• Title/Summary/Keyword: cement binder

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Physicochemical properties and autogenous healing performance of ternary blended binders composed of OPC-BFS-CSA clinker

  • H.N. Yoon;Joonho Seo;Naru Kim;H.M. Son;H.K. Lee
    • Advances in concrete construction
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    • v.15 no.1
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    • pp.11-22
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    • 2023
  • Autogenous healing of concrete can be helpful in structural maintenance by healing cracks using a healing material created by the precipitation of calcite and by the hydration of unhydrated binder around the cracks. Against this backdrop, this study investigated the physicochemical properties and autogenous healing performance of ternary blended binder composed of ordinary Portland cement (OPC), blast furnace slag (BFS), and calcium sulfoaluminate (CSA) clinker. Ternary blended binders with various contents of OPC-BFS-CSA clinker were prepared, and their physicochemical properties and autogenous healing performances were examined using various analytical techniques and visually observed using a microscope. The obtained results indicated that increase in the BFS content accompanied the increased the amount of unreacted BFS even after 28 days of curing and had a positive effect on the autogenous healing performance due to its latent hydration. However, replacing the CSA clinker did not increase the autogenous healing performance owing to an insufficient sulfate source for the formation of ettringite. The main precipitates around the cracks were calcite, C-S-H. Other hydration products such as portlandite, monosulfate, and ettringite, which were not found in the Raman and scanning electron microscope analyses.

Mechanical Properties of Hwangtoh-Based Alkali-Activated Concrete

  • Yang, Keun-Hyeok;Hwang, Hey-Zoo;Lee, Seol
    • Architectural research
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    • v.11 no.1
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    • pp.25-33
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    • 2009
  • This study presents the testing of 15 hwangtoh-based cementless concrete mixes to explore the significance and limitations of the development of eco-friendly concrete without carbon dioxide emissions while maintaining various beneficial effects. Hwangtoh, which is a kind of kaolin, was incorporated with inorganic materials, such as calcium hydroxide, to produce a cement-less binder. The main variables investigated were the water-to-binder ratio and fine aggregate-to-total aggregate ratio to ascertain the reliable mixing design of hwangtoh-based cementless concrete. The variation of slump with elapsed time was recorded in fresh concrete specimens. Mechanical properties of hardened concrete were also measured: including compressive strength gain, splitting tensile strength, moduli of rupture and elasticity, stress-strain relationship, and bond resistance. In addition, mechanical properties of hwangtoh-based cement-less concrete were compared with those of ordinary portland cement (OPC) concrete and predictions obtained from the design equations specified in ACI 318-05 and CEB-FIP for OPC concrete, wherever possible. Test results show that the mechanical properties of hwangtoh-based concrete were significantly influenced by the water-to-binder ratio and to less extend by fine aggregate-to-total aggregate ratio. The moduli of rupture and elasticity of hwangtoh-based concrete were generally lower than those of OPC concrete. In addition, the stress-strain and bond stress-slip relationships measured from hwangtoh-based concrete showed little agreement with the design model specified in CEB-FIP. However, the measured moduli of rupture and elasticity, and bond strength were higher than those given in ACI 318-05 and CEB-FIP. Overall, the test results suggest that the hwangtoh-based concrete shows highly effective performance and great potential as an environmental-friendly building material.

Physical Properties of Sulfur Concrete with Modified Sulfur Binder (유황개질 바인더를 사용한 유황 콘크리트의 물리적 특성)

  • Bae, Sung Geun;Gwon, Seong Woo;Kim, Se Won;Cha, Soo Won
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.34 no.3
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    • pp.763-771
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    • 2014
  • Recently, a huge amount of sulfur has been produced as a byproduct of petroleum refining processes in Korea. Sulfur concrete is made of modified sulfur binder instead of cement paste, which has advantages of reducing $CO_2$ emission from cement industry as well as utilizing surplus sulfur. Also, sulfur concrete is a sustainable material that can be repetitively recycled. In this study, the physical properties of sulfur concrete are experimentally investigated. From the test results, sulfur concrete showed compressive strengths higher than at least 50MPa. Also, the unit weight, modulus of elasticity and splitting tensile strength of sulfur concrete was similar to that of Portland cement concrete (PCC). The coefficient of thermal expansion of sulfur concrete was a little larger than that of Portland cement concrete and sulfur concrete with mineral filler is helpful to lower the coefficient of thermal expansion. recycled aggregate sulfur concrete resulted in a slight reduction in the compressive strength, but sulfur concrete with recycled aggregate can achieve the high strength characteristics.

