• Applied Chemistry for Engineering
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• v.16 no.3
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• pp.434-439
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• 2005

The reaction of hydration proceeded at the same time the vapor was introduced into the reactor that was filled with calcined dolomite. It has shown that the temperature has begun to fall from the bottom of reactor after increase of temperature by the heat of hydration reaction. The reaction initiated at the pipe wall and the heat was transfer to the center of block between the fins. The results show that the use of copper fin in the reactor reducted the hydration reaction time by half when compared to the case without using the fins.

• 비료회보
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• s.274
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• pp.35-40
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• 1984

• Korean Chemical Engineering Research
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• v.51 no.2
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• pp.245-249
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• 2013

The depropanizing, debutanizing and deisobutanizing fractionation steps of processing natural gas liquids were improved through studying complex distillation arrangements, including the double dividing wall column arrangement (DDWC), the sequence including a dividing wall column (DWC) and a bottom DWC (BDWC), and the sequence including a DWC and a BDWC with top vapor recompression heat pump. These arrangements offer benefits by decreasing reboiler and condenser power consumption. Reducing the number of columns and their diameters can potentially reduce construction costs. The result also showed that operating cost could be reduced most significantly through novel combinations of internal and external heat integration: bottom dividing wall columns employing a top vapor recompression heat pump.

• Clean Technology
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• v.7 no.2
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• pp.151-159
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• 2001

Mathematical modeling and numerical simulation studies have been conducted for a falling film type absorber of the ammonia absorption heat pump. A rigorous absorber model has been developed by considering temperature effects on physical properties and its predictability proved far superior to that of existing models, which has been confirmed by the experimental data. Using the developed model, effects of cooling water condition - temperature and flow rate - on the efficiency of absorber has been examined. As the result of simulation, the efficiency of absorber has increased as the cooling water temperature has decreased and flow rate has increased.

• Applied Chemistry for Engineering
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• v.19 no.3
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• pp.338-344
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• 2008

The improvement of energy conservation is mandatory to decrease consumption of fossil fuels and to minimize negative impacts on the environment which originates from large cooling and heating demand. The absorption heat pump technology has a large potential for energy-saving in this respect. Absorption heat pump is a means to upgrade waste heat without the addition of extra thermal energy. The higher performance of absorber is of great importance for absorption heat pump cycle. In this study, in order to improve the performance of absorber, the absorber of tangential feed of a liquid phase with spiral tube has been investigated using methanol-glycerine as a working fluid. The spiral tube and tangential feeding generate the turbulence into the liquid flow while increasing the mass and heat transfer coefficients. The simultaneous heat and mass transfer were found to take place in a liquid turbulent film in the absorber with the spiral tube during the process of gas absorption. By calculating mass and heat transfer coefficients by measurement of the concentration and the temperature of each position in the absorber, the entrance was found to be more effective in enhancing mass and heat transfer.

• Journal of the Korean Solar Energy Society
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• v.22 no.1
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• pp.9-21
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• 2002

To develope chemical heat pump using available energy sources, solar heat and other kinds of waste thermal energy, we have studied the heat transfer rate in cylindrical bed reactor packed with calcined Dolomite. Two dimensional (radial and circumferential) Partial differential equations, concerning heat and mass transfer in packed bed of calcined Dolomite, are solved numerically to describe the characteristics of the reaction of calcined Dolomite and heat transfer. The results obtained by numerical analysis about two dimensional profiles of temperature and conversion of reactant in the packed bed reactor and the amount of exothermic heat released from the reactor are follows. It was found that all of calcined Dolomite packed bed kept the reaction temperature of about 750K throughout the entire part of the bed, immediately after the steam was introduced exothermic reaction of hydration was proceeded from the packed bed inpu to output and from wall side to center. The rate of thermochemical reaction depends on the temperature and concentration and it is also governed by the boundary conditions and heat transfer rate in the particle packed bed.

• Journal of the Korean Institute of Gas
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• v.21 no.4
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• pp.42-46
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• 2017

As $CO_2$ emission with imprudent using fossil fuel, annual mean temperature of earth is increased in every year. Geothermal energy is inexhaustible energy resource to solve this problem. Heat pump performance and heat exchange efficiency of ground loop are important to distribute widely. Thus, this study are performed to increase heat pump performance and heat exchange efficiency of ground loop with dual expansion valves and spacer. As a results, COP of cooling & heating is obtained improvement up to 11.4% using dual expansion valves, and heat exchange efficiency is increased up to 17.5% using spacer. It will be reduced initial installation cost due to increasing heat pump performance and heat exchange efficiency of ground loop.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.17 no.9
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• pp.808-815
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• 2005

A technical analysis was conducted to predict the development trends for heat pump system. This study was based on submitted patents from 1983 to 2002 in Korea, USA, and Japan. The total number of raw data from the registered database was 19,261 and the obtained data to be analyzed through the filtering process was 5,143. Japan's technical development for the heat pump system was more dominant than the other countries. Approximately $54\%$ of the total patents related with the heat pump system was registered by Japan. The number of patents for the heat pump system registered by Korea was very low in 1980's, but it increased rapidly in 1990's. As a result, the number of patents applied by Korea was $21\%$ of all patents. When the patent was categorized into compression, absorption/ad-sorption, and chemical type, the technology of compression type made up over $80\%$ in each country. Approximately $93\%$ of the patents surveyed in this study was developed for air or water source heat pumps because of easy applications compared with other heat sources. The $89\%$ of all patents was applied by companies when applicants were divided into three groups of company, individual, and the others (national institute, university, and so on).

• Journal of the Korean Solar Energy Society
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• v.23 no.1
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• pp.29-38
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• 2003

To develope chemical heat pump using available energy sources, solar heat and other kinds of waste thermal energy, we have studied the material and heat transfer rate in the cylindrical bed reactor packed with Calcined Dolomite. Our results from the studies are as follows ; 1 The time needed to complete dehydration reaction at the wall side of the cylindrical reactor(r/rL=0.5) was shorter than that of the center(r/rL=0.0) as much as 12%. 2. Two dimensional (radial and circumferential) partial differential equations, concerning heat and mass transfer rate in the packed bed of calcined Dolomite, are solved numerically to describe the characteristics of the reaction in the cylindrical reactor. The solution reads rate of reaction in the packed bed reactor depends on the temperature and concentration of reactants. These results read the supplied heat transfers from the wall side of the cylinder to the center, dehydration reaction begins at the inner side of the wall of the cylindrical reactor and the dehydration reaction proceeds from the wall side to center of cylinder.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.11 no.6
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• pp.799-807
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• 1999

Exergy analysis is widely used in energy system analysis for more efficient energy use. Pinch technology has focused on chemical plants, such as pure heat exchanger networks. In this study, the objective is to seek more effective means with integrating above two methods. In order to demonstrate effective result and to prove possibility for pinch analysis, the steam turbine is adopted to make heat recovery in the heat exchanger network. Three cases are introduced using the integration of exergy and pinch analysis. The standard steam turbine utility is the base case, and adding the heat pump to this system is the second case. The third case is the system with the heat pump and minimum utilities. The results show that the output power of steam turbine in the case(2) and case(3) are increased up to 42% and 46%, respectively, compared with that of base case.