• Title/Summary/Keyword: charging effect

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A Study of Hydrogen Embrittlement on a Material of CNG Storage Tank (CNG 저장용기 재료의 수소취성에 관한 연구)

  • Han, J.O.;Lee, Y.C.;Lee, J.S.;Chae, J.M.;Hong, S.H.
    • Journal of the Korean Institute of Gas
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    • v.15 no.2
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    • pp.9-14
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    • 2011
  • A set of test was conducted on a SA-372 steel for CNG storage tank to study the effect of hydrogen embrittlement. Tensile tests were carried out several conditions such as CNG, HCNG and H2 gas environment including air and Ar under the 35 MPa. Also, the test speed was set at 4*10^-4/s and 4*10^-5/s respectively. To maintain the high pressure for environmental gas during test process, we chose MTS which was installed autoclave. Test results showed that tensile stress, elongation rate and cross sectional contraction under Ar and CNG charging condition were similar to that of reference of air. And there was little bit change with test speed variations. However, hydrogen added conditions such as HCNG and H2 were revealed noticeable change in elongation rate and cross sectional contraction. Tensile stress was still uniform for all conditions. From the results, the effect of hydrogen embrittlement was confirmed on the hydrogen enriched conditions. Also its effect was showed more strong with much hydrogen concentration and slower test speed.

Effect of the pH Value of Seed Coating Solution on Microstructure of Silicalite-1 Zeolite Separation Layer Grown on α-Alumina Support (종결정 코팅용액 pH 값이 α-알루미나 지지체 표면에 성장하는 Silicalite-1 제올라이트 분리층의 미세구조에 미치는 영향)

  • Hu, Sigui;Kim, Min-Zy;Lee, Du-Hyoung;Sharma, Pankaj;Han, Moon-Hee;Cho, Churl-Hee
    • Membrane Journal
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    • v.25 no.5
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    • pp.422-430
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    • 2015
  • The present study announces that the pH value of seed coating solution makes a significant effect on the microstructure of silicalite-1 zeolite layer formed on ${\alpha}$-alumina support. Seed with an average diameter of 75 nm was dispersed in ethanol to prepare three kinds of seed coating solutions with different pH values, and dip-coated on the support. The pH value was controlled to be 2.2, 7.0, and 9.3, respectively. In the secondary growth process, pH 7 seed solution resulted an uniform, 3 to $4{\mu}m$ thick, completely covered, and 100 nm grained silicalite-1 zeolite separation layer. The uniformity and completeness were explained by a uniform, closely packed, multi-layered, and completely covered seed coating in the pH 7 condition. In the condition, ${\alpha}$-alumina support and seed are oppositely charged: support is positively charged (8.4 mV) and seed, negatively (-1.7 mV). The opposite charging induced a strong electrostatic attraction between seed and support, which made the good seed coating state. On the other hand, pH 2.2 and pH 9.3 seed solutions resulted non-uniform, partially covered, and around $1{\mu}m$ grained zeolite separation layer, since seed and support are the same sign charged in the conditions. The same sign charging induced a strong electrostatic repulsion between seed and support which caused a low coverage of seed. It could be concluded that the pH value of seed coating solution is a key parameter to determine the microstructure of silicalite-1 zeolite separation layer.

Generation of Charged Clusters and their Deposition in Polycrystalline Silicon Hot-Wire Chemical Vapor Deposition (열선 CVD 증착 다결정 실리콘에서 전하를 띈 클러스터의 생성 및 증착)

