• International Journal of Concrete Structures and Materials
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• v.10 no.4
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• pp.527-537
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• 2016

This study evaluated the mechanical characteristics and durability of porous concrete produced with a cementless binder based on ground granulated blast furnace slag (BFS), fly ash (FA) and flue gas desulfurization gypsum (CP). As a result, the void ratio was increased slightly from the target void ratio, by 1.12-1.42 %. Through evaluating the compressive strength, it was found that the compressive strength of porous concrete with cementless binder decreased in comparison to the compressive strength of porous concrete with ordinary Portland cement (OPC), but the difference was insignificant, at 0.6-1.4 MPa. Through the freeze-thawing test to evaluate the durability, it was found that the relative dynamic elastic modulus of porous concrete with cementless binder decreased to 60 % or less at 80 cycles. The result of the chemical resistance test showed that the mass reduction rate was 12.3 % at 5 % HCl solution, and 12.7 % at 12.3 and 5 % $H_2SO_4$ solutions.

• Advances in concrete construction
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• v.10 no.3
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• pp.237-245
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• 2020

Past research efforts already established geopolymer as an environment-friendly alternative binder system for ordinary Portland cement (OPC) and recycled aggregate is also one of the promising alternative for natural aggregates. In this study, an effort was made to produce eco-friendly mortar mixes using geopolymer as binder and recycled fine aggregate (RFA) partially and study the resistance ability of these mortar mixes against the aggressive environments. To form the geopolymer binder, 70% fly ash, 30% ground granulated blast furnace slag (GGBS) and alkaline solution comprising of sodium silicate solution and 14M sodium hydroxide solution with a ratio of 1.5 were used. The ratio of alkaline liquid to binder (AL/B) was also considered as 0.4 and 0.6. In order to determine the resistance ability against aggressive environmental conditions, acid attack test, sulphate attack test and rapid chloride permeability test were conducted. Change in mass, change in compressive strength of the specimens after the immersion in acid/sulphate solution for a period of 28, 56, 90 and 120 days has been presented and discussed in this study. Results indicated that the incorporation of RFA leads to the reduction in compressive strength. Even though strength reduction was observed, eco-friendly mortar mixes containing geopolymer as binder and RFA as fine aggregate performed better when it was produced with AL/B ratio of 0.6.

• Corrosion Science and Technology
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• v.8 no.3
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• pp.110-115
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• 2009

At the onset of corrosion of steel in concrete, hydrogen ions usually evolve in the process of electrochemical reaction, thereby decreasing the pH of the pore solution, which can be buffered by cement hydration products, as being representatively illustrated by calcium hydroxide. Hence, a fall in the pH is dependent on properties of cement hydration (i.e. hydration products and degree of hydration). The present study tested acid neutralization capacity (ANC) of cementitious binders of OPC(Ordinary Portland Cement), 30% PFA(Pulverized Fuel Ash), 60% GGBS(Ground Granulated Blast Furnace Slag), 10% SF(Silica Fume) to quantify the resistance of cement matrix to a pH fall. Cement pastes were cast at 0.4 of a free W/C ratio with 1.5% chlorides by weight of binder in cast. Powder samples obtained crushed and ground specimen after 200 days of curing were diluted in still water combined with different levels of 1M nitric acid solution, ranging from 0.5 to 20 mol/kg. Then, the pH of diluted solution was monitored until any further change in the pH did not take place. It was seen that the pH of the diluted solution gradually decreased as the molar amount of nitric acid increased. At some particular values of the pH, however, a decrease in the pH was marginal, which can be expressed in the peak resistances to a pH fall in the ANC curve. The peaks occurred at the variations in the pH, depending on binder type, but commonly at about 12.5 in the pH, indicate a resistance of precipitated calcium hydroxide. The measurement of water soluble chloride at the end of test showed that the amount of free chloride was significantly increased at the pH corresponding to the peaks in the ANC curve, which may reflect the adsorption of hydration products to chlorides.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.537-540
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• 2008

Up to now, the RC structures have been recognized as being socially semi-permanent. But in recent years there were reports about the cases of early deterioration of RC structures. Most of all pore structure effects on the durability of concrete as well as mechanical properties of concrete. Therefore, in this study, mixing design was proportioned with the water-binder ratio 0.55 binder compositions corresponding to cement without any supplementary materials(OPC), cement with 50% blast-furnace slag replacement (BFS50), cement with 15% fly ash replacement (FA15), and ternary cement with cement, 15% fly ash, and 35% slag replacement (BFS35+FA15). And this study is to compare pore structure property of concrete by carbonation to investigate the effect of the permeation of deterioration factors such as $CO_2$ and chloride ion under the combined deterioration environments. The results showed that pore volume effects on the diffusibility of chloride ion.

