• Title/Summary/Keyword: cement toxicity

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Survey on the Recycling of Waste Slag Generated by Smelting Reduction of Deep-Sea Manganese Nodules (망간단괴 용융환원 폐슬래그의 재활용 방안)

  • Park, Hyungkyu;Nam, Chulwoo;Kim, Sungdon
    • Resources Recycling
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    • v.23 no.4
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    • pp.69-74
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    • 2014
  • Slags generated in the smelting reduction of deep sea manganese nodule could be utilized as an additional materials for making Fe-Si-Mn alloys by mixing with cokes and re-smelting at an arc furnace. In this re-melting process slag is also generated, and the secondary slag is treated as waste. In this survey, recycling of the waste slag of Mn nodule was studied. It is tried to utilize the waste slag as ceramic materials or construction materials. However, it is difficult to use the waste slag directly as an additional material to ceramics such as portland cement or castable refractory material due to the much difference of chemical compositions. As an altercation road constructing material is considered, and toxicity on the soil of the waste slag was tested according to Korean Standard for testing permissible amount of toxic substances. The test result was satisfied with the requirements on the standard. So, it should be suggested that the waste slag of the Mn nodule could be utilized as constructing materials such as road filler or base materials.

THE EFFECT OF INTRACANAL BASE ON PREVENTION OF APICAL LEAKAGE OF BLEACHING AGENTS (무수치 표백술에서 근관내 Base가 표백약제의 누출 방지에 미치는 영향)

  • Choi, Seung-Ho;Ro, Byeng-Duck;Park, Sung-Ho;Lee, Seung-Jong
    • Restorative Dentistry and Endodontics
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    • v.24 no.3
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    • pp.453-464
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    • 1999
  • The non-vital bleaching technique has been used widely as a very effective treatment method on discolored non-vital teeth. But periodontal tissue deterioration and cervical external root resorption have been reported because of the high toxicity of hydrogen peroxide in bleaching agents. So in previous studies, placement of base over the root canal obturation prior to bleaching has been suggested in order to prevent microleakage of bleaching agents, however, the effectiveness of base is still controversial. The purpose of this study was to evaluate the effects of base and root canal sealer on prevention of leakage of bleaching agents in non-vital bleaching. Fifty-two extracted sound teeth with single root were used. For root canal obturation, Tubuli seal$^{(R)}$(Kerr Co., USA) was used in 39 teeth and in others, AH-26$^{(R)}$(De Trey Dentsply, Inc., Switzerland) was used as a root canal sealer. 26 teeth among the teeth obturated with Tubuli seal$^{(R)}$ were divided into two groups, and Dentin cement$^{(R)}$(GC corp., Japan) and JRM$^{(R)}$(De Trey Dentsply, Inc. Germany) were used in each group as a intracanal base. In all teeth, non-vital bleaching using bleaching agent mixed with methylene blue dye was performed and all specimens were stored in $37^{\circ}C$ water bath for 72 hours. After sectioning longitudinally, the depth of dye leakage was measured with digital vernier calipers under the stereobinocular microscope using ${\times}40$ magnification. It can be concluded as follows: 1. The microleakage of bleaching agent was observed ill all groups regardless of type of the base and the sealer. 2. The microleakage in the groups using AH-26$^{(R)}$ as a sealer was significantly reduced (p<0.05). 3. In the groups with intracanal base, micro leakage was observed through almost the whole depth of the base and there was no significant difference between Dentin cement$^{(R)}$ and IRM$^{(R)}$ group(p>0.05). In conclusion, all the basing materials and the sealers in this study did not prevent the microleakage of bleaching agent. Therefore further studies and attempts to seal off the pulp chamber will be necessary.

