• Title/Summary/Keyword: cationic

Search Result 1,230, Processing Time 0.027 seconds

In vitro and in vivo transfection efficiency of a cationic lipid containing sodium cholate

  • Kim, Adele;Lee, Eun-Hye;Choi, Sung-Hee;Kim, Chong-Kook
    • Proceedings of the PSK Conference
    • /
    • 2002.10a
    • /
    • pp.425.3-426
    • /
    • 2002
  • Cationic lipids have been used as one of the major components for making most promising non-viral gene delivery systems. whereas sodium cholate. an edge activator has been used as a surfactant in making ultradeformable and ultraflexible liposomes called Transfersomes. Using both a cationic lipid, DOTAP and sodium cholate. a newly formulated ultradeformable cationic liposome has been prepared. The average particle size of this formulation was approximately 80nm. (omitted)

  • PDF

Interaction of Antibiotic with PAN and Cationic-Dyeable PET Fibers in Development of Infection Resistant Biomedical Materials

  • Choi Hyung-Min
    • Fibers and Polymers
    • /
    • v.7 no.1
    • /
    • pp.1-7
    • /
    • 2006
  • Interaction of a representative antibiotic, doxycycline(Doxy), with commercial poly(acrylonitrile) (PAN) and cationic-dyeable poly(ethylene terephthalate)(PET) fiber was studied in development of infection resistant biomedical materials. Regular PET was also employed for a comparison purpose. Their interactions were investigated at different treatment temperatures, times, and pHs. Fibers were also hydrolyzed by 1% NaOH for 1 or 2 hours at $85^{\circ}C\;and\;100{\circ}C$ to study effect of hydrolysis on antibiotic sorption. Infection-resistant characteristics of the substrates were evaluated by zone of inhibition (ZOI) test. Results revealed that a significant chemical change occurred in PAN and cationic-dyeable PET due to hydrolysis. Additional functional groups obtained by hydrolysis not only enhanced sorption of the antibiotics but also provided greater ZOI values, indicating substantial improvement in sustained infection resistance properties.

Effects of Recycling on Adsorption Characteristics of Cationic Polyacrylamide onto Primary and Secondary Fines (리사이클링 횟수에 따른 일차미세섬유와 이차미세섬유의 폴리아크릴아미드 흡착특성 변화)

  • 주성범;이학래
    • Journal of Korea Technical Association of The Pulp and Paper Industry
    • /
    • v.31 no.2
    • /
    • pp.34-41
    • /
    • 1999
  • Adsorption of cationic polyacrylamide dry strength resins onto the surface of papermaking fibers and fines is critical for their effective utilization. Since dry strength resins are frequently employed when recycled fibers containing a great deal of fines are used as a raw material, their adsorption characteristic onto the recycled fiber fines is of great importance. In this study, effects of recycling on adsorption characteristics of cationic polyacrylamide onto primary and secondary fines were examined. Never dried bleached hardwood kraft pulp was beaten and dried for recycling. In each recycling step the adsorption characteristic of a cationic PAM onto primary and secondary fines was evaluated by kjeldahl nitrogen analysis method. The influence of recycling on water retention value and carboxyl content along with the sheet density and tensile strength was examined. Secondary fines of never dried pulp adsorbed twice as much of C-PAM as the primary fines, however, the adsorption capacity of the secondary fines decreased rapidly during the course of recycling and showed lower adsorption capacily than primary fines.

  • PDF

Drainage and Shear Stability of Microparticle Retention Systems Based on Cationic Guar Gums and Colloidal Silicas (양이온성 구아검과 콜로이달 실리카를 이용한 마이크로파티클 보류시스템의 탈수 및 전단안정성)

  • Ham, Choong-Hyun;Lee, Hak-Lae
    • Journal of Korea Technical Association of The Pulp and Paper Industry
    • /
    • v.40 no.2
    • /
    • pp.1-7
    • /
    • 2008
  • The trend of using more hardwood and recycled fibers, and closing more tightly of the paper mill white water system has resulted in build-up of fines as well as organic and inorganic contaminants in the white water. This changes in papermaking wet end requires developing chemical additive system that provides good fiber retention and drainage in closed white water system. In this study the effect of charge densities and chemical characteristics of microparticle systems consisted of cationic guar gums and anionic colloidal silica sols on drainage and retention have been examined. Results showed that higher charge density of cationic guar gum and anionic colloidal silica sol gave better retention and drainage. Particularly highly structured silica gave greater retention efficiency.

A Study on Dyeing Properties of Cationic Agent Treated Cotton Fibre with Direct Dye (캐티온화제 처리한 면섬유의 집접 염료의 염색성)

  • Jung, Young Jin;Lee, Young Hee;Lee, Myoung Hane;Lee, Eon Pil
    • Textile Coloration and Finishing
    • /
    • v.7 no.2
    • /
    • pp.1-8
    • /
    • 1995
  • Polymer cationic agent was prepared by the initial polymerization of epichlorohydrin followed by amination with diethyl-amine. Cotton fibre treated with the polymer (6∼8% o.w.f.) is highly cationic and exhibit increased substantivity for anionic dyes. The modified substrate could be dyed with direct dyes without salt or a little salt from dye bath. The increased concentration of cationic agents resulted in an increase the colour yield. Futhermore, treated cotton has an electropositive surface charge. Adsorption of direct dye can be attributed to both van der waals force and electrostatic attraction.

