• Title/Summary/Keyword: chemical integration

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Design and control of extractive distillation for the separation of methyl acetate-methanol-water

  • Wang, Honghai;Ji, Pengyu;Cao, Huibin;Su, Weiyi;Li, Chunli
    • Korean Journal of Chemical Engineering
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    • v.35 no.12
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    • pp.2336-2347
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    • 2018
  • The azeotrope of methyl acetate methanol and water was isolated using extractive distillation with water as entrainer. The pressure-swing extractive distillation (PSED) process and vapor side-stream distillation column (VSDC) with the rectifier process were designed to separate the methyl acetate, methanol and water mixture. It was revealed that the VSDC with the rectifier process had a reduction in energy consumption than the PSED process. Four control schemes of the two process were investigated: Double temperature control scheme (CS1), $Q_R/F$ feedforward control of reboiler duty scheme for PESD (CS2), $Q_R/F$ feedback control scheme for VSDC (CS3), the feedback control scheme of sensitive plate temperature of side-drawing distillation column to dominate the compressor shaft speed (CS4). Feed flow and composition disturbance were used to evaluate the dynamic performance. As a result, CS4 is a preferable choice for separation of methyl acetate-methanol-water mixture. A control scheme combining the operating parameters of dynamic equipment with the control indicators of static equipment was proposed in this paper. It means using the sensitive plate temperature of side-drawing column to control the compressor shaft speed. This is a new control scheme for extractive distillation.

Optimization of Heat Exchanger Network in the Steam Assisted Gravity Drainage Process Integration

  • Rho, Seon-Gyun;Yuhang, Zhang;Hwang, InJu;Kang, Choon-Hyoung
    • International Journal of Advanced Culture Technology
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    • v.8 no.2
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    • pp.260-269
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    • 2020
  • The Steam Assisted Gravity Drainage (SAGD) process is an enhanced method to extract oil from bitumen which involves surface and central process facilities. This paper describes the Central Process Facilities (CPF) of SAGD and proposes several retrofit plans to the Heat Exchanger Network (HEN). In this approach, the process integration scheme is applied to estimate the energy saving in HENs, and various cases are modeled in favor of a commercial simulator. Throughout this work, a minimum approach temperature of 10℃ is assumed. The results reveal that, due to the HEN optimization using process integration, the heating and cooling duties can be reduced to 29.68MW and 1.886MW, respectively. Compared with the Husky case, all cases considered in this study indicate a potential reduction of at least 6% in total cost, including investment and operation costs.

40channel Arrayed Waveguide Grating with O.75delta% Refractive Index (0.75Δ% 굴절율차를 가진 40채널 광파장 다중화 및 역다중화 소자 제작 및 특성)

  • Moon, H.M.;Choi, G.S.;Lee, K.H.;Kim, D.H.;Lee, J.H.;Lee, D.H.;Oh, J.K;Kwak, S.C.;Kwon, O.K.;Kang, D.S.;Choi, J.S.;Jong, G;Lee, H.Y.
    • Korean Journal of Optics and Photonics
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    • v.16 no.3
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    • pp.196-200
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    • 2005
  • A 40 channel arrayed-waveguide grating (AWG) filter operating in C-band and L-band wavelength regions has been fabricated using PLC (Planar Lightwave Circuit) processes with 0.75 refractive index difference. Its design was optimized for matching the center wavelength with the ITU-recommended wavelength. The characteristics of the fabricated C-band AWG are as follows; average insertion loss < 2.5 dB, polarization-dependent loss < 0.3 dB, non-adjacent crosstalk >35dB, and the loss uniformity of 0.8 dB. In the L-band AWG, wavelength accuracy is below 0.02nm.

Optimal Basis Functions for Siegert Resonance State Representation in Al2 Electronic Predissociation

  • Jang, Hyo Weon
    • Journal of the Korean Chemical Society
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    • v.57 no.2
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    • pp.172-175
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    • 2013
  • We compare the relative usefulness of common basis functions and numerical integration methods in representing complex resonance state encountered in the molecular scattering problem of aluminum dimer electronic predissociation. Specifically, the basis set size and computing CPU times are monitored in order to find the minimum requirement for ensuring the modest accuracy of calculated resonance energies (0.1 $cm^{-1}$) for more than 100 resonance states. The combination of the so-called one-dimensional box eigenfunctions and energy-dependent boundary functions are found to be most efficient if integration is done using the basis set quadrature rules.

