• Bulletin of the Korean Chemical Society
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• v.18 no.3
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• pp.328-333
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• 1997

Dicyanovinyl-containing bis-hydroxy monomers, p-bis[1-(4-hydroxypiperidinyl)]-2,2-dicyanovinyl]benzene (2), p-bis[1-[1-(2-hydroxyethyl)piperazinyl]-2,2-dicyanovinyl]benzene (3), p-bis[1-(4-hydroxyphenylamino)-2,2-dicyanovinyl]benzene (4) and p-bis[1-[N-methyl-(N-hydroxyethyl)amino]]-2,2-dicyanovinyl]benzene (5) were prepared from p-bis(1-chloro-2,2-dicyanovinyl)benzene (1) and the corresponding amino alcohol. The poly(enaminonitriles-ester)s with a variety of chemical structures in the main chain were prepared from them. The chemical structure of polymers was confirmed through the syntheses of their corresponding model compounds. The polymers are easily soluble in polar aprotic solvents such as DMF, DMSO and NMP. Brittle and hard films can be cast from DMF solutions of polymers. Most polymers showed a large exotherm in DSC analyses and undergo a curing reaction around 350 ℃ to form insoluble materials. The polymers consisting of rigid aromatic moieties show 80-88% residual weight at 500 ℃ under nitrogen.

• Korean Journal of Chemical Engineering
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• v.35 no.11
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• pp.2303-2312
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• 2018

Pretreatment process of silica-coated PET fabrics, a major low-grade PET waste, was developed using the reaction with NaOH solution. By destroying the structure of silica coating layer, impurities such as silica and pigment dyes could be removed. The removal of impurity was confirmed by X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), and energy dispersive X-ray spectroscopy (EDX). The pretreated PET fabric samples were used for depolymerization into its monomer, bis(2-hydroxylethyl) terephthalate (BHET), by glycolysis with ethylene glycol (EG), and zinc acetate (ZnAc) catalyst. The quality of BHET was confirmed by DSC, TGA, HPLC and NMR analyses. The highest BHET yield of 89.23% was obtained from pretreated PET fabrics, while glycolysis with raw PET fabric yielded 85.43%. The BHET yield from untreated silica-coated PET fabrics was 60.39%. The pretreatment process enhances the monomer yield by the removal of impurity and also improves the quality of the monomer.

• Computers and Concrete
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• v.27 no.2
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• pp.175-184
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• 2021

The incorporation of pozzolans to Portland cement pastes adds value in the development of new materials for the construction industry. This study presents a new computational method, complementary to the pozzolanic identification by compressive strength at 28 days method, for supporting the validation of pozzolanic mortars for non-structural purposes. An algorithm capable of classifying the pixels of micrographs of specimens fragments was developed. Therefore, comparative analyses were generated from fractional Gaussian representations in four intervals of the same amplitude that indicated the predispositions to form larger void indices (intervals 1 and 2). The results showed that the computational method indicators are in accordance with the physical and chemical indicators.

• Journal of Korean Society of Water and Wastewater
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• v.30 no.2
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• pp.167-177
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• 2016

This work investigated the decomposition of aqueous anatoxin-a originated from cyanobacteria using an underwater dielectric barrier discharge plasma system based on a porous ceramic tube and an alternating current (AC) high voltage. Plasmatic gas generated inside the porous ceramic tube was uniformly dispersed in the form of numerous bubbles into the aqueous solution through the micro-pores of the ceramic tube, which allowed an effective contact between the plasmatic gas and the aqueous anatoxin-a solution. Effect of applied voltage, treatment time and the coexistence of nutrients such as $NO_3{^-}$, $H_2PO_4{^-}$ and glucose on the decomposition of anatoxin-a was examined. Chemical analyses of the plasma-treated anatoxin-a solution using liquid chromatography-mass spectrometry (LC-MS) and ion chromatography (IC) were performed to elucidate the mineralization mechanisms. Increasing the voltage improved the anatoxin-a decomposition efficiency due to the increased discharge power, but the energy required to remove a given amount of anatoxin-a was similar, regardless of the voltage. At an applied voltage of 17.2 kV (oxygen flow rate: $1.0L\;min^{-1}$), anatoxin-a at an initial concentration of $1mg\;L^{-1}$ (volume: 0.5 L) was successfully treated within 3 min. The chemical analyses using LC-MS and IC suggested that the intermediates with molecular weights of 123~161 produced by the attack of plasma-induced reactive species on anatoxin-a molecule were further oxidized to stable compounds such as acetic acid, formic acid and oxalic acid.

