• Title/Summary/Keyword: chemical defense

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Inhibitory effects of environment-friendly materials and defense response signaling chemicals against anthracnose occurrence in Jujube (Zizyphus jujuba Miller)

  • Kim, Su Jun;Kim, Eun Su;Kim, Seung Heui;Yun, Hae Keun
    • Korean Journal of Agricultural Science
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    • v.45 no.3
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    • pp.365-378
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    • 2018
  • Anthracnose caused by Colletotrichum gloeosporioides, which is one of the major diseases of red dates, causes severe damages in jujube (Zizyphus jujuba Miller) production in Korea. This study was done to evaluate the inhibition of anthracnose occurrence and pathogen growth by the treatment of environment-friendly materials such as a Bordeaux mixture and loess-sulfur mixture and by defense-response signaling in jujube. The in vitro test of the environment-friendly materials and signaling molecules that were routinely applied did not exhibit any antifungal activities against the pathogen for jujube anthracnose. The Bordeaux mixture and loess-sulfur mixture at a two-fold concentration showed inhibition zones that were 16.0 and 20.3 mm in diameter, respectively. In the pathogen inoculation test with detached jujube tree leaves, while treatment with the environment-friendly materials diluted by half showed no inhibition of lesion development, they did show inhibition of lesion development when they were routinely applied to the leaves. In detached jujube fruits inoculated with the pathogen, better suppressive effects by the treatment of the environment-friendly materials were seen in the fruits at a young stage rather than in the ripening stage. The in vivo test with jujube trees in pots showed that the treatment of salicylic acid (1 mM) resulted in the best suppressive effects against lesion development. The results suggest that it is possible to manage the incidence of anthracnose by the treatment of environment-friendly materials such as the Bordeaux and loess-sulfur mixtures and signaling chemicals such as ethephon, hydrogen peroxide, methyl jasmonate, and salicylic acid in jujube trees and fruits. Consequently, these findings suggest that environment-friendly materials and defense response signaling molecules could be used as suitable candidates for sustainable agrochemicals to manage anthracnose in jujube production.

Surface Modification of High Energetic Materials by Molecular Self-assembly (자기조립법을 이용한 고에너지물질의 표면개질 연구)

  • Kim, Ja-Young;Jeong, WonBok;Shin, Chae-Ho;Kim, Jin-Seok;Lee, Keundeuk;Lee, Kibong
    • Journal of the Korean Society of Propulsion Engineers
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    • v.20 no.2
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    • pp.18-23
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    • 2016
  • Self-assembly of organic molecules is formed spontaneously on surfaces by electrostatic interaction with substrate. This research has shown that the self-assembly improves safety and handling tractability of high-energetic materials (HEMs). According to the recent study, control of the specific crystal size for reducing the internal defects is mightily important, because the internal defects are a factor in unstability of HEMs. In turn, we performed self-assembly of organic molecules and HEMs by using nano-sized HEMs, which were produced by drowing-out or milling/crystallization. Surface modification efficiency was decided by size distribution, zeta-potential, friction sensitivity and electrostatic charge.

Study of the Crystal Structure of a Lyocell Precursor for Carbon Fibers (탄소섬유용 리오셀 전구체의 결정구조에 관한 연구)

  • Park, Gil-Young;Kim, Woo-Sung;Lee, Su-Oh;Hwang, Tae-Kyung;Kim, Yun-Chul;Seo, Sang-Kyu;Chung, Yong-Sik
    • Journal of the Korean Society of Propulsion Engineers
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    • v.23 no.5
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    • pp.36-42
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    • 2019
  • In this study, the pre-treatment of lyocell fabrics was performed using phosphoric acid (PA) as a phosphorus flame retardant and melamine resin (MR) as a cross-linking agent to fabricate carbon fabrics using lyocell fibers. The physical and chemical changes were investigated by thermogravimetric analysis (TGA), Fourier transform infrared spectroscopy (FT-IR), X-ray diffractometry (XRD) and weight analysis. We confirmed that the weight yield of the carbon fabrics compared to the untreated fabrics increased by 14.7%, and width and length yield of the fabrics increased by 15% and 15.5%, respectively. This may be due to the effect of promoting the dehydration reaction of cellulose, forming char on the fiber surface, which induces a crosslinking reaction in the cellulose molecule and stabilizes the structure upon pyrolysis.