Advances in the Technology of Solid State Hydrogen Storage Methods Using Novel Nanostructured Materials (나노구조물질을 이용한 고체수소저장 기술 동향)

  • Zacharia, Renju;Kim, Keun Young;Nahm, Kee Suk
    • Korean Chemical Engineering Research
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    • v.43 no.4
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    • pp.439-451
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    • 2005
  • This article provides a panoramic overview of the state-of-the-art technologies in the field of solid-state hydrogen storage methods. The emerging solid-state hydrogen storage techniques, such as nanostructured carbon materials, metal organic framework (MOFs), metal and inter-metal hydrides, clathrate hydrates, complex chemical hydride are discussed. The hydrogen storage capacity of the solid-sate hydrogen storage materials increases in proportion to the surface area of the solid materials. Also, it is believed that new functional nanostructured materials will offer far-reaching solutions to the development of on-board hydrogen storage system for the application of the transportation vehicles.

Modeling of continuous diffusion dialysis of aqueous solutions of sulphuric acid and nickel sulphate

  • Bendova, Helena;Palaty, Zdenek
    • Membrane and Water Treatment
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    • v.2 no.4
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    • pp.267-279
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    • 2011
  • At steady state, the simultaneous transport of sulphuric acid and nickel sulphate through an anion-exchange membrane Neosepta-AFN (Astom Corporation, Tokyo, Japan) was investigated in a two-compartment counter-current dialyzer with single passes. The transport was quantified by the recovery yield of acid, rejection of salt and four phenomenological coefficients, which were correlated with the acid and salt concentrations in the feed. The phenomenological coefficients were determined by the numerical integration of the basic differential equations describing the concentration profiles of the components in the dialyzer. This integration was combined with an optimizing procedure. The experiments proved that the acid recovery yield is in the limits from 63 to 91 %, while salt rejection is in the limits from 79 to 97 % in the dependence on the volumetric liquid flow rate and composition of the feed.

Developement of Dynamic Process Simulator I. (화학공정 비정상상태 모사기 개발 I)

  • 이강주;윤인섭
    • 제어로봇시스템학회:학술대회논문집
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    • 1988.10a
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    • pp.482-487
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    • 1988
  • A sequential-clustered integrator based on GEAR method is developed for the purpose of dynamic simulation of chemical processes. And a single simulator structure capable of employing various integration approaches is designed and its efficiency and flexiblity is evaluated. Sequential integration method is superior to simultaneous method for the process without recycle, but simultaneous method is very powerful for the coupled process with recycle.

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Molecular Dynamics and Quantum Chemical Molecular Dynamics Simulations for the Design of MgO Protecting Layer in Plasma Display Panel

  • Kubo, Momoji;Serizawa, Kazumi;Kikuchi, Hiromi;Suzuki, Ai;Koyama, Michihisa;Tsuboi, Hideyuki;Hatakeyama, Nozomu;Endou, Akira;Takaba, Hiromitsu;Kajiyama, Hiroshi;Shinoda, Tsutae;Miyamoto, Akira
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.1049-1052
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    • 2008
  • We developed novel molecular dynamics and quantum chemical molecular dynamics simulators for the design of MgO protecting layer in plasma display panel. These simulators were applied to the investigations on the destruction processes of the MgO protecting layer as well as the evaluation of its second electron emission ability. From the simulation results, we successfully proposed new guidelines for MgO protecting layer with high durability and high second electron emission ability.

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Numerical Studies of Transient Opposed-Flow Flames using Adaptive Time Integration

  • Im, Hong-Geun
    • Journal of Mechanical Science and Technology
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    • v.14 no.1
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    • pp.103-112
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    • 2000
  • Numerical simulations of unsteady opposed-flow flames are performed using an adaptive time integration method designed for differential-algebraic systems. The compressibility effect is considered in deriving the system of equations, such that the numerical difficulties associated with a high-index system are alleviated. The numerical method is implemented for systems with detailed chemical mechanisms and transport properties by utilizing the Chemkin software. Two test simulations are performeds hydrogen/air diffusion flames with an oscillatory strain rate and transient ignition of methane against heated air. Both results show that the rapid transient behavior is successfully captured by the numerical method.

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