• Journal of the Korean Recycled Construction Resources Institute
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• v.10 no.3
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• pp.269-275
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• 2022

In this study, the setting time and compressive strength of cement paste composites applied with nano-micro pozzolanic binders were experimental analyzed. The pozzolanic binder was reduced initial and final setting time and the compressive strength was increased. Micro silica was effective in decrease the initial setting and final setting time and impressing the compressive strength. When two or more cement binders were used, the using of silica fume and a small amount of nano silica at reduced the setting time to 62-64 % to OPC cement and the compressive strength was increased to 117 %. A small amount of mixing the nano silica was effect to pore filling and pozzolanic activation. However, the addition of a chemical admixture should be considered when mixing table design because pozzolanic binders high specific surface area causes a decrease in cement composites flow.

• Journal of the Korea institute for structural maintenance and inspection
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• v.11 no.6
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• pp.143-151
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• 2007

This study presents the experimental results of frost durability including resistance to freezing-thawing and surface scaling of concrete. Mixing design was proportioned with the various water-binder ratio between 0.37 and 0.47 and three different binder compositions corresponding to Type I cement without any supplementary cementitious materials(OPC), Type II cement with 50% blast-furnace slag replacement(BFS50), and ternary cement with Type III cement, 15% fly ash, and 35% slag replacement (BFS35%+FA15%). Test results showed that the mixing design with BFS50% and BFS35%+FA15% exhibited higher durability factor than that made with OPC only. Finally, the use of blend cement containing slag can be used effectively in terms of frost durability of the concrete exposed to severe condition under coastal environment like as flying salt, sea water spray, etc.

• Journal of Korean Society of Environmental Engineers
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• v.36 no.12
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• pp.843-850
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• 2014

This study investigated to recycle ash produced in the sewage sludge incinerator using reduction/stabilization. Nonsintering process was performed by binding cement, geobond and sand mixed with sewage sludge ash (SSA). Results showed that unconfined compressive strength could be obtained components of sewage sludge ash. it exceeded more than double score of the 22.54 Mpa ($229.7kg/cm^2$) Korean standard. chemical ingradients of the sewage sludge ash was mainly composed of $SiO_2$, $Al_2O_3$, $Fe_2O_3$, CaO and others, which were similar to those of the each binders consisting cement and geobond. microstructure of solidified speceimen for the different admixture was related to the compressive strength according to SEM analysis. optimum mixing range of the sewage sludge ash to inorganic binder was found to be 10~40% which can widly safely regulate the confined compressive strength. This study revealed the sewage sludge ash can be partial replacement of the inorganic binder for recycling.

• Journal of the Korean Recycled Construction Resources Institute
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• v.7 no.3
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• pp.235-242
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• 2019

The objective of this study is to modify the mixture proportions of concrete that were developed for section enlargement strengthening elements using a specially designed binder composed of 5% ultra-rapid hardening cement, 10% polymer, and 85% ordinary portland cement in order to assign the self-compaction property to such concrete. The self-compaction abilities of concrete were estimated by the performance criteria specified in JSCE and EFNARC provions. Test results showed that the increase in the unit binder content at the consistent water-to-bider ratio led to increase in viscosity of fresh concrete but did not exhibit the decrease in the fluidity due to a greater viscosity. The mixture proportioning of self-compaction section enlargement concrete could be considered at the following conditions: unit binder contents of $430kg/m^3{\sim}470kg/m^3$ and fine aggregate-to-total aggregate ratios of 40%~46% at the water-to-binder ratio of 38%.

• Proceedings of the Korea Concrete Institute Conference
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• 2006.05b
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• pp.25-28
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• 2006

This study investigated pre-mixed cement combined with ordinary portland cement, BF and SF, in order to manufacture cement binder, which is possible to produce 150MPa ultra high strength concrete. The BF used in this study reduces and control hydration heat. It can also improve concrete fluidity, while AP increases hydration product and accelerates reaction of BF. SF has micro filler effect and makes pozzolanic reaction. It also fabricates high density internal organization. This developed pre-mixed cement can reduce hydration heat and increase hydration product. It is possible to fabricate high density organization and to secure homogeneity. The mock-up test of ultra high strength concrete showed excellent dispersibility and workability and indicated compressive strength more than 150MPa at 28 days.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2017.05a
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• pp.118-119
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• 2017

In the S.C.W (soil cement wall) grouting solution, Cement grout ratio of 1 part Portland cement and 1part water is being used. However, Co₂ and harmful heavy metals such as cr6+ are discharged in the process, causing a serious environmental issue. The purpose of the present study is therefore to substitute cement grout to inorganic binder and identify durability properties of ground solidification materials.