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Microstructural Characteristics of Oxidation Resistant Cr-Si-Al alloys in Cast State and after High Temperature Heating (내산화성 Cr-Si-Al합금의 주조상태 및 고온가열 후의 미세조직 특성)

  • Kim, Jeong-Min;Kim, Chae-Young;Yang, Won-Chul;Park, Joon-Sik
    • Korean Journal of Materials Research
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    • v.31 no.3
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    • pp.156-161
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    • 2021
  • Cr-Si based alloys are not only excellent in corrosion resistance at high temperatures, but also have good wear resistance due to the formation of Cr3Si phase, therefore they are promising as metallic coating materials. Aluminum is often added to Cr-Si alloys to improve the oxidation resistance through which stable alumina surface film is formed. On the other hand, due to the addition of aluminum, various Al-containing phases may be formed and may negatively affect the heat resistance of the Cr-Si-Al alloys, so detailed investigation is required. In this study, two Cr-Si-Al alloys (high-Si & high-Al) were prepared in the form of cast ingots through a vacuum arc melting process and the microstructural changes after high temperature heating process were investigated. In the case of the cast high-Si alloy, a considerable amount of Cr3Si phase was formed, and its hardness was significantly higher than that of the cast high-Al alloy. Also, Al-rich phases (with the high Al/Cr ratio) were not found much compared to the high-Al alloy. Meanwhile, it was observed that the amount of the Al-rich phases reduced by the annealing heat treatment for both alloys. In the case of the high temperature heating at 1,400 ℃, no significant microstructural change was observed in the high Si alloy, but a little more coarse and segregated AlCr phases were found in the high Al alloy compared to the cast state.

Structural safety evaluation of decrepit gray cast iron water valves for the control of water supply (노후 회주철 수도용 제수밸브의 구조적 안전성 평가)

  • Lee, Ho-Min;Choi, Tae-Ho;Park, Jeong-Joo;Bae, Cheol-Ho
    • Journal of Korean Society of Water and Wastewater
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    • v.36 no.5
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    • pp.261-273
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    • 2022
  • In this study, we collect water control valves that have had accidents due to existing cracks, etc. are collected, and propose investigation items for strengthening the valve structural safety evaluation through a series of analyzes from valve specifications to physicochemical properties are proposed. The results of this study are as follows. First, there was a large variation in the thickness of the body or flange of the valves to be investigated, which is considered to be very important factor, because it may affect the safety of the valve body against internal pressure and the flange connected with the bolt nut. Second, 60% of the valves under investigation had many voids in the valve body and flange, etc. and the decrease in thickness due to corrosion was relatively large on the inner surface in contact with water rather than the outer surface. It is judged that the investigation of depth included voids is very important factor. Third, all valves to be investigated are made of gray cast iron foam, and therefore it is judged that there is no major problem in chemical composition. It is judged that the chemical composition should be investigated. Fourth, as a physical investigation item, the analysis of metal morphology structure seems to be a very important factor for nodular cast iron from rather than a gray cast iron foam water valve with a flake structure. As it was found to be 46.7~68.8% of the standard recommended by KS, it could have a direct effect on damage such as cracks, and therefore it is judged that the evaluation of tensile strength is very important in evaluating the safety of the valve.

Development of Glass Fiber Composite Material to Extend the Life of Fly Ash Transport Pipe: Wear Test (비회 운송관의 수명연장을 위한 유리섬유 복합재의 개발: 내마모성 평가)

  • Jeong, Gyu-Sang;Chang, Yoon-Sang
    • Clean Technology
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    • v.15 no.1
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    • pp.16-22
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    • 2009
  • In this study, a fiber reinforced plastic (FRP) pipe with superior wear resistance was developed to replace the fly ash pipe of cast iron. Wear test was performed with various combinations of SiC filler and resin materials of unsaturated polyester, vinylester, epoxy, and phenol. Test results of ASTM D4060 showed the optimal combinations of resin, filler size, and resin/filler ratios. Test results of comparison between FRP and cast iron showed the possibility to replace cast iron pipe with the FRP pipe. Field test executed to compare the wear resistance between cast iron pipe and developed FRP pipe showed the superiority of the FRP pipe.

