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A Study on Benzene Synthesis for the Radiocarbon Dating (방사성탄소 연대측정을 위한 벤젠합성법 연구)

  • Kim, Nak Bae;Woo, Hyung Joo;Hong, Wan;Cho, Soo Young
    • Analytical Science and Technology
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    • v.5 no.1
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    • pp.25-31
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    • 1992
  • A benzene synthesizer was manufactured and has been used for the treatment of the various samples such as wood, charcoal, shell and soil for radiocarbon dating using liquid scintillation counter. The experimental conditions were optimized in each successive step of the synthesis of carbon dioxide, acetylene and the final product of benzene. Fifteen hours operation of the benzene synthesizer leads to product yields consistently in excess of 85% based on the content of calcium carbonate for the organic samples. Purity of the synthesized benzene was measured to be more than 99.9% by GC/MS.

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Efficient Plant Regeneration from Petal Segment of Standard-Type Chrysanthemum

  • Chhetri, Mahesh;Jeon, Su-Min;Naing, Aung Htay;Kim, Chang Kil
    • Current Research on Agriculture and Life Sciences
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    • v.31 no.2
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    • pp.94-100
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    • 2013
  • An efficient plant regeneration protocol is developed for a standard-type chrysanthemum. When petal segments derived from flower buds (4 or 8cm in diameter) were used as the culture material, the highest shoot regeneration frequency (96%) was obtained on a Murashige and Skoog (MS) medium supplemented with 0.5 mg/L IAA, 2 mg/L BA, 3% sucrose, and a 0.8% agar. Pre-culturing the explants under dark conditions for 14 days produced better results for the shoot regeneration frequency than the explants cultured under a continuous 16 h photoperiod ($40{\mu}molm^{-2}s^{-1}$). The shoot regeneration frequency ranged from 19.0% for the Shinmato cultivar to 89.1% for the Baeksun cultivar. Activated charcoal (0.2%) enhanced the root formation of the regenerated shoots in a hormone-free MS medium. The rooted plantlets were acclimatized and successfully established in a greenhouse.

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Construction of Resource Recovery System for Organic Wastes (유기성 폐기물의 자원화 체제구축에 관한 연구)

  • 양재경;최경민
    • Journal of Korea Technology Innovation Society
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    • v.2 no.2
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    • pp.290-308
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    • 1999
  • In this study a system for the treatment or recyling of organic wastes from both urban and rural area was recommended. It was developed based on the resource recovery system regarding human being by four tectnologies; forage, methane production, high-grade composting and complete decomposition. High quality compost can be produced by combining several kind of wastes produced from urban and agricultural areas. High quality compost must possess not only general characteristics of ordinary compost, but also a superior ability to improve the soil properties and must contain more nutrients for plant. Cedar chips were recommended as the main bulking agent to adjust moisture contents and air permeability. Charcoal and zeolite can be used not only as the second bulking agent but also as fertilizer for improve the soil amendment. Complete decomposition of organic wastes is defined by organic matter being completely converted to $CO_2$ and water. All the input water was evaporated by the heat produced through the oxidation of organic matter, In the present study, the complete treatments were successfully achieved for Shochu wastewater, swine wastes, thickened excess sewage sludge, wastes produced by Chinese restaurant and anaerobic digested sludge. First of all, recycling center of organic wastes should be established for the protect the environments and effective recovery of organic resources. This may means the way to derive the recovery of human value.

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Electrochemical characteristics of active carbon prepared by chemical activation for anode of lithium ion battery (이차전지 음극용 화학적 활성화법으로 제조된 활성탄의 전기화학적 특성)

  • Lee, Ho-Yong;Kim, Tae-Yeong;Lee, Jong-Dae
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.3
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    • pp.480-487
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    • 2015
  • In this study, several kinds of active carbons with high specific surface area and micro pore structure were prepared from the coconut shell charcoal using chemical activation method. The physical property of prepared active carbon was investigated by experimental variables such as activating chemical agents to char coal ratio, flow rate of inert gas and temperature. It was shown that chemical activation with KOH and NaOH was successfully able to make active carbons with high surface area of $1900{\sim}2500m^2/g$ and mean pore size of 1.85~2.32 nm. The coin cell using water-based binder in the electrolyte of LiPF6 dissolved in mixed organic solvents (EC:DMC:EMC=1:1:1 vol%) showed better capacity than that of oil-based binder. Also, it was found that the coin cell of water-based binder shows an improved cycling performance and coulombic efficiency.

