm^{-1}$) for more than 100 resonance states. The combination of the so-called one-dimensional box eigenfunctions and energy-dependent boundary functions are found to be most efficient if integration is done using the basis set quadrature rules.

• Korean Chemical Engineering Research
• /
• 제43권4호
• /
• pp.439-451
• /
• 2005

수소저장기술은 수소경제를 달성하기 위해 개발해야할 핵심요소기술이다. 이 논문에서는 고체수소저장기술의 최신 개발 동향을 고찰하였다. 나노구조 탄소계 물질(nanostructured carbon materials), 유기금속구조물(metal organic framework, MOFs), 금속수소화물(metal hydrides), 클래스레이트수화물(clathrate hydrates), 금속착수소화물(complex chemical hydrides)과 같은 고체수소저장매체를 중점적으로 고찰하였다. 그 결과 지금까지 개발된 고체수소저장재료의 수소저장용량은 고체의 표면적에 비례하여 증가함을 알 수 있었다. 또한 수송용 탑재형 수소저장 응용을 목적으로 안전하면서도 가역적 고밀도 수소저장이 가능한 기능성 신 나노재료의 개발 방향을 제시하였다.

• Membrane and Water Treatment
• /
• 제2권4호
• /
• pp.267-279
• /
• 2011

At steady state, the simultaneous transport of sulphuric acid and nickel sulphate through an anion-exchange membrane Neosepta-AFN (Astom Corporation, Tokyo, Japan) was investigated in a two-compartment counter-current dialyzer with single passes. The transport was quantified by the recovery yield of acid, rejection of salt and four phenomenological coefficients, which were correlated with the acid and salt concentrations in the feed. The phenomenological coefficients were determined by the numerical integration of the basic differential equations describing the concentration profiles of the components in the dialyzer. This integration was combined with an optimizing procedure. The experiments proved that the acid recovery yield is in the limits from 63 to 91 %, while salt rejection is in the limits from 79 to 97 % in the dependence on the volumetric liquid flow rate and composition of the feed.

• 한국재료학회:학술대회논문집
• /
• 한국재료학회 1998년도 IUMRS-ICEM ABSTRACT BOOK
• /
• pp.78.3-78
• /
• 1998

• 제어로봇시스템학회:학술대회논문집
• /
• 제어로봇시스템학회 1988년도 한국자동제어학술회의논문집(국내학술편); 한국전력공사연수원, 서울; 21-22 Oct. 1988
• /
• pp.482-487
• /
• 1988

A sequential-clustered integrator based on GEAR method is developed for the purpose of dynamic simulation of chemical processes. And a single simulator structure capable of employing various integration approaches is designed and its efficiency and flexiblity is evaluated. Sequential integration method is superior to simultaneous method for the process without recycle, but simultaneous method is very powerful for the coupled process with recycle.

• 한국정보디스플레이학회:학술대회논문집
• /
• 한국정보디스플레이학회 2008년도 International Meeting on Information Display
• /
• pp.1049-1052
• /
• 2008

We developed novel molecular dynamics and quantum chemical molecular dynamics simulators for the design of MgO protecting layer in plasma display panel. These simulators were applied to the investigations on the destruction processes of the MgO protecting layer as well as the evaluation of its second electron emission ability. From the simulation results, we successfully proposed new guidelines for MgO protecting layer with high durability and high second electron emission ability.

• Journal of Mechanical Science and Technology
• /
• 제14권1호
• /
• pp.103-112
• /
• 2000

Numerical simulations of unsteady opposed-flow flames are performed using an adaptive time integration method designed for differential-algebraic systems. The compressibility effect is considered in deriving the system of equations, such that the numerical difficulties associated with a high-index system are alleviated. The numerical method is implemented for systems with detailed chemical mechanisms and transport properties by utilizing the Chemkin software. Two test simulations are performeds hydrogen/air diffusion flames with an oscillatory strain rate and transient ignition of methane against heated air. Both results show that the rapid transient behavior is successfully captured by the numerical method.