• Title/Summary/Keyword: characteristics degradation

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Degradation Characteristics of Eutectic and Pb-free Solder Joint of Electronics mounted for Automotive Engine (자동차 엔진룸용 전장품 유무연 솔더 접합부의 열화특성)

  • Kim, A Young;Hong, Won Sik
    • Journal of Welding and Joining
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    • v.32 no.3
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    • pp.74-80
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    • 2014
  • Due to environmental regulations (RoHS, WEEE and ELV) of the European Union, electronics and automotive electronics have to eliminate toxic substance from their devices and system. Especially, reliability issue of lead-free solder joint is increasing in car electronics due to ELV (End-of-Life Vehicle) banning from 2016. We have prepared engine control unit (ECU) modules soldered with Sn-40Pb and Sn-3.0Ag-0.5Cu (SAC305) solders, respectively. Degradation characteristics of solder joint strength were compared with various conditions of automobile environment such as cabin and engine room. Thermal cycle test (TC, $-40^{\circ}C$ ~ ($85^{\circ}C$ and $125^{\circ}C$), 1500 cycles) were conducted with automotive company standard. To compare shear strength degradation rate with eutectic and Pb-free solder alloy, we measured shear strength of chip components and its size from cabin and engine ECU modules. Based on the TC test results, finally, we have known the difference of degradation level with solder alloys and use environmental conditions. Solder joints degradation rate of engine room ECU is superior to cabin ECU due to large CTE (coefficient of thermal expansion) mismatch in field condition. Degradation rate of engine room ECU is 50~60% larger than cabin room electronics.

Degradation of BTX by Klebsiella gr. 47 in the Biological Wastewater Treatment (Klebsiella gr. 47을 이용한 생물학적 폐수처리에서 BTX 분해 특성)

  • 염승호;최석순
    • Journal of Environmental Science International
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    • v.7 no.3
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    • pp.393-400
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    • 1998
  • A microorganism, Klebsiella gr. 47, capable of degrading BTX(benzene, toluene and xylene) was isolated from oil-contaminated soil and its characteristics of BTX degradation were investigated. When benzene and toluene were fed to Klebstella gr. 47 simulataneously, they showed competitive ingibition. The degradation rate of xylene was enhanced as much as 3 times when xylene was fed with benzene or toluene. Degradation rate of benzene and toluene was also enhanced by cocultured with Alcaligenes xylosoxidans. When benzene-adapted microorganism was used, each BTX compound was degraded efficiently within 5 hours.

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Analysis of the ESD-Induced Degradation Behavior of Oxide VCSELs Using an Equivalent Circuit Model (ESD에 따른 산화형 VCSEL 열화 과정의 등가회로 모델을 이용한 분석)

  • Kim, Tae-Yong;Kim, Sang-Bae
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.45 no.3
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    • pp.6-21
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    • 2008
  • We have investigated the effect of the forward and reverse ESD pulse accumulation on the development of the oxide VCSEL's electrical and optical characteristics. The forward ESD-induced degradation is complicated, showing three degradation phases with increasing ESD voltage while the reverse ESD-induced degradation is divided by a sudden distinctive change in elecorl-optical characteristics. By comparing the measured L-I-V characteristics and their derivatives with the fitted characteristics using an equivalent circuit model as well as the large signal circuit model, the development of the oxide VCSEL's electro-optical characteristics under forward and reverse ESD conditions has been fully understood.

Effects of Different Additives on Fermentation Characteristics and Protein Degradation of Green Tea Grounds Silage

