• Journal of the Korean Recycled Construction Resources Institute
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• v.8 no.4
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• pp.467-474
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• 2020

Carbon nanotube has excellent mechanical strength and functionality, so it has been utilized in various applications. In recent years, utilization of carbon nanotube in construction material has started to get interests from researchers in the area of construction materials. However, there is limited amount of work with respect to the rheological properties of cement paste using carbon nanotube. In this work, solution made of multi-walled carbon nanotube with dispersing agent of polyvinyl pyrrolidone was used to prepare cement paste specimens, and rheological properties and 28 day compressive strengths of cement paste using multi-walled carbon nanotube were measured. According to the experimental results, as the amounnt of multi-walled carbon nanotube increased, plastic viscosity and yield stress of cement paste specimens also increased. It was also found that such effect was higher with lower w/c cement paste specimens. With respect to the compressive strength, it was maximized at carbon nanotube content of 0.1wt.% for w/c 0.30 cement paste, whereas the maximum strength of w/c 0.40 cement paste was observed with carbon nanotube content of 0.2wt%.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2018.05a
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• pp.214-215
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• 2018

This paper has been researched that the earlier compressive strength of the cement pastes containing nano-TiO₂ particle curing 1day, 3days and 7days. For the compressive strength measurements, all samples(dimensions 50×50×50mm) were prepared in accordance with ASTM C109. The compressive strength of the specimens with nano-TiO₂ at the early age(1day, 3days and 7days) stage was lower than that of the reference group. Therefore, nano-TiO₂ has little positive effect on the improvement of the compressive strength of cement pastes during early ages.

• Journal of the Korea Institute of Building Construction
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• v.22 no.5
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• pp.431-439
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• 2022

In this study, Neutralized red mud(LRM+S) at a pH of 6-8 was prepared by adding sulfuric acid to liquefied red mud(LRM) at a pH of 10~12. After adding LRM and LRM+S to the cement paste, the hydration heat, compressive strength, and hydration products were examined. The observed accumulated hydration heat revealed that the calorific value of the cement paste with LRM was low and its and peak was delayed when compared with that of plain cement paste(referred to as Plain), whereas the calorific value of the cement paste with LRM+S was similar to that of Plain. At the age of 28 days, the compressive strength of the cement paste with 20% LRM was 55% of the strength of Plain. Using X-ray diffraction, it was determined that the cement paste with 20% LRM exhibited a Ca(OH)₂ peak after 3 days, whereas the cement paste with 20% LRM+S and Plain exhibited a Ca(OH)₂ peak after an hour. Thus, the strength degradation of cementitious materials was improved by adding neutralized red mud prepared by adjusting the pH of highly alkaline LRM with sulfuric acid.

• Journal of the Korean Recycled Construction Resources Institute
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• v.5 no.3
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• pp.78-83
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• 2010

This paper presents the feasibility of incorporating ultrafine particles collected in the separator bag filter (separator bag filter cement, SBFC) during the cement manufacturing process as an substitution material for cement. SBFC does not require additional processes needed in the existing processes to manufacture high early strength cement such as modifying mineral components and adjusting the firing temperature. Moreover, it can also solve the issue of efficiency decrease resulted from the increase of the grinding time applied in the existing process of manufacturing microcement. Therefore, this research has examined the characteristics of SBFC and fresh properties and mechanical properties after making paste and mortar using SBFC in order to use SBFC as a material to gain early strength of concrete. For results, analyzing the chemical composition and physical properties of SBFC, its blaine value was $6,953cm^3/g$, about double than that of OPC, but its chemical composition showed no significant difference. According to the result of the paste and mortar examination, the paste and mortar mixed with SBFC showed a lower flowability, earlier setting time, and higher compressive strength than that with OPC. The result of microstructure analysis of paste, the paste mixed with SBFC indicated about 9% lower internal porosity at an early age than that of OPC. The compressive strength and flexural strength of mortar were higher in the order of SBFC ratio of 100, 50 and 0% SBFC.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2022.04a
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• pp.184-185
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• 2022

