• Title/Summary/Keyword: charge reversal

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The Effect of Magnesium and Aluminium Ions on Zeta Potential of Bubbles (수중의 마그네슘과 알루미늄 이온이 기포의 제타전위에 미치는 영향)

  • Han, Moo-Young;Ahn, Hyun-Joo;Shin, Min-Seok
    • Journal of Korean Society of Water and Wastewater
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    • v.18 no.5
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    • pp.573-579
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    • 2004
  • Electroflotation, which is used as an alternative to sedimentation, is a separation treatment process that uses small bubbles to remove low-density particulates. Making allowances for recent collision efficiency diagram based on trajectory analysis, it is necessary to tailor zeta potential of bubbles that collide with negatively charged particles. In this paper, the study was performed to investigate the effects of magnesium and aluminium ions on zeta potential of bubbles. And, it was studied to find out factors which could affect the positively charged bubbles. Consequently, zeta potential of bubbles increased both with higher concentration of metal ions and in the acidic pH value. And, a probable principle that explained the procedure of charge reversal could be a combined mechanism with both specific adsorption of hydroxylated species and laying down of hydroxide precipitate. It also depended on the metal ion concentration in the solution to display its capacity to control the bubble surface.

SPECTRAL DIAGNOSTICS OF NON-THERMAL PARTICLES IN THE SOLAR CHROMOSPHERE

  • FANG C.;XU Z.;DING M. D.
    • Journal of The Korean Astronomical Society
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    • v.36 no.spc1
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    • pp.55-61
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    • 2003
  • There are at least three effects of the non-thermal particle bombardment on the solar atmosphere: (1) non-thermal ionization and excitation; (2) proton-hydrogen charge exchange; (3) impact line polarization. Due to the non-thermal ionization and excitation effects of electron bombardments in flares, H$\alpha$ line is widely broadened and shows a strong central reversal. Significant enhancements at the line wings of Ly$\alpha$ and Ly$\beta$ are also predicted. In the case of proton bombardment, less strong broadening and no large central reversal are expected. However, due to proton-hydrogen charge exchange, the enhancements at the red wings of Ly$\alpha$ and especially of Ly$\beta$ lines at the early impulsive phase of flares are significant. Electron beam can also in some cases generates visible and UV continuum emission in white-light flares. However, at the onset phase, a negative 'black' flare may appear in several seconds, due to the increase of the $H^-$ opacity. The impact polarization of atomic lines can provide complementary information on the energetic particles, the energy transport and deposit in the solar chromosphere. New results of spectropolarimetric analysis for the major flare on July 23, 2002 are also given in the paper.

Evaluation of polarization and mobile charge in ferroelectric films using TVS(Triangular Voltage Sweep) method (삼각전압소인법을 이용한 강유전체 박막내에서의 분극 및 유동이온에 대한 평가)

  • 김용성;이남열;정순원;김진규;정상현;김광호;유병곤;이원재;유인구
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.86-89
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    • 2000
  • The detection technique both the polarization and the mobile charge density at the same time in ferroelectric films on Si using TVS method have been proposed. This method yields a polarizable and an ionic displacement current peaks whose areas are proportional to the total polarization reversal charge and the total moble ionic space charge, respectively. The calculated polarization and the mobile charge density were 0.42 [$\mu$C/$\textrm{cm}^2$] and 5.5$\times$10$^{11}$ (ions/$\textrm{cm}^2$) in the SBT film of MFIS structure measured at 25$0^{\circ}C$, and 1.4 [$\mu$C/$\textrm{cm}^2$] in the LiNbO$_3$ film of MFS structure measured at 30$0^{\circ}C$, respectively.

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Study on the effect of DC voltage in oil-immersed transformer insulation system (DC 전압이 유입변압기 절연시스템에 미치는 영향에 관한 연구)

  • Jang, Hyo-Jae;Kim, Yong-Han;Seok, Bok-Yeol
    • Proceedings of the KIEE Conference
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    • 2011.07a
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    • pp.1552-1553
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    • 2011
  • The HVDC transformer which is one of the main equipments for HVDC(High Voltage Direct Current) electric power transmission systems is exposed to not only AC voltage but also the inflowing DC voltage which comes from the DC-AC converter systems. Therefore, the HVDC transformer insulation system is required to withstand the electric field stress under AC, DC and DC polarity reversal conditions. However the electric field distributions under those conditions are different because the AC electric field and DC electric field are governed by permittivity and conductivity, respectively. In this study, the changes of electric potential and electric field of conventional AC transformer insulation system under DC polarity reversal test condition were analyzed by FEM(Finite Element Method). The DC electric field stress was concentrated in the solid insulators while the AC electric field stress was concentrated in the mineral oil. In addition, the electric stress under that condition which is affected by the surface charge accumulation at the interfaces between insulators was evaluated. The stress in some parts could be higher than that of AC and DC condition, during polarity reversal test. The result of this study would be helpful for the HVDC transformer insulation system design.

