• Title/Summary/Keyword: cathod material

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Electrochemical properties of $Li_{2}O-P_{2}O_{5}-V_{2}O_{5}$ Glass by Heat-treatment (열처리 조건에 따른 $Li_{2}O-P_{2}O_{5}-V_{2}O_{5}$ 유리의 전기화학적 특성변화)

  • 김윤선;손명모;이헌수;구할본
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.733-736
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    • 2001
  • Instead of a solution technigue producing amorphous LiV$_3$O$_{8}$ form, we prepared Lithium vanadate glass by melting Li$_2$O-P$_2$O$_{5}$-V$_2$O$_{5}$, composition in pt. crucible and by quenching on the copper plate. From the crystallization of Li$_2$O-P$_2$O$_{5}$-V$_2$O$_{5}$, we could abtain crystal phase, LiV$_3$O$_{8}$. The material heat-treated at lower-temperature, 25$0^{\circ}C$ was less crystalline, but had higher capacity. In present paper, we describe eletrochemical properties during crystallization process and find the best crystallization condition of Li$_2$O-P$_2$O$_{5}$-V$_2$O$_{5}$ glass as cathod material.cathod material.

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Crystallization properties of $LiO_2-P_2O_5-Bi_2O_3-V_2O_5$ Glass for cathod material (정극 재료용 $LiO_2-P_2O_5-Bi_2O_3-V_2O_5$ 유리의 결정화 특성)

  • Son, Myung-Mo;Lee, Heon-Su;Gu, Hal-Bon;Jeong, In-Seong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.05b
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    • pp.311-315
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    • 2000
  • Vanadate glass in the $LiO_2-P_2O_5-Bi_2O_3-V_2O_5$ system containing 10mol% glass fonner, $P_2O_5$ and $Bi_2O_3$ was prepared by melting the batch in pt. crucible followed by Quenching on the copper plate. We found that $LiO_2-P_2O_5-Bi_2O_3-V_2O_5$ glass-ceramics obtained from nucleation of glass showed signifieantly higher capacity and longer cycle life than conventionally made crystalline $LiV_3O_{8}$. In the present paper, we describe the charge / discharge properties during crystallization process and find the best crystallization condition of $LiO_2-P_2O_5-Bi_2O_3-V_2O_5$ glass as cathod material.

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Crystallization and Electrochemical properties of $Li_{2}O=P_{2}O_{5}=V_{2}O_{5}$ Glasses ($Li_{2}O=P_{2}O_{5}=V_{2}O_{5}$ 유리의 결정화에 따른 전기 화학적 특성변화)

  • 손명모;이헌수;구할본;김상기
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.523-527
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    • 2000
  • Vanadate glasses in the Li$_2$O-P$_2$O$_{5}$-V$_2$O$_{5}$ system containing 10mo1% glass former, P$_2$O$_{5}$ were prepared by melting the batch in pt. crucib1e followed by quenching on the copper plate. We found that Li$_2$O-P$_2$O$_{5}$-V$_2$O$_{5}$ glass-ceramics obtained from nucleation of glass showed significantly higher capacity and longer cycle life than conventionally made crystalline LiCoO$_2$, LiNiO$_2$and LiV$_3$O$_{8}$. In the present paper, We describe electro-chemical properties during crystallization process and find the best crystallization condition of Li$_2$O-P$_2$O$_{5}$-V$_2$O$_{5}$ g1ass as cathod material. Li$_2$O-P$_2$O$_{5}$-V$_2$O$_{5}$ glass-ceramics shows superior rechargeable capacity of 220 mAh/g in the cycling between 2.0 and 3.9V.etween 2.0 and 3.9V.

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A Study on the Preparation and Characteristics of Polyaniline/Zn Battery (Polyaniline/Zn 전지의 제조 및 특성 연구)

  • 문성인;김인성;안병성;강동필;윤문수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1989.06a
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    • pp.26-28
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    • 1989
  • In this paper, The preparation and characteristics of polyaniline/Zn battery by (NH$_4$)$_2$S$_2$O$\sub$8/ and used as cathod active material to investigate the characteristics of polyaniline/Zn battery. Characteristics of polyaniline/Zn battery was affected of amounts of electrolytes and additives such as graphite and carbon black.