This study researched the effect of graphene nanoribbons (0.05 wt%) on cement-based materials' mechanical and electrical properties. The results were compared with the ordinary Portland cement (OPC) paste and OPC paste with the same content of carbon nanotubes. The experiment results showed that after curing for 28 days, the compressive and splitting tensile strength of the sample with graphene nanoribbons were increased by 17.8% and 6.6% compared to OPC paste, and its reinforced effect for cement-based materials was superior to carbon nanotubes. Besides, due to the excellent electrical properties of graphene nanoribbons, the sample reinforced by graphene nanoribbons had a lower electrical resistivity (135.5 Ω·m) than OPC paste (418.5 Ω·m) and paste with carbon nanotubes (175.5 Ω·m). This proved the promising application of graphene nanoribbons on cement-based materials.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2022.04a
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• pp.95-96
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• 2022

Carbon nanotubes has a positive effect on the mechanical properties, functionality, and durability of cement-based materials. In this study, carbon nanotube solutions mixed with two different types of superplasticizers were dispersed by high-pressure homogenizer, and used for preparation of cement paste. The 7and 28day compressive strength were evaluated.

• Journal of the Korean Ceramic Society
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• v.48 no.6
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• pp.504-509
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• 2011

In this study, the effect of superplasticizers on the dispersibility and hydration properties of cement with silica fume were investigated. Superplasticizers are used Naphthalene type, Ligno-sulfate type and polycarboxylate type. Compared with plastic viscosity of cement paste without superplasticizers(Plain), plastic viscosity of cement paste with superplasticizers are reduced and yield stress of cement pastes with each superplasticizer is increased rather than Plain. And then, plastic viscosity of cement paste with Naphthalene type superplasticizer was the least of all types. Compared with other two types, setting and hydration of cement paste with Polycarboxylate type(PC) superplasticizer is very fast. At compressive strength after 3-day, PC is higher than other two types, But, compressive strength of after 7-day and 28-day, PC is smaller than other two types.

• Journal of Electrochemical Science and Technology
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• v.15 no.2
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• pp.242-252
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• 2024

To date, methods used to assess the interfacial transition zone (ITZ), which represents the boundary between the aggregate and paste inside concretes, have primarily relied on destructive tests, and non-destructive tests has received little attention until recently. This study assessed the interfaces of concretes with lightweight aggregates based on electrochemical impedance spectroscopy (EIS) for high-strength concretes and examined the possibility of estimating the compressive strength of concretes through non-destructive testing using EIS. The experimental results revealed that the impedance of the hardened cement increased with increasing compressive strength and aggregate density. In particular, when the results of impedance measurement were displayed as a Nyquist plot, the intercept of the x-axis depicting the effective conductivity was proportional to the compressive strength. Furthermore, an equivalent circuit was selected to interpret the correlation between cement aggregates and impedance. Consequently, the compressive strength was found to increase with the value of the resistances of the electrolyte filled in continuous pores in the cement aggregate. And, the pores formed in the ITZ affect this value. The resistance at the ITZ for different aggregates was also obtained, and it was found that the resistance was consistent with the results predicted by SEM images of the ITZ and correlated with the strength of the concretes. The proposed method can be used as a way to easily determine the strength of cement according to differences in aggregate.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2023.11a
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• pp.93-94
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• 2023

This study evaluated the mechanical properties and microstructure of calcium silicate cement based paste according to carbonation curing conditions. As a result, both compressive strength and carbonation depth increased with the carbonation curing period.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2022.04a
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• pp.243-244
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• 2022

Recently, the utilization of carbon nanotubes (CNT) in cement paste has been widely investigated in terms of improving the dispersion quality and enhancing the cement paste mechanical performance. While methods of functionalizing the CNT using surfactants to disperse the nanoparticles have been studied to some extent, the literature on the effects of chemical covalent functionalization is still scarce. This work focuses on chemical functionalization of multiwall carbon nanotubes (MWCNT) using acid treatment, and a consequent addition of the modified MWCNT to the cement paste. The microstructural observation and degree of the MWCNT functionalization are examined using FE-SEM. The compressive strength is measured at an age of 28 days. The results of the study suggest that the acid-functionalized MWCNT are dispersed better compared to the pristine MWCNT due to presence of functional groups. The better dispersion of the nanotubes and the attached functional groups may contribute to the refinement of the microstructure of the cement paste and hence, increase its mechanical strength.