• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제53권6호
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• pp.305-311
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• 2004

Charge transport phenomena of polyaniline-DBSA/High Impact Polystyrene (PAM-DBSA/HIPS) blends have been studied through an examination of electrical conduction. HIPS used host polymer in the blends and PANI-DBSA obey a space charge limited conduction mechanism and a ohmic conduction mechanism respectively. However, PANI-DBSA/HIPS blends do not obey any classical conduction mechanism. Analysis of conduction mechanism revealed that the charging current of PANI-DBSA/HIPS blends increased with the increase of PANI-DBSA content. This result migrlt be explained by the reduction in the distance between PANI-DBSA particles enabling the charge carriers to migrate from a chain to a neighboring chain via hopping or micro tunneling. It was also found that the charging current of PANI-DBSA/HIPS blends decreased as the temperature was elevated, which is of typical phenomena in metals. It is speculated that the charge transport in PANI-DBSA particle was somewhat constrained due to strong phonon scattering.

• Transactions on Electrical and Electronic Materials
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• 제16권3호
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• pp.107-111
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• 2015

Our work is based on the development of a numerical model to develop a methodology for predicting the aging and breakdown in insulation due to the dynamics of space charge packets. The model of bipolar charge transports is proposed to simulate space charge dynamic for high DC voltage in law-density polyethylene (LDPE), taking into account the trapping and detrapping of recombination phenomena, this model has been developed and experimentally validation. Theoretical formulation of the physical problem is based on the Poisson, the continuity and the transport equations as well as on the appropriate models for injection. Numerical results provide temporal and local distributions of the electric field, the space charge density for the different kinds of charges, conduction and displacement current densities, and the external current.

• Advances in nano research
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• 제1권1호
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• pp.29-34
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• 2013

The conversion of mechanical energy into electrical energy at nanoscale using piezoelectric nanowire arrays has been in detail shown by deflection of nanowires. Recently it has performed an analytical model, both at classical and at quantum level, for describing the most important quantities concerning transport phenomena; the model predicts interesting peculiarities, as high initial charge diffusion in nanodevices constituting by nanowires and permits also in particular to deduce interesting informations about the devices sensitivity, focusing on the correlation between sensitivity and high initial diffusivity of these materials at nanometric level.

• 한국가시화정보학회지
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• 제19권1호
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• pp.50-56
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• 2021

With the advances in recent nanotechnology, mass transport phenomena have been receiving large attention both in academic researches and industrial applications. Nonetheless, it is not clearly determined which parameters are dominant at nanoscale mass transport. Especially, membrane is a kind of technology that use a selective separation to secure fresh water. The development of great separation membrane and membrane-based separation system is an important way to solve existing water resource problems. In this study, glass fiber-based membranes which are treated by graphene oxide (GO), poly-styrene sulfonate (GOP) and sodium dodecyl sulfate (GPS) were fabricated. Mass transport parameters were investigated in terms of material-specific and structure-specific dominance. The 3D structural information of GO, GOP, and GPS was obtained by using synchrotron X-ray nano tomography. In addition, electrostatic characteristic and water absorption rate of the membranes were investigated. As a result, we calculated internal structural information using Tomadakis-Sotrichos model, and we found that manipulation of surface characteristics can improve spacer arm effect, which means enhancement of water permeability by control length of ligand and surface charge functionality of the membrane.

• 에너지공학
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• 제20권4호
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• pp.278-285
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• 2011

본 연구에서는 리튬이온 전지의 충 방전 특성에 관한 모델링과 전산모사를 수행하였다. 전지의 시스템 구성은 단순화된 2차원 형태의 단일셀에 대하여 모델링하였고, 공학적 편미분방정식 풀이자인 FEMLAB을 이용하여 288 K와 318 K 범위내에서 충방전 특성에 대한 열적 모델링을 수행하였다. 모델링에 채택한 물성치 변수들에 대하여 온도특성을 고려하였으며, 이를 통하여 전지의 특징적인 충방전의 사이클 변화와 충방전 전하량의 변화를 체계적으로 전산모사하였다. 그 결과 충방전 속도에 상관없이 충방전의 주기가 온도가 낮아질수록 짧아짐을 정량적으로 해석할 수 있었다. 이에 부가하여 전지내에서 리튬이온의 물질전달 현상을 해석하여, 전지의 충방전 특성과의 상관관계를 고찰하였다.