Structural Support of Aluminum Honeycomb on Cast PBX (알루미늄 허니컴(HC) 구조재 적용 주조형 복합화약)

  • Seonghan Kim;Keundeuk Lee;Haneul Park;Mingu Han
    • Journal of the Korea Institute of Military Science and Technology
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    • v.27 no.2
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    • pp.222-229
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    • 2024
  • As the operating condition for the penetrating missile has been more advanced, the survivability of main charge has been strongly required when the warhead impacts the target. Lots of efforts to desensitize explosives such as the development of insensitive molecular explosives or optimizing plastic-bonded explosives(PBX) systems has been made to enhance the survivability of main charge. However, these efforts face their limits as the weapon system require higher performance. Herein, we suggest a new strategy to secure the survivability of main charge. We applied structurally supportable aluminum honeycomb(HC) structure to cast PBX. The aluminum HC structure reinforces the mechanical strength of cast PBX and helps it to withstand external pressure without the reaction like detonation. In this study, impact resistance character, shock sensitivity and internal blast performance of PBXs reinforced with HC structure were investigated according to the application of aluminum HC structure. The newly suggested aluminum HC structure applied to cast PBX was proved to be a promising manufacturing method available for high-tech weapon systems.

Effects of Ni and Si on the Matrix Structure and Graphite Formation in Fe-12Mn-3.5C Alloy (Fe-12Mn-3.5C 계주철(系鑄鐵)에서 기지조직(基地組織)과 흑연석출(黑鉛析出)에 미치는 Ni 및 Si 의 영향)

  • Ra, Hyong-Yong;Son, Won-Tak
    • Journal of Korea Foundry Society
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    • v.3 no.3
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    • pp.174-180
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    • 1983
  • The matrix changes and graphite formation in high manganese cast iron (Fe-12Mn-3.5C) are studied with increasing nickel and silicon content. Also, the decomposition of carbides and graphite precipitation are studied by adequate heat treatment.The results obtained in this work are as follows. 1. In high manganese cast iron, fine flakes graphite appeared by adding 5 wt% nickel and A-type flakes graphite can be obtained by adding 7 wt% nickel. 2. Nodular graphite are obtained by graphite spheroidizing treatment with same melt. 3. In high manganese cast iron containing 7 wt% nickel, full austenitic matrix with nodular graphite can be achieved by water quenching after 10 hours' solution heat treatment at $1050^{\circ}C$ in case of containing 2.0 wt% silicon, and 6 hours' at the same temperature in case of containing 2.5 wt% silicon.

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(${\lceil}$Effects of Ni addition on the Structure and Strength of gray cast iron containing aluminium${\rfloor}$ (("저(低)알루미늄 합금주철(合金鑄鐵)의 응고조직(凝固組織)과 기계적(機械的) 성질(性質)에 미치는 니켈의 영향(影響)")

  • Kang, Nak-Won;Kang, In-Chan
    • Journal of Korea Foundry Society
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    • v.7 no.4
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    • pp.352-357
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    • 1987
  • Recently there were many studies on the development of cast iron for increasing strength, thermal resistance and mechanical properties, etc. The effects on mechanical properties and variation of solidification structure of hypo-eutectic cast iron was investigated when Ni(Al) was added with a fixed quantity of Al(Ni) content. The conclusions are as follows. 1) Tensile strength was the maximum(over 41 kg/ $mm^2$) when Al is added about 0.72%. 2) Torsional strength and angle were increased with increasing Al content and represents maximum value, when Al and Ni content are 1.5 and 2.0%. 3) With increasing Ni content, tensile strength decreased because of the effect of graphite coarsening. But torsional strengths were increased with the appropriate addition of (Ni%+Al%) content because of the effect of strengthened matrix.