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Review of the Literature on Level of Biological Exposure and Trends in Possible and Probable Occupational Disease among Chromium Workers (크롬 직업병 유소견자와 요관찰자 추이 및 취급 근로자의 생물학적 노출수준 고찰)

  • Park, Sang-il;Kim, Nam-Soo;Hwangbo, Young;Kim, Hwa-Sung;Lee, Sung-Soo;Kim, Yong-Bae
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.31 no.3
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    • pp.213-225
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    • 2021
  • Objectives: This study identifies the trends in possible and probable occupational disease among chromium workers and reviews the literature on domestic and foreign chromium workers to review the industries, biological exposure levels, and major results. Methods: The results of the Ministry of Employment and Labor's special health-screening program for hazard agents among workers from 2009 to 2019 were used. Also, the industries, biological exposure levels, and major results on chromium workers were reviewed using PubMed and RISS. Results: The average annual proportion of both possible and probable occupational disease for chromium workers has recently increased. The average annual proportion of possible and probable occupational disease that can occur was high for both men and women in their 60s or older by age and 10 to 14 years by work duration. By industry, possible occupational disease showed high in manufacturing. In the literature review, many electroplating-related chromium-workers reported high levels of exposure to blood and urine chromium, as did dental technicians; tannery, tile factory or glass mill workers; cement workers; and sodium bichromate workers. Furthermore, a number of main findings in recent studies have reported that chromium exposure is related to genetic toxicity among workers. Conclusions: In this study, the average annual rate of both possible and probable occupational disease in domestic chromium workers is increasing, and a body of literature shows that chromium exposure is related to genetic toxicity and associated indicators among workers, which requires more systematic study.

A Study on the Applicability of Acrylic Water Leak Repair Materials used to Repair Cracks in Conduits and Underground Structures (관거 및 지하구조물 균열 보수에 사용되는 아크릴 누수 보수재의 적용성에 대한 연구)

  • Eunmi Lee;Kyungik Gil
    • Journal of Wetlands Research
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    • v.26 no.2
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    • pp.139-146
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    • 2024
  • Various injection materials, such as asphalt-based injection materials, urethane-based injection materials, cement- based injection materials, and acrylic-based injection materials, are used for the repair of aged conduits and underground structures with cracks. In this study, research was conducted on an environmentally friendly acrylic- based leak repair material that exhibits good curing properties even in humid conditions and stability in temperature fluctuations. To compare the performance of the improved acrylic leak repair material with the existing acrylate injection material, experiments were conducted using KS standard methods, including underwater length change rate tests, underwater leakage resistance tests, and chemical performance tests. The comparative experiments revealed that the improved acrylic leak repair material showed no changes in shrinkage due to humidity, temperature variations, or chemical reactions compared to the existing acrylate injection material. In the underwater resistance test, the improved acrylic leak repair material did not show any leakage. Additionally, to assess the environmental impact of the improved acrylic leak repair material, acute fish toxicity tests and acute oral toxicity tests were conducted, and the results showed no mortality and no specific concerns with the test specimens. The experimental results led to the conclusion that the improved acrylic leak repair material is considered to be superior in performance, environmentally safe, and harmless to the human body. Based on various experimental results, it is inferred that the improved acrylic leak repair material is suitable for use as a repair material for cracks in manholes and underground structures compared to the existing acrylate repair material. This study aims to propose valuable data for future technological development by evaluating the applicability of acrylic leak repair materials.

A Study on the Development of the Mercury Emission Factor from Coal-fired Power Plant (석탄 화력발전시설에서의 수은 배출계수 개발에 관한 연구)

  • Kim, Hyung-Chun;Park, Jung-Min;Jang, Kee-Won;Lee, Sang-Bo;Jung, No-El;Song, Deok-Jong;Hong, Ji-Hyung;Lee, Suk-Jo;Kim, Sang-Kyun
    • Journal of Korean Society for Atmospheric Environment
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    • v.28 no.2
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    • pp.172-181
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    • 2012
  • Mercury is one of the most hazardous air pollutants. Recently, mercury has been a concern in domestic and overseas because it has lethal toxicity, long distance transport, persistence and bioaccumulation in the environment. Stationary combustion sources such as coal-fired power plants, waste incinerators, and cement kilns are the major sources of mercury emissions. The objectives of this study were to measure the concentration for mercury from coal-fired power plants and to calculate emission factor to estimate its emission. The results showed that the mercury concentrations in the flue gas were 1.63-3.03 mg/$Sm^3$ in anthracite-fired power plants (average 2.32 mg/$Sm^3$) and 1.95-3.33 mg/$Sm^3$ in bituminous-fired power plants (average 2.6 mg/$Sm^3$). Mercury emission factor was estimated as 25.74 mg/ton for anthracite-fired power plants and 12.48 mg/ton for bituminous-fired power plants. Because actual measurements are limited in quantity, it is desirable to refine our estimates by extending the actual measurements.

