• Title/Summary/Keyword: chemical homogenization

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Effect of Alloying Elements and Homogenization Treatment on Carbide Formation Behavior in M2 High Speed Steels (합금성분변화와 균질화처리에 따른 M2 고속도강의 탄화물 형성거동)

  • Ha, Tae Kwon;Yang, Eun Ig;Jung, Jae Young;Park, Shin Wha
    • Korean Journal of Metals and Materials
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    • v.48 no.7
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    • pp.589-597
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    • 2010
  • In the present study, the effect of variation in alloying elements on the carbide formation behavior during casting and homogenization treatment of M2 high speed steels was investigated. M2 high speed steels of various compositions were produced by vacuum induction melting. Contents of C, Cr, W, Mo, and V were varied from the basic composition of 0.8C, 0.3Si, 0.2Mn, 4.0Cr, 6.0W, 5.0Mo, and 2.0V in weight percent. Homogenization treatment at $1150^{\circ}C$ for 1.5 hr followed by furnace cooling was performed on the ingots. Area fraction and chemical compositions of eutectic carbide in as-cast and homogenized ingots were analyzed. Area fraction of eutectic carbide appeared to be higher in the ingots with higher contents of alloying elements the area fraction of eutectic carbide also appeared to be higher on the surface regions than in the center regions of ingots. As a result of the homogenization treatment, $M_2C$ carbide, which was the primary eutectic carbide in the as-cast ingots, decomposed into thermodynamically stable carbides, MC and $M_6C$. The latter carbide was found to be the main one after homogenization. Fine carbides uniformly distributed in the matrix was found to be MC type carbide and coarsened by homogenization.

Analysis of propagation characteristics of elastic waves in heterogeneous nanobeams employing a new two-step porosity-dependent homogenization scheme

  • Ebrahimi, Farzad;Dabbagh, Ali;Rabczuk, Timon;Tornabene, Francesco
    • Advances in nano research
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    • v.7 no.2
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    • pp.135-143
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    • 2019
  • The important effect of porosity on the mechanical behaviors of a continua makes it necessary to account for such an effect while analyzing a structure. motivated by this fact, a new two-step porosity dependent homogenization scheme is presented in this article to investigate the wave propagation responses of functionally graded (FG) porous nanobeams. In the introduced homogenization method, which is a modified form of the power-law model, the effects of porosity distributions are considered. Based on Hamilton's principle, the Navier equations are developed using the Euler-Bernoulli beam model. Thereafter, the constitutive equations are obtained employing the nonlocal elasticity theory of Eringen. Next, the governing equations are solved in order to reach the wave frequency. Once the validity of presented methodology is proved, a set of parametric studies are adapted to put emphasis on the role of each variant on the wave dispersion behaviors of porous FG nanobeams.

Miscibility of Branched Polycarbonate Blends with Poly(ethylene-co-1,4-dimethyl cyclohexane terephthalate) Copolyesters

  • Song, Jeong-Oh;Jeon, Mi-Young;Kim, Chang-Keun
    • Macromolecular Research
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    • v.15 no.7
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    • pp.640-645
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    • 2007
  • The phase behavior of branched polycarbonate (BPC) blends with poly(ethylene terephthalate-co-1,4-dimethyl cyclohexane terephthalate) copolyesters (PECT), as well as their rheological properties, were assessed. Even though BPC blends with PECT prepared by solvent casting proved to be immiscible, BPC and PECT copolyesters containing 1,4-dimethyl cyclohexane (CHDM) from 32 to 80 mole% formed homogeneous mixtures upon heating. The homogenization temperatures of the blends decreased with increasing CHDM content in PECT. The interaction energies of the BPC-PECT pairs calculated from the phase boundary in accordance with the lattice-fluid theory were positive and also decreased with increasing CHDM content in PECT. It was shown that the phase homogenization of these blends occurs upon heating when the combinatorial entropy term, which is favorable for miscibility, overcomes unfavorable energetic terms at elevated temperatures. A novel product, which is not limited by the drawbacks of linear polycarbonate (PC) and evidences processability superior to that of the PC/PECT blends, can be developed via the blending of BPC and PECT.

Preparation and Its Stability of a Coenzyme Q10 Nanoemulsion by High Pressure Homogenization with Different Valve Type Conditions (초고압균질기 밸브 타입에 따른 coenzyme Q10 나노에멀젼의 제조 및 안정성)

  • Lim, Ji-Sun;Gang, Ho-Jin;Yoon, Sung-Woo;Kim, Hyeong-Min;Suk, Jong-Woo;Kim, Do-Un;Lim, Jae-Kag
    • Korean Journal of Food Science and Technology
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    • v.42 no.5
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    • pp.565-570
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    • 2010
  • A coenzyme Q10 nanoemulsion was prepared using high pressure homogenization with different valve type conditions (A, B, and C) and cycle numbers (1, 2, and 3). The particle size, transmittance, zeta potential, and coenzyme Q10 content of the prepared coenzyme Q10 nanoemulsion were measured. The stability of the prepared coenzyme Q10 nanoemulsion was evaluated on heating ($95^{\circ}C$), freezing ($-20^{\circ}C$), and different pH (2-10) conditions. Also, the prepared coenzyme Q10 nanoemulsion was stored at different temperatures of 4, 25, and $40^{\circ}C$ for 12 weeks to evaluate its storage stability. In this study, the optimal conditions of high pressure homogenization for the preparation of a coenzyme Q10 nanoemulsion were identified to be 150 MPa, C valve, and a cycle number of 3. The results showed that the prepared coenzyme Q10 nanoemulsion had an average particle size of 40 nm, generated no deposits or floating matter when stored at either 4 or $25^{\circ}C$ for 12 weeks, and displayed excellent dispersibility and transparency when processed at different pHs (4-10) or heating ($95^{\circ}C$) and, freezing ($-20^{\circ}C$) conditions. Our results indicated that a coenzyme Q10 nanoemulsion prepared by high pressure homogenization can be used for preparing beverages in the food industry.