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The Study on the Wear-Corrosion Behavior of Ductile Cast Iron in the Acidic Environment (산성환경 중에서 구상흑연주철재의 마멸-부식거동에 관한 연구)

  • 임우조;박동기
    • Tribology and Lubricants
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    • v.18 no.4
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    • pp.299-304
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    • 2002
  • This paper reports the studies on the wear-corrosion behavior of ductile cast iron in the acidic environment. In atmosphere and variety of pH solution, specific wear rate and wear-corrosion characteristics of GCD 60 with various sliding speed and distance were investigated. And electrochemical polarization test of GCD 60 was examined in the environment of various pH values. The main results are as following : As the contact pressure increases, the critical velocity of specific wear rate becomes transient at low sliding speed. As pH value becomes low, wear-corrosion loss increases in the aqueous solution. As the corrosion environment is acidified, corrosion potential of GCD 60 becomes noble and corrosion current density increases.

A STUDY ON WEAR BEHAVIORS OF CAM SPINDLES MANUFACTURED FROM CK 45 STEEL AND CAM SPINDLES MANUFACTURED FROM GGG-50 SPHERICAL GRAPHITE CAST IRON AND BORONED

  • Sert, H.;Selcuk, B.;Toprak, H.;Samtas, G.
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2002.10b
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    • pp.325-329
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    • 2002
  • This study targets mainly to reduce the manufacturing costs of cam spindles and manufacturing of mechanical components with longer service durations through application of surface engineering techniques on cam spindles. Within the frame of this study, we have attempted to establish the performances of cam spindles manufacture from forged steel and SGCI, through performance of wear tests in plate-disk system, metalographic investigations, SEM imaging, EDS analyses and micro hardness scans on test samples having the same sizes with original cam that once obtained from casting of Spherical Graphite Cast Iron (SGCI) are subjected partially to Boronising and partially to hardening in a salt solution and cam spindles currently manufactured from CK 45 through cauterization based reshaping.

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The Effect on the Wear-Corrosion Behavior of Ductile Cast Iron in the Various pH Environments (구상흑연주철재의 마멸-부식특성에 미치는 pH의 영향)

  • 임우조;박동기
    • Tribology and Lubricants
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    • v.19 no.1
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    • pp.31-35
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    • 2003
  • This paper reports the studies on the wear-corrosion behavior of ductile cast iron in the various pH environments. In the variety of pH solutions, corrosion and wear-corrosion loss of GCD 600 were investigated. Also, the anodic polarization test of GCD 600 using potentiostat/galvanostat was carried out. And rubbed surface of GCD 60 using scanning electron micrographs after immersion and wear-corrosion test was examined in the environment of various pH values. The main results are as following In alkali zone, the wear-corrosion loss of GCD 600 increases, but corrosion loss decreases. The unevenness and crack of wear-corrosion surface in neutral zone becomes duller than that in alkali zone. As the corrosive environment is acidified, wear-corrosion behavior of GCD 600 with passing immersion time becomes sensitive.

Effects of Mo on the Mechanical Properties of Ductile Cast Iron with Cu Austempered at 380℃ (Cu가 함유된 구상흑연주철의 380℃에서 오스템퍼링 시 Mo이 기계적 특성에 미치는 영향)

  • Kim, G.Y.
    • Journal of the Korean Society for Heat Treatment
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    • v.26 no.5
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    • pp.219-224
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    • 2013
  • In this study, we investigated effect of Mo addition on mechanical properties of Cu added ADI. Ductile cast iron specimens were austenitized at $900^{\circ}C$ for 150 min and then austempered at $380^{\circ}C$ for the various time periods from 15 min to 480 min. Mo added ADI had a higher volume fraction of retained austenite, and the volume fraction of retained austenite was determined by XRD analysis. As decreasing volume fraction of retained austenite, the elongation was also decreased as expected. But the UTS and yield strength were not decreased.