Analysis of Boundary Layer in Solid Rocket Nozzle and Numerical Analysis of Thermal Response of Carbon/Phenolic using Finite Difference Method (고체 로켓 노즐의 경계층 해석과 유한차분법을 이용한 탄소/페놀릭의 열반응 해석 연구)

  • Seo, Sang Kyu;Hahm, Hee Cheol;Kang, Yoon Goo
    • Journal of the Korean Society of Propulsion Engineers
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    • v.22 no.1
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    • pp.36-44
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    • 2018
  • The thermal response of carbon/phenolic used in a solid rocket nozzle liner was analyzed. In this paper, the numerical analysis of the thermal response of carbon/phenolic consists of (1) the integration equation of the boundary layer to obtain the convective heat transfer coefficient of the combustion gas on the rocket nozzle wall and (2) 1-D finite difference method for heat conduction of carbon/phenolic to calculate the ablation, char, and temperature. The calculated result was compared with the result of a blast-tube-type test motor. It is found that the calculated result shows good agreement with the thermal response of the test motor, except at the vicinity of the throat insert.

CNN based Raman Spectroscopy Algorithm That is Robust to Noise and Spectral Shift (잡음과 스펙트럼 이동에 강인한 CNN 기반 라만 분광 알고리즘)

  • Park, Jae-Hyeon;Yu, Hyeong-Geun;Lee, Chang Sik;Chang, Dong Eui;Park, Dong-Jo;Nam, Hyunwoo;Park, Byeong Hwang
    • Journal of the Korea Institute of Military Science and Technology
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    • v.24 no.3
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    • pp.264-271
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    • 2021
  • Raman spectroscopy is an equipment that is widely used for classifying chemicals in chemical defense operations. However, the classification performance of Raman spectrum may deteriorate due to dark current noise, background noise, spectral shift by vibration of equipment, spectral shift by pressure change, etc. In this paper, we compare the classification accuracy of various machine learning algorithms including k-nearest neighbor, decision tree, linear discriminant analysis, linear support vector machine, nonlinear support vector machine, and convolutional neural network under noisy and spectral shifted conditions. Experimental results show that convolutional neural network maintains a high classification accuracy of over 95 % despite noise and spectral shift. This implies that convolutional neural network can be an ideal classification algorithm in a real combat situation where there is a lot of noise and spectral shift.

Experimental Study on the Characteristics of Microbubbles Generated by an Effervescent Tablet in Water (수중 내 발포성 정제로부터 생성된 미세기포 특성에 관한 실험적 연구)

  • Myeong, Jaewon;Maeng, Juyoung;Kim, Young Jun;Cho, Kyungmin;Lee, Woonghee;Kim, Sungho;Park, Youngchul;Sohn, Youngku;Shin, Weon Gyu
    • Journal of the Korean Society of Visualization
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    • v.19 no.3
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    • pp.84-91
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    • 2021
  • Effervescent tablets generate gas bubbles when chemical reaction occurs between water and tablets. Most of previous studies have been focused on pharmaceutical characteristics of tablets. However, for their applications in disinfectants, cleaners, and pesticides, physical characteristics of bubbles released from the effervescent tablets when they are in water are important. In this study, we experimentally investigated the characteristics of microbubbles generated by an effervescent tablet made of sodium bicarbonate and tartaric acid using PDPA and high-speed camera. Microbubbles were generated using different weights of effervescent tablet as well as in different water temperature. The experimental study shows increase in reaction time, bubble concentration and rise velocity as the weight of effervescent tablet increases from 1 to 20 g. The decrease in average bubble diameter was observed when the temperature of water increased from 25 to 45 ℃. Further, reaction time varies inversely with increase in water temperature, while bubble rise velocity is directly proportional to increase in water temperature. Effervescent table continuously generates the bubble with approximately constant diameter (235 ㎛) in the water. However, bubble concentration and bubble rise velocity decreased over time.

The Experimental Study of SPM(Selectively Permeable Membrane Materials) by using Aerosol Test Instrument (에어로졸 시험장비를 이용한 방호 의복 소재의 여과 효율에 대한 연구)

  • Kwon, Tae Geun;Seo, Hyeon Kwan;Kim, Jin Won;Kang, Jae Sung;Kang, Ki Tae;Ahn, Kang Ho;Choi, Jin Soo;Cho, Jae Ho;Kwon, Yong Taek;Park, Hyen Bae
    • Particle and aerosol research
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    • v.10 no.3
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    • pp.109-117
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    • 2014
  • In Korea, permeable protection clothes for chemical agent is being developed and distributed. But permeable protection clothes are vulnerable for biological agent of particle type. Therefore selective permeable membranes are being developed to protect chemical agent and biological agent simultaneously. In this study, aerosol collection efficiency test was performed to validate the protection performance of permeable clothes and selective permeable membranes. Aerosol collection efficiency test was performed by using the aerosol test equipment that could test aerosol particle diameter from $0.005{\mu}m$ to $3.0{\mu}m$. This study shows the test method and performance test results for collection efficiency by using the aerosol test equipment.