An Analysis of the Characteristics of Environmental Impact for PSC Beam Bridges using Life Cycle Assessment (LCA 기반 PSC 교량의 환경부하 특성분석에 대한 연구)

  • Cho, Namho;Yun, Won Gun;Lee, Wan Ryul;Kim, Kyong Ju
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.36 no.2
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    • pp.297-305
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    • 2016
  • This study aims to analyze characteristics of environmental load for the construction phase of PSC beam bridge based on Life Cycle Assessment. For detail computation of environmental load, the construction materials and energy consumption are derived from the BOQ, also connecting with environmental load by Korea LCI Database Information Network. The characteristic of environmental impact was analyzed by 25 cases and cut-off ratio was 80% to 94%. The result sorted by construction materials revealed that environmental load were 53.3% for ready-mixed concrete, 9.6% for wire rod, 7.8% for rebar, 6.8% for cement, 5.5% for plywood, and 5.2% for energy. Furthermore, the result of environmental impact revealed that 45.5% for global warming, 30.4% for abiotic resources depletion, 10.5% for human toxicity, and 8.9% for photochemical oxidant creation. In the future, we can make a decision considering environmental load based on LCA at design phase.

The Patent Analysis of the Treatment Technology of Asbestos Wastes (석면 폐기물 처리 특허기술 분석)

  • Kim, Jong-Heon;Cho, Jin-Dong;Lee, Sang-Kwon;Cha, Seong-Ki
    • Economic and Environmental Geology
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    • v.44 no.5
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    • pp.451-462
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    • 2011
  • Asbestos or its applications have been used for long times and for various purposes in our life because of their merits, namely fire resistance, electric insulation and chemical resistance capacity etc. Despite of theses many merits, one of the problems of asbestos is shown toxicity according to its fiber type. So we need data to solve about this problem. In this paper, we study on the technical method of asbestos waste treatment and on the trends of asbestos researches and developments by the analysis of its patents and DWPI database materials. As a result, the asbestos-waste treatment data in the its related patents is used 267 cases to analyze. These data are divided into 86(32.5%) cases of solid waste disposal(B09B). 41(16.6%) cases of separation(B01D) and 27(10.2%) of lime, magnesia, slag, cement and their composites(C04B).

Quality Characteristics and Environmental Impact Assessment of Alkali-Activated Foamed Concrete (알카리활성 기포콘크리트의 품질특성 및 환경영향 평가)

  • Yang, Keun-Hyeok;Yoo, Sung-Won;Lee, Hyun-Ho;Kim, Sang-Chel
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.1 no.2
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    • pp.114-119
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    • 2013
  • The present study tested 5 concrete mixes to develop reliable mixing proportions for the sustainable alkali-activated(AA) foamed concrete as a thermal insulation material for the floor heating system of buildings. The AA binder used was composed of 73.5% ground granulated blast-furnace slag, 15% fly ash, 5% calcium hydroxide, and 6.5% sodium silicate. As a main variable, the unit binder content varied from $325kg/m^3$ to $425kg/m^3$ at a space of $25kg/m^3$. The test results revealed that AA foamed concrete has considerable potential for practical applications when the unit binder content is close to $375kg/m^3$, which achieves the minimum quality requirements specified in KS F 4039 and ensures economic efficiency. In addition, lifecycle assessment demonstrated the reduction in the environmental impact profiles of all specimens relative to typical ordinary portland cement foamed concrete as follows: 99% for photochemical oxidation potential, 87~89% for global warming potential, 78~82% for abiotic depletion, and 70~75% for both acidification potential and human toxicity.

