• Title/Summary/Keyword: change of physical properties

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Electrical Properties of Low Density Polyethylene Film by Superstructure Change (고차구조 변화에 따른 저밀도폴리에틸렌 박막의 전기적 특성)

  • Shin, Jong-Yeol;Shin, Hyun-Taek;Lee, Soo-Won;Hong, Jin-Woong
    • Journal of the Korean Society of Safety
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    • v.17 no.4
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    • pp.101-109
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    • 2002
  • The electrical properties of polyethylene are changed by the superstructure. Such crystalline polymer as polyethylene or polypropylene changes crystallinity and products spherulite or trans-crystal when it is cooled slowly. In this study, after thermal treatment of LDPE at 100[${circ}C$], in silicone oil for an hour, we made specimens in order of slow cooling, water cooling, quenching according to cooling speed. Also, to study the influence of electrical properties due to the superstructure change, we analyzed physical properties and performed dielectric breakdown experiments using DC and impulse voltage Moreover we measured space charges in bulk using Laser Induced Pressure Pulse(LIPP) method. Trap level of specimen is 0.064[eV] at the low temperature region 0.31[eV] at the high temperature region in DC dielectric strength, 0.03[eV] at the low temperature region 0.0925[eV] at the high temperature region in impulse dielectric strength. As its result shows that the quantity of charges induced from the electrode surface increases with applied voltage time, and the distribution of space charges in samples increases the quantity of charges in proportion to applied voltage.

Deterioration Characteristics of Naturally Aged AA 2026 due to ExpoSure to High Temperatures (자연 시효 처리된 AA 2026의 고온 노출에 따른 물성 열화 특성에 대한 연구)

  • HaNeul Kim;HyeonWoo Kang;ByoungLok Jang;HeeKook Kim
    • Journal of the Korean Society for Heat Treatment
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    • v.37 no.3
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    • pp.114-120
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    • 2024
  • AA 2026, which is used as an aviation material, is an improved version of 2024 and has higher physical properties, and is a material that has the potential to be applied to supersonic aircraft to be developed in the future. However, when an aircraft exceeds supersonic speeds, the surface heats up and the material must be resistant to this. Therefore, this study confirmed the high-temperature properties of AA 2026, an aviation structural material. AA 2026, solution treated at 500℃ for 4hr, was naturally aged at room temperature for more than 168 hr. Changes in microstructure and physical properties were confirmed over several hours of exposure to 100℃, 200℃, and 300℃, respectively. As a result of microstructure analysis, there was no significant change at 100℃, and from 200℃, GPB, a strengthening mechanism, grew and formed an S Phase. It was confirmed that the S Phase grew as the exposure time increased. Through a tensile test, it was confirmed that physical properties deteriorated as the precipitates grew. However, it was confirmed that the properties were stably maintained at 100℃, which is the temperature when the speed of a supersonic aircraft is less than Mach 2.

Comparison of the Physical Properties Korean and Japanese Lining Papers (국내.외 배접지의 물성 비교 분석)

  • Jeong, So-Young;Choi, Kyoung-Hwa;Park, Ji-Hee;Kang, Yeong-Seok
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.41 no.3
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    • pp.60-64
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    • 2009
  • Paper is easily damaged by physical and chemical deterioration under several factors. Damaged paper cultural heritage is usually restored by Lining. A traditional method of Lining is attaching the lining paper behind the original paper cultural heritage using starch and water. It supports the weakened quality of paper. In Japan, paper cultural heritage is restored with "Washi" which is made from mixture of Paper mulberry and Japanese cedar. In the west, the lining paper made from Paper mulberry, which has extraordinary excellent conservativeness, is usually used as a restoration material for paper. But Japanese Washi has dominated the demand for restoration materials as the most preferred restoration paper, and most kinds of paper made from Paper mullbery have been called as 'Japanese paper'. Result showed that the strength of the Korean lining papers was generally higher than that of the Japanese ones. As a result from measuring the rate of dimensional change after water-immersion and drying, sample B of the Korean lining papers and sample E of the Japanese lining papers showed the highest stability.