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The Effect of NiO and $MnO_2$ Addition on the Dielectric Piezoelectric and Polarization-Reversal Properties of PLZT (NiO와 $MnO_2$ 의 첨가가 PLZT의 유전특성과 압전특성 및 분극반전특성에 미치는 효과)

  • 조경익;주웅길;고경신
    • Journal of the Korean Ceramic Society
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    • v.20 no.4
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    • pp.315-323
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    • 1983
  • Effect of NiO and $MnO_2$ addtivies on the dielectric piezoelectrics and polarization-reversal properties of $(Pb_{0.936} La_{0.064})$$(Zr_{0.60}Ti_{0.40})O_3$ ceramics have been investigated. The specimens were prepared by the mixed oxide techni-que and atmosphere sintering method. The room temperature X-ray diffraction studies show that perfect perovskite solution with tetragonal structure was obtained from PLZT and its additives. The dielectric constant and dissipation factor decreased with the addition of both NiO and $MnO_2$ The Curie of Curie temperature was not observed but they displayed broadened maxima. The planar coupling factor was improved by addition of NiO and also increased with increasing sintering time carried out at 105$0^{\circ}C$ Addition of $MnO_2$ yielded a markedly high mechanical quality factor. The space-charge field decreased with the addition of NiO but increased with the addition of $MnO_2$ The planar coupling factor and space-charge field showed same dependence on the additivies. The tetragonality Curie temperature and planar coupling factor of $(Pb_{0.936} La_{0.064})$$(Zr_{0.60}Ti_{0.40})O_3$ were higher than those of $(Pb_{0.936} La_{0.064})$$(Zr_{0.568}NU_{0.032}Ti_{0.40})_{0.984}O_3$ but the grain size lattic parameter dielectric constant dissipation factor mechanical quality factor and space-charge field of the former were lower than those of the latter.

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SPECTRAL DIAGNOSTICS OF THE ENERGETIC PARTICLES IN SOLAR FLARES

  • FANG C.;DING M. D.;HENOUX J. C.;GAN W. Q.
    • Journal of The Korean Astronomical Society
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    • v.29 no.spc1
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    • pp.295-298
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    • 1996
  • Non-LTE calculations, with the non-thermal ionization effects included, indicated that for electron bombardment, the H$\alpha$ line is widely broadened and shows a strong central reversal. Significant enhancements at the line wings of Ly$\alpha$ and Ly$\beta$ are also predicted at the beginning of the impulsive phase of flares. For the proton bombardment, no strong broadening and no large central reversal are expected. However, due to proton-hydrogen charge exchange, the enhancements at the red wings of Ly$\alpha$ and Ly$\beta$ lines at the early impulsive phase of flares are significant. Our results show that the electron beam can also in some cases generate visible and UV continuum emission in white-light flares. However, at the onset phase, a negative flare may appear within several seconds, due to the increase of the H- opacity. Another spectroscopic signature of energetic particles, i.e. the impact polarization of atomic lines, is also mentioned.

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Quantitative estimation of reversibility of the discharge process undergone by nickel hydroxide film cathodically deposited on pure nickel as a positive supercapacitor electrode using cyclic voltammetry and potential drop method

  • Pyun Su-Il;Moon Sung-Mo
    • Journal of the Korean Electrochemical Society
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    • v.1 no.1
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    • pp.8-13
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    • 1998
  • This work presents the way how to evaluate the degree of reversibility of the discharging process undergone by the nickel hydroxide film cathodically deposited on pure nickel as a positive electrode for electrochemical capacitor using the combined cyclic voltammetry and potential drop method, supplemented by galvanostatic discharge and open-circuit potential transient methods. The time interval necessary just to establish the current reversal of anodic to cathodic direction from the moment just after applying the potential inversion of anodic to cathodic direction, was obtained on cyclic voltammogram. The cathodic charge density passed upon dropping the applied potential, was calculated on potentiostatic current density-time curve. Both the time interval and the cathodic charge density in magnitude can be regarded as being measures of the degree of reversibility of the discharging process undergone by the positive active material for supercapacitor, i.e. , the longer the time interval is, the lower is the degree of reversibility and the greater the cathodic charge density is, the higher is the degree of reversibility. From the applied potential dependences of the time interval and cathodic charge density, discharge at $0.42 V_{SCE}$ was determined to be the most reversible.

