• 제목/요약/키워드: ceramic industry

검색결과 281건 처리시간 0.025초

Sol-Gel 법으로 제작한 Zn1-xCoxO 박박의 미세조직 및 자기적 특성 (Microstructure and Magnetic Properties of Zn1-xCoxO Thin Films Grown by Sol-Gel Process)

  • 고윤덕;태원필;김응권;김기출;최춘기;김종민;송준태;박태석;서수정;김용성
    • 한국세라믹학회지
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    • 제42권7호
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    • pp.475-482
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    • 2005
  • Zn$_{l-x}$Co$_{x}$O (x = 0.05 - 0.20) films were grown on Coming 7059 glass by sol-gel process. A homogeneous and stable Zn$_{l-x}$Co$_{x}$O sol was prepared by dissolving zinc acetate dihydrate (Zn(CH$_{3}$COO)$_{2}$$\cdot$2H$_{2}$O), cobalt acetate tetrahydrate ((CH$_{3}$)$_{2}$$\cdot$CHOH) and aluminium chloride hexahydrate (AlCl$_{3}$ $\cdot$ 6H$_{2}$O) as solute in solution of isopropanol ((CH$_{3}$)$_{2}$$\cdot$CHOH) and monoethanolamine (MEA:H$_{2}$NCH$_{2}$CH$_{2}$OH). The films grown by spin coating method were postheated in air at 650°C for 1 h and annealed in the condition of vacuum (5 $\times$ 10$^{-6}$ Torr) at 300$^{\circ}C$ for 30 min and investigated the nature of c-axis preferred orientation and physical properties with different Co concentrations. Znl_xCOxO thin films with different Co concentrations were well oriented along the c-axis, but especially a highly c-axis oriented Zn$_{l-x}$Co$_{x}$O thin film was grown at 10 at$\%$ Co concentration. The transmittance spectra showed that Zn$_{l-x}$Co$_{x}$O thin films occur typical d-d transitions and sp-d exchange interaction became activated with increasing Co concentration. The electrical resistivity of the films at 10 at$\%$ Co had the lowest value due to the highest c-axis orientation. X-ray photoelectron spectroscopy and alternating gradient magnetometer analyses indicated that no Co metal cluster was formed, and the ferromagnetic properties appeared, respectively. The characteristics of the electrical resistivity and room temperature ferromagnetism of Zn$_{l-x}$Co$_{x}$O thin films suggested the possibility for the application to dilute magnetic semiconductors.

Physical and Chemical Properties of Cement Mortar with Gamma-C2S

  • Lee, Sung-Hyun;Kim, Kyungnam;Mabudo, Mabudo;Song, Myong-Shin
    • 한국세라믹학회지
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    • 제53권2호
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    • pp.194-199
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    • 2016
  • Presently, for the cement industry, studies that seek to reduce $CO_2$, because of the development of the plastic industry and demand for reduction of energy use, have been actively conducted among them, studies attempting to use Gamma-$C_2S({\gamma}-C_2S)$ to fix $CO_2$ have been actively conducted. The ${\gamma}-C_2S$ compound has an important function in reacting to $CO_2$ and stiffening through carbonatization in the air. The ${\gamma}-C_2S$ compound, reacting to $CO_2$ in the air, generates $CaCO_2$ within the pore structure of cement materials and densifies the pore structure this leads to an improvement of the durability and to the characteristic of resistance against neutralization. Therefore, in this experiment, in order to synthesize ${\gamma}-C_2S$, limestone sludge and waste foundry sands are used these materials are plasticized for 30 or 60 minutes at $1450^{\circ}C$, and are prevented from being cooled in the temperature range of $30{\sim}1000^{\circ}C$ when they are about to be cooled. XRD analysis and XRF analysis are used to determine the effects of this process on ${\gamma}-C_2S$ synthesization, the temperature at which a thing is plasticized, and the conditions for cooling that obtain in the plasticized clinker also, in order to confirm the $CO_2$ capture function, analysis of the major hydration products is conducted through an analysis of carbonatization depth and compressive strength, and through MIP analysis and XRD Rietveld analysis. As a result of these analyses, it is found that when ${\gamma}-C_2S$ was synthesized, the clinker that was plasticized at $1450^{\circ}C$ for one hour demonstrated the highest yield rate the sample with which the ${\gamma}-C_2S$ was mixed generated $CaCO_3$ when it reacted with $CO_2$ therefore, carbonatization depth and porosity were reduced, and the compressive strength was increased.

