• Journal of the Korean Applied Science and Technology
• /
• v.23 no.3
• /
• pp.264-271
• /
• 2006

PU type flame-retardant coatings (TBAO/L-75, TBAOL ; TBAO/N-100, TBAON) were prepared by blending bromine-containing modified polyester (TBAO) which was synthesized in our earlier work. with two kinds of isocyanate curing agents, Desmodur L-75 and Desmodur N-100. Physical properties of the prepared flame-retardant coatings were tested. TBAOL shows better hardness than TBAON, while TBAON shows better viscosity, accelerated weathering resistance, yellowness index and lightness index difference than TBAOL. There were no remarkable differences in fineness of grind, $60^{\circ}$ specular gloss, cross-hatch adhesion, and abrasion resistance of TBAOL and TBAON. There was no discernable difference in flame-retardancy between the two flame-retardant coatings, TBAOL and TBAON. When the content of tribromo acetic acid, which is flame-retarding component, was 30wt% the LOI value was in a range of $29{\sim}30%$, which indicates that the two coatings are good flame-retardant coatings.

• Analytical Science and Technology
• /
• v.8 no.4
• /
• pp.487-492
• /
• 1995

The chemical compositions and pyrolysis characteristics of oil shales and source rocks distributed in the southwestern and southeastern parts of the Korean peninsular have been investigated. In order to compare the results of Korean samples with those of shales giving high oil yields, two Colorado oil shale samples and one Paris source rock samples were also investigated. Chemical compositions of the samples were analysed by means of gravimetry, CHN analysis, X-ray diffraction method, inductively coupled plasma atomic emission spectrometry and atomic absorption spectrometry. A custom made pyrolyser and a Rock-Eval system were used for the pyrolysis studies. Pyrolyses of the samples were carried out by means of a temperature controlling device to $600^{\circ}C$ at a heating rate of $5^{\circ}C/min$ with a helium flow rate of $1200m{\ell}/min$. The results of pyrolysis study indicated that Colorado shale samples belong to type I and all the other samples belong to type II.

• Proceedings of the Membrane Society of Korea Conference
• /
• 2003.07a
• /
• pp.61-64
• /
• 2003

Optical resolution of a-amino acid (tryptophan and tyrosine) optical isomers was achieved by a pressure driven membrane separation process, using self-supporting crosslinked membranes base on polysaccharide with different swelling indices that ranged from 100 to 70%. The membranes prepared by casting and drying the polymer solution containing 5wt% acetic acid on an acryl plate followed by crosslinking with glutaraldehyde were characterized using such analytical methods as FTIR and swelling index measurements. On the way of separating the optical isomers, several experimental factors such as the concentration of the feed solutions, operating pressure and temperature, and degree of crosslinking of the membranes have been studied. When the chitosan membranes with 70% of swelling index were used , almost complete optical resolution was obtained; 97.92% of enantiomeric excess (ee %) and 2.26 g/$m^2$ㆍh of flux. The operating pressure and the concentration of feed solutions were respectively 1.0 kgf/$\textrm{cm}^2$ and 0.49 mmol/L.

• Journal of the Korean Geotechnical Society
• /
• v.25 no.7
• /
• pp.55-64
• /
• 2009

In this study, improved test methods, which consider the real site test conditions, were suggested to measure for geosynthetics chemical resistance. For this purpose index and performance tests were done to specify and regulate the test method most approaching to the installation condition and accelerated model by Arrhenius equation was applied to interpretate the experimental data. Through the analysis and comparison of the overall experimental results, we could suggest the possibility and setup of the advanced chemical resistance test method for geosynthetics fitting to the field installation conditions.

• Proceedings of the Korean Society for Agricultural Machinery Conference
• /
• 2017.04a
• /
• pp.44-44
• /
• 2017

The objective of this study was to evaluate firmness, and sweetness index (SI) of tomatoes (Lycopersicum esculentum) by using hyperspectral imaging (HSI) in the range of 1000-1400 nm. The mean spectra of the 95 matured tomato samples were extracted from the hyperspectral images, and the reference firmness and sweetness index of the same sample were measured and calibrated with their corresponding spectral data by partial least squares (PLS) regression with different preprocessing method. The results showed that the regression model developed by PLS regression based on Savitzky-Golay (S-G) second-derivative preprocessed spectra resulted in better performance for firmness, and SI of tomatoes compared to models developed by other preprocessing methods, with correlation coefficients (rpred) of 0.82, and 0.74 with standard error of prediction (SEP) of 0.86 N, and 0.63 respectively. Then, the feature wavelengths were identified using model-based variable selection method, i.e., variable important in projection (VIP), resulting from the PLS regression analyses and finally chemical images were derived by applying the respective regression coefficient on the spectral image in a pixel-wise manner. The resulting chemical images provided detailed information on firmness, and sweetness index (SI) of tomatoes. Therefore, these research demonstrated that HIS technique has a potential for rapid and non-destructive evaluation of the firmness and sweetness index of tomatoes.

