• Analytical Science and Technology
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• v.13 no.4
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• pp.539-543
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• 2000

The quantitative aspects of 2D carbon-13 INADEQUATE (Incredible Natural Abundance DoublE QUAntum Transfer Experiment) experiment were studied on the basis of the time needed in various concentrations of samples. In order to evaluate the quantitative time of this experiment, eight compounds were selected (M. W. ca. 150-500). The effect on time needed of various concentrations showed exponential decay function, Y=$8.15X^{-0.64}$.

• Carbon letters
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• v.25
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• pp.103-112
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• 2018

Hierarchically porous, chemically activated carbon materials are readily derived from biomass using hydrothermal carbonization (HTC) and chemical activation processes. In this study, empty fruit bunches (EFB) were chosen as the carbon source due to their sustainability, high lignin-content, abundance, and low cost. The lignin content in the EFB was condensed and carbonized into a bulk non-porous solid via the HTC process, and then transformed into a hierarchical porous structure consisting of macro- and micropores by chemical activation. As confirmed by various characterization results, the optimum activation temperature for supercapacitor applications was determined to be $700^{\circ}C$. The enhanced capacitive performance is attributed to the textural property of the extremely high specific surface area of $2861.4m^2\;g^{-1}$. The prepared material exhibited hierarchical porosity and surface features with oxygen functionalities, such as carboxyl and hydroxyl groups, suitable for pseudocapacitance. Finally, the as-optimized nanoporous carbons exhibited remarkable capacitive performance, with a specific capacitance of $402.3F\;g^{-1}$ at $0.5A\;g^{-1}$, a good rate capability of 79.8% at current densities from $0.5A\;g^{-1}$ to $10A\;g^{-1}$, and excellent life cycle behavior of 10,000 cycles with 96.5% capacitance retention at $20A\;g^{-1}$.

• Bulletin of the Korean Chemical Society
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• v.35 no.1
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• pp.165-172
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• 2014

The distribution of basic nitrogen-containing compounds in three vacuum gas oils (VGOs) with different boiling ranges and their dewaxed oils from the lube base oil refining unit of a refinery were characterized by positive-ion electrospray ionization (ESI) Fourier transform-ion cyclotron resonance mass spectrometry (FT-ICR MS). It turned out that the composition of basic nitrogen compounds in the samples varied significantly in DBE and carbon number, and the dominant basic N-containing compounds in these oil samples were N1 class species. $N_1O_1$, $N_1O_2$, and $N_2$ class species with much lower relative abundance were also identified. The composition of basic nitrogen compounds in VGOs and dewaxed VGOs were correlated with increased boiling point and varied in DBE and carbon numbers. The comparison of the analytical results between VGOs and dewaxed VGOs indicated that more basic N-containing compounds in VGO with low carbon number and small molecular weight tend to be removed by solvent refining in lube base oil processing.

• Journal of The Korean Astronomical Society
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• v.35 no.4
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• pp.209-220
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• 2002

In order to increase the completeness of the investigations of stellar abundances, we can use spectrum synthesis method, new atomic data and observation of stellar spectra with resolution comparable to solar spectral atlases. We made a brief review of main problems of these three ways. We present new results of abundance determinations in the atmospheres of four stars. The first is the implementation of new atomic data to well known Przybylski's star. We show that the number of spectral lines, which can be identificated in the spectrum of this star, can be significantly higher. The second example is the investigation of $\zeta$ Cyg. We found the abundances of 51 elements in the atmosphere of this mild barium star. The third example is halo star HD221170. Our preliminary abundance pattern consists of 42 elements. The heaviest elements in this pattern are U and Th. The last star is the spectroscopic binary HD153720. The number of elements investigated in the spectra of components of this star is not large, but the results show that the components are Am-stars.

• Journal of Microbiology and Biotechnology
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• v.28 no.9
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• pp.1517-1526
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• 2018

Investigating bacterial diversity and its metabolic capabilities is crucial for interpreting the ecological patterns in a desert environment and assessing the presence of exploitable microbial resources. In this study, we evaluated the spatial heterogeneity of physicochemical parameters, soil bacterial diversity and metabolic adaptation at meter scale. Soil samples were collected from two quadrats of a desert (Thar Desert, India) with a hot, arid climate, very little rainfall and extreme temperatures. Analysis of physico-chemical parameters and subsequent variance analysis (p-values < 0.05) revealed that sulfate, potassium and magnesium ions were the most variable between the quadrats. Microbial diversity of the two quadrats was studied using Illumina bar-coded sequencing by targeting V3-V4 regions of 16S rDNA. As for the results, 702504 high-quality sequence reads, assigned to 173 operational taxonomic units (OTUs) at species level, were examined. The most abundant phyla in both quadrats were Actinobacteria (38.72%), Proteobacteria (32.94%), and Acidobacteria (9.24%). At genus level, Gaiella represented highest prevalence, followed by Streptomyces, Solirubrobacter, Aciditerrimonas, Geminicoccus, Geodermatophilus, Microvirga, and Rubrobacter. Between the quadrats, significant difference (p-values < 0.05) was found in the abundance of Aciditerrimonas, Geodermatophilus, Geminicoccus, Ilumatobacter, Marmoricola, Nakamurella, and Solirubrobacter. Metabolic functional mapping revealed diverse biological activities, and was significantly correlated with physicochemical parameters. The results revealed spatial variation of ions, microbial abundance and functional attributes in the studied quadrats, and patchy nature in local scale. Interestingly, abundance of the biotechnologically important phylum Actinobacteria, with large proposition of unclassified species in the desert, suggested that this arid environment is a promising site for bioprospection.

• Journal of The Korean Astronomical Society
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• v.17 no.2
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• pp.69-103
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• 1984

Five different calibrations of metal abundances of globular clusters are examined and these are compared with metallicity ranking parameters such as $(Sp)_c$, . Q39 and IR-indices. Except for the calibration $[Fe/H]_H$ by the high dispersion echelle analysis. the other calibration scales are correlated with the morphological parameters of red giant branch. In the $[Fe/H]_H$-scale. the clusters later than ${\sim}F8$ have nearly a constant metal abundance. $[Fe/H]_H{\simeq}-1.05$, regradless of morphological characteristics of horizontal branch and red giant branch. By the two fundamental calibration scales of $[Fe/H]_L$ (derived by the low dispersion analysis) and $[Fe/H]_{{\Delta}s}$ (derived by the spectral analysis of RR Lyrae stars). the globular clusters are divided into the halo clusters with [Fe/H]<-1.0 and the disk clusters confined within the galactocentric distance ${\tau}_G=10\;kpc$ and galactic plane distance |z|=3 kpc. In this case the abundance gradient is given by d[Fe/H]/$dr_G{\approx}-0.05\;kpc^{-1}$ and d[Fe/H]/$d|z|{\simeq}-0.08\;kpc^{-1}$ within ${\tau}_G=20\;kpc$ and |z|=10 kpc, respectively. According to these characteristics of the spatial distribution of globular clusters. the chemical evolution of the galactic globular clusters can be accounted for by the two-zone (disk-halo) slow collapse model when the $[Fe/H]_L$-or $[Fe/H]_{{\Delta}s}$-scale is applied. In the case of $[Fe/H]_H$-scale, the one-zone fast collapse model is preferred for the evolution of globular clusters.