  • Lee, Jae-Ik;Kim, Jin-Yong;Kim, Do-Hyeon;Hwang, Nong-Moon
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.11a
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    • pp.561-566
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    • 2005
  • Polycrystalline silicon films were deposited using hot wire CVD (HWCVD). The deposition of silicon thin films was approached by the theory of charged clusters (TCC). The TCC states that thin films grow by self-assembly of charged clusters or nanoparticles that have nucleated in the gas phase during the normal thin film process. Negatively charged clusters of a few nanometer in size were captured on a transmission electron microscopy (TEM) grid and observed by TEM. The negatively charged clusters are believed to have been generated by ion-induced nucleation on negative ions, which are produced by negative surface ionization on a tungsten hot wire. The electric current on the substrate carried by the negatively charged clusters during deposition was measured to be approximately $-2{\mu}A/cm^2$. Silicon thin films were deposited at different $SiH_4$ and $H_2$ gas mixtures and filament temperatures. The crystalline volume fraction, grain size and the growth rate of the films were measured by Raman spectroscopy, X-ray diffraction and scanning electron microscopy. The deposit ion behavior of the si1icon thin films was related to properties of the charged clusters, which were in turn controlled by the process conditions. In order to verify the effect of the charged clusters on the growth behavior, three different electric biases of -200 V, 0 V and +25 V were applied to the substrate during the process, The deposition rate at an applied bias of +25 V was greater than that at 0 V and -200 V, which means that the si1icon film deposition was the result of the deposit ion of charged clusters generated in the gas phase. The working pressures had a large effect on the growth rate dependency on the bias appled to the substrate, which indicates that pressure affects the charging ratio of neutral to negatively charged clusters. These results suggest that polycrystalline silicon thin films with high crystalline volume fraction and large grain size can be produced by control1ing the behavior of the charged clusters generated in the gas phase of a normal HWCVD reactor.

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Human Effect for Commercial Wireless Power Transfer System Operating at Low Frequency (상용 자기유도방식 무선전력전송 시스템의 인체영향 분석)

  • Kang, Jun-Seok;Lee, Seungwoo;Hong, Ic-Pyo;Cho, In-Kui;Kim, Nam
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.28 no.5
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    • pp.382-390
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    • 2017
  • In this paper, we consider particular exposure scenarios to evaluate human effects for inductive commercial wireless charging device operating at low frequency. The coil used in this study is the A10 model in Qi standard proposed by WPC(Wireless Power Consortium), and input power is 5 W to the operating frequency of 155 kHz. In perfectly aligned condition, the max leakage magnetic field is $257.58{\mu}T$ which is obtained at the side of the device, and it is exceeded about 7.4 times of the ICNIRP 1998 reference level. The SAR is evaluated with homogeneous phantom which has electric constants of wet skin. The max value of the SAR is $134.47{\mu}W/kg$ which is obtained at the side of the device also, and it is much lower than the international guidelines. Especially, it showed higher SAR values in case of misalignment condition, so we will need to consider the misalignment condition importantly when we evaluate human effects for wireless power transfer system.

Effect of Cathode/anode Weight Ratio in $LiCoO_2/MPCF$ Cell ($LiCoO_2/MPCF$전지에서 정$\cdot$부극 중량비의 영향)

  • Kim Sang-Pil;Cho Jeong-Soo;Kim Hee-Je;Park Jeong-Hu;Yun Mun-Soo
    • Journal of the Korean Electrochemical Society
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    • v.2 no.2
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    • pp.75-80
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    • 1999
  • Li-ion cells employ lithium transtion metal oxide as the cathode material and carbon as anode material. To manufacture Li-ion cell with higher capacity and better cycle life, the utilization of electrode materials should be as high as possible without lithium deposition onto the carbon surface during charging. A careful design of cell balance between cathode and anode materials as well as a proper charge method is a key factor to design Li-ion cell with long cycle life. In this study, we investigated the effect of cathode/anode weight ratio on the performance of $LiCoO_2/MPCF$ cell. First we evaluated the charge-discharge behaviours of half-cells. And cylindrical Li-ion cells were fabricated using graphitized MPCF anode and $LiCoO_2$ cathode. The voltage profiles for each half-cell in $LiCoO_2/MPCF$ cell were measured by using lithium metal as a reference electrode. Also, we evaluated the cyclic performance of $LiCoO_2/MPCF$ cells according to weight ratio. From the result of experiment $LiCoO_2$ cathode utilization was independent of weight ratio, but MPCF anode utilization was dependant on weight ratio. Also, the optimal weight ratio of $LiCoO_2/MPCF$ cell was found to be $2.0\~2.2$.

The Relationship between Job Stress and Job Satisfaction of Geriatric Care Helpers (요양보호사의 직무스트레스와 직무만족 간의 관계)

