• Journal of the Korean Ceramic Society
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• v.52 no.4
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• pp.253-263
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• 2015

Ordinary Portland cement is a widely favored construction material because of its good strength and durability and its reasonable price; however, spalling behaviour during fire exposure can be a serious risk that can lead to strength degradation or collapse of a building. Geopolymers, which can be synthesized by mixing aluminosilicate source materials such as metakaolin and fly ash, and alkali activators, are resistant to fire. Because the chemical composition of geopolymers controls the properties of the geopolyers, geopolymers with various Si:Al ratios were synthesized and evaluated as fire resistant construction materials. Rejected fly ash generated from a power plant was quantitatively analyzed and mixed with alkali activators to produce geopolymers having Si:Al ratios of 1.5, 2.0, and 3.5. Compressive strength of the geopolymers was measured at 28 days before and after heating at $900^{\circ}C$. Geopolymers having an Si:Al ratio of 1.5 presented the best fire resistance, with a 44% increase of strength from 29 MPa to 41 MPa after heating. This material also showed the least expansion-shrinkage characteristics. Geopolymer mortar developed no spalling and presented more than a 2 h fire resistance rating at $1,050^{\circ}C$ during the fire testing, with a cold side temperature of $74^{\circ}C$. Geopolymers have high potential as a fire resistant construction material in terms of their increased strength after exposure to fire.

• Journal of the Korea Concrete Institute
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• v.18 no.2 s.92
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• pp.189-198
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• 2006

The composition of most engineering materials is heterogeneous at some degree. It is simply a question of scale at which the level of heterogeneity becomes apparent. In the case of cementitious granular materials such as concrete the heterogeneity appears at the mesoscale where it is comprised of aggregate particles, a hardened cement paste and voids. Since it is difficult to consider each separate particle in the topological description explicitly, numerical models of the meso-structure are normally confined to two-phase matrix particle composites in which only the larger inclusions are accounted for. 2-D and 3-D concrete blocks(Representative Volume Element, RVE) are used to simulating heterogeneous concrete meso-structures in the form of aggregates in the hardened mortar with nearly zero-thickness linear or planar interfaces. The numerical sensitivity of these meso-structures are Investigated with respect to the different morphologies of heterogeneity and the different level of coupling constant among fracture mode I, II and III. In addition, a numerically homogenized concrete block in 3-D using Hashin-Shtrikman variational bounds provides an evidence of the effective cracking paths which are quite different with those of heterogenous concrete block. However, their average force-displacement relationship show a pretty close match each other.

• Journal of Energy Engineering
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• v.27 no.2
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• pp.55-60
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• 2018

In this study investigated the Controlled Low Strength Materials using coal ash and steel slag(KR slag) as the main material in the thermal power plant classified as waste resource. Bottom ash and KR slag are mixed at a ratio of 7: 3 to expand the use of industrial by-products through carbonate($CO_2$-fixation) reactions and inhibit the exudation of heavy metals. The results showed that the water content increased as the content of bottom ash increased. It was confirmed that as the powder content increased, the bleeding ratio decreased. Also, as the content of one kind of ordinary portland cement (OPC) decreased, activation of hydration reaction decreased and compressive strength decreased. However, when the mixed composition is appropriately adjusted, the compressive strength of 2.0 MPa required for the controlled low-strength material can be satisfied.

• Journal of Korean Society of Environmental Engineers
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• v.28 no.6
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• pp.661-666
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• 2006

The compressive strength of a paste composed of a low-calcium Class F fly ash and alkaline activator solutions was investigated. These activator solutions, made with sodium hydroxide, water glass and water, have a very high $OH^-$ concentration. The composition of alkaline activator solution and temperature have been shown to notably influence the development of the compressive strength of the fly ash-cements paste. Compressive strength of 50 MPa could be achieved by curing of the fly ash at $60^{\circ}C$ for 48 hrs or $85^{\circ}C$ for 24 hrs. This study presented the optimum mixing ratio of Class F fly ash/sodium hydroxide/water glass as 25:8:2 in weight basis, and activator/fly ash as 0.6/1.0 for high strength paste.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2017.05a
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• pp.79-79
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• 2017

Metallic biomaterials have been mainly used for the fabrication of medical devices for the replacement of hard tissue such as artificial hip joints, bone plates, and dental implants. Because they are very reliable on the viewpoint of mechanical performance. This trend is expected to continue. Especially, Ti and Ti alloys are bioinert. So, they do not chemically bond to the bone, whereas they physically bond with bone tissue. For their poor surface biocompatibility, the surface of Ti alloys has to be modified to improve the surface osteoinductivity. Recently, ceramic-like coatings on titanium, produced by plasma electrolytic oxidation (PEO), have been developed with calciumand phosphorus-enriched surfaces. A lso included the influences of coatings, which can accelerate healing and cell integration, as well as improve tribological properties. However, the adhesions of these coatings to the Ti surface need to be improved for clinical use. Particularly Silicon (Si) has been found to be essential for normal bone, cartilage growth and development. This hydroxyapatite, modified with the inclusion of small concentrations of silicon has been demonstrating to improve the osteoblast proliferation and the bone extracellular matrix production. Strontium-containing hydroxyapatite (Sr-HA) was designed as a filling material to improve the biocompatibility of bone cement. In vitro, the presence of strontium in the coating enhances osteoblast activity and differentiation, whereas it inhibits osteoclast production and proliferation. The objective of this work was to study Morphology of bone-like apatite formation on Sr and Si-doped hydroxyapatite surface of Ti-6Al-4V alloy after plasma electrolytic oxidation. Anodized alloys was prepared at 270V~300V voltages with various concentrations of Si and Sr ions. Bone-like apatite formation was carried out in SBF solution. The morphology of PEO, phase and composition of oxide surface of Ti-6Al-4V alloys were examined by FE-SEM, EDS, and XRD.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.665-668
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• 2008