국내 업종별 결정형 유리규산 노출 평가 (Evaluation of Crystalline Silica Exposure Level by Industries in Korea)

  • 연동은;최상준
    • 한국산업보건학회지
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    • 제27권4호
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    • pp.398-422
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    • 2017
  • Objectives: The major aim of this study is to construct the database of retrospective exposure assessment for crystalline silica through reviews of literatures in South Korea. Methods: Airborne concentrations of crystalline silica were collected using an academic information search engine, Research Information Service System(RISS), operated by the Korea Education & Research Information Service(KERIS). The key words used for the literature search were 'silica', 'crystalline silica', 'cristobalite', 'quartz' and 'tridymite'. A total number of 18 published documents with the information of crystalline silica level in air or bulk samples were selected and used to estimate retrospective exposures to crystalline silica. Weighted arithmetic mean(WAM) calculated across studies was summarized by industry type. Industries were classified according to Korea Standard Industrial Classification(KSIC) using information provided in the literature. Results: A total of 2,131 individual air sampling data measured from 1987 to 2012 were compiled. Compiled individual measurement data consisted of 827 respirable crystalline silica (RCS), 31 total crystalline silica(TCS), 24 crystalline silica(CS), 778 respirable dust(RD) and 471 total dust(TD). Most of RCS measurements(68.9%) were collected from 'cast of metals(KSIC 243)'. Comparing industry types, 'mining coal and lignite(KISC 051)' showed the highest WAM concentration of RCS, $0.14mg/m^3$, followed by $0.11mg/m^3$ of 'manufacture of other non-metallic mineral products(KSIC 239)', $0.108mg/m^3$ of 'manufacture of ceramic ware(KSIC 232)', $0.098mg/m^3$ of 'heavy construction(KSIC 412)' and $0.062mg/m^3$ of 'cast of metals(KSIC 243)'. In terms of crystalline silica contents in airborne dust, 'manufacture of other non-metallic mineral products(KSIC 239)' showed the highest value of 7.3%(wt/wt), followed by 6.8% of 'manufacture of ceramic ware(KSIC 232)', 5.8% of 'mining of iron ores(KSIC 061)', 4.9% of 'cast of metals(KSIC 243)' and 4.5% of 'heavy construction(KSIC 412)'. WAM concentrations of RCS had no consistent trends over time from 1994 ($0.26mg/m^3$) to 2012 ($0.12mg/m^3$). Conclusion: The data set related RCS exposure level by industries can be used to determine not only the possibility of retrospective exposure to RCS, but also to evaluate the level of quantitative retrospective exposure to RCS.

Individual Character 산업을 위한 전통 주술 문양의 캐릭터 개발 연구 (A Study on the Character Creation of Traditional Incantatory Pattern for Individual Character Industry)