  • Wang, R.R.;Wang, H.L.;Liu, X.;Xu, C.C.
    • Asian-Australasian Journal of Animal Sciences
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    • v.24 no.5
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    • pp.616-622
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    • 2011
  • This study evaluated the fermentation characteristics and protein degradation dynamics of wet green tea grounds (WGTG) silage. The WGTG was ensiled with distilled water (control), or lactic acid bacteria (LAB), enzyme (E), formic acid (FA) and formaldehyde (FD) prior to ensiling. Three bag silos for each treatment were randomly opened at 0, 3, 7, 14, 28 and 60 days after anaerobic storage. For all the treatments, except for FA, there was a rapid decline in pH during the first 7 days of ensiling. LAB treatment had higher lactic acid content, lower ammonia-N ($NH_3$-N) and free-amino nitrogen (FAA-N) contents than other treatments (p<0.05). E treatment had higher lactic acid, water-soluble carbohydrates (WSC) and non-protein nitrogen (NPN) content than the control (p<0.05). FA treatment had higher $NH_3$-N and FAA-N content than the control (p<0.05). FD treatment had lower NPN and FAA-N content than the control, but it did not significantly inhibit the protein degradation when compared to LAB treatment (p>0.05). Results indicate that LAB treatment had the best effect on the fermentation characteristics and protein degradation of WGTG silage.

Enzymatic Characteristics of Biosynthesis and Degradation of Poly-$\beta$-hydroxybutyrate of Alcaligenes latus

  • Kim, Tae-Woo;Park, Jin-Seo;Lee, Yong-Hyun
    • Journal of Microbiology and Biotechnology
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    • v.6 no.6
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    • pp.425-431
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    • 1996
  • The enzymatic characteristics of Alcaligenes latus were investigated by measuring the variations of various enzyme activities related to biosynthesis and degradation of poly-${\beta}$-hydroxybutyrate (PHB) during cultivation. All PHB biosynthetic enzymes, ${\beta}$-ketothiolase, acetoacetyl-CoA reductase, and PHB synthase, were activated gradually at the PHB accumulation stage, and the PHB synthase showed the highest value among three enzymes. This indicates that the rate of PHB biosynthesis is mainly controlled by either ${\beta}$-ketothiolase or acetoacetyl-CoA reductase rather than PHB synthase. The enzymatic activities related to the degradation of PHB were also measured, and the degradation of PHB was controlled by the activity of PHB depolymerase. The effect of supplements of metabolic regulators, citrate and tyrosine, was also investigated, and the activity of glucose-6-phosphate dehydrogenase was increased by metabolic regulators, especially by tyrosine. The activities of ${\beta}$-ketothiolase and acetoacetyl-CoA reductase were also activated by citrate and tyrosine, while the activity of PHB depolymerase was depressed. The increased rate and yield of PHB biosynthesis by metabolic regulators may be due to the increment of acetyl-CoA concentration either by the repression of the TCA cycle by citrate through product inhibition or by the activation of sucrose metabolism by the supplemented tyrosine.

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Characteristics of Anaerobic Degradation on Dewatered Liquid of Household Food Waste. (음식물쓰레기 탈수액의 혐기성 생분해 특성)

  • Kim, Woo-Sung;Seo, Jeoung-Yoon;Lee, Young-Hyeong
    • Korean Journal of Environmental Agriculture
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    • v.17 no.3
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    • pp.234-238
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    • 1998
  • Anaerobic degradation characteristics of dewatered liquid of household food waste including methane conversion efficiency and degradation kinetics were studied in an anaerobic batch reactor of 5 L volume. The ultimate methane production for dewatered liquid of household food waste tested was over 0.31L $CH_4/L{\cdot}dewatered$ liquid of household food waste. The kinetic constant of dewatered liquid of household food waste tested was $0.223d^{-1}/L$. The kinetic behavior of anaerobic degradation was described as a first order series reaction. The determinant of rate-limiting step(DR) that is balanced out from the rates of reaction steps was defined by the logarithmic difference of the maximum acidification rate and the maximum methanation rate. Anaerobic degradation characteristics of organic materials were evaluated by the value of DR. The DR of dewatered liquid of household food waste tested was 1.17.

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Degradation Assessment of Thermoplastic Synthetic Resin Using Propagation Characteristics of Ultrasound (초음파 전파특성을 이용한 열가소성 합성수지의 열화 평가)

  • Jeon, Woo-Sang;Kim, Gi-Jin;Kwon, Sung-Duk
    • Journal of the Korean Society for Nondestructive Testing
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    • v.34 no.2
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    • pp.141-147
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    • 2014
  • A nondestructive ultrasonic technique was applied to evaluate the thermal characteristics and degradation of synthetic polymer resin (plastics) with better cost-effectiveness and functionality than glass and metal. Thermoplastic and transparent acrylic resin (PMMA) specimens were annealed at below the glass transition temperature ($T_g$), and the propagation characteristics (attenuation and velocity) were measured. The attenuation increased and the velocity decreased with thermal degradation. The results showed that the thermal aging of the specimens could be evaluated quantitatively and that the Tg could be evaluated qualitatively.