Evaluation of Environment Friendly High Performance Ternary Cement Concrete Deck Overlay Pavement by Experimental Construction (시험시공을 통한 친환경 고성능 3성분계 시멘트 콘크리트 교면 포장의 성능 평가)

  • Choi, In-Hyeok;Kim, Dae-Seong;Lee, Jun-Ho
    • International Journal of Highway Engineering
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    • v.13 no.2
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    • pp.85-93
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    • 2011
  • This study experimented to evaluate the environment friendly high performance ternary cement concrete deck overlay pavement using mineral admixture such as fly ash and ground granulated blast-furnace slag. It was measured to find best binder mixing according to replacement rate of mineral admixture with compressive strength and flexural strength. After finding best binder, it is also experimented to evaluate durability on chloride penetration resistance, freezing- thawing resistance, scaling resistance of deicing chemicals, abrasion resistance, alkali-silica reactivity test and bonded environment friendly high performance ternary cement concrete deck overlay pavement experimented to evaluate bonded old deck and new concrete overlay pavement using special polymer cement mortar. In additions, bonded environment friendly high performance ternary cement concrete deck overlay pavement by experimental construction was evaluated at interchange bridge of North Yeoju. Result, examination was indicated better binding with binder replacement of cement 70%, ground granulated blast-furnace slag 15% and fly ash 15%. And special polymer cement mortar used in old deck and new overlay concrete was indicated better bonding both laboratory and construction.

Fluidization characteristics of Non-sirtered cement mortar using blast furnace slag and fly ash (고로슬래그와 플라이애시를 이용한 비소성 시멘트 모르타르의 유동화 특성)

  • Byun, Hui-Jae;Na, Hyeong-Won;Hyung, Won-Gil
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2022.04a
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    • pp.186-187
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    • 2022
  • The purpose of this study was to give fluidizing properties to non-sirtered cement made using by-products that can replace Portland cement by using a fluidizing agent. Blast furnace slag, C-type fly ash, and F-type fly ash were used for non-sirtered cement, and sand was used for aggregate. The amount of fluidizing agent used was fixed at 1%, and the water-cement ratio (W/C) was different by setting the binder blending ratio of the non-sintered cement differently, and the fluidity test and flow were compared. As a result of the experiment, when the flow standard was 170mm when the fluidizing agent was used, the fluidizing properties were shown at an average water-cement ratio (W/C) of 36%. Through this study, it was confirmed that the fluidizing properties appeared when the fluidizing agent was used in non-sintered cement.

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Tensile Properties and Adhesion of Hybrid-Type Anti-Corrosion Polymer Cement Slurry (하이브리드형 방식 폴리머 시멘트 슬러리의 인장특성 및 접착성)

  • Jo, Young-Kug
    • Journal of the Korea Concrete Institute
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    • v.20 no.5
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    • pp.635-642
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    • 2008
  • In recent years, epoxy-coated reinforcing bars have been widely used in order to prevent the corrosion of ordinary reinforcing bar. However, they have a bad balance between performance and cost. Especially, they have a brittleness properties, low bond strength to cement concrete and no good bend-ability in the field. The purpose of this study is to evaluate the tensile properties and adhesion of hybrid-type anti-corrosion polymer cement slurry (PCS). PCSs are prepared with four types polymer dispersions using fly ash and silica fume, and tested for proper coating thickness, tensile properties, adhesion to steel plate and bend-ability. From the test results, the viscosity of PCS is effected by polymer dispersion types, and is a little decreased by using fly ash. The coating thickness of PCS has a proper thickness at polymer-binder ratio of 100%. It is apparent that the coating thickness has various values according to viscosity of PCS, water-binder ratio and polymer-binder rato. PCS has a good various anticorrosion properties and physical properties such as tensile strength, adhesion and bend-ability. It is also recommended that proper coating thickness to reinforcing bar is in the ranges of 150 to $250{\mu}m$ for bond strength, adhesion and bend-ability. It is also expected that the coated reinforcing bar using PCS is widely used instead of epoxy coated reinforcing bar in the industrial field.