  • 신승택
    • 디자인학연구
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    • 제16권1호
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    • pp.127-136
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    • 2003
  • 세계는 점차적으로 각 나라에 대한 정체성, 각 단체에 대한 정체성, 개인에 대한 정체성을 추구하고 있으며, 그 정체성이 타문화 또는 타 단체와 차별되는 특징을 갖는 고유 디자인을 요구하고 있다. 또한 캐릭터를 비롯한 만화, 애니메이션, CF등 캐릭터 관련 산업들이 곳곳에서 대두되면서 개개인의 개성을 부각시킬 수 있는 마스코트 개념의 캐릭터 개발이 요구되었다. 이러한 개인의 정체성을 표현한 캐릭터를 포함한 캐릭터 관련 상품 시장을 'Individual Character" 산업이라 명하고, 본 연구는 위 산업을 위한 차별적 특징을 갖는 디자인으로 한국적 소재를 사용하여 마스코트 또는 수호천사 개념으로 "Individual Character"를 개발하였다. 본 연구는 이를 개발하기 위해, 한국의 전통 주술 문양을 분석하고, 캐릭터 산업 및 국내외 전통 문양 소재의 캐릭터 조사를 통해 12지를 소재로 한 캐릭터를 하나의 인격을 갖는 형태로서 line art 캐릭터, 오방색 2D 캐릭터, 글자 '||'&'||' 그림 3D 캐릭터, 3가지 형태로 개발하였다. 이 3타입의 캐릭터들은 유형별 전략을 모색한 후 각각 캘린더, 도자기, 금속, Animation Source, 생활 용품, 악세사리 등 각종 상품에 적용 개발하였다. 상품 적용은 line art, 2D, 3D 타입에 대한 상품 적용을 목적으로 Re-design을 하여 적용하였으며, 금속, 지류, web, 도자 등 각 소재별 표현제약을 고려하여 각 상품을 유형별로 개발하였다. 본 연구는 이를 통해 전통주술 문양을 소재로 한 "Individual Character"가 한국적 디자인 창출을 통한 문화적 정체성과 독창성을 발굴할 수 있었으며, 캐릭터 산업에 "Individual Character"라는 개념을 새롭게 적용하여, 한 가지 소재로 다원화된 캐릭터를 개발하며, 소비자 대상에 따른 각종 상품에 적용을 시도하였다.

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국내 도자기용 태토의 토질 및 광물 특성 (Physical and Mineralogical Properties of Pottery-Making Soils in Korea)

  • 김학준;이용천;이유진;이호정;정찬호
    • 지질공학
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    • 제32권4호
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    • pp.685-696
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    • 2022
  • 도자기 제작을 위한 점토의 사용은 오랜 역사를 가지고 있지만, 도자기 업계에서 특정 목적으로 흙을 사용하기 위해서는 이 흙이 적정한 물리적 특성을 충족해야 한다. 이 연구의 목적은 다른 유형의 점토에 대하여 도자기 재료로서 점토의 물리적 및 광물성분을 비교 평가하는데 있다. 이 연구를 위하여 도재상에 따라 자신들만의 비법으로 제작하여 널리 판매하고 있는 백자토, 청자토, 산청토, 분청토, 조형토에 대한 물성실험을 수행하였고, XRF와 XRD 분석을 통하여 화학성분과 구성광물을 정량화하였다. 태토의 종류별 흙의 입도분포, 광물성분, 가소성 범위를 제시하였다. 실험결과를 비교하여 각 도재상에서 특정 유형의 도자기를 생산하는 흙들의 물성 및 광물조성의 상관관계를 결정하였다. 국내에서는 토질실험을 활용한 태토의 정량적인 연구가 미흡한 상태이므로 향후 국내 도자기 산업의 발전을 위해서는 이에 대한 적극적인 연구가 필요하다.

비금속광물 제품제조업에서 발생하는 분진 농도와 분진 노출기준 적용에 따른 문제점 고찰 (The concentrations of airborne dust in non-metallic products factories and problems associated with the application of the occupational exposure limits)

