• Title/Summary/Keyword: chemical component

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Fixed bed column modeling of lead(II) and cadmium(II) ions biosorption on sugarcane bagasse

  • Vera, Luisa Mayra;Bermejo, Daniel;Uguna, Maria Fernanda;Garcia, Nancy;Flores, Marittza;Gonzalez, Enrique
    • Environmental Engineering Research
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    • v.24 no.1
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    • pp.31-37
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    • 2019
  • In this paper the results of the biosorption of lead(II) and cadmium(II) with sugarcane bagasse in fixed bed columns are presented. Experimental data were fitted to several models describing the rupture curve for single-component and two-component systems. The percentages of removal of lead and cadmium in single-component systems are 91% and 90%, respectively. In lead-cadmium bicomponent systems the percentage of elimination of lead was 90% and cadmium 92%. In single-component systems, Yoon-Nelson and Thomas models successfully reproduce the rupture curves. In two-component system, the Dose-Response model was the best one reproducing the experimental rupture curves in the entire measured range.

Magnesium Bistrifluoromethanesulfonimide Catalyzed Three-component Synthesis of Protected Homoallylic Amines

  • Wang, Hongshe;Zeng, June
    • Bulletin of the Korean Chemical Society
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    • v.32 no.7
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    • pp.2203-2206
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    • 2011
  • A mild and efficient procedure has been developed for the one-pot, three-component reaction of aldehydes, benzyl carbamate and allyltrimethylsilane in the presence of 3 mol % of magnesium bistrifluoromethanesulfonimide at room temperature to afford the corresponding protected homoallylic amines in high yields.

Pervaporation Separation of Water/Ethanol Mixtures through PBMA/anionic PAA IPN Membrane

  • Jin, Young-Sub;Kim, Sung-Chul
    • Proceedings of the Membrane Society of Korea Conference
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    • 1996.10a
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    • pp.86-87
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    • 1996
  • IPN (Interpenetrating Polymer Network) is a mixture of two or more crosslinked polymers with physically interlocked network structures between the component polymers. IPN can be classified as an alloy of thermosets and has the characteristics of thermosets such as the thermal resistance and chemical resistance and also has the characteristics of polymer alloys with enhanced impact resistance and amphoteric properties. The physical interlocking during the synthesis restricts the phase separation of the component polymer with chemical pinning process, thus the control of morphology is possible through variations of the reaction temperature and pressure, catalyst concentration and crosslinking agent concentration. Finely dispersed domain structure can be obtained through IPN synthesis of polymer components with gross immiscibility. In membrane applications, particularly for the separation of liquid mixtures, crosslinked polymer component with specific affinity to the permeate is needed. With the presence of the permeant-inert polymer component, the mechanical strength and the selectivity of the membranes are enhanced by restricting the swelling of the transporting polymer component networks.

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Strain hardening behavior of linear polymer melts

  • Hong Joung Sook;Ahn Kyung Hyun;Lee Seung Jong
    • Korea-Australia Rheology Journal
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    • v.16 no.4
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    • pp.213-218
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    • 2004
  • Linear high-density polyethylene (PE) was controlled to induce strain-hardening behavior by introducing a small amount of second component with an anisotropic structure. In order to form an anisotropic structure in the PE matrix, the polymer was extruded through a twin-screw extruder, and the structure was controlled by varying the extrusion conditions. Depending on conditions, the second component formed a film, thread and droplet structure. If the second component was kept rigid, the morphology evolution could be delayed and the second component could maintain its film or thread structure without further relaxation. In par­ticular, the second component of the thread structure made a physical network and gave rise to remarkable strain hardening behavior under high extension. This study suggests a new method that induces strain hard­ening behavior by introducing a physically networked second component into the linear polymer melt. This result is anticipated to improve the processibility of linear polymers especially when extensional flow is dominant, and to contribute to our understanding of strain hardening behavior.

Relativistic Molecular Theory

  • Nakajima, Takahito
    • Bulletin of the Korean Chemical Society
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    • v.24 no.6
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    • pp.809-811
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    • 2003
  • This brief review contains surveys of both four-component and two-component relativistic molecular theories. First the four-component relativistic approach is reviewed. Emphasis is placed on efficient computational schemes for the four-component Dirac-Hartree-Fock and Dirac-Kohn-Sham methods. Next, in the twocomponent relativistic framework, two relativistic Hamiltonians, RESC and higher-order Douglas-Kroll (DK), are introduced. An illustrative application is shown for the relativistic study on valence photoelectron spectrum of OsO₄. The developing four-component relativistic and approximate quasi-relativistic methods have been packed in a program suite named REL4D.