• Korean Journal of Remote Sensing
• /
• v.39 no.5_2
• /
• pp.837-847
• /
• 2023

In this study, we explored a method for assessing the extent of damage caused by chemical substances at an accident site through the use of a vegetation index. Data collection involved the deployment of two different drone types, and the damaged area was determined using photogrammetry technology from the 3D point cloud data. To create a vegetation index image, we utilized spectral band data from a multi-spectral sensor to generate an orthoimage. Subsequently, we conducted statistical analyses of the accident site with respect to the damaged area using a predefined threshold value. The Kappa values for the vegetation index, based on the near-infrared band and the green band, were found to be 0.79 and 0.76, respectively. These results suggest that the vegetation index-based approach for analyzing damage areas can be effectively applied in investigations of chemical accidents.

• Journal of the Korean Geographical Society
• /
• v.50 no.5
• /
• pp.505-514
• /
• 2015

This study analyzes a correlation between water content values and chemical index of alteration (CIA) for coarse sedimentary rocks of Mt. Cheonsaeng in Gumi-si, Kyeongsangbuk-do. Through measurement of various water values of 20 samples including water content rate, water absorption rate and equipment measuring we comparatively analyzed the values with CIA of the samples obtained by X-ray fluorescence. As a result of analysis water content rate and water absorption rate in a sedimentary rock are likely to be higher when matrix is psephitic and less compact. Furthermore the higher water content rate is, the higher CIA is due to increase of $SiO_2$ and $Al_2O_3$ and decrease of CaO and $Na_2O$ derived by chemical weathering of felspar. This correlation between water content rate and CIA represents a similar result with previous studies targeting granite.

• Journal of Adhesion and Interface
• /
• v.2 no.4
• /
• pp.24-31
• /
• 2001

Polypropylenes(PP) with different melt index values were mixed with ethylene-propylene rubber(EPR) or ethylene-propylene diene monomer rubber(EPDM) and an ethylene copolymer containing carboxylic acid group in a twin screw extruder. Then test specimens were prepared from the pellets of the blends with an injection molding machine. The mechanical properties and morphology of fractured surfaces were measured. Relative peak intensities of carboxylic acid group on the specimen surface were measured with an attennuated total reflection infrared spectrometer (ATR-IR) and compared with each other. The blend specimens were found to have the gradient morphology of rubber domains in PP matrix in the core region and PP skin layer. The blends containing PP of higher melt index showed greater content of ethylene copolymer containing carboxylic acid on the surface when the relative peak intensities of ATR-IR for carboxylic acid were compared. As the melt index values were increased, the decrease tendency in mechanical propeties such as tensile strength and impact strength was more significant for PP/EPR blends than PP/EPDM blends.

• The Pure and Applied Mathematics
• /
• v.27 no.4
• /
• pp.171-186
• /
• 2020

Long back in 1972, it was shown that the sum of the squares of vertex degrees and the sum of cubes of vertex degrees of a molecular graph both have large correlations with total 𝜋-electron energy of the molecule. Later on, the sum of squares of vertex degrees was named as first Zagreb index and became one of the most studied molecular graph parameter in the field of chemical graph theory. Whereas, the other sum remained almost unnoticed until recently except for a few occasions. Thus it got the name "forgotten" index or F-index. This paper investigates extremal graphs with respect to F-index among the class of bicyclic graphs with n vertices and k pendant vertices, 0 ≤ k ≤ n - 4. As consequences, we obtain the bicyclic graphs with largest and smallest F-indices.

• Proceedings of the KSRS Conference
• /
• 2003.11a
• /
• pp.1203-1205
• /
• 2003

To detect dust-loaded air-mass over land and ocean, we propose an index, which is essentially the difference in Rayleigh-corrected reflectance between 412 and 443 nm bands of SeaWiFS. Radiative transfer simulations are conducted to show that the index is linearly related to the optical thickness of modeled dust-contaminated aerosol while showing insensitivity against non-absorbing model aerosols. Asian SeaWiFS data set of 2001 spring is used to produce daily composite imagery of the index, which compares well with TOMS Aerosol Index and with predicted aerosol optical thickness predicted by CFORS chemical weather forecast.