  • 김현욱;피영규;원정일;고원경;노영만;신창섭
    • 한국산업보건학회지
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    • 제10권1호
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    • pp.104-114
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    • 2000
  • This study was carried out to estimate current status of dust concentrations in the factories producing non-metallic products in Korea. Data were gathered from the environmental monitoring reports by 40 workplace environmental monitoring institutes and the questionnaire designed for the study by the authors. A total of 1838 dust samples from 368 plants were obtained from the reports and were analyzed with no data modifications. But data on asbestos, rock wool, and welding fumes were excluded in this evaluation. The factories were classified into eight groups according to the standard industrial classification scheme in Korea. The results of this study were as follows; 1. The factories included were glass, non-refractory ceramic, refractory ceramic ware, structural non-refractory clay and ceramic, cement and lime, articles of concretes, and stone. Mean(geometric mean) concentrations of total dust samples ranged from $1.75(0.84)mg/m^3$ to $5.87(2.84)mg/m^3$. Statistically significantly higher dust concentrations were found in the cement and lime industries compared with other industries. 2. The non-compliance rates were 15.2% in glass and 20.6% in other non-metallic mineral products industries. Although all institutions surveyed utilized the identical sampling and classification scheme for dusts as specified in the current occupational exposure limits, wide discrepancies were found in collecting samples and classifying dusts. Further problems were discovered in classifying dusts. A dust sample collected could be classified into any of the three groups regardless of silica content. The results of this study showed that dust concentrations in the non-metallic products industries varied widely. Also discovered was classification errors of dust types among workplace monitoring institutes. These errors could adversely affect the results of exposure assessments and the true nature of dust hazards. Further, no institutions performed respirable dust sampling and analysis of crystalline silica. In order to correct these malpractices, current standards of occupational exposure limits should be revised and tight supervision by the Ministry of Labour be suggested.

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결합 전송선로 이론을 이용한 적층 세라믹 커패시터의 임피던스 특성 예측 (Prediction of Impedance Characteristics of Multi-Layer Ceramic Capacitor Based on Coupled Transmission Line Theory)

  • 전지운;김종현;푸 보;장 난;송승제;나완수
    • 한국전자파학회논문지
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    • 제26권2호
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    • pp.135-147
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    • 2015
  • 전자 산업에서의 소형화와 디지털화에 따라 적층 세라믹 커패시터(Multi-Layer Ceramic Capacitors: MLCC) 또한 DC Blocking, 디커플링, 필터링 등의 기능이 이에 부응하여 그 수요가 꾸준히 증가해왔다. 이에 따라 MLCC의 등가회로를 모델링하는 기법이 많이 연구되었는데, 지금까지의 연구를 살펴보면 대부분이 소자의 주파수 특성을 측정한 후, 그 결과를 바탕으로 소자를 모델링하므로 제작 과정과 측정 과정에서 물질적, 시간적 손실을 수반한다. 이를 해결하기 위한 방법으로 본 논문에서는 구조 정보와 물질 정보로부터 설계단계에서 MLCC의 임피던스 특성을 예측할 수 있는 모델링 방법을 제시한다. 미분 방정식으로 표현되는 결합 전송선로 방정식으로부터 임의의 N개 층을 가지는 다층 평판 커패시터(N-Layer Capacitor)의 임피던스를 구조 정보와 물질 정보의 수식으로 표현할 수 있음을 보였다. 이렇게 정의된 임피던스 수식으로부터 임의의 구조 정보와 물질 정보를 가지는 MLCC의 임피던스를 예측하였으며, EM 시뮬레이션 결과와 비교하였다. 그 결과, 제시한 임피던스 예측 모델링 결과와 측정 결과가 잘 일치하였고, EM 시뮬레이션보다 훨씬 빠르게 예측 결과를 얻을 수 있음을 보였다.

세라믹 모노리스에 담지된 CuO와 ZnO계 촉매에 의한 이산화탄소의 메탄올로의 전환에 관한 연구 (Study on Conversion of Carbon Dioxide to Methyl Alcohol over Ceramic Monolith Supported CuO and ZnO Catalysts)