• Journal of the Korean Institute of Landscape Architecture
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• v.32 no.6 s.107
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• pp.95-102
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• 2005

This study was carried out to find out the heavy metal contents and the physico-chemical properties for the improvement of dredged soils which widely exist in lowlands of Korea. At first all the average heavy metal contents were close to background level and were much lower than concern level of the Soil Environment Conservation Act of Korea. And the results of physical analyses of soils showed on the average $2.46\~2.74 Mg/m^3$ in Particle density, $0.45\~2.45 kg/kg$ in soil water contents, $0.34\~0.90 Mg/m^3$ in bulk density, $0.67\~0.87m^3/m^3$ in porosity, $2.18\times10^{-5}\~1.20\times10^{-8} m/s$ in saturated hydraulic conductivity, R0.12\~0.65 m^3/m^3$ in available water contents. Finally the results of chemical analyses of soils showed on the average $6.5\~8.2\;in\; pH,\;5\~48 g/kg\;in\; OM,\;0.48\~4.51g/kg\;in\;T-N,\;19\~25mg/kg$ in available phosphate, $0.28\~11.80 dS/m\;in\;EC,\;8.7\~38.1cmol/kg$ in CEC, respectively Accordingly, the physicochemical properties of soils ought to be analyzed accurately before dredging for effective using of dredged soils. And it will be more effective, if the dredged soils are used with proper balance among each content of components with consideration to the physicochemical properties of common soils.

• Journal of the Korean Chemical Society
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• v.19 no.3
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• pp.198-206
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• 1975

Polymers with photosensitive functional groups, the naphthoquinone-1,2-diazide-5-sulfonyl esters(PGND, BEND and PVAND) of polyglyceryl phthalate(PG), bisphenol A-epichlorohydrin polycondensate(BE) and polyvinyl alcohol(PVA), were prepared. The molecular weights of the starting materials were determined by the cryoscopic method, i.e., in the range of 650${\sim}$1200 for PG and 780${\sim}$1320 for BE, PGND, BEND and PVAND were prepared by esterification of PG, BE and PVA with naphthoquinone-1,2-diazidie-5-sulfonyl chloride, and the replacements of such a functional groups were confirmed by the infrared absorption spectra and elemental analyses. The good agreement between the observed values of elemental analyses (PGND, BEND and PVAND) and the calculated values, indicated that the degree of polymerization did not change in the course of esterification of PG, BE and PVA.

• Economic and Environmental Geology
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• v.34 no.1
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• pp.13-23
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• 2001

Bentonite layers are intercalated within the basal conglomerates in the Tertiary sedimentary basins of Kampo, Janggi and Pohang, southeastern Korea. Eighteen samples of the bentonites went through X-ray diffraction, scanning electron microscopy, heavy mineral analyses, chemical analyses and oxygen, hydrogen stable isotope analyses to define the mineralogical characters of the bentonites. Heavy minerals such as zircons, apatites, amphiboles and biotites separated from bentonites show clean and euhedral surfaces, which are the characteristic features of volcanic origin. But biotites from the Chunbook Conglomerate are found as altered and heavily broken flakes which implies longer transportation of these bentonites. $TiO_{2}/Al_{2}O_{3} ratios of <2 $\mu$m particle fractions (the Chunbook Conglomerate 0.031; Janggi 0.029; Kampo 0.025) suggest that those are originated from volcanic tuffs. That is, the higher the value is, the more mafic in chemical compositions of the original tuffs. Authigenic montmorillonite and zeolite minerals were observed by SEM, which indicates diagenesis origin of bentonites. But the samples from the Chunbook Conglomerate showed only chaotically packed clay flakes in the matrix of sands or conglomerates, which implies detrital influence, not authigenic origin. The structural formulae of montmorillonite from these basins reflects their environment of formation. Fe (Ⅵ) can show the redox condition of its past environment and much lower $Fe^{2+}(Ⅵ)/Fe^{3+}(Ⅵ)$ ratios in montmorillonite of the Chunbook Conglomerate imply the greater oxidizing influence. Calculated burial depths from oxygen stable isotope data of the samples from the Chunbook Conglomerate generally fall to the range of 929~963 m whereas the real burial depth of this area is only 530~580 m. This could be explained as the bentonites of the Chunbook conglomerate had not been formed in situ. Discriminant analyses with the data from chemical analyses and structural formulae of montmorillonites show that bentonites from three different basins could definitely be distinguished with each other. This result arises from the different chemical compositions of original volcanic ashes and the difference of sedimentary environments.