Recently the city construction and the concrete structures are more becoming extra weight and the efficient use of the space by the population intensively and follow in industrial intensive commerce and the residence commerce composition building which leads the high story of the building. Consequently the high rise of the building which space applies efficiently in objective which will increase continuously. Also with high rise of buildings durability it will be able to increase the life of the structure is emphasized and the concrete structure is demanding the more high strength.

• Journal of the Korean Recycled Construction Resources Institute
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• v.3 no.4
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• pp.301-306
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• 2015

For the purpose of developing high performance marine concrete with improved crack resistance and durability, this analytical study aimed to estimate strength, hydration heat characteristics, and chloride attack resistance of concrete with mineral admixture. Ground granulated furnace slag and fly ash were considered for mineral admixture. The replacement of ground granulated furnace slag and fly ash considered in the analysis was in the range of 0~70% and 0~40 %, respectively. The analysis results indicated that both ground granulated furnace slag and fly ash decreased compressive strength, and the effect of adding ground granulated furnace slag on mitigation of hydration heat was limited whereas fly ash had an noticeable influence on it. It was also found that the replacement with ground granulated furnace slag enhanced the chloride attack resistance but fly ash deteriorated the resistance. From the analytical studies, It could be expected that a ternary blended cement composition with proper amount of ground granulated furnace slag and fly ash might be effective to control crack resistance as well as chloride attack resistance of marine concrete.

• Journal of the Korean Recycled Construction Resources Institute
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• v.8 no.3
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• pp.310-316
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• 2020

In this study, the stability and EMP shielding performance of metal-based industrial by-products aggregates with excellent conductivity and easy procurement to be used as concrete aggregates for EMP shielding are evaluated. The industrial by-products are electronic-arc-furnace oxidizing slag, copper smelting slag, and ferro-moldibdenum. The composition analysis of aggregates and aggregate stability are evaluated. As a result of the experiment, ferro-moldibdenum is shown to have l ow stability as an aggregate due to its high Free-CaO. The remaining aggregates are evaluated to be safe to use as aggregates for concrete. In addition, industrial by-products aggreagate-specimens excluding ferro-moldibdenum are shown higher compressive strength than the plain specimen. The recycle aggregates, electronic-arc-furnace oxidizing slag and copper smelting slag, are shown excellent EMP shielding performance, the EMP shielding performance is expected to increase if the average particle diameter of the aggregate is small or evenly distributed.

• Journal of the Korean Ceramic Society
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• v.44 no.9
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• pp.471-476
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• 2007

The hydration mechanism of the $3CaO{\cdot}Al_2O_3-CaSO_4{\cdot}2H_2O$ system in the presence of alkali sulfates has been investigated. The early hydration rate of $3CaO{\cdot}Al_2O_3$ was accelerated by the addition of $Na_2SO_4$ and $K_2SO_4$. This is closely related to the formation of syngenite $(CaSO_4{\cdot}K_2SO_4{\cdot}H_2O)$, and the U-phase added $K_2SO_4$ and $Na_SO_4$ in the $3CaO{\cdot}Al_2O_3-CaSO_4{\cdot}2H_2O$ system, respectively. The formation of the rigid syngenite and U-phase structure led to rapid setting and decreases the sulfate content in the liquid phase of the hydrating cement to the extent that it cannot adequately retard the hydration of $3CaO{\cdot}Al_2O_3$. In case of the alkali sulfate not added to the $3CaO{\cdot}Al_2O_3-CaSO_4{\cdot}2H_2O$ system, the ettringite was transformed to monosulfoaluminate immediately after the consumption of gypsum. However, when the alkali sulfates were added to this system, the ettringite did not transform to monosulfoaluminate immediately even though the gypsum was completely consumed. There was a stagnation period to transform to the monosufoaluminate after the consumption of gypsum because the syngenite and U-phase remained as the sulfate source.

• Resources Recycling
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• v.26 no.6
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• pp.45-49
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• 2017

Most Waste slurry is produced in the process of silicon manufacturing for semiconductor industry, containing silicon (Si) and silicon carbide (SiC). Waste slurry is simply stored with solidifying by cement or buried. On the other hand, it was suggested in this study that the waste slurry should be used for heating source as supplementary material in steel making process. The waste slurry was refined and pulverized, which was recycled into SiC-based sludge briquette. Chemical composition for SiC-based sludge briquette was analyzed and the feature of heating source was observed in accordance with the injection time and input amount. As a result, SiC-based sludge briquette in terms of low cost and high efficiency had an effect on increasing liquid steel temperature in steel making plants.