Substrate Removal Characteristics for Low Temperature by Biological Activated Carbon (저온에서 생물활성탄의 기질제거특성)

  • Ryu, Seong Ho;Park, Chung Hyun
    • Journal of Korean Society of Water and Wastewater
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    • v.11 no.2
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    • pp.76-93
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    • 1997
  • Activated carbon is widely used for the treatment of water, wastewater and other liquid wastes. Biological activated carbon (BAC) process is water and wastewater treatment process developed in the 1970's. In addition to activated carbon adsorption, biodegradation organic pollutants occurs in the BAC bed where a large amount of aerobic biomass grows. This results in a long operation time of the carbon before having to be regenerated and thus a low treatment cost. Although the BAC process has been widely used, its mechanisms have not been well understood, especially the relationship between biodegradation and carbon adsorption, whether these two reactions can promote each other or whether they just simultaneously exist in the BAC bed. Also, the phenomenon of bioregeneration has been confused that previously occupied adsorption sites appear to be made available through the actions of microorganisms. And that, because biological process is influenced by low temperature, the mechanism of the BAC process is also effected by temperature variation in our country of winter temperature near the freezing point. Therefore, the objective of this study examines closely the mechanism of the BAC process by temperature variation using phenol as substrate. From this study, biological activated carbon is good substrate removal better than non adsorbing materials (charcoal, sand) as temperature variation, especially low temperature(near $5^{\circ}C$).

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Determinants of Lake Zone Forest Resources' Status: Analyzing the Impact of Implemented Policies in Tanzania

  • Mihayo, Isege Z.;Peng, Daiyan
    • Journal of Forest and Environmental Science
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    • v.36 no.3
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    • pp.233-242
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    • 2020
  • The Lake (Victoria) zone of Tanzania, which has the least forest resources in the country, is a potential economic growth zone in the country. Therefore, this study analyses the impact of implemented forest policies on the status of forest resources in the area, given the unique features. The study identifies the status of forested lands in the area, and then fits binary logistic regression to identify the impact of policies related elements (i.e. type of forest, type of management) on the status; forest area and location (region) are used as control variables. Results show that 63% of the forested land in the area is destructed; main activities being agriculture, residential, firewood, and charcoal burning activities. Logistic results showed natural forests, forests located in Geita region, forests managed by municipal councils are more likely to be destructed; while plantation forests, forests located in Kagera region, privately managed forests are less likely to be destructed. Thus, the study concludes that policies and measures are not enough for the preservation of forest resources in the area; some of the economic activities in the area are occurring at the expenses of the forests; hence recommend more sustainable development plans and incorporating different crossing cutting sectors in the policies.

A Convenient Method for the Catalytic Hydrogenation of Aromatic Nitro Compounds to Aromatic Primary Amines (수소첨가 촉매 반응에 의한 니트로 화합물에서 방향족 1차 아민을 제조하는 편리한 방법)

  • Kim, Misoo;Lee, Hagyoung
    • Transactions of the Korean hydrogen and new energy society
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    • v.8 no.3
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    • pp.131-135
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    • 1997
  • Aromatic primary amines were prepared by the catalytic hydrogenation of aromatic nitro compounds in a benzene solution over 50 mg of 10 % palladium on charcoal at a room temperature under 45 psi. This paper describes a study on the catalytic hydrogenation of nitrobenzene-$d_5$, $^{15}N$-labelled nitrobenzene, and 4'-nitrobenzo-15-crown-5, respectively. The infrared absorption spectra exhibited a characteristic N-H stretching vibrations at 3450 and $3350cm^{-1}$. The results suggest that the non-readily available aromatic amines would be commercially produced by catalytic hydrogenation because of its good yield and little by-product formation.

