• Proceedings of the Korea Concrete Institute Conference
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• 2002.05a
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• pp.687-692
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• 2002

The chemical shrinkage and the autogenous shrinkage have been determined experimentally for cement pastes incorporating different W/C ratio and different amount of the following addition: silica fume, fly ash and sand. The measurement method of the chemical shrinkage and autogenous shrinkage both were the volumetric technique. The silica fume has a effect of increasing the autogenous shrinkage while have a minor effect on the chemical shrinkage. The addition of fly-ash and sand both decreased the amount of chemical shrinkage and autogenous shrinkage.

• Journal of the Korean Ceramic Society
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• v.33 no.3
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• pp.307-312
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• 1996

In following addition of 0.3, -0.6, 0.8, 1.0 and 5 weight percent MgSiF66H2O studies have been made of the setting and hardening characteristics of ordinary portland cement. MgSiF66H2O retarded the setting time of ordinary portland cement and extended the induction pariod of the hydration. In ordinary portland cement the setting characteristics were drastically altered especially at high MgSiF66H2O contents. Evidence was also obtained by the formation of a KSiF6 which was very fine particle. The results wee as follows. 1. Slump was slightly decreased when MgSiF66H2O added. 2. Setting time was retarded depending on the amount of retarding agent 2 to 8 hours 3. Compressive strength was almost same or some increased in comparision with opc. 4. When MgSiF66H2O was added to cement paste K2SiF6 were formed It was fine-sized distributed uniformly in cement grain and caused retardation of cement setting.

• Journal of the Korea institute for structural maintenance and inspection
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• v.20 no.2
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• pp.26-33
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• 2016

The alkali-slag-red mud(ASRC) cement belongs to clinker free cementitious material, which is made from alkali activator, blast-furnace slag(BFS) and red mud in designed proportion. This study is to investigate strength and pore characteristics of alkali-activated slag cement(NC), clinker free cementitious material, and ordinary portland cement(C) mortars using polymer according to red mud content. The results showed that the hardened alkali-activated slag-red mud cement paste was mostly consisted of C-S-H gel, being very fine in size and extremely irregular in its shape. So the hardened ASRC cement paste has lower total porosity, less portion of larger pore and more portion of smaller pore, as compared with those of hardened portland cement paste, and has higher strength within containing 10 wt.(%) of alkali-activated slag cement(NC) substituted by red mud.

• Advances in concrete construction
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• v.1 no.3
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• pp.239-252
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• 2013

Mortar microstructure is considered as a three-phase composite material, which is cement paste, fine aggregate and interfacial transition zone. Interfacial transition zone is the weakest link between the cement paste and fine aggregate, so it has a significant role to determine the properties of cementitious composites. In this study, specimens (w/c = 0.35, 0.45, 0.55) with various volume fractions of fine aggregate ($V_f$ = 0, 0.1, 0.2, 0.3 and 0.4) were cast and tested. To predict the equivalent migration coefficient ($M_e$) and migration coefficient of interfacial transition zone ($M_{itz}$), double-inclusion method and Mori-Tanaka theory were used to estimate. There are two stages to estimate and calculate the thickness of interfacial transition zone (h) and migration coefficient of interfacial transition zone ($M_{itz}$). The first stage, the data of experimental chloride ion migration coefficient ($M_s$) was used to calculate the equivalent migration coefficient of fine aggregate with interfacial transition zone ($M_e$) by Mori-Tanaka theory. The second stage, the thickness of interfacial transition zone (h) and migration coefficient of interfacial transition zone ($M_{itz}$) was calculated by Hori and Nemat-Nasser's double inclusion model. Between the theoretical and experimental data a comparison was conducted to investigate the behavior of interfacial transition zone in mortar and the effect of interfacial transition zone on the chloride migration coefficient, the results indicated that the numerical simulations is derived to the $M_{itz}/M_m$ ratio is 2.11~8.28. Additionally, thickness of interfacial transition zone is predicted from $10{\mu}m$, 60 to $80{\mu}m$, 70 to $100{\mu}m$ and 90 to $130{\mu}m$ for SM30, M35, M45 and M55, respectively.

• Journal of the Korean Ceramic Society
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• v.53 no.6
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• pp.676-681
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• 2016

For the purpose of reducing the amount of limestone, which is used as a desulfurization agent to absorbing $SO_X$ gas in thermal power plants, and to recycle limestone sludge generated from a steel mill, limestone sludge was utilized as a desulfurization agent. In this study, cement, made of flue gas desulfurization (FGD) gypsum obtained in a desulfurization process using limestone sludge, was manufactured then, experiments were conducted to identify the physical properties of the paste and mortar using the cement. The results of the crystal phase and microstructure analyses showed that the hydration product of the manufactured cement was similar to that of ordinary Portland cement. No significant decline of workability or compressive strength was observed for any of the specimens. From the results of the experiment, it was determined that FGD gypsum manufactured from limestone sludge did not influence the physical properties of the cement also, quality change did not occur with the use of limestone sludge in the flue gas desulfurization process.