  • Lim, Jung-Do
    • The Journal of the Korea Contents Association
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    • v.11 no.1
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    • pp.225-235
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    • 2011
  • The research on the analysis of relationship between job stress and job satisfaction has been conducted targeting 355 Geriatric Care Helpers who are caring for the elderly people in the geriatric care centers in the area of Busan by the Act of Long-term Care Insurance for the Geriatric. As the method for the analysis t-test was conducted to investigate their job stress, counter-stress experience and effort, and job satisfaction. Also regression analysis was conducted to analyse the factors having effect on the job satisfaction of geriatric care helpers. The results of analysis can be summarized as following. First, job stress of geriatric care helpers at hospitals has shown significant difference from that at geriatric care centers, while job satisfaction of geriatric care helpers at care centers has shown some difference from that at hospitals. Second, measurement experience and effort of job stress was shown to some difference according to each institution. Third, the effect factors on geriatric care helpers were employment type, job stress, stress with patients in the case of hospitals, while those on geriatric care helpers were average wage, employment type, the number of charging patients, job stress, job requirement stress, and stress with patients. However, regardless of the type of employed institution, job satisfaction was shown high in case of full time job, low job stress, and high stress with patients.

Development of Orofacial Pains Therapy System based on Acupuncture Principles (침치료 원리를 이용한 안면 통증 치료기 개발)

  • Lee Yong-Heum;Bak Chang-Gye
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.9 no.5
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    • pp.1045-1051
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    • 2005
  • We developed an orofacial pains diagnosis/therapy system which can enlarge a therapy effect through a new stimulation. Contrary to its established method, this therapy system(DDTS-1) is a treating method which absorbs a surplus ion charge- the cause of an outbreak of a pain-of the human body using a capacitor. Absorbing a surplus ion charge of the human body with effect, it obtained optimal parameters which is control signal to control charging/discharging a capacitor to be 6Hz, and capacitance to be $0.1\~0.33{\mu}F.$ Through clinical demonstration, experimented on among patients-namely dental pain patients, joint disorders patients, and trigeminal neuralgia patients to verification of system. In result, an EAST stimulater had a very low change of abnormal potential against normal potential before/after being placed under medical care. DDTS-1 showed obvious differences that two potentials are one and the same potential or one potential is similar to the other one. DDTS-1 comparing with EAST showed the remedial value of the comparative advantage in all the medical treatment of pains. Therefore, stimulation of DDTS-1 is more effective than the existing electric stimulation. We verified its validity of ion charge absorption in the human body using capacitor which presented the present thesis. That is, we verified theoretical adequacy of control action in a pain, and its efficiency as well as confidence.

A Study on the Public-Private Partnership in the Emergency Medical System in Korea (한국응급의료서비스 민관파트너십 도입의 타당성에 관한 연구)

  • Kim, Kook-Rae;Kim, Tae-Yun
    • Fire Science and Engineering
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    • v.20 no.2 s.62
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    • pp.31-43
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    • 2006
  • In Korea, the Emergency Medical Service, EMS is provided by Fire Services with 119 EMS and all the public uses the service for free. Although it appears very successful and is respected nationally, structural problem EMS exist and are worsening. First of all, the "free riding effect" becomes increasingly problematic. Some argue that 30% of the demands is not urgent or emergent. The total number of demands is increasing even without the free riding effect. The Current EMS system itself cannot meet the increasing EMS demand. The medical aspect is so poor that the EMS cannot dispatch a medical specialist to the scene. The cardiac arrest resuscitation rate is only $1.24{\sim}9.9%$, compared to 40% in Boston, MA, USA. But due to the regulations and limitations of the Fire Service organization, it is difficult to secure enough EMS resources. To work out these problems, it needs a structural innovation. To secure enough resources and achieve higher medical performance we should invite the medical sector and the private sector into EMS arena by contracting partnerships with Fire Services and charging a reasonable EMS fee. We found through statistical test that any partnership system is more effective than fire-alone system and most countries around the world have partnership system rather than fire-alone system.

Performance Evaluation of Aqueous Redox Flow Battery using Quinone Redox Couple Dissolved in Ammonium Chloride Electrolyte (염화암모늄 전해질에 포함된 퀴논 레독스 활물질 조합을 이용한 수계 레독스 흐름 전지 성능 평가)

