• 한국자동차공학회논문집
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• 제10권1호
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• pp.45-50
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• 2002

Use of a phenomenological model, developed far prediction of catalytic deactivation, is demonstrated in comparing harshness of different driving cycles that are currently used to rapidly age catalytic converters on engine test benches. The model shows that seemingly equivalent driving cycles cause the catalytic converters to reach significantly different levels of deactivation. The comparison of the model prediction with the limited vehicle data seems encouraging despite the simplicity of the model at the current stage of its infancy.

• 대한기계학회논문집B
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• 제31권4호
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• pp.376-383
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• 2007

This research represents the catalytic converter for application in the motorcycle. We have to consider about catalytic converter for reducing exhaust gas strength regarding the displacement volume enlargement. The catalytic converter has been widely used to satisfy the regulations of pollutant emissions from automobiles. Recently, all catalytic converter researches are about automobile. Study about motorcycle catalytic converter has not been conducted yet. In this study, flow uniformity and pressure distribution were simulated in the monolithic inlet of catalytic converter for motorcycle. Exhaust pulsation pressure was set as transient condition about. It was found that flow uniformity shown in base model (0.85) was lower than megaphone model (0.98).

• 한국자동차공학회논문집
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• 제14권5호
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• pp.138-144
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• 2006

This research represents the catalytic converter for application in the motorcycle. Present research model type is a monolithic catalytic converter and this type has been widely used for satisfaction on and the regulations of pollutant emissions in automobiles. The experiment range is found for light-off temperature time of the catalyst converter. And we has to experiment for effective area of catalytic monolith. The experimental result indicated an increase effective area in the catalytic monolith. Specialty, it was found from the result that the more positive effect from result of thermal image camera in the megaphone model. The rate of effective area for base model was about 8.97% and megaphone model was 41.52%, 34.60%, 33.43%, 25.43% and 17.82% on the diffuser angle $4^{\circ}$ to $8^{\circ}$. Comparing with base type, megaphone type has more suitable for application to motorcycle.

• 대한기계학회논문집B
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• 제31권6호
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• pp.507-513
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• 2007

This study represents the temperature uniformity in catalytic converter. Present research model type is a monolithic catalytic converter. This type was been widely used for complying the regulations of pollutant emissions from automobiles. The mean experimental parameters are engine speed and ceramics monolith in the catalytic converter. The experimental test engine model used was the 124.1cc motorcycle engine. The experimental study using thermal imaging method shows the megaphone type model has larger effective area than the basic model. The rate of effective area in the basic model is about 8.9 % and the megaphone type model are 41.52 %, 34.60 %, 33.43 %, 25.43 %, 17.82 % according to the diffuser angle $4^{\circ}\;to\;8^{\circ}$. In conclusion, the megaphone type monolithic converter has higher efficiency of reducing the pollution with less noise compared to the basic shape. We believe this will be very important as a design guide of the advanced motorcycle.

• International Journal of Fluid Machinery and Systems
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• 제5권3호
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• pp.134-142
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• 2012

The competition to deliver ultra-low emitting vehicles at a reasonable cost is driving the automotive industry to invest significant manpower and test laboratory resources in the design optimization of increasingly complex exhaust after-treatment systems. Optimization can no longer be based on traditional approaches, which are intensive in hardware use and laboratory testing. The CFD is in high demand for the analysis and design in order to reduce developing cost and time consuming in experiments. This paper describes the development of a comprehensive practical model based on experiments for simulating the performance of automotive three-way catalytic converters, which are employed to reduce engine exhaust emissions. An experiment is conducted to measure species concentrations before and after catalytic converter for different loads on engine. The model simulates the emission system behavior by using an exhaust system heat conservation and catalyst chemical kinetic sub-model. CFD simulation is used to study the performance of automotive catalytic converter. The substrate is modeled as a porous media in FLUENT and the standard k-e model is used for turbulence. The flow pattern is changed from axial to radial by changing the substrate model inside the catalytic converter and the flow distribution and the conversion efficiency of CO, HC and NOx are achieved first, and the predictions are in good agreement with the experimental measurements. It is found that the conversion from axial to radial flow makes the catalytic converter more efficient. These studies help to understand better the performance of the catalytic converter in order to optimize the converter design.