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Bioethanol Production from Eucheuma spinosum using Various Yeasts (Eucheuma spinosum으로부터 다양한 효모를 이용한 바이오에탄올 생산)

  • Kim, Min-Ji;Kim, Jung-Soo;Ra, Chae Hun;Kim, Sung-Koo
    • KSBB Journal
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    • v.28 no.5
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    • pp.315-318
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    • 2013
  • Ethanol fermentations were performed using separate hydrolysis and fermentation (SHF) processes with monosaccharides from pretreated seaweed, Eucheuma spinosum as the biomass. The pretreatment was carried out with 11% (w/v) seaweed slurry and 150 mM $H_2SO_4$ at $121^{\circ}C$ for 40 min. Enzyme hydrolysis after $H_2SO_4$ pretreatment was performed with Celluclast 1.5 L at $45^{\circ}C$ for 24 h. Five % active charcoal were added to hydrolysate to removed 5-hydroxy methylfurfural. Ethanol fermentation with 11% (w/v) seaweed hydrolysate was performed for 72~96 h using Kluyvermyces marxianus, Pichia stipits, Saccharomyces cervisiae and Candida tropicalis. Ethanol concentration was reached to 18 g/L by K. marxianus, 16 g/L by P. stipitis, 15 g/L by S. cerevisiae and 10 g/L by C. tropicalis, respectively. The ethanol yield from total monosugar was obtained 0.50 and ethanol productivity was obtained 0.38 g/L/h by K. marxianus.

Synthesis of Spherical Carbons Containing Titania and Their Physicochemical and Photochemical Properties

  • Oh, Won-Chun;Kim, Jong-Gyu;Kim, Hyuk;Chen, Ming-Liang;Zhang, Feng-Jun;Meng, Ze-Da;Choi, Jong-Geun;Zhang, Kan
    • Journal of the Korean Ceramic Society
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    • v.48 no.1
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    • pp.6-13
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    • 2011
  • In this study, we used activated carbon (AC) and charcoal (CH) as carbon sources with $TiO_2$ powder to prepare spherical carbons containing titania (SCCT) by using phenolic resin (PR) as a bonding agent. The physicochemical characteristics of the SCCT samples were examined by BET, XRD, SEM, EDX, iodine adsorption and compressive strength. The photocatalytic activity was evaluated by measuring the removal efficiency of three kinds of organic dyes: methylene blue (MB), methyl orange (MO) and rhodamine B (Rh.B) under a UV/SCCT system. In addition, evaluation of chemical oxygen demand (COD) of piggery waste was done at regular intervals and gave a good idea about the mineralization of wastewater.

Sensibility Preference of Eco-Friendly Fabric Products and Trust Reliability (친환경 섬유의류 제품의 감성 선호도와 신뢰도 조사 연구)

  • Na, Young-Joo;Kim, Hyo-Won
    • Fashion & Textile Research Journal
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    • v.14 no.3
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    • pp.430-437
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    • 2012
  • This study analyzed the sensibility of eco-friendly fabrics for college students and investigated their attitude on environmental problems, trust reliability onto eco-apparel products, and their purchase state. We tested 6 eco-friendly fabrics (recycled polyester, organic cotton, green tea, charcoal, bamboo, and nettle) through a survey using the Likert scale of 12 polar sensibility words. Most fabrics showed feelings that were smooth, natural, female, and country these were followed by fashion, cheap, functional, sustainable, warm, and vintage. In addition, nettle fabric showed 'rough' feeling, and recycled polyester fabric showed an 'artificial' feeling. Correspondence analysis showed the distance and direction between fabric types and sensibility words with a 2D diagram where the X axis was named with 'Soft <-> Hard' and Y axis was with 'Environmental <-> Manmade' to represent the relationship between fabric types and the sensibility words. According to the results of the multiple regression analysis, the cognition level of the consumer for environmental problems was found to be the most influential variable on the loyalty purchase of eco-friendly products; however, the trust reliability level of consumer onto eco-friendly apparel products was found to be the most influential variable on the conditional purchase of eco-friendly apparel products.