• Journal of the Korea Institute of Building Construction
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• v.13 no.1
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• pp.20-28
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• 2013

Flexure toughness of Steel Fiber Reinforced Concrete (SFRC) shows a time-dependent characteristic due to the hydration process of the cement matrix in the SFRC system. The effect of two important factors, water/cement (w/c) ratio and fiber volume fraction, on the flexure toughness development of SFRC were investigated. Three different SFRC mixtures with hooked-end steel fibers were tested using a four-point bending testing configuration. Each mixture was tested at five different ages. The results showed that the post-peak toughness of SFRC developed at an earlier age than the first-crack toughness.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2018.11a
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• pp.73-74
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• 2018

In this study, it evaluate the tensile properties of polyamide fiber reinforced cementitious composite and hooked steel fiber reinforced cementitious Composites by strain rate. Polyamide fiber reinforced cement composites (PAFRCC) and Hooked Steel Fiber Reinforced Cement Composite(HSFRCC) were fabricated. Each specimen was reinforced with 1.0 and 2.0vol% fiber. The length of the reinforced fiber was 30 mm for both fibers, and the tensile test specimen was made in dumbbell shape. As a result, the tensile strength of fiber in polyamide fiber and the mechanical bonding between fiber and matrix in hooked steel fiber are considered to be the main factors affecting tensile behavior of fiber reinforced cement composite.

• Proceedings of the Korea Concrete Institute Conference
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• 2006.11a
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• pp.229-232
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• 2006

The HPFRCCs show that the multiple crack propagation, high tensile strength and ductility due to the interfacial bonding of the fibers to the cement matrix. Moreover, performance of cement composites varies according to type and weight contents of reinforcing fiber. and HPFRCCs with hybrid fiber have better performance than HPFRCCs with single fiber in damage tolerance. Total four cylindrical specimens were tested, and the main variables were the type and weight contents of fiber, which was polyvinylalchol (PVA), polyethylene (PE). In order to clarify effect of hybrid types on the characteristics of fracture and damage process in cement composites, AE method was performed to detect micro-cracking in HPFRCCs under cyclic compression. Loading conditions of the uniaxial compression test were monotonic and cyclic loading. And from AE parameter value, it is found that the second and third compressive load cycles resulted in successive decrease of the amplitude as compared with the first compressive load cvcle.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2017.11a
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• pp.100-101
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• 2017

LEFC(Light Emotion Friendly Conceret) was developed in Korea with demands of esthentic requirements in line with the recent developmental trend of concrete technology. The LEFC is made by inserting transparent transparent rods, and this forms a heterogeneous structure in the concrete matrix causing the LEFC substrate to crack due low adhesion between the rod and the cement. In this study, as a way to strengthen the bonding to the rod inserted in the LEFC, high strength vinylon fibers of varying mixture ratios were applied and physical properties were tested accordingly. To study the effect of different spacing of the bars on the LEFC, physical property testing was conducted on respective specimens with two different diameters (5mm, 10mm) inserted in different intervals of spacing (10mm, 15mm, and 20mm).

• Journal of the Korean Ceramic Society
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• v.50 no.4
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• pp.275-279
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• 2013

The purpose of this study was to prepare calcium phosphate cement [CPC] for use in artificial bone. Nano-crystalline calcium phosphate [CaP] was precipitated at $37^{\circ}C$ using highly active $Ca(OH)_2$ in DI water and an aqueous solution of $H_3PO_4$. From the XRD measurements, the nano-CaP powder was close to apatitic TCP phase and the powders fired at $800^{\circ}C$ showed a critical ${\beta}$-TCP phase. A mixture of one mole $CaCO_3$ and two moles di-calcium phosphate was calcined at $1100^{\circ}C$ to make a reference ${\beta}$-TCP material. The nano-CaP powders were added to the normal ${\beta}$-TCP matrix and fired at $900^{\circ}C$ to make a ${\beta}$-TCP block. The sintered block showed improved mechanical strength, which was caused by the solid state interaction between nano-CaP and normal ${\beta}$-TCP.

• Journal of the Korea Concrete Institute
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• v.21 no.4
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• pp.441-447
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• 2009

This paper presents a detailed experimental study on the sulfate resistance of specimens made with portland cement exposed to sulfate attack. The mortar specimens were immersed in a 5% sodium sulfate solution for 360 days and regularly monitored for visual damage, compressive strength loss and expansion. In addition, at the end of 360 days, the products of sulfate attack and the mechanism of attack were investigated through X-ray diffraction, TG&DSC and scanning electron microscopy. The test results indicated that the sulfate deterioration data was ordinary portland cement > sulfate resistance portland cement > low heat portland cement. The microstructural studies indicated that the main reaction product of deterioration of the mortar specimens was the formation of ettringite, gypsum and thaumasite due to sulfate attack. For portland cement matrices, a low heat cement matrix containing the lowest C3A and silicate ratio (C/S) was beneficient against the sulfate attack.