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Electro-chemical properties of $Li_{2}O=P_{2}O_{5}-V_{2}O_{5}$ Glass-ceramics for Cathode Materials (정극재료용 $Li_{2}O=P_{2}O_{5}-V_{2}O_{5}$ 계 결정화 유리의 전기화학적 특성)

  • 손명모;이헌수;구할본;김윤선
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.295-298
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    • 2000
  • Vanadate glasses in the Li$_2$O-P$_2$O$_{5}$-V$_2$O$_{5}$ system containing 10~20mo1% glass former, P$_2$O$_{5}$ were prepared by melting the batch in pt. crucible followed by quenching on the copper plate. We found that Li$_2$O-P$_2$O$_{5}$-V$_2$O$_{5}$ g1ass-ceramics obtained from crystallization of glass showed significantly higher capacity and longer cycle life than Li$_2$O-P$_2$O$_{5}$-V$_2$O$_{5}$ g1ass. In the present paper, we describe electro-chemical properties during crystallization process and find the best crystallization condition of Li$_2$O-P$_2$O$_{5}$-V$_2$O$_{5}$ g1ass as cathod material. Li$_2$O-P$_2$O$_{5}$-V$_2$O$_{5}$ glass-ceramics shows superior rechargeable capacity of 220 mAh/g in the cycling between 2.0 and 3.9V. between 2.0 and 3.9V.

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Electrochemical Characteristics of Expanded Graphite by Microwave Irradiation in Lithium Ion Battery (리튬 이온 커패시터에서 마이크로파 조사에 의한 팽창 흑연의 전기화학적 특성)

  • Seol, Sun-hwa;Park, Soo-gil;KIM, Han-Ju;Kim, Hong-il
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2014.11a
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    • pp.167-167
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    • 2014
  • Graphite is used as a negative electrode active material of Lithium ion capacitor (LIC). At the cathod, electrostatic reaction of EDLC is a very high reaction rate compared to a oxidaion reduction reaction. When the graphite was expanded that the length between the sheet, the intercalation of lithium ions is smoothed. And thus, the power density increases. By measuring the XRD, it was confirmed that the increase in interlayer spacing of graphite. And by measuring an electrochemical reactionin Lithium Ion Battery (LIB), it was confirmed the tendency of power density is improved.

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A Study of the High Sensitive Nonsilver Halide Imaging Material( II ) - Study of the aqueous coating mechanism and washing effect of the CGL in the $\varepsilon$-CuPc/PVK double-layered organic photoconductor - (고감도 비은염 화상재료 개발연구 ( II ) - Copper Phthalocyanine/PVK 전자사진감광체의 CGL의 수성 coating mechanism과 세정효과에 관한 연구 -)

  • 이상남
    • Journal of the Korean Graphic Arts Communication Society
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    • v.9 no.1
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    • pp.27-44
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    • 1991
  • In this research, double-layered photoconductor consist of the carrier generation layer(CGL) of ${\varepsilon}$ type copper phthalocyanine thin film by an aqueous coating method and the carrier transport layer(CGL) of polyvinyl carbazol(PVK) by spin coating. We inverstigated effect of the surfactant solution and cathod electrolysis to the crystal type of ${\varepsilon}$-CuPc in CGL with TEM, SEM and X-ray diffraction spectroscopy and studied the mechanism of an aqueous coating for the preparation of CGL. The effect of the washing of CGL about the electrophotographic characteristics of the ${\varepsilon}$-CUPC/PVK double-layered photoconductors is studied also.