  • Lee, Wonmi;Chung, Kun Yong;Kwon, Yongchai
    • Korean Chemical Engineering Research
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    • v.57 no.2
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    • pp.239-243
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    • 2019
  • In this study, anthraquinone-2,7-disulfonic acid (2,7-AQDS) is used as negative active material and Tiron is used as positive active material for aqueous redox flow battery (RFB). In previous results that used the 2,7-AQDS and Tiron, sulfuric acid ($H_2SO_4$) was a supporting electrolyte. However, in this study, ammonium chloride ($NH_4Cl$) is suggested as the electrolyte for the first time. By changing the supporting electrolyte from $H_2SO_4$ to $NH_4Cl$, the cell voltage of RFB is improved from 0.76 V to 1.01 V. To investigate the effect of $NH_4Cl$ supporting electrolyte of the performance of RFB, the full-cell tests of RFB using 2,7-AQDS and Tiron that are dissolved in $NH_4Cl$ supporting electrolyte are carried out, while cut-off voltage range is a main parameter to determine their performance. When the cut-off voltage range is 0.2~1.6 V, the hydrogen evolution occurs during charging step. To address the side reaction effect, the cut-off voltage range is changed to 0.2~1.2 V. When the revised cut-off voltage range is used and the current density of $40mA/cm^2$ is applied, hydrogen evolution is not observed and the optimal RFB shows the charge efficiency of 99% and discharge capacity of 3.3 Ah/L at 10cycle.

Recent Progress in Air-Conditioning and Refrigeration Research : A Review of Papers Published in the Korean Journal of Air-Conditioning and Refrigeration Engineering in 2016 (설비공학 분야의 최근 연구 동향 : 2016년 학회지 논문에 대한 종합적 고찰)

  • Lee, Dae-Young;Kim, Sa Ryang;Kim, Hyun-Jung;Kim, Dong-Seon;Park, Jun-Seok;Ihm, Pyeong Chan
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.29 no.6
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    • pp.327-340
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    • 2017
  • This article reviews the papers published in the Korean Journal of Air-Conditioning and Refrigeration Engineering during 2016. It is intended to understand the status of current research in the areas of heating, cooling, ventilation, sanitation, and indoor environments of buildings and plant facilities. Conclusions are as follows. (1) The research works on the thermal and fluid engineering have been reviewed as groups of flow, heat and mass transfer, the reduction of pollutant exhaust gas, cooling and heating, the renewable energy system and the flow around buildings. CFD schemes were used more for all research areas. (2) Research works on heat transfer area have been reviewed in the categories of heat transfer characteristics, pool boiling and condensing heat transfer and industrial heat exchangers. Researches on heat transfer characteristics included the results of the long-term performance variation of the plate-type enthalpy exchange element made of paper, design optimization of an extruded-type cooling structure for reducing the weight of LED street lights, and hot plate welding of thermoplastic elastomer packing. In the area of pool boiling and condensing, the heat transfer characteristics of a finned-tube heat exchanger in a PCM (phase change material) thermal energy storage system, influence of flow boiling heat transfer on fouling phenomenon in nanofluids, and PCM at the simultaneous charging and discharging condition were studied. In the area of industrial heat exchangers, one-dimensional flow network model and porous-media model, and R245fa in a plate-shell heat exchanger were studied. (3) Various studies were published in the categories of refrigeration cycle, alternative refrigeration/energy system, system control. In the refrigeration cycle category, subjects include mobile cold storage heat exchanger, compressor reliability, indirect refrigeration system with $CO_2$ as secondary fluid, heat pump for fuel-cell vehicle, heat recovery from hybrid drier and heat exchangers with two-port and flat tubes. In the alternative refrigeration/energy system category, subjects include membrane module for dehumidification refrigeration, desiccant-assisted low-temperature drying, regenerative evaporative cooler and ejector-assisted multi-stage evaporation. In the system control category, subjects include multi-refrigeration system control, emergency cooling of data center and variable-speed compressor control. (4) In building mechanical system research fields, fifteenth studies were reported for achieving effective design of the mechanical systems, and also for maximizing the energy efficiency of buildings. The topics of the studies included energy performance, HVAC system, ventilation, renewable energies, etc. Proposed designs, performance tests using numerical methods and experiments provide useful information and key data which could be help for improving the energy efficiency of the buildings. (5) The field of architectural environment was mostly focused on indoor environment and building energy. The main researches of indoor environment were related to the analyses of indoor thermal environments controlled by portable cooler, the effects of outdoor wind pressure in airflow at high-rise buildings, window air tightness related to the filling piece shapes, stack effect in core type's office building and the development of a movable drawer-type light shelf with adjustable depth of the reflector. The subjects of building energy were worked on the energy consumption analysis in office building, the prediction of exit air temperature of horizontal geothermal heat exchanger, LS-SVM based modeling of hot water supply load for district heating system, the energy saving effect of ERV system using night purge control method and the effect of strengthened insulation level to the building heating and cooling load.