Evaluation of Shear Strength at Interface Between Geotextile and Cementitious Binder Materials (시멘트계 결합재가 적용된 지오텍스타일의 접촉면 전단강도 평가)

  • Son, Dong-Geon;Byun, Yong-Hoon
    • Journal of The Korean Society of Agricultural Engineers
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    • v.64 no.1
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    • pp.91-98
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    • 2022
  • Multi-layered geotextile tubes may have problems on its stability when used as cofferdam. This study presents the shear strength characteristics at the interface between geotextiles and a cementitious binder material to improve the stability of the multi-layered geotextile tubes. In this study, two different types of geotextiles are used. After mixing with a rapid setting cement, fly ash, sand, accelerator, and water, the cementitious binder material is prepared at the interface between two geotextile samples and cured under water for a desired period. The specimen is placed on upper and lower direct shear boxes by using clamping systems. A series of direct shear tests for two different geotextiles are performed along the curing time under three vertical stresses. Experimental results show that the shear strength at the interface between the cementitious binder material and geotextiles is greater than that at the interface between two geotextiles. For two types of geotextiles, apparent cohesion occurs at the interface between the cementitious binder material and geotextiles. In addition, the friction angles for any curing time are improved, compared to the interface between two geotextiles. The cementitious binder material suggested for the interface between two geotextiles may be useful for the reinforcement of multi-layered geotextile tubes.

Strength Development of Low Heat Portland Cement Concrete in High Strength Range (저열 포틀랜드 시멘트 콘크리트의 고강도 영역에서의 강도발현 특성)

  • Ha Jae Dam;Um Tai Sun;Lee Jong Ryul;Kwon Young Ho
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.05b
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    • pp.353-356
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    • 2005
  • Strength development of low heat portland cement(Type IV) concrete in high strength range is tested. In this study strength development according to water-binder ratio, strength development according to age, effect of fly ash and super plasticizer are tested. This study tests effect of low heat portland cement in high strength range concrete and provide guide line concrete mix design for later study and/or construction.

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Study on the characteristic of liner and cover material by accelerating agent type (급결제 종류에 따른 광산 차수재의 특성 연구)

  • Cho, Yong-Kwang;Nam, Seong-Young;Lee, Yong-Mu;Kim, Chun-Sik;Seo, Shin-Seok;Jo, Sung-Hyun;Lee, Hyoung-Woo;Ahn, Ji-Whan
    • Journal of Environmental Science International
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    • v.27 no.2
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    • pp.75-81
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    • 2018
  • At present research on mining backfill materials is being carried out to prevent ground subsidence and breaking by underground cavern of exhausted mines. However, backfill materials can cause secondary environmental issues such as ground pollution. To solve these issues, liner and cover materials are constructed before backfill materials constructed, to inhibit toxic substances form moving to the surroundings. Liner and cover materials, however, should have an accelerating performance after construction and when the accelerating performance is degraded, the work efficiency can be lowered, and the construction cost can be increased, by many rebound content. Therefore, this study develops mining liner and cover materials, and evaluates their accelerating performance and physical properties of liner and cover materials by types and content of accelerating agent. In case of aluminate accelerating agent, it is mixed with more than 5% of liner and cover materials(binder/ratio); thus an accelerating performance satisfying Korean Industrial Standards(KS) occurs, and in case of alkali-free accelerating agent, when it is mixed with more than 7%(binder/ratio), accelerating performance satisfying KS occurs. The more the accelerating agent capacity increases, the more compressive strength decreases. In addition, it is confirmed that compressive strength of aluminate accelerating agent is more degraded than compressive strength of the alkali-free accelerating agent. It is also confirmed that drying shrinkage stability of the alkali-free accelerating agent is better than the drying shrinkage stability of the aluminate accelerating agent.

Prediction of compressive strength of slag concrete using a blended cement hydration model

  • Wang, Xiao-Yong;Lee, Han-Seung
    • Computers and Concrete
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    • v.14 no.3
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    • pp.247-262
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    • 2014
  • Partial replacement of Portland cement by slag can reduce the energy consumption and $CO_2$ emission therefore is beneficial to circular economy and sustainable development. Compressive strength is the most important engineering property of concrete. This paper presents a numerical procedure to predict the development of compressive strength of slag blended concrete. This numerical procedure starts with a kinetic hydration model for cement-slag blends by considering the production of calcium hydroxide in cement hydration and its consumption in slag reactions. Reaction degrees of cement slag are obtained as accompanied results from the hydration model. Gel-space ratio of hardening slag blended concrete is determined using reaction degrees of cement and slag, mixing proportions of concrete, and volume stoichiometries of cement hydration and slag reaction. Furthermore, the development of compressive strength is evaluated through Powers' gel-space ratio theory considering the contributions of cement hydration and slag reaction. The proposed model is verified through experimental data on concrete with different water-to-binder ratios and slag substitution ratios.