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Synthesis of $LiMn_2O_4$ Cathode Materials by Emulsion Method and Its Electrochemical Properties

  • Youn Kyu Choi;Bok Hee Kim
    • The Korean Journal of Ceramics
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    • v.5 no.3
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    • pp.250-254
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    • 1999
  • Synthesis of the spinel $LiMn_2O_4$ by emulsion method was investigated. $LiOH.H_2O \;and \;Mn(NO_3)_2.6H_2O$ were used as starting materials to prepare mixed aqueous solution (0.5 mol/$\ell$ for the $LiMn_2O_4$). Kerosene, paraffin oil and span 80 were used for organic phase. The aqueous solutioin and organic phase were mixed in the ratio of 2:1 and emulsified at the speed of 4000 rpm for 5 min. The prepared emulsions were dropped into the petroleum heated at $170^{\circ}C$ to evaporate water in the silicon oil bath, dried at $120^{\circ}C$ in the oven the remove petroleum and calcined at temperature ranges from 600 to $900^{\circ}C$ for 48 hrs. The characteristics of powders were investigated by XRD, SEM, BET and electrochemical properties of synthesized cathode materials were measured with Galvanostatic system. $Li_{1.05}Mn_2O_4$ calcined at $800^{\circ}C$ for 48 hrs showed initial discharge capacity of 125.9mAH/g.

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The effects of short persistent CCFL in Blinking Back Light Unit to reduce blur on TFT-LCD (단잔광특성의 CCFL을 사용한 Blinking Back Light의 구현과 화질 평가)

  • Park, Jeong-Kuk;Han, Jeong-Min;Bae, Kyung-Woon;Kim, Seo-Yoon;Kim, Yun-Ho;Lim, Young-Jin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.04a
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    • pp.160-164
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    • 2003
  • LCD를 TV 향으로 적용하기 위해서는 몇 가지 해결해야만 하는 문제가 있으며, 이중 하나가 동화상 재생시에 발생하는 잔상현상의 해결이다. LCD는 기존의 CRT와 같은 불연속 자발광 소자가 아니라, 연속수광소자로서, 잔상현상이 치명적인 약점으로 나타난다. 기종의 Monitor 대응품에서는 실제로 Monitor를 통해서 사용자가 관찰하는 이미지 정보가 정지화상 중심으로 구성되어 있기 때문에 문제가 되지 않았으나, TV의 경우 연속적인 동화상만을 취급하고 있어, 잔상현상의 해결 없이는 TV 향 제품에 적용할 수 없다. 따라서 본 연구에서는 잔상현상을 근본적으로 없애기 위해서 LCD를 CRT와 같이 불연속적의 분절적 이미지로 구동하는 방법을 실험하였으며, VIDEO 입력 신호에 대해서 16.7msec의 1Frame을 기준으로 점등 구간과 비점등 구간을 6:4로 나누어 BL(Back Light)을 점멸하는 방법을 구현하였다. 또한 종래의 CCFL(cold Cathod Flourescent Lamp)로는 점멸 속도에 대한 대응이 불가하므로, 이를 해결하기 위해서 광원의 형광체에 대해서 잔광시간특성의 개선도 동시에 실시하였다. 실험 결과 육안 및 사진촬영에서 잔상없는 화면을 얻을 수 있었으며, 응답파형 측정 결과 CRT 측정시와 마찬가지로 분절적인 이미지의 생성이 가능한 것을 알 수 있었다.

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A Study on the Improvement of the Electron Transport Properties in $SF_{6+}Ar$ Mixtures Gas ($SF_{6+}Ar$혼합기체의 전자수송특성 개선에 관한 연구)

  • 하성철;김상남;유회영;서상현;임상원;전병훈
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.1
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    • pp.67-73
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    • 1998
  • In this paper, the electron swarm parameters in the 0.5% and 0.2% SF\ulcorner+Ar mixtures are measured by time of flight method over the E/N(Td) range from 30 to 300(Td). The measurements have been carried out by the double shutter drift tube with variable drift distance from the cathod. A two-term approximation of the boltzmann equation analysis and Monte Carlo simulation have been also used to study electron transport coefficients. We have calculated W, $ND_L,\;ND_T,\;\alpha,\;\eta,\;\alpha-\eta$, and the limiting breakdown electric field to gas mixtures ratio in pure $SF_6$+Ar mixtures. The electron energy distribution function has been analysed in $SF_6$+Ar mixtures at E/N : 200(Td) for a case of the equilibrium region in the mean electron energy. The measured results and the calculated results have been compared each other.

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