• Advances in concrete construction
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• v.9 no.6
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• pp.547-556
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• 2020

This study aimed to develop reference materials (RMs) that are chemically stable and can simulate the flow characteristics of cement paste. To this end, the candidate components of RMs were selected considering the currently required properties of RMs. Limestone, slag, silica, and kaolin were selected as substitutes for cement, while glycerol and corn syrup were selected as matrix fluids. Moreover, distilled water was used for mixing. To select the combinations of materials that meet all the required properties of RMs, flow characteristics were first analyzed. The results revealed that silica and kaolin exhibited bilateral nonlinearity. When an analysis was conducted over time, slag exhibited chemical reactions, including strength development. Moreover, fungi were observed in all mixtures with corn syrup. On the other hand, the combination of limestone, glycerol, and water exhibited a performance that met all the required properties of RMs. Thus, limestone, glycerol, and water were selected as the components of the RMs. When the influence of each component of the RMs on flow characteristics was analyzed, it was found that limestone affects the yield value, while the ratio of water and glycerol affects the plastic viscosity. Based on this, it was possible to select the mixing ratios for the RMs that can simulate the flow characteristics of cement paste under each mixing ratio. This relationship was established as an equation, which was verified under various mixing ratios. Finally, when the flow characteristics were analyzed under various temperature conditions, cement paste and the RMs exhibited similar tendencies in terms of flow characteristics. This indicated that the combinations of the selected materials could be used as RMs that can simulate the flow characteristics of cement paste with constant quality under various mixing ratio conditions and construction environment conditions.

• Journal of the Korean Recycled Construction Resources Institute
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• v.6 no.4
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• pp.365-372
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• 2018

3D printing technology of construction field can be divided into structural materials, interior and exterior finishing materials, and is mainly done by extruding and adapting. Particularly when it is applied as an exterior materials, it is mainly applied to an unstructured exterior materials and high accuracy is required. The exterior materials can be used as a cement composite materials, it is suitable also for a additive type manufacturing, and the role of a redispersible polymer powder is important. But, high temperatures, redispersible polymer cement base material beget dehydration and micro crack of cement matrix. In this research, we developed a EVA, EVCL redispersible polymer cement base material applicable as a 3D printing exterior materials, confirmed density and strength characteristics for application as an exterior materials, a flame retardancy test for improving the fire resistance of buildings and confirmed its possibility. From the test result, developed EVCL redispersible polymer cement mortar showed good stability in high temperatures. These high temperature stability is caused by the ethylene-vinyl chloride binding. Thus, this result indicates that it is possible to fire resistant 3D printing interior and exterior finishing materials.

• Environmental Engineering Research
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• v.11 no.1
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• pp.54-61
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• 2006

An electron probe microanalysis (EPMA) investigation can provide quantitative and qualitative insight into the nature of the surface and bulk chemistry on solidified waste forms(SWF). The proportion of Pb in grain areas is below 0.3 wt. %, and the proportion near the border of the grain slightly increases to 0.98 wt. % but in the inter-particle areas farther from the grain, the concentration of Pb markedly increases. It is apparent that very little Pb diffuses into the tricalcium silicate($C_3S$) particles and most of the Pb exists as precipitates of sulfate, hydroxide, and carbonate in the cavity areas between $C_3S$ grains. Calcite additions on Pb-doped SWF are also observed to induce deeper incorporation of lead into the cement grains with EPMA line-analysis of cross-sections of cement grains. The line-analysis reveals the presence of $0.2{\sim}5$ weight % Pb over $5\;{\mu}m$ from cement grain boundaries. In the inter-particle areas, the ratio of Ca, Si, Al and S to Pb is relatively similar even at some distance from the grain border and the Pb (wt. %) ratio is reasonably constant throughout the whole inter-particles area. It is apparent that the enhanced development of C-S-H on addition of calcite can increasingly absorbs lead species within the silica matrix.

• Smart Structures and Systems
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• v.18 no.2
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• pp.217-231
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• 2016

The present work aims to develop piezoresistive sensors of excellent piezoresistive response attributable to change in nanoscale structures of multi-wall carbon nanotube (MWNT) embedded in cement. MWNT was distributed in a cement matrix by means of polymer wrapping method in tandem with the ultrasonication process. DC conductivity of the prepared samples exhibited the electrical percolation behavior and therefore the dispersion method adopted in this study was deemed effective. The integrity of piezoresistive response of the sensors was assessed in terms of stability, the maximum electrical resistance change rate, and sensitivity. A composite sensor with MWNT 0.2 wt.% showed the lowest stability and sensitivity, while the maximum electrical resistance change rate exhibited by this sample was the highest (96 %) among others and even higher than those found in the literature. This observation was presumably attributed by the percolation threshold and the tunneling effect. As a result of the MWNT content (0.2 wt.%) of the sensor being near the percolation threshold (0.25 wt.%), MWNTs were close to each other to trigger tunneling in response of external loading. The sensor with MWNT 0.2 wt.% was able to maintain the repeatable sensing capability while sustaining a vehicular loading on road, demonstrating the feasibility in traffic flow sensing application.