Disinfection Models to Predict Inactivation of Artemia sp. via Physicochemical Treatment Processes (물리·화학적 처리공정을 이용한 Artemia sp. 불활성화 예측을 위한 소독 모델)

  • Zheng, Chang;Kim, Dong-Seog;Park, Young-Seek
    • Journal of Environmental Science International
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    • v.26 no.4
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    • pp.421-432
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    • 2017
  • In this study, we examined the suitability of ten disinfection models for predicting the inactivation of Artemia sp. via single or combined physical and chemical treatments. The effect of Hydraulic Retention Time (HRT) on the inactivation of Artemia sp. was examined experimentally. Disinfection models were fitted to the experimental data by using the GInaFiT plug-in for Microsoft Excel. The inactivation model were evaluated on the basis of RMSE (Root Mean Square Error), SSE (mean Sum Square Error) and $r^2$. An inactivation model with the lowest RMSE, SSE and $r^2$ close to 1 was considered the best. The Weibull+Tail model was found to be the most appropriate for predicting the inactivation of Artemia sp. via electrolytic treatment and electrolytic-ultrasonic combined treatment. The Log-linear+Tail model was the most appropriate for modeling inactivation via homogenization and combined electrolytic-homogenization treatment. The double Weibull disinfection model was the most suitable for the predicting inactivation via ultrasonic treatment.

Homogenization of Plastic Behavior of Metallic Particle/Epoxy Composite Adhesive for Cold Spray Deposition (저온 분사 공정을 위한 금속입자/에폭시 복합재료 접착제의 소성 거동의 균질화 기법 연구)

  • Yong-Jun Cho;Jae-An Jeon;Kinal Kim;Po-Lun Feng;Steven Nutt;Sang-Eui Lee
    • Composites Research
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    • v.36 no.3
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    • pp.199-204
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    • 2023
  • A combination of a metallic mesh and an adhesive layer of metallic particle/epoxy composite was introduced as an intermediate layer to enhance the adhesion between cold-sprayed particles and fiber-reinforced composites (FRCs). Aluminum was considered for both the metallic particles in the adhesive and the metallic mesh. To predict the mechanical characteristics of the intermediate bond layer under a high strain rate, the properties of the adhesive layer needed to be calculated or measured. Therefore, in this study, the Al particle/epoxy adhesive was homogenized by using a rule of mixture. To verify the homogenization, the penetration depth, and the thickness decrease after the cold spray deposition from the undeformed surface, was monitored with FE analysis and compared with experimental observation. The comparison displayed that the penetration depth was comparable to the diameters of one cold spray particle, and thus the homogenization approach can be reasonable for the prediction of the stress level of particulate polymer composite interlayer under a high strain rate for cold spray processing.

Effect of trans-Cinnamaldehyde and High Pressure Treatment on Physico-chemical and Microbial Properties of Milk during Storage Periods

  • Chun, Ji-Yeon;Kim, Kwon-Beom;Shin, Jong-Boo;Min, Sang-Gi
    • Food Science of Animal Resources
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    • v.33 no.1
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    • pp.16-23
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    • 2013
  • This study was carried out to investigate the effect of trans-cinnamaldehyde and high pressure treatment on milk. Cinnamon oil milk was manufactured by high speed homogenization (3,000 rpm) and high pressure homogenization (500 and 2,000 bar) processing UHT milk and trans-cinnamaldehyde of various concentrations (0 to 0.1% (w/v)). Cinnamon oil milk was inoculated with Escherichia coli (6.4 Log CFU/mL) and kept at $7^{\circ}C$ for 10 d to observe the antibacterial effect. The cinnamon oil milk containing 0.05% (w/v) trans-cinnamaldehyde initially began to show an antibacterial effect and Escherichia coli completely died in cinnamon oil milk added 0.1% (w/v) trans-cinnamaldehyde on the 6th day of storage. The result of the TBA value showed that the addition of 0.1% (w/v) trans-cinnamaldehyde was also effective to protect lipid oxidation. In the physical properties of cinnamon oil milk, particle sizes were enlarged in all samples during storage periods and the total color difference of cinnamon oil milk was slightly increased as level of high pressure. The surface tension of cinnamon oil milk treated 2,000 bar was remarkably higher than other samples. It seems that trans-cinnamaldehyde showed antibacterial activity and antioxidation effect at 0.05 and 0.1% (w/v) of concentration. Remarkably, high pressure treatment did not influence its microbial property but slightly affected the physical properties of cinnamon oil milk.

A rheo-optical investigation of shear-induced morphological changes in biopolymeric blends

  • Puyvelde, P.Van;Antonov, Y.A.;Moldenaers, P.
    • Korea-Australia Rheology Journal
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    • v.14 no.3
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    • pp.115-119
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    • 2002
  • In this paper, a rheo-optical methodology based on small angle light scattering and polarimetry is applied to investigate in-situ and on a time resolved basis the flow-induced structures in aqueous biopolymeric blends. Water-dextran-gelatin is chosen as an example. It is verified to what extent the laws and scaling relations, originally developed for synthetic polymer blends, are valid for the morphology development in this aqueous biopolymeric mixture. It was observed that under low shear rate conditions, the biopolymeric emulsion can be regarded as a conventional emulsion. However, at high shear rates flow induced homogenization occurs.