• Journal of the Korea Concrete Institute
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• v.21 no.1
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• pp.21-27
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• 2009

In this study, experimental findings on the resistance to magnesium sulfate attack of portland cement mortar and paste specimens incorporating metakaolin (MK) are presented. Specimens with four replacement levels of metakaolin (0, 5, 10 and 15% of cement by mass) were exposed to solutions with concentrations of 0.424% and 4.24% as $MgSO_4$ at ambient temperature. The resistance of mortar specimens was evaluated through visual examination and linear expansion measurements. Additionally, in order to identify the products formed by magnesium sulfate attack, microstructural analyses such as XRD, DSC and SEM/EDS were also performed on the paste samples incorporating metakaolin. Results confirmed that mortar specimens with a high replacement level of metakaolin exhibited lower resistance to a higher concentration of magnesium sulfate solution. It was found that the negative effect of metakaolin on the magnesium sulfate attack is partially attributed to the formation of gypsum and thaumasite. Conclusively, it is necessary to pay a special attention when using metakaolin in concrete structures, particularly under highly concentrated magnesium sulfate environment.

• Journal of the Korea Concrete Institute
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• v.27 no.3
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• pp.265-272
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• 2015

In this study, a method to reduce temperature rise due to hydration in mass concrete is investigated. It is to use retarder (glucose) for reducing heat of hydration and to use calcium silicate hydrate (C-S-H) for compensating the retardation effect due to its role as a nucleation seed. For this purpose, the temperature rise of cement paste due to hydration was measured and the effect of using both C-S-H and glucose on setting and 28-day compressive strength of mortar specimens was investigated. According to the experimental results, using C-S-H and glucose caused the reduction in the maximum temperature but accelerated the time to reach the maximum temperature compared to that of retarded cement paste using glucose. In addition, using C-S-H and glucose did not show significant effect on 28-day compressive strength of mortar specimens, indicating that the method shown in this study can be a successful alternative to control maximum temperature rise in mass concrete.

• Proceedings of the IEEK Conference
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• 2001.10a
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• pp.571-575
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• 2001

To examine the grinding effect through preheating of waste concrete as a way of retrieving coarse aggregates from waste concrete, the removal rates of cement mortar and paste of both recycled aggregates and heated and grinded ones were investigated. As the preheating temperature increased, the removal rate of cement mortar from waste concrete was raised, and this kind of removal hardly affected the abrasion rate and specific gravity of aggregates. On the other hand, when it was treated over 40$0^{\circ}C$ of preheating temperature, the absorptance was reduced to less than 2.17, and cement mortar was effectively separated from waste concrete. It could meet the Korean Standards on recycled aggregates for concrete, and it is expected to expand the scope of utilization by making it possible to retrieve the aggregates which have the properties close to natural aggregates.

• Proceedings of the Korea Concrete Institute Conference
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• 1998.10a
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• pp.262-268
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• 1998

This research is to examine the selected method of optimal mixing proportion and cost analysis in the super flowing concrete. As confined water $ratio($\beta_p$)$ and K is introduced, itis to establish optimal mixing design of super flowing concrete according to the steps of paste, mortar and concrete. From paste and mortar test, it was led to $$\beta_p$$ and $K_p$satisfying the optimum condions depending on the kinds of binders. Then $$\beta_p$$ and $K_p$ is reflected to the mix condition of super flowing concrete. The result of test, the mix condition of super flowing concrete satisfied the quality performance of concrete with adjustment of additional rate of the superplasticizer. Besides, in case of design strength $350kg/\textrm{cm}^2$ of concrete, material cost in super flowing concrete is able to be reduced 5~16% in replacement of fly ash 30% in ordinary portland cement and slag cement.

• Journal of the Korean Recycled Construction Resources Institute
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• v.4 no.4
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• pp.483-488
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• 2016

The present study proposes an economical embedded ring-sensor that can measure a strain behavior of cement paste and mortar in early age. Using the proposed ring-sensor, the experimental method is proposed that can measure the setting time of the cement paste and mortar conveniently. The experimental study has been conducted using the mixtures of which W/C are 0.30, 0.35, 0.40, and 0.45. From the test result, the setting times measured by convectional test methods such as vicat method and penetration resistance method are compared with the setting time proposed by this study. The result reveals that the proposed ring-sensor can effectively measure the early age behavior so that can evaluate the time when the contraction starts. In addition, the contraction starting time can be regarded as a rational setting time, which is similar to the initial setting of convectional test methods.