  • 박철민;안원주;조웅규;송진훈;김기중;정운조;손보균;안병권;정민철;박권필;안호근
    • 한국대기환경학회지
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    • 제29권1호
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    • pp.97-104
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    • 2013
  • Methyl alcohol is one of the basic intermediates in the chemical industry and is also being used as a fuel additive and as a clean burning fuel. In this study, conversion of carbon dioxide to methyl alcohol was investigated using catalytic chemical methods. Ceramic monoliths (M) with $400cell/in^2$ were used as catalyst supports. Monolith-supported CuO-ZnO catalysts were prepared by wash-coat method. The prepared catalysts were characterized by using ICP analysis, TEM images and XRD patterns. The catalytic activity for carbon dioxide hydrogenation to methyl alcohol was investigated using a flow-type reactor under various reaction temperature, pressure and contact time. In the preparation of monolith-supported CuO-ZnO catalysts by wash-coat method, proper concentration of precursors solution was 25.7% (w/v). The mixed crystal of CuO and ZnO was well supported on monolith. And it was known that more CuO component may be supported than ZnO component. Conversion of carbon dioxide was increased with increasing reaction temperature, but methyl alcohol selectivity was decreased. Optimum reaction temperature was about $250^{\circ}C$ under 20 atm because of the reverse water gas shift reaction. Maximum yield of methyl alcohol over CuO-ZnO/M catalyst was 5.1 mol% at $250^{\circ}C$ and 20 atm.

기하학적 형태를 활용한 테이블웨어 디자인개발 연구 (A Study on the Tableware Design using Geometric Pattern)

  • 유유리
    • 디지털융복합연구
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    • 제12권8호
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    • pp.475-480
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    • 2014
  • 대상을 상징하는 기호로서의 의미를 포함하고 있는 기하학적 패턴은 조형표현에 있어서 20세기 이후 예술가들의 작품을 통해 재구성되어 현대적인 이미지를 나타내는 중요한 모티브가 되고 있으며 패턴의 단순하고 간결한 형태는 외형뿐만 아니라 문양 장식을 통하여 새로운 아름다움을 창출하고 있다. 기하학적 패턴의 문양장식은 단순화되고, 이성적이며 현대적인 세련미와 잘 어울린다. 이렇듯 기하학적 패턴을 활용한 문양은 팔각형, 반원, 삼각형, 사각형 등의 기하학적 도형들을 이용하여 단순한 미로 현대인에게 만족감을 준다. 또한, 기하학적 패턴은 규칙적이고 단순명료하여 시각적으로 강렬한 효과를 유도하며 운동감과 속도감이 주는 역동성으로 3차원적 공간감으로 확장되기도 한다. 이로 인해 주목성이라는 특성이 나타나는데 테이블웨어에서도 이러한 기학학적 패턴을 이용한 디자인은 강한 주목성으로 시각적인 즐거움을 준다. 또한 이는 우연성의 요소에 근거해서 만들어지는 형태가 아니기 때문에 객관화될 수 있으며 반복적인 재현이 가능하다. 이러한 반복구성은 테이블웨어를 만드는 많은 디자이너에게 영향을 줄 수 있으며 테이블웨어 디자인을 더욱 더 고급화하여 도자 산업에 고부가가치를 창출할 수 있는 새로운 가능성을 제시할 것으로 생각된다.

압전발전 모듈의 안정성 해석 및 최적 매립위치 결정 (Stability Analysis of Piezoelectric Module and Determine of Optimal Burying Location)

  • 손인수;김지원;주홍회;조대환
    • 한국산업융합학회 논문집
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    • 제26권1호
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    • pp.193-199
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    • 2023
  • In this study, an analysis was conducted to analyze the structural stability of the piezoelectric power generation module and to determine the optimal burying hole interval for concrete, the installation site of the power generation module. A piezoelectric element refers to a functional ceramic having a piezoelectric direct effect that converts mechanical energy into electrical energy and a piezoelectric reverse effect. In the analysis of the piezoelectric power generation module, the load condition was applied with about 16 tons and a total of 10 wheels in consideration of the container trailer. The purpose was to evaluate the stability of major components of the piezoelectric power generation module through finite element analysis. In order to determine the optimal burying location of the concrete ground for burying the piezoelectric power generation module, the stability of the ground structure according to the distance of the holes was determined. As a result of the analysis, the maximum stress of the piezoelectric power generation module was generated in the support spring, showing a stress of about 276.7 MPa. It was found that the spacing of holes for embedding the piezoelectric power generation module should be set to a minimum of 100 mm or more.