  • PDF

Development and Application of Cationic Agent (I) (Quaternized Polyepichlorohydrine) (카치온화제의 개발과 응용 (I) (4급화 폴리에피크로로히드린))

  • Kim, Moon Sik;Jung, Young Jin;Park, Soo Min
    • Textile Coloration and Finishing
    • /
    • v.7 no.2
    • /
    • pp.70-76
    • /
    • 1995
  • The polyepichlorohydrine(poly(ECH)) was prepared by the condensation polymerization of epichlorohydrine. The cationic agent was prepared from poly(ECH) by amination of poly(ECH) with dimethyleneamine. Pretreatment of cellulosic fabric with the poly(ECH)amine produced a modified fabrics that could be dyed under neutral condition with reactive dye using small amount of the salt. Colour yield of cellulosic fabric were increased by increasing salt concentraction. cationic agent concentration. The optimum condition for colour yield was the concentration of cationic agent 5%(o.w.f), that of NaCl 4g/l, and that of $Na_{2}CO_{3}$5g/l. The dyeing of treated fabrics exhibits improved colour yield and high wash fastness.

  • PDF

Visible light-induced reduction of Cr(VI) in cationic micelle solution

  • Kyung, Hyunsook;Cho, Young-Jin;Choi, Wonyong
    • Rapid Communication in Photoscience
    • /
    • v.4 no.3
    • /
    • pp.73-75
    • /
    • 2015
  • Cr(VI) reduction was successfully achieved in the presence of cationic micelles (CMs) under visible light illumination. Micelle formation of cationic surfactants seems to be critical in Cr(VI) reduction. Cr(VI) was reduced very fast above the critical micelle concentration (cmc) of CTAB solutions, but was not reduced at all either below or around the cmc of CTAB. The reduction rate of Cr(VI) was enhanced in the absence of dissolved oxygen, supporting that the removal of Cr(VI) should be achieved via a reductive pathway. When CTAB was substituted by Brij 35 or SDS, the reduction of Cr(VI) was negligible. This indicates that the electrostatic interaction between Cr(VI) and headgroups of surfactants is important in the visible light-induced Cr(VI) reduction in micellar solutions.

Effects of the Surface Chemical Properties of Silica Sols on the Retention and Drainage of Microparticles Systems

  • Min, Choon-Ki
    • Journal of Korea Technical Association of The Pulp and Paper Industry
    • /
    • v.32 no.1
    • /
    • pp.26-32
    • /
    • 2000
  • The impact of major surface chemical properties of silica sols on the retention and drainage performance of the silica based micrparticle system, Compozil was investigated using four different silica sols. And the effect of silica properties on the interactions with cationic starch and cationic plyacrylamide has also been identified. The surface charge density and the stability over pH of silica sols were increased by introducing aluminosilicate anions at surface. It was found that the charge density of silica sols determined the addition level necessary to attain the maximum retention and drainage. When silica sols were combined with cationic starch, the change density of the product was the critical properties and the degree of microagregation was of minor importance. In the cationic polyacrylamide system the degree of colloid structure appeared to be a more critcial property than the charge density of silica sols.

  • PDF

DETERMINATION OF THE CATIONIC DEMAND OF PAPERMAKING STOCK USING CHROMOPHORIC LABELED CATIONIC POLYMERS

  • Hiroo Tanaka;Hideaki Ichiura;Takuya Kitaoka
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
    • /
    • 1999.11b
    • /
    • pp.79-83
    • /
    • 1999
  • A cationic demand(CD) is a very useful indication for determining the optimum dosage rate of retention aids to the papermaking stock at the wet end. Polyelectrolyte titration has been most often used to determine a CD. Highly accurate results can be obtained by this method when the ionic strength of sample is low. But this is accompanied by the serious errors when the ionic strength is higher than that corresponding to 20 milli molar(mM) monovalent, 2 mM divalent or 0.2 mM trivalent ions because of no occurrence of the end point of titration. Therefore, it is very difficult or almost impossible for the conventional method to be applied to the industrial suspensions such as papermaking stock and industrial waste water. Then a novel method using chromophoric labeled cationic polymer which can be applicable to the sample with high ionic strength has been developed.

Effects of Surface Charges on the Retention of Placenta-loaded Liposome Formulations Administered by Intramuscular Route

  • Noh, Sang-Myoung;Park, Da-Eui;Kim, Young-Bong;Oh, Yu-Kyoung
    • Journal of Pharmaceutical Investigation
    • /
    • v.39 no.5
    • /
    • pp.333-337
    • /
    • 2009
  • We aimed to optimize the formulation of porcine placental extract (PPE)-loaded liposomes for intramuscular administration and to investigate the effect of surface charges on the muscular retention in mice. PPE-loaded liposomes were formulated to have neutral, anionic, or cationic surface charges. The in vitro release profiles were studied by spectrofluorometry. In vivo distribution patterns at mice were studied using molecular imaging technology. Among the three types of liposomes, 1,2-dioleoyl-3-trimethylammonium-propane and 1,2-dioleoyl-sn-glycero-3-phosphoethanolamine-based cationic liposomes showed the most prolonged in vitro release profile. Consistent with the in vitro results, the in vivo distribution study revealed that the cationic liposomes were retained at the site of administration for the longest period. Our results suggest the potential of cationic PPE-loaded liposomes for sustained release of the components after intramuscular administration.