• 한국자동차공학회논문집
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• 제15권4호
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• pp.108-114
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• 2007

This research represents the catalytic converter for application in the motorcycle. We have to consider about catalytic converter for reducing exhaust gas strength regarding the displacement volume enlargement. The catalytic converter has been widely used to satisfy the regulations of pollutant emissions from automobiles. Recently, all catalytic converter researches are about automobile. Study about motorcycle catalytic converter has not been conducted yet. In this study, flow uniformity and pressure distribution were simulated in the monolithic inlet of catalytic converter for motorcycle. Exhaust pulsation pressure was set as transient condition about. It was found that flow uniformity shown in base model (0.85) was lower than megaphone model (0.98).

• 한국자동차공학회논문집
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• 제7권5호
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• pp.107-120
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• 1999

Catalytic converters are the most fascinating and complicated chemical reactors. They are most often operated in the transient state with respect to composition, flow rate, temperature, etc. The mathermatical model developed in this work accounts for simultaneous heat and mass transfer, chemical reaction, and multi dimensional flow characteristics to analyze the light-off performance of monolithic catalytic converter with comparable mass flow rate. To validate the mathematical model, comparison between experimental and numerical results has been performed. The numerical results show a good agreement with experimental data. It is forund that inflow rate shows major effect on the characteristics of termal response of catalytic converter.

• 한국연소학회지
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• 제19권4호
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• pp.49-55
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• 2014

Design criterion for the size of micro Pt-catalytic combustor is investigated in terms of heat release rate. One-dimensional plug flow model is applied to determine the surface reaction constants using the experimental data at stoichiometric butane-air mixture. With these reaction constants, the mass fraction of butane and heat release rate predicted by the plug flow model are in good agreement with the experimental data at the combustor exit. The relationship between the size of micro catalytic combustor and mixture flowrate is introduced in the form of product of two terms-the effect of fuel conversion efficiency, and the effect of chemical reaction rate and mass transfer rate.

• 한국생물공학회:학술대회논문집
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• 한국생물공학회 2000년도 추계학술발표대회 및 bio-venture fair
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• pp.571-574
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• 2000

Hydrolase는 생물학적 공정에서 가장 널리 사용되는 효소군 중의 하나이다. 본 연구에서는 hydrolase들 중에 xylanase, lysozyme, glucoamylase, barnase가 대상 hydrolase로 선택하여 최적 pH를 예측하는 방법론을 제시하였다. Tanford-Kirkwood(TK) model에 기반을 두고 선택된 효소들의 catalytic residue들의 전하 변화가 optimum pH에 중요한 인자로서 그 catalytic residue들의 전하 차이가 최대일 때의 pH가 optimum pH로 나타났다. 이렇게 예측된 optimum pH 결과들은 실험적으로 결정된 optimum pH와 서로 잘 일치하고 있음을 보여준다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2009년도 제38회 동계학술대회 초록집
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• pp.35-35
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• 2010

Understanding the mechanistic details of heterogeneous catalytic reactions will provide a way to tune the selectivity between various competing reaction channels. In this regard, catalytic decomposition of alcohols over the rutile $TiO_2$(110) surface as a model oxide catalyst has been studied to understand the reaction mechanism employing the temperature-programmed desorption (TPD) technique. The $TiO_2$(110) model catalyst is found to be active toward alcohol dehydration. We find that the active sites are bridge-bonded oxygen vacancies where RO-H heterolytically dissociates and binds to the vacancy to produce alkoxy (RO-) and hydroxyl (HO-). Two protons adsorbed onto the bridge-bonded oxygen atoms (-OH) readily react with each other to form a water molecule at ~500 K and desorb from the surface. The alkoxy (RO-) undergoes decomposition at higher temperatures into the corresponding alkene. Here, the overall desorption kinetics is limited by a first-order decomposition of intermediate alkoxy (RO-) species bound to the vacancy. We show that detailed analysis on the yield and the desorption temperatures as a function of the alkyl substituents provides valuable insights into the reaction mechanism. After the catalytic role of the oxygen vacancies has been established, we employed x-ray photoelectron spectroscopy to further study the surface electronic structure related to the catalytically active defective sites. The defect-related state in valence band has been related to the chemically reduced $Ti^{3+}$ defects near the surface region and are found to be closely related to the catalytic activity of the $TiO_2$(110) surface.