The Effects of the Surfactant Type on the Nanofluids Stability (계면활성제 특성에 따른 나노입자 분산안정도 향상 연구)

  • Kang, Chi-Hoon;Hong, Sung-Wook;Kang, Yong-Tae;Koo, June-Mo
    • Proceedings of the SAREK Conference
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    • 2008.11a
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    • pp.275-280
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    • 2008
  • The effects of the surfactant type, i.e., CTAB(cationic), SDS(anionic), and GA(polymeric), on the stability of 0.1 vol.% $Al_2O_3$ nanofluids were investigated. The changes in size and zeta potential of nanoparticles in nanofluids with pH, surfactant concentration, and time were experimentally observed. The nanofluids adding CTAB, which ionizes of the same charge with the bare particle surface, was found to have the best stability regardless of the surfactant concentration, whereas those with SDS became unstable under low surfactant concentration conditions, i.e. lower than the critical micellel concentration(CMC), before the charge reversal occurred. With higher SDS concentration over CMC, they became stable. Gum Arabic, which had been used often to stabilize the nanofluids, was also tested. In result, it was found that the type and concentration of surfactants to add should be selected considering pH and the sign of the bare particle surface charge.

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Study on the effects of space charge and conduction current by reversal of polarity (극성반전에 따른 공간전하 분포와 전도전류의 변화)

  • Gwak, Min-Woo;HwangBo, Seung;Chun, You-Jun;Shin, Hyun-June
    • Proceedings of the KIEE Conference
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    • 2011.07a
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    • pp.1578-1579
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    • 2011
  • 본 논문에서는 고분자 절연체가 인가된 전압의 시간에 따라 변화하는 공간전하와 전도 전류의 영향에 대하여 조사를 하였다. 또한 극성반전에 따른 공간전하의 분포와 전도 전류에 변화에 대한 연구를 실시하였다. 기존의 공간전하 분포 측정법들은 주로 고분자 절연재료 내에서 공간전하분포의 측정만을 목표로 한 반면에 공간전하 측정법 중의 하나인 PEA(Pulsed Electro-Acoustic method)을 개선시켜 공간전하와 전도전류의 동시 측정을 가능하게 하였다. 개선된 PEA법은 시간변화에 따른 공간전하와 전기전도의 직접적인 상관관계와 미리 형성 되어 있는 공간전하가 전기전도 및 절연특성에 미치는 영향을 직접적으로 분석할 수 있는 장점을 가지고 있다. 이러한 공간전하와 전류의 동시 측정법을 이용하여 연구하였다.

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Simulation for nanoimprint lithography process using temperature controlled nonequilibrium molecular dynamics (온도 제어 비평형 분자동역학 방법을 이용한 나노임프린트 리소그라피 공정의 전산모사)

  • Kwon, Sung-Jin;Lee, Young-Min;Im, Se-Young
    • Proceedings of the KSME Conference
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    • 2007.05a
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    • pp.332-336
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    • 2007
  • Temperature is an essential process variable in nanoimprint lithography(NIL) where the temperature varies between room temperature and above the glass transition temperature. To simulate NIL process, we employ both the Nose-Poincare method for temperature controlled molecular dynamics(MD) and force field for polymer material i.e. polymethyl methacrylate(PMMA), which is most widely selected as NIL resist. Nose-Poincare method, which convinces the conservation of Hamiltonian structure and time-reversal symmetry, overcomes the drawbacks inherent in the conventional methods such as Nose thermostat and Nose-Hoover thermostat. Thus, this method exhibits enhanced numerical stability even when the temperature fluctuation is large. To describe PMMA, we adopt the force field which account for bond stretch, bending, torsion, inversion, partial charge, and van der Waals energy.

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