FLEXURAL STRENGTH OF IMPLANT FIXED PROSTHESIS USING FIBER REINFORCED COMPOSITE (섬유성 강화 컴포지트를 사용한 임플랜트 고정성 보철물의 굴곡강도)

  • Kang, Kyung-Hee;Kwon, Kung-Rock;Lee, Sung-Bok;Choi, Dae-Gyun
    • The Journal of Korean Academy of Prosthodontics
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    • v.44 no.5
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    • pp.526-536
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    • 2006
  • Statement of problem : Use of fiber composite technology as well as development of nonmetal implant prosthesis solved many problems due to metal alloy substructure such as corrosion. toxicity, difficult casting, expensiveness and esthetic limit. After clinical and laboratory test, we could find out that fiber-reinforced composite prostheses have good mechanical properties and FRC can make metal-free implant prostheses successful. Purpose : The purpose of this study is to evaluate the flexural strength of implant fixed prosthesis using fiber reinforced composite. Material and methods : 2-implant fixture were placed in second premolar and second molar area in edentulous mandibular model, and their abutments were placed, and bridge prostheses using gold, PFG, Tescera, and Targis Vectris were fabricated. Tescera was made in 5 different designs with different supplements. Group I was composed by 3 bars with diameter 1.0mm and 5 meshes, 2 bars and 5 meshes for Group II, 1 bar and 5 meshes for Group III, and only 5 meshes were used for Group IV. And Group V is composed by only 3 bars. Resin (Tescera) facing was made to buccal part of pontic of gold bridge. All of gold and PFG bridges were made on one model, 5 Targis Vectris bridges were also made on one model, and 25 Tescera bridges were. made on 3 models. Each bridge was attached to the test model by temporary cement and shallow depression was formed near central fossa of the bridge pontic to let 5 mm metal ball not move. Flexual strength was marked in graph by INSTRON. Results : The results of the study are as follows. The initial crack strength was the highest on PFG. and in order of gold bridge Tescera I, Tescera II, Targis vectris, Tescera IV, Tescera III, and Tescera V. The maximum strength was the highest on gold bridge, and in order of PFG, Tescera I, Tescera IV Tescera II, Targis vectris, Tescera III, and Tescera V. Conculsions : The following conclusions were drawn from the results of this study. 1. Flextural strength of implant prosthesis using fiber reinforced composite was higher than average posterior occlusal force. 2. In initial crack strength, Tescera I was stronger than Tescera V, and weaker than PFG. 3. Kinds and number of auxillary components had an effect on maximum strength, and maximum strength was increased as number of auxillary components increased. 4 Maximum strength of Tescera I was higher than Targis vectris, and lower than PFG.

Treatment of Open Proximal Humerus Fracture by Gunshot (총격에 의한 개방성 근위 상완골 골절의 치료 - 증례 보고 -)

  • Kim, Sung-Jae;Lee, Jae-Hoo;Chun, Yong-Min
    • Clinics in Shoulder and Elbow
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    • v.15 no.1
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    • pp.37-42
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    • 2012
  • Purpose: To consider the proper management of proximal humerus fracture on gunshot wounds. Materials and Methods: A 28-year-old male patient, who sustained a gunshot injury on the left arm 5 days ago, was admitted through the emergency department. Although he underwent an emergency surgery (bullet fragment removal and debridement), there remained bullet fragments around the proximal humerus fracture site. The wound seemed to be infected and a partial dehiscence occurred. No neurologic deficit was noted. Immediate exploration and debridement were performed, and an external fixator was applied to restore the anatomical alignment and manage the wounds. Intravenous antibiotics were administered. On the 9th postoperative day, wound debridement was done again, and cement beads mixed with antibiotics were inserted. After two weeks, the external fixator was removed, and the pin sites were closed after debridement. One week later, the open reduction and internal fixation with locking compression plate and screws were done. Result: At 3 months after the internal fixation, the bone union was obtained with satisfactory alignment of the humerus. Conclusion: The severity of the soft tissue injury influences the fracture management plan. Further, the risk on lead toxicity should be considered.