• Bulletin of the Korean Chemical Society
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• v.35 no.6
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• pp.1675-1680
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• 2014

A peroxopolyoxotungsten-based ionic hybrid was synthesized by anion-change of peroxopolyoxometalate (POM) $PW_4O{_{24}}^{3-}$ with dicationic long-chain alkyl imidazolium ionic liquids. The characterization was conducted by FT-IR, TGA, $^1H$-NMR and CHN Elemental analyses. Its catalytic performance was evaluated by the epoxidation of soybean oil with $H_2O_2$ under solvent-free condition, including testing of organic cations influence, catalytic reusability and reaction conditions. The catalyst was proved to be a highly efficient recyclable catalyst for epoxidation of various vegetable oils with $H_2O_2$, showing high $H_2O_2$ utilization efficiency, high catalytic activity, convenient recovery and good reuse ability.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2006.04a
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• pp.307-311
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• 2006

Chemical analyses were conducted for Nakdong River water and riverbank filtrate in Daesan-Myeon area, Changwon City in 2005. Chemical components show different trends in wet season (June, July, August and September) and dry season (the other months). The patterns of chemical variation are classified into four types. Chemical components belonging Type I, as Na and $HCO_3$, show decrease in concentration during wet season and increase in concentration during dry season for both Nakdong River water and the riverbank filtrate. Chemical components belonging Type II, as Mg and $SO_4$, show decrease in concentration during wet season and increase in concentration during dry season for Nakdong River water while show the opposite trend for the riverbank filtrate. Chemical components belonging Type III, as Cl and $NO_3$, show increase in concentration from the start of wet season and high concentration during dry season for both Nakdong River water and the riverbank filtrate. Chemical components belonging Type IV, as Fe, show increase in concentration during wet season and decrease in concentration during dry season for both Nakdong River water and the riverbank filtrate.

• Water Engineering Research
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• v.7 no.1
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• pp.9-20
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• 2006

The watersheds are functional geographical areas that integrate a variety of environmental and ecological processes and human impacts on landscapes. Geographical assessments using GIS recognize the relationship between interdependence of resources and ecological/environmental components in watersheds. They are useful methodology for viable long term natural resource management. This paper performs through the using hydrological analyses, landscape ecological analyses, remote sensing, and GIS. Indicators are items or measures that represent key components of the small watersheds, and they are developed to be evaluated. Some indicators are described that they represent watershed condition and trend as well as focus on physical, biological and chemical properties of small watershed. Also, ecological functions such as stability, resilience, and sensitivity are inferred from them. The model implemented in GIS allows to reflect the ecological and hydrological functioning of watershed. Methodology from image analysis, landscape ecological analysis, spatial interpolation, and numerical process modeling are integrated within GIS to provide assessment for eco-logical/environmental condition. Results are described from the small watershed of Gwynns Falls in Baltimore County and Baltimore City, Maryland, an area of about 66.5 square miles. The small watershed within Gwynns Falls watershed are subject to a number of land-use. But it is predominantly urban, with significantly lesser amounts of forest and agriculture. The increasing urbanization is ass-coiated with ecological/environmental impacts and citizen conflicts.