Degradation Characteristics of Aqueous MEA Solution by Corrosion Products and Absorption Conditions (흡수 조건 및 부식 생성물에 의한 MEA 수용액의 변성 특성)

  • NAM, SUNGCHAN;SONG, YOONAH;BAEK, ILHYUN;YOON, YEOIL;YOU, JEONGKYUN;LEE, CHANGHA
    • Transactions of the Korean hydrogen and new energy society
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    • v.27 no.3
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    • pp.290-297
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    • 2016
  • The absorbent loss due to degradation in $CO_2$ capture process using aqueous alkanol amine solution has adverse effect on the economics of overall process. The degradation causes absorbent loss, equipment corrosion, foaming, adhesive material producing and viscosity increase in operation. In this study, the degradation characteristics of $CO_2$ capture process using MEA (monoehtanolamine) under various conditions such as $O_2$ partial pressure, $CO_2$ loading and absorbent temperature. The effects of iron, which generated from the equipment corrosion, on absorbent degradation were studied using $Fe_2SO_4$ containing MEA solution. The produced gases were analyzed by FT-IR(Fourier Transform Infrared Spectrophotometer) and the specifically measured $NH_3$ concentration was used as a degradation degree of aqueous MEA solution. The experiments showed that the higher $CO_2$ loadings (${\alpha}$), $O_2$ fraction ($y_{O2}$) and reaction temperature enhanced the more degradation of aqueous MEA solution. Comparing other operation parameters, the reaction temperature most affected on the degradation. Therefore, it could be concluded that the above parameters affects on degradation should be considered for the selections of $CO_2$ absorbent and operating conditions.

A Study on the Degradation Characteristics of EPN (EPN의 분해특성에 관한 연구)

  • 이용두;김현희;김창영
    • Journal of Environmental Science International
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    • v.11 no.10
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    • pp.1103-1108
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    • 2002
  • In order to evaluate the degradation organophosphorus pesticide, EPN, in water environment, the effects of water temp.(10$^{circ}C,\;30^{\circ}C$), pH(3-11) and sunlight on its degradation were investigated during 10 days. The degradation rate of EPN(200 rpm) was faster at higher water temp. and higher pH, i.e., its degradation rate at pH 3, 5, 7, 9, 11 was 57, 63, 66, 69, 75%(1$0^{\circ}C$), and 70, 74, 79, 91, 97%(3$0^{\circ}C$) after 10 days, respectively. The effect of water temp. on its degradation was little in acidic condition, but was rather great in alkaline condition, with time. EPN was degraded fast at the alkaline condition by photolysis. At the condition of pH 11, EPN was degraded fast at the early stage in the first 2 days, but after that the degradation rate was weakened.

Degradation of 2-chlorophenol by Ferrate(VI) (Ferrate(VI)를 이용한 2-chlorophenol의 분해특성 연구)

  • Choi, Hye-Min;Kwon, Jae-Hyun;Kim, Il-Kyu
    • Journal of Korean Society of Water and Wastewater
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    • v.25 no.1
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    • pp.63-74
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    • 2011
  • The degradation characteristics of 2-chlorophenol(2-CP) by Ferrate(VI) were studied. The degradation efficiency of 2-CP in aqueous solution was investigated at various values of pH, Fe(VI) dosage, initial concentration and aqueous solution temperature. The maximum degradation efficiencies of 2-CP were obtained at pH 7.0 and aqueous solution temperature of 25$^{\circ}C$. The degradation efficiency was proportional to dosage of Fe(VI). Also, the initial rate constant of 2-CP degradation increased with decreasing of the 2-CP initial concentration. In addition, the degradation pathway study for 2-CP was conducted with GC-MS analysis. Acetic acid, formic acid, benzaldehyde and benzoic acid were identified as reaction intermediates of the 2-CP degradation by Ferrate(VI).