• 공업화학
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• 제34권3호
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• pp.272-278
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• 2023

이 연구에서는 전류밀도와 전기삼투 현상이 전기투석(electrodialysis, ED)의 탈염성능에 미치는 영향을 분석하였다. 농축액의 농도를 10~200 g/L로 변화시키면서 정전압 조건에서 ED 실험을 진행하였다. ED 운전과정에서 스택에 공급되는 전류밀도와 전하량, 희석액과 농축액의 농도, 그리고 전기삼투에 의한 물 이동량을 측정하여 탈염성능을 분석하였다. 농축액의 농도가 증가함에 따라 이온교환막의 선택성이 감소하여 전류효율이 감소하였다. 또한 전류효율은 스택에 공급되는 전류밀도에 영향을 받는 것으로 나타났다. 전류밀도가 15 mA/cm² 이상에서는 역 확산이 억제되어 전류효율이 증가하였다. ED 운전과정에서 전기삼투에 의한 물 이동량을 분석하였다. 물 이동량은 농축액과 희석액의 농도비에 비례하여 증가하는 것을 알 수 있었다. 농도비가 100 이상에서는 삼투압에 의한 물 이동량이 급격히 증가하여 200 g/L 이상의 농축액을 얻는데 한계가 있는 것으로 나타났다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1998년도 추계학술대회 논문집
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• pp.299-302
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• 1998

Electroluminescent(EL) devices based on organic materials have been of great interest due to their possible applications for large-area flat-panel displays. They are attractive because of multicolor emission low operation voltage. In this study, several Eu complexes such as Eu(TPB)$_3$(Phen) and Eu(TPB)$_3$(Bpy) were synthesized and the photoluminescence(PL) and electroluminescence (EL) characteristics of their thin films were investigated by fabricating the devices having a structure of glass substrate/ITO/TPD/Europium-complexs/Alq$_3$/Al, where aromatic diamine(TPD) was used as an hole transporting and Alq$_3$ was used as an electron transporting materials. It was found that the photoluminescence(PL) and electroluminescence(EL) characteristics of these Europium complexes were dependent upon the ligands coordinated to Europium metal. Details on the explanation of electrical transport phenomena of the structure with I-V characteristics of the OLEDs using the trapped-charge-limited current(TCLC) model will be discussed.

• Journal of Electrical Engineering and Technology
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• 제7권1호
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• pp.97-102
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• 2012

To predict accurately the breakdown voltage in air at atmospheric pressure, a fully coupled finite element analysis combining the hydrodynamic diffusion-drift equations with Poisson's equation is proposed in the current paper. As three kinds of charged transport particles are nonlinearly coupled with spatial electric fields, the equations should be solved by an iterative numerical scheme, in which secondary effects, such as photoemission and photoionization, are considered. The proposed method has been successfully applied to evaluate the breakdown voltage in circular parallel-plane electrodes. Its validity has been proved through the comparison of the predicted and experimental results. The effects of numerical conditions of the initial charge, photoemission, and background ionization on the discharge phenomena are quantitatively assessed through Taguchi's design of experiment method.

• 대한약학회:학술대회논문집
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• 대한약학회 2003년도 Proceedings of the Convention of the Pharmaceutical Society of Korea Vol.2-2
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• pp.233.3-234
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• 2003

Electroosmotic flux during iontophoresis originates due to the net negative charge of the current passing channel (pores) in skin at physiological pH (pH 7.4). Thus, the channel is permselective to cations, and this causes the convective solvent flow, from anode to cathode direction. This solvent flow facilitates the flux of cations (from anode), inhibits that of anions (from cathode), and enables the enhanced transport of neutral, polar solutes. In this work, we have investigated the effect of a series of polyethylene glycols (PEGs) with different molecular weights on the electroosmtic flow to get more detail understanding of this phenomena. (omitted)

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2008년도 춘계학술대회 논문집
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• pp.33-36
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• 2008

The transient behavior of a passive air breathing direct methanol fuel cell (DMFC) operated on vapor-feeding mode is studied in this paper. It generally takes 30 minutes after starting for the cell response to come to its steady-state and the response is sometimes unstable. A mathematical dynamic one-dimensional model for simulating transient response of the DMFC is presented. In this model a DMFC is decomposed into its subsystems using lumped model and divided into five layers, namely the anodic diffusion layer, the anodic catalyst layer, the proton exchange membrane (PEM), the cathodic catalyst layer and the cathodic diffusion layer. All layers are considered to have finite thickness, and within every one of them a set of differential-algebraic governing equations are given to represent multi-components mass balance, such as methanol, water, oxygen and carbon dioxide, charge balance, the electrochemical reaction and mass transport phenomena. A one-dimensional, isothermal and mass transport model is developed that captures the coupling between water generation and transport, oxygen consumption and natural convection. The single cell is supplied by pure methanol vapor from a methanol reservoir at the anode, and the oxygen is supplied via natural air-breathing at the cathode. The water is not supplied from external source because the cell uses the water created at the cathode using water back diffusion through nafion membrane. As a result of simulation strong effects of water transport were found out. The model analysis provides several conclusions. The performance drop after peak point is caused by insufficiency of water at the anode. The excess water at the cathode makes performance recovery impossible. The undesired crossover of the reactant methanol through the PEM causes overpotential at the cathode and limits the feeding methanol concentration.