Solid Dispersion of an HIV Protease Inhibitor

  • Park, Jae-Hyeon;Lee, Sung-Hack;Lee, Yong-Hee;Kim, Ae-Ri
    • Journal of Pharmaceutical Investigation
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    • v.41 no.2
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    • pp.75-82
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    • 2011
  • LB71350 is an HIV protease inhibitor with poor aqueous solubility and extensive first pass effect. The purpose of the present study was to test the feasibility of solid dosage form of LB71350 with improved bioavailability utilizing solid dispersion. Three different compositions with varying ratio of (LB71350: Gelucire 44/14: Tween 20) were studied. Capsule filling of these solid dispersion compositions was tested using a semi-automatic capsule filling system. Oral bioavailability in dog was tested. Chemical and physical stability at 4, 25 and $40^{\circ}C$ was monitored by HPLC assay, dissolution test, powder XRD and microscopy. The capsule filling system yielded uniform products of drug loading up to 10%. Oral bioavailability in dog was improved compared to the aqueous suspension of crystalline LB71350. Capsules were chemically stable for up to 6 months at $40^{\circ}C$. However, there were temperature and composition dependent physical changes. Decrease in dissolution rates after storage at $40^{\circ}C$ was due to the polymorphic change. In conclusion, manufacturing process, bioavailability, and physico-chemical stability have been considered to propose a solid dispersion capsule formulation for the HIV protease inhibitor with poor physico-chemical properties. A new less soluble crystalline form identified during the physical stability test warrants further study.

Influence of Thermal Aging in Change of Crosslink Density and Deformation of Natural Rubber Vulcanizates

  • Choe, Seong Sin
    • Bulletin of the Korean Chemical Society
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    • v.21 no.6
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    • pp.628-634
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    • 2000
  • Crosslink is the most important chemistry in a rubber vulcanizate. Degree and type of crosslinks of the vulcanizate determine its physical properties. Change of crosslink density and deformation of a rubber vulcanizate by thermal aging were studied using natural rubber (NR) vulcanizates with various cure systems (conventional, semi-EV, and EV) and different cure times (under-, optimum-, and overture). All the NR vulcanizates were deformed by the thermal aging at 60-100 $^{\circ}C.$ The higher the aging temperature is, the more degree of the deformation is. The undercured NR vulcanizates after the thermal aging were deformed more than the optimumand overcured ones. The NR vulcanizates with the EV cure system were less deformed than those with the conventional and semi-EV cure systems. The deformation of the NR vulcanizates was found to be due to change of the crosslink density of the vulcanizates. The crosslink densities of all the vulcanizates after the extraction of organic materials were also changed by the thermal ging. The sources to change the crosslink densities of the vulcanizates by the thermal aging were found to be dissociation of the existing sulfur crosslink and the formation of new crosslinks by free sulfur, reaction products of curing agents, and pendent sulfide groups.

The Study on Piezoresistance Change Ratio of Cantilever type Acceleration Sensor (압저항 가속도 센서의 압저항 변화율 분포도에 관한 연구)

  • 심재준;한근조;한동섭;이성욱;김태형
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2004.10a
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    • pp.186-189
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    • 2004
  • Sensor used by semiconductor process produced an MAP sensor and applied to several industry. Among those sensors divided as transducer which convert physical quantity into electrical value, piezoresistive type sensor has been studied for the properties and sensitivity of piezoresistor. In this paper, the variation of seismic mass which have been functioned as actuator moving the cantilever beam analyzed the effect on distribution of resistance change ratio and supposed the optimal shape and position of piezoresistor. The resulting are following; According to the increment of seismic mass size, the value of resistance change ratio decreased caused by improve the stiffness. Y directional piezoresistor is formed in spot of 100 m apart from cantilever edge and length of that is 800$\mu$m. To increase the sensitivity, piezoresistor is made as n-type and x-direction.

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Determination of the Minimum Instream Flows for the Landscape of Riverside (하천의 경관 유지 수량의 결정)

  • 홍형순;이주헌;정상만
    • Journal of the Korean Institute of Landscape Architecture
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    • v.30 no.6
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    • pp.17-25
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    • 2003
  • The physical components of a river, such as water surface width/river width ratio, water level, and flow velocity vary according to different flowrates. Moreover, the riverside landscapes are greatly affected by the change of physical components of the stream or river. This paper provides an analysis of the influence of changing physical components of a river on the riverside landscape using a survey-based quantification method. The questionnaire was developed based on current literature, and was submitted to 326 people who each visited a representative station along the riverside.This survey was implemented three times at each representative station during periods of different flowrates. The results of this analysis and survey have Produced an understanding of the relationship between the variation of physical components and riverside landscapes. Survey results about the flow comparison are summarized as follows. Viewing riverside landscapes, most respondents are sensitive to the change of the flow velocity and prefer high water levels to low water levels. As a whole, respondents prefer abundant stream flows and moderate flow velocity in which they can perceive the flow of water. The minimum instream flows for riverside landscapes is estimated at each representative station by using a survey-based quantification method, and the estimated results of some representative stations were greater than the mean monthly flow at each station. The result of this analysis shows that establishing minimum instream flows for riverside landscapes is not only a technical problem, but also a legal problem. Therefore, in the to establish the instream flows in a river, the estimated results have to be considered as a relative standard. Regarding the survey results, respondents' satisfaction level didn't show any clear inclination according to the variation of various hydraulic properties. In determining the minimum instream flow using such an inquiry method, the structure of riverside scenery may vary according to the change of seasons or months. Therefore, to determine a consistent general inclination about the flow rate, it is necessary to have more detailed flow rates for each season or month combined with more inquiries.