Decontamination of Interior of Field Tent Employed Geobacillus stearothermophilus Spores using a Hydrogen Peroxide Vapor System (과산화수소증기 시스템을 이용한 야전용 천막 내 Geobacillus stearothermophilus 아포 제독)

  • Yoon, Sung Nyo;Kim, Yun Ki;Jeung, Jeung Hoon;Yoo, Hyun Sang;Min, Kyung Yool;Kim, Min Cheol;Kim, Se Kye;Ryu, Sam Gon
    • Journal of the Korea Institute of Military Science and Technology
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    • v.19 no.5
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    • pp.669-674
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    • 2016
  • The purpose of this study is to demonstrate the suitability of hydrogen peroxide($H_2O_2$) vapor system for platform interior decontamination. Geobacillus stearothermophilus biological indicator(BI) strips and a field tent were used as a biological simulant and as a simulated platform, respectively. Decontamination was performed based on injection rates and tent sizes with exposure time 60 minutes. We standardized the conditions for the field tent decontamination : 8.0 g/min for $30m^3$($H_2O_2$ vapor concentration of 150~500 ppm, relative humidity of 50 %) and 12.0 g/min for $60m^3$($H_2O_2$ vapor concentration of 250~400 ppm, relative humidity of 55 %). Thus we suggest the system is one of the possible candidates for decontamination of platform interiors.

Development of Wireless Real-Time Gas Detector System for Chemical Protection Performance Test of Personal Protective Equipment (화생방 보호의 성능평가를 위한 무선 실시간 가스 검출기 개발)

  • Kah, Dong-Ha
    • Journal of the Korea Institute of Military Science and Technology
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    • v.23 no.3
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    • pp.294-301
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    • 2020
  • Man-In-Simulant Test(MIST) provides a test method to evaluate chemical protective equipments such as protective garments, gloves, footwear and gas mask. The MIST chamber is built to control concentration of chemical vapor that has a activity space for two persons. Non-toxic methyl-salicylate(MeS) is used to simulate chemical agent vapor. We carried out to measure inward leakage MeS vapors by using passive adsorbent dosimeter(PAD) which are placed on the skin at specific locations of the body while man is activity according to the standard procedure in MIST chamber. But more time is required for PADs and there is concern of contamination in PADs by recovering after experiment. Therefore detector for measuring in real time is necessary. In order to analyze in real time the contamination of the personal protective equipment inside the chemical environment, we have developed a wireless real-time gas detector. The detector consists of 8 gas-sensors and 1 control-board. The control-board includes a CPU for processing a signal, a power supply unit for biasing the sensor and Bluetooth-chipset for transmission of signals to external PC. All signals from gas-sensors are converted into digital signals simultaneously in the control-board. These digital signals are stored in external PC via Bluetooth wireless communication. The experiment is performed by using protective equipment worn on manikin. The detector is mounted inside protective equipment which is capable of providing a real-time monitoring inward leakage MeS vapor. Developed detector is demonstrated the feasibility as real-time detector for MIST.

Studies on the Stabilization of Rayon Fabrics: 3. Effects of Long-Term Isothermal Stabilization at Low Temperatures and Chemical Pre-treatment (레이온직물의 안정화에 관한 연구: 3. 저온 장시간 등온 안정화 및 화학전처리 영향)

  • Cho, Chae Wook;Cho, Donghwan;Park, Jong Kyoo;Lee, Jae Yeol
    • Journal of Adhesion and Interface
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    • v.11 no.1
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    • pp.15-25
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    • 2010
  • In the present study, isothermal stabilization processes for rayon fabrics were performed at two relatively low temperatures $180^{\circ}C$ and $200^{\circ}C$ for a long period of time. The results of weight loss, dimensional shrinkage, X-ray diffraction and scanning electron microscopic observations studied with the rayon fabrics before and after the isothermal stabilization indicated that the chemical and physical changes of rayon precursor fibers proceeded continuously and slowly at the stabilization temperature below $200^{\circ}C$. And the pre-treatment with four different chemical compounds done prior to stabilization process influenced differently the characteristics of rayon fabrics. As a result, it was noticed that under the given stabilization conditions, $H_3PO_4$ and $Na_3PO_4$ played a role in catalyzing the stabilization reaction of rayon fabric whereas $NH_4Cl$ and $ZnCl_2$ played a role in delaying or retarding the reaction. $H_3PO_4$ showed the lowest percent weight loss of the fabric in the second stabilization conducted at $350^{\circ}C$. It was considered that phosphoric acid, which has a function of flame retardant, contributed to retarding somewhat the subsequent reaction even in the second stabilization step.