Analysis of Damaged Instance and Forming Fault for Disc Part in Automotive Steel Wheel (자동차용 스틸휠 디스크부품의 성형불량 및 파손사례분석)

  • Lee, Sung-Hee;Kim, M.Y.;Kim, T.G.;Yun, H.Y.;Kang, S.W.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2006.05a
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    • pp.234-238
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    • 2006
  • In this research, an analysis of damaged instance and forming fault for disc part in automotive steel wheel was performed. Rolled steel material, which had been used in the manufacturing of the damaged disc part, was prepared for tensile test, quantitative analysis of chemical component and acquirement of scanning electron microscope images. Although the results of mechanical properties and chemical component ratio for the material satisfied the suggested specification, some material inherent problem was found in the scanning electron microscope images. Finally, in an analysis of chemical component for the damaged disc part used in road condition, mismatching of chemical component ratio between the suggested specification and test result was found.

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Development of Component Reliability Database for Korean Nuclear Power Plants and Chemical Plants (국내 원자력 발전소 및 화학공장의 기기 신뢰도 데이터베이스 구축)

  • 최선영;한상훈
    • Proceedings of the Korean Reliability Society Conference
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    • 2000.11a
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    • pp.269-277
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    • 2000
  • The component reliability database is required in PSA (Probabilistic Safety Analysis) for NPP (Nuclear Power Plant). We have applied a generic database to the PSA for the Korean NPPs, since there is no specific component reliability database. Therefore we are developing the plant-specific component reliability database for domestic NPPs. We also extend the experience and knowledge of PSA and component reliability database for NPP to chemical industry We collect the raw data like component operation history and maintenance history and then input the required data for the component reliability database through failure analysis. With the database, we can not only perform PSA with real data but also perform maintenance optimization.

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Preparation of multi-component ceramic proton conductors for intermediate temperature fuel cell (중온형 연료전지를 위한 다성분계 세라믹 수소이온 전도체 제조)

  • Lim, Byeong-mu;Seo, Dong-ho;Park, Sang-sun;Lee, Hong-yeon;Shul, Yong-Gun
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.410-411
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    • 2009
  • The multi-component ceramic proton conductor, $BaZr(Y)O_3-SiO_2-TiO_2-ZrO_2$ (BZY-STZ) and $LaPO_4-SiO_2-TiO_2-ZrO_2$ (LP-STZ), were synthesized by micro-emersion and sol-gel technique. The characterization of proton conductors were carried out using X-ray diffraction(XRD), thermogravimetric analysis(TGA), differential thermal analysis(DTA), impedance analysis. The proton conductors indicate the possibility of application for the intermediate temperature up to $700^{\circ}C$.

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ABS 수지상의 화학도금에서의 최적 Eteching 조건에 관한 연구

  • 김원택;이인배
    • Journal of the Korean institute of surface engineering
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    • v.5 no.2
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    • pp.1-4
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    • 1972
  • We have studied about the optimum chemical etching and sensitizing conditions of the plating on plastics. As specimen 'Mitzubishi Nobren MM2A' was used. The results were as follow. 1) The optimum chemical etching conditions. Etched the specimens for $10{\sim}40$ minutes at $70{\sim}80^{\circ}C$ with the etching solution of table 1, and for $10{\sim}15$ minutes at $65{\sim}70^{\circ}C$ with the etching solution of table 2 Table 1. Etching solution (I) Composition : $H_2SO_4(95%)-Component : 250 ml, Composition : $H_3PO_4(85%)$ - Component : 75ml, Composition : $K_2Cr_2O_7$ - Component : 12.5g, 2) The optimum sensitizing conditions. Sensitized the specimens for $60{\sim}90$ seconds at $25^{\circ}C$ with the sensitizing solution of table 3 Table 2. Etching solution (II) Composition : $H_2SO_4(95%)$ - Component : 22.5ml, Composition : $H_3PO_4(85%)$ - Component : 15ml, Composition : $CrO_3$ - Component : 105g, Composition : Water - Component : 150 ml, Table 3. Sensitizing solution Composition : $SnCl_2$ - Component : 9g, Composition : HCl(35%) - Component : 36ml, Composition : Water - Component : 300 ml

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