The effect of irradiation on hydrodynamic properties of extraction mixtures based on diamides of N-heterocyclic dicarboxylic acids in heavy fluorinated diluents

  • Belova, E.V.;Skvortsov, I.V.;Kadyko, M.I.;Yudintsev, S.V.
    • Nuclear Engineering and Technology
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    • v.51 no.4
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    • pp.1163-1168
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    • 2019
  • Hydrodynamic properties have been investigated for promising extraction systems: $0.05mol\;L^{-1}$ solutions of di(N-ethyl-4-ethylanilide) of 2,2'-bipyridine-6,6'-dicarboxylic acid, di(N-ethyl-4-fluoroanilide) of 2,6-pyridinedicarboxylic acid and di(N-ethyl-4-hexylanilide) of 2,2'-bipyridine-6,6'-dicarboxylic acid in meta-nitrobenzotrifluoride (F-3) or trifluoromethylphenyl sulfone (FS-13) diluents. To evaluate the perspectives for their use as extraction mixtures at the final stage of the nuclear fuel cycle, the change in density, viscosity, surface tension, and phase separation rate under irradiation with accelerated electrons was studied. The concentrations of extractants in the irradiated mixtures have been determined and the radiation-chemical yields have been calculated. Irradiation significantly decreases the phase separation rate at the stages of extraction and back extraction for all the studied systems. The viscosity of the DYP-7 solution in FS-13 increase above the values suitable for its use in extraction processes.

Study of physical simulation of electrochemical modification of clayey rock

  • Chai, Zhaoyun;Zhang, Yatiao;Scheuermann, Alexander
    • Geomechanics and Engineering
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    • v.11 no.2
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    • pp.197-209
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    • 2016
  • Clayey rock has large clay mineral content. When in contact with water, this expands considerably and may present a significant hazard to the stability of the rock in geotechnical engineering applications. This is particularly important in the present work, which focused on mitigating some unwelcomed properties of clayey rock. Changes in its physical properties were simulated by subjecting the rock to a low voltage direct current (DC) using copper, steel and aluminum electrodes. The modified mechanism of the coupled electrical and chemical fields acting on the clayey rock was analyzed. It was concluded that the essence of clayey rock electrochemical modification is the electrokinetic effect of the DC field, together with the coupled hydraulic and electrical potential gradients in fine-grained clayey rock, including ion migration, electrophoresis and electro-osmosis. The aluminum cathodes were corroded and generated gibbsite at the anode; the steel and copper cathodes showed no obvious change. The electrical resistivity and uniaxial compressive strength (UCS) of the modified specimens from the anode, intermediate and cathode zones tended to decrease. Samples taken from these zones showed a positive correlation between electric resistivity and UCS.

Colour Change of Black-dyed PET Fabrics by Sputter Coloration and Their Physical Properties (Sputter 착색에 의한 Black-dyed PET 직물의 색상 및 물성변화)

  • Koo, Kang;Won, Eun-Hee;Park, Young-Mi
    • Textile Coloration and Finishing
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    • v.18 no.4
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    • pp.11-19
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    • 2006
  • Black-dyed PET fabrics were sputtered with stainless steel through DC-magnetron type device to investigate the possibility of coloration effect, and then considered the morphological structure and physical characteristics such as water permeation ability and washing fastness. Change in color was estimated on the basis of CIELAB color system. The color coordination of metal plated PET was shifted to yellow-red from red-blue. Colour difference$({\Delta}E^*)$ was increased by sputtering conditions with increasing ion current and treatment time. Especially, $Lightness(L^*)$ value of PET was remarkably increased by sputtering, whereas $Chroma(C^*)$ increased gradually. From SEM analysis, rough and uneven craters were found and thickened on the fiber surfaces with longer sputtering time. And washing fastness was a little poor and absorption ability slightly decreased. There were little changes of breaking load and breaking extension. It was evident that observed uneven craters in the plated thin layer resulted